中国钴着色材料的分类和来源

中国历史上的钴显色材料有颜料、玻璃、陶瓷釉。花绀青、钴蓝属历史颜料;钴显色蓝色玻璃可能始于西汉;钴显色蓝色陶瓷釉始于战国陶胎釉珠,唐朝唐三彩陶瓷釉发展成多个品种。钴显色材料有国产钴土矿类和进口Smalt类。原料矿中带入的锰、铁、镍、砷、铋等杂质对色彩有一定影响。     

Portuguese Blue‐on‐Blue 16th–17th Century Pottery

Blue‐on‐blue (‘berettino’) sherds have appeared in numerous production and consumption archaeological excavations in Lisbon and other archaeological sites in Portugal (dated from the mid‐16th century to the beginning of the 17th century). The abundance of this interesting faience led us to compare it with similar pottery from other well‐known production centres in Italy, namely Liguria (Savona and Albisola), Spain (the Triana kilns) and the Low Countries. Differences in the diffraction patterns of the sherds' pastes from the four countries were observed. In most samples, cobalt blue silicate (cobalt olivine) was identified in the dark blue or light blue glazes through the use of micro‐Raman spectroscopy and diffuse reflectance spectra. A remarkable difference in the calcite contents of the Lisbon and Seville pottery sherds was observed, in accordance with previous observations of high calcite contents of Seville ceramics. A comparison was also made for all of the blue‐on‐blue sherds studied here with many other 16th–17th century sherds from Lisbon using bivariate plots of K/Si versus Ca/Si. Lisbon and Seville pottery behave very differently, whereas sherds from Italy and the Low Countries occupy intermediate positions.     

THE DISCOVERY OF ANOMALOUSLY HIGH SILVER ABUNDANCES IN POTTERY FROM EARLY ROMAN EXCAVATION CONTEXTS IN JERUSALEM*

This is the first study on the differential distribution and concentrations of silver in ceramics recovered from archaeological excavations. The chemical compositions of 1174 pottery vessels from 38 Roman‐period sites in Israel have been determined. Unusually high and variable abundances of silver were discovered in pottery samples of all vessel types and chemical compositions from four distinct archaeological contexts dating to late first century bce to 70 ce Jerusalem. The large majority of the Jerusalem vessels could be distinguished by their silver abundances from all analysed pottery pieces recovered at rural sites outside Jerusalem, even when the pottery types and chemical compositions, except for silver, of pottery found within and outside Jerusalem were indistinguishable. The evidence is suggestive of a human origin for the high and variable silver abundances, and dispersion of the silver by aqueous transport. The differential silver concentrations found in excavated pottery from Jerusalem and other urban and rural sites suggest that attention to the distribution of silver in pottery from excavated contexts may be helpful for evaluating the nature and function of archaeological remains and patterns of urban contamination.     

CYPRIOT BYZANTINE GLAZED POTTERY: A STUDY OF THE PAPHOS WORKSHOPS

Twenty‐five samples of Byzantine glazed pottery from two archaeological sites between Limassol and Paphos region (Cyprus), dated between the 12th and 15th century ad were studied using micro X‐ray fluorescence spectroscopy, scanning electron microscopy and X‐ray diffraction analysis. It was found that all the glazes contain lead, following the main manufacturing process of medieval pottery in the Mediterranean territory, while some of them contain tin, possibly for better opacity. Furthermore, it is shown that copper, iron and cobalt with nickel are responsible for the decoration colours. Finally, the application of principal component analysis revealed significant differentiation for some of the samples.     

LAST ORDERS: CHOOSING POTTERY FOR FUNERALS IN ROMAN ESSEX

Summary.   This paper examines ceramic vessels from Roman-period funerary contexts in Essex. Using correspondence analysis, it charts changes in the choice of funerary pottery and isolates the elements in pottery assemblages that unite or differentiate sites. The paper finds that the status of sites can be distinguished on ceramic grounds, reflecting cultural differences in life. Jars and beakers are characteristic of settlement cemeteries, while cups are more typical of high-status burials. Flagons and samian ware are common between them. Underlying funerary traditions are rooted in continuity from the Late Iron Age, rather than post-conquest change. The study also suggests that funerary pottery was selected out of the supply intended for domestic use.     

潮湿彩绘陶加固材料对比研究及应用

针对考古出土的彩绘陶存在脆弱易毁、难以保存的问题,选择明胶和水性氟碳作为潮湿彩绘陶片的加固材料,采用不同浓度的加固材料对4种颜色彩绘陶片进行加固,并对加固前后的强度、色差以及光泽度进行检测和对比,结果表明较为理想的浓度选择为明胶在1%左右,水性氟碳浓度在20%左右。同时,对有底层和无底层两种类型的彩绘陶片进行加固对比实验,发现经明胶加固及老化后,有底层试样的色差和光泽度变化比无底层试样小;经水性氟碳加固后,有底层试样的色差和光泽度变化比无底层试样小,但老化后,则相反。在实践应用时,选用这两种材料对盱眙出土的一组潮湿彩绘陶进行了抢救性加固保护,都取得理想的效果。     

PETROGRAPHIC AND GEOCHEMICAL EVIDENCE FOR LONG‐STANDING SUPPLY OF RAW MATERIALS IN NEOLITHIC POTTERY (MENDANDIA SITE,SPAIN)

Pottery from the Neolithic Mendandia site has been studied. The radiocarbon dating of the site corresponds to a range of dates from 7488–7546 cal bc to 5283–5437 cal bc : the first occurrence of pottery is dated at 5968–6040 cal bc for the lower level III, and up to 5386–5560 cal bc for level II. The antiquity of the potsherds places them within the oldest pottery production sequences in the Iberian Peninsula, which adds to the interest of this study. Ten potsherds from level II and five from level III are analysed for their petrographic and chemical characterization. The petrographic data show two different methods of raw materials manufacture—intentionally tempered pottery (ITP), using calcite and/or limestone and grog, and naturally or non‐intentionally tempered pottery (NTP). According to the matrix paste features, on the basis of the amount, shape, and average or size range of the mineral inclusions, clayed (type A) and sandy (type B) paste types were established and related to two different source areas. The chemical features also indicate two raw material sources and are in agreement with the petrographic paste types. The absence of significant chemical and mineralogical differences between the pottery from levels II and III suggests two contrasting areas for raw materials supply that lasted for at least 600 years.     

Implications of burial alterations on luminescence dating of archaeological ceramics

Recent mineralogical studies on archaeological pottery samples report significant variations in alkali metal concentrations due to environmental alterations during burial. Here we examine the effects of potassium (K) leaching on luminescence dating. The effect on the estimation of the dose rate is studied by considering four models of leaching (exponential, linear, early and late) and their impact on fine- and coarse-grain dating are calculated. The modeling approaches are applied to two cases of pottery in which evidence for alteration was found. Additionally, TL dating performed on pottery of one of the studied cases, indicates the importance of leaching effects on absolute dating measurements.     

NEW EVIDENCE FOR APULIAN RED‐FIGURE PRODUCTION CENTRES

A total of 52 South Italian red‐figure vases were subjected to neutron activation analysis. The primary aim of the study was to determine whether all Apulian red‐figure pottery datable to the period c. 430–340 bc was produced at the Greek colony of Taras, as has been widely assumed. Three chemically distinct compositional groups were isolated and compared to archaeological reference material from Taranto. The results of this comparison suggest that some Early Apulian red‐figure pottery may have been produced outside of Taras from the fifth century bc onwards.     

LEAD ISOTOPIC ANALYSIS FOR THE IDENTIFICATION OF LATE BRONZE AGE POTTERY FROM HALA SULTAN TEKKE (CYPRUS)

Lead isotopic compositions were measured for 65 sherds from five pottery wares (Plain White, Coarse, Canaanite, White Slip and Base‐ring) excavated from the Late Bronze Age site of Hala Sultan Tekke (Cyprus). The elemental composition and isotopic signature of the sherds were compared with those of 65 clay samples collected in south‐east Cyprus, mainly in the surroundings (<20 km) of Hala Sultan Tekke. This work shows the effectiveness of using lead isotopic analysis in provenance studies, along with other analytical techniques, such as X‐ray diffraction (XRD) and a scanning electron microscope (SEM) equipped with an energy dispersive X‐ray detection (EDX) facility, to identify the composition of pottery wares and the clay sources used for pottery ware production.     

THE HISTORY OF THE LAWRENCE BERKELEY NATIONAL LABORATORY INSTRUMENTAL NEUTRON ACTIVATION ANALYSIS PROGRAMME FOR ARCHAEOLOGICAL AND GEOLOGICAL MATERIALS

The Lawrence Berkeley National Laboratory pottery provenance group developed standards and instrumental neutron activation analysis (INAA) methods that are used at many archaeometry laboratories around the world. The background and development of ‘Standard Pottery’ and of methods for INAA are described. Early pottery provenance studies are described, and other research programmes, involving obsidian and magmatic mixing, the origin of the stone used for the Colossi of Memnon, and the ‘Plate of Brass’, are mentioned. Research work by the Laboratory included the discovery of the world‐wide iridium anomaly and extensive subsequent research on what has come to be known as the ‘Asteroid Impact Theory’. Characteristics of the analytical programme for pottery provenance work, including overall aims, precision and accuracy, intercalibration, and irradiation and measurement protocols, are discussed. New research areas developed in the past 15 years, to broaden the usefulness of chemical compositional data for archaeological investigation, and examples of recent work, are described. This research, which makes use of high‐precision X‐ray fluorescence analysis in addition to INAA measurements on sample splits, includes distinguishing the products of different workshops located at the same production site, studies on the significance of the distribution of silver in archaeological pottery and the use of high‐precision chemical compositional data as an aid for making chronological distinctions.     

PASTE CHARACTERIZATION OF WEEDEN ISLAND POTTERY FROM KOLOMOKI AND ITS IMPLICATIONS FOR SPECIALIZED PRODUCTION

Abstract

We report the results of a petrographic analysis of pottery from Kolomoki, a Middle and Late Woodland period mound and village complex in southwestern Georgia. Thin sections of 65 sherds representing several prestige and utilitarian Weeden Island pottery types, from both domestic (midden) and ceremonial (mound) contexts, were obtained. For comparison, we also analyzed samples from a few potential clay sources. We characterize the range of variability in paste/resource groupings present in the Kolomoki assemblage and use these data to address patterns of manufacture and exchange of Weeden Island pottery through comparisons to thin sections of comparable types from the McKeithen site and other Weeden Island sites in the region.     

Archaeological Quantification of Pottery: The Rims Count Adjusted using the Modulus of Rupture (MR)

Archaeological quantification is a recurrent issue in research about pottery, its typologies and its distribution. We accept the validity of other methods of quantification—sherd count, minimum number of individuals (MNI) or sherd weight—but the methodology that we have proposed for quantification of assemblages of archaeological contexts is the rims count, which has to be transformed into coefficients of reference through a correction using the modulus of rupture (MR). Such correctors are obtained through measuring the percentage of preserved rim of a significant number of sherds of each type and establishing the average of that percentage. This quantification method is easily applicable to all pottery types and it is also statistically reliable. Besides, it can be used in any study in which the gross number of rims is published. Finally, in the case of ceramic transport containers, a second correction can be applied by multiplying the corrected coefficient (number of rims × MR) by its average capacity (AC), another corrector that will allow us to gather statistics according to the litres of transported product. We believe that the rims count (the easiest part to classify) is a fast, relatively easy and very reliable method that needs to be corrected using the MR.     

CLAY RESOURCES AND TECHNICAL CHOICES FOR NEOLITHIC POTTERY (CHALAIN,JURA, FRANCE): CHEMICAL,MINERALOGICAL AND GRAIN‐SIZE ANALYSES*

Many authors have considered pottery manufacturing constraints and sociocultural elements as factors in change in past civilizations over time. The main issue of this research is to better understand the reasons for changes, or choices, in pottery raw materials. The very precise and detailed stratigraphy and cultural succession of occupations is based on dendrochronological data from the lake‐dwelling sites of Chalain (Jura, France). Petrographic, palaeontological and chemical analyses were used to determine the nature and origins of the raw materials used by the Neolithic potters. Stratigraphy and dendrochronological data were used to reconstruct in detail the evolution dynamics of fabric changes. Several raw material sources were identified for many of the pottery groups. Each of them was sampled for qualitative experimental tests of pottery forming. The experimental results show a high variability between the sediments tested. This variability was quantitatively estimated by XRF, XRD, the Rietveld method, calcium carbonate quantification and laser grain‐size analyses of matrices, indirect measures of plasticity. These analytical results allow a better understanding of the differences observed in the experimental tests. On the basis of these experimental and analytical results, changing parameters such as pottery manufacturing constraints, mineralogical characteristics of raw materials and sociocultural factors are considered. In conclusion, all the social and technical parameters, in each archaeological context, must be taken into account for a better understanding of the changes occurring throughout the chronological sequence.     

LOCAL POTTERY PROVENIENCE STUDIES: A ROLE FOR CLAY ANALYSIS

This article deals with a problem of pottery provenience in which Neutron Activation Analysis was employed to establish chemical ‘fingerprints’. Because of the special nature of the problem, it was necessary to collect clays systematically to reveal the compositions of pottery that would have been made in the vicinity. By so doing, it was possible to ascertain the local provenience of a range of common household wares. Large numbers of vessels were analysed, making possible a meaningful application of statistics in the evaluation of the data.     

MODIFIED MAHALANOBIS FILTERS FOR GROUPING POTTERY BY CHEMICAL COMPOSITION*

A statistical procedure for grouping pottery in provenance studies by chemical data is presented, which now is routinely in use in our laboratory. It is based on the Mahalanobis filter method and X² -statistics, and can be used for both establishing groups and assigning single sherds to already known groups, thus replacing principal components analysis or cluster analysis and avoiding their problems in grouping pottery. The new method is able to consider correlations, uncertainties of measurement and constant shifts of the data in case of dilution. In particular, considering dilution effects results in both a better assignment to and separation of reference groups and is also equivalent to the compositional data approach, if log-transformed data are used. Other distortions of data (e.g., mixing of clays) can also be considered.     

GAUSSIAN CURVES FOR VISUALIZING CHRONOLOGICAL PATTERNS OF CERAMIC FINDS AND RESIDUALITY*

This paper describes a particular statistical approach to chronological data from assemblages of archaeological finds (namely pottery) using Gaussian curves: the method enables us to obtain a graphic representation of chronological patterns that avoids an excessive flattening of data, adding an extra dimension to the usual linear temporal concepts. This enables us to arrive at more likely absolute dating and also visualize residuality. The method has been built during the study of a stratigraphic context from the Site of Ancient Ships of Pisa – San Rossore, Italy, and applied to its pottery. Archaeologists may find in the model a useful tool that is easy to apply.     

STATISTICAL ASPECTS OF POTTERY QUANTIFICATION FOR THE DATING OF SOME ARCHAEOLOGICAL CONTEXTS*

This paper describes some statistical analyses of a particular archaeological material (pottery) originating at some sites in the city of Tours. An important part of the archaeological study of pottery is the comparison of ceramic assemblages to establish the absolute dates of contexts. In this paper, a statistical model is built to assess this comparison. The statistical procedure uses classical tools (correspondence analysis, linear regression and resampling methods) in an iterative scheme. Archaeologists may find in the paper a useful set of known statistical methods, while statisticians can learn a method of ‘arranging’ well‐known techniques. No method is new, but their combination is characteristic of this application.