Contrasting paleofluid systems in the continental basement: a fluid inclusion and stable isotope study of hydrothermal vein mineralization,Schwarzwald district,Germany

An integrated fluid inclusion and stable isotope study was carried out on hydrothermal veins (Sb‐bearing quartz veins, metal‐bearing fluorite–barite–quartz veins) from the Schwarzwald district, Germany. A total number of 106 Variscan (quartz veins related to Variscan orogenic processes) and post‐Variscan deposits were studied by microthermometry, Raman spectroscopy, and stable isotope analysis. The fluid inclusions in Variscan quartz veins are of the H₂O–NaCl–(KCl) type, have low salinities (0–10 wt.% eqv. NaCl) and high T_h values (150–350°C). Oxygen isotope data for quartz range from +2.8‰ to +12.2‰ and calculated δ¹⁸O_H2O values of the fluid are between ?12.5‰ and +4.4‰. The δD values of water extracted from fluid inclusions vary between ?49‰ and +4‰. The geological framework, fluid inclusion and stable isotope characteristics of the Variscan veins suggest an origin from regional metamorphic devolatilization processes. By contrast, the fluid inclusions in post‐Variscan fluorite, calcite, barite, quartz, and sphalerite belong to the H₂O–NaCl–CaCl₂ type, have high salinities (22–25 wt.% eqv. NaCl) and lower T_h values of 90–200°C. A low‐salinity fluid (0–15 wt.% eqv. NaCl) was observed in late‐stage fluorite, calcite, and quartz, which was trapped at similar temperatures. The δ¹⁸O values of quartz range between +11.1‰ and +20.9‰, which translates into calculated δ¹⁸O_H2O values between ?11.0‰ and +4.4‰. This range is consistent with δ¹⁸O_H2O values of fluid inclusion water extracted from fluorite (?11.6‰ to +1.1‰). The δD values of directly measured fluid inclusion water range between ?29‰ and ?1‰, ?26‰ and ?15‰, and ?63‰ and +9‰ for fluorite, quartz, and calcite, respectively. Calculations using the fluid inclusion and isotope data point to formation of the fluorite–barite–quartz veins under near‐hydrostatic conditions. The δ¹⁸O_H2O and δD data, particularly the observed wide range in δD, indicate that the mineralization formed through large‐scale mixing of a basement‐derived saline NaCl–CaCl₂ brine with meteoric water. Our comprehensive study provides evidence for two fundamentally different fluid systems in the crystalline basement. The Variscan fluid regime is dominated by fluids generated through metamorphic devolatilization and fluid expulsion driven by compressional nappe tectonics. The onset of post‐Variscan extensional tectonics resulted in replacement of the orogenic fluid regime by fluids which have distinct compositional characteristics and are related to a change in the principal fluid sources and the general fluid flow patterns. This younger system shows remarkably persistent geochemical and isotopic features over a prolonged period of more than 100 Ma.     

Interpretation of observed fluid potential patterns in a deep sedimentary basin under tectonic compression: Hungarian Great Plain, Pannonian Basin

The ≈ 40 000 km² Hungarian Great Plain portion of the Pannonian Basin consists of a basin fill of 100 m to more than 7000 m thick semi‐ to unconsolidated marine, deltaic, lacustrine and fluviatile clastic sediments of Neogene age, resting on a strongly tectonized Pre‐Neogene basement of horst‐and‐graben topography of a relief in excess of 5000 m. The basement is built of a great variety of brittle rocks, including flysch, carbonates and metamorphics. The relatively continuous Endr?d Aquitard, with a permeability of less than 1 md (10^?15 m²) and a depth varying between 500 and 5000 m, divides the basin's rock framework into upper and lower sequences of highly permeable rock units, whose permeabilities range from a few tens to several thousands of millidarcy. Subsurface fluid potential and flow fields were inferred from 16 192 water level and pore pressure measurements using three methods of representation: pressure–elevation profiles; hydraulic head maps; and hydraulic cross‐sections. Pressure–elevation profiles were constructed for eight areas. Typically, they start from the surface with a straight‐line segment of a hydrostatic gradient (γ_st = 9.8067 MPa km^?1) and extend to depths of 1400–2500 m. At high surface elevations, the gradient is slightly smaller than hydrostatic, while at low elevations it is slightly greater. At greater depths, both the pressures and their vertical gradients are uniformly superhydrostatic. The transition to the overpressured depths may be gradual, with a gradient of γ_dyn = 10–15 MPa km^?1 over a vertical distance of 400–1000 m, or abrupt, with a pressure jump of up to 10 MPa km^?1 over less than 100 m and a gradient of γ_dyn > 20 MPa km^?1. According to the hydraulic head maps for 13 100–500 m thick horizontal slices of the rock framework, the fluid potential in the near‐surface domains declines with depth beneath positive topographic features, but it increases beneath depressions. The approximate boundary between these hydraulically contrasting regions is the 100 m elevation contour line in the Duna–Tisza interfluve, and the 100–110 m contours in the Nyírség uplands. Below depths of ≈ 600 m, islets of superhydrostatic heads develop which grow in number, areal extent and height as the depth increases; hydraulic heads may exceed 3000 m locally. A hydraulic head ‘escarpment’ appears gradually in the elevation range of ? 1000 to ? 2800 m along an arcuate line which tracks a major regional fault zone striking NE–SW: heads drop stepwise by several hundred metres, at places 2000 m, from its north and west sides to the south and east. The escarpment forms a ‘fluid potential bank’ between a ‘fluid potential highland’ (500–2500 m) to the north and west, and a ‘fluid potential basin’ (100–500 m) to the south and east. A ‘potential island’ rises 1000 m high above this basin further south. According to four vertical hydraulic sections, groundwater flow is controlled by the topography in the upper 200–1700 m of the basin; the driving force is orientated downwards beneath the highlands and upwards beneath the lowlands. However, it is directed uniformly upwards at greater depths. The transition between the two regimes may be gradual or abrupt, as indicated by wide or dense spacing of the hydraulic head contours, respectively. Pressure ‘plumes’ or ‘ridges’ may protrude to shallow depths along faults originating in the basement. The basement horsts appear to be overpressured relative to the intervening grabens. The principal thesis of this paper is that the two main driving forces of fluid flow in the basin are gravitation, due to elevation differences of the topographic relief, and tectonic compression. The flow field is unconfined in the gravitational regime, whereas it is confined in the compressional regime. The nature and geometry of the fluid potential field between the two regimes are controlled by the sedimentary and structural features of the rock units in that domain, characterized by highly permeable and localized sedimentary windows, conductive faults and fracture zones. The transition between the two potential fields can be gradual or abrupt in the vertical, and island‐like or ridge‐like in plan view. The depth of the boundary zone can vary between 400 and 2000 m. Recharge to the gravitational regime is inferred to occur from infiltrating precipitation water, whereas that to the confined regime is from pore volume reduction due to the basement's tectonic compression.     

Early Holocene palaeoseasonality inferred from the stable isotope composition of Unio shells from Çatalhöyük,Turkey

Seasonal δ¹³C and δ¹⁸O data are presented from 14 Unio sub-fossil shells unearthed at the archaeological site of Çatalhöyük in central Turkey, spanning the occupation period ca. 9150–8000 cal years BP. The shells likely lived in the small lakes/wetlands around the site before being gathered and taken to Çatalhöyük. Wet-dry seasonal cycles are clearly apparent in the δ¹⁸O_shell profiles with low winter values reflecting winter precipitation and high δ¹⁸O in the summer resulting from evaporation. The most striking trend in the δ¹⁸O data is the drop in maximum summer δ¹⁸O ca. 8300 years BP, which we infer as indicating lower summer evaporation and hence a reduction in seasonality. Previous palaeoclimate records from the area have suggested cooler and more arid conditions, with reduced precipitation, around this time. While the drop in summer δ¹⁸O values could be due to reduced summer temperatures reducing summer evaporation, but there was little change in winter δ¹⁸O, perhaps suggesting winter growth cessation or reduced influence of winter climate change on δ¹⁸O. This shift in seasonal climate could be linked to solar-forced climate change beginning ca. 8600 years BP, and enhanced by the regional expression of the 8·2k event. Changing water balance over the occupation period is likely an important contributory factor behind observed cultural changes at Çatalhöyük in the Late Neolithic/Early Chalcolithic period. Our results might be considered to support the fission-fusion farming hypothesis as we provide additional evidence for wet winter/early spring conditions during the Early Holocene which likely caused flooding of the Çar?amba Fan. The changing water balance after ca. 8300 years BP (i.e. reduced seasonality and potentially reduced local summer evaporation) is also coincidental with the proposed end of this farming system due to multi-decadal drought.     

Mean winds at 60–90 km observed with the MU radar (35°N)

Mean winds at 60–90 km altitudes observed with the MU radar (35°N, 136°E) in 1985–1989 are presented in this paper. The zonal wind at 70 km became westward and eastward in summer and winter, respectively, with a maximum amplitude of 45 m s⁻¹ westward in early July and 80 m s⁻¹ eastward at the end of November. The meridional wind below 85 km was generally northward with the amplitudes less than 10 m s⁻¹. In September to November, the meridional wind at 75–80 km becomes as large as 20–30 m s⁻¹. Those zonal wind profiles below 90 km show good coincidence with the CIRA 1986 model, except for the latter half of winter, from January to March, when the observational result showed a much weaker eastward wind than the CIRA model. The height of the reversal of the summer wind from westward to eastward was determined as being 83–84 km, which is close to the CIRA 1986 model of 85 km. The difference between the previous meteor radar results at 35–40°N, which showed the reversal height below 80 km, could be due to interannual variations or the difference in wind measurement technique. In order to clarify that point, careful comparative observations would be necessary. These mean winds were compared with Adelaide MF radar observations, and showed good symmetry between the hemispheres, including the summer reversal height, except for the short period of eastward winds above Kyoto and the long period over Adelaide.     

Origin of palaeofluids in a normal fault setting in the Aegean region

The province of Burdur (SW Turkey) is seismically an active region. A structural, geochronological, petrographical, geochemical and fluid inclusion study of extension veins and fault‐related calcite precipitates has been undertaken to reconstruct the palaeofluid flow pattern in this normal fault setting in the Aegean region. A palaeostress analysis and U/Th dating of the precipitates reveals the neotectonic significance of the sampled calcites. Fluid inclusion microthermometry of calcites‐filling extension veins shows final melting temperatures (T_m ice) of 0°C. This indicates pure water, most likely of meteoric origin. The oxygen isotope values (?9.8‰ to ?6.5‰ VPDB) and the carbon isotopic composition (?10.4‰ to ?2.9‰ VPDB) of these calcites also show a near‐surface meteoric origin of the fluid responsible for precipitation. The microstructural characteristics of fault‐related calcites indicate that calcite precipitation was linked with fault activity. Final melting temperature of fault‐related calcites ranges between 0 and ?1.9°C. The oxygen isotope values show a broad range between ?15.0‰ and ?2.2‰ VPDB. Several of these calcites have a δ¹⁸O composition that is higher or lower than the oxygen isotopic composition of meteoric calcites in the area (i.e. between ?10‰ and ?6‰ VPDB). The δ¹³C composition largely falls within the range of the host limestones and reflects a rock‐buffered system. Microthermometry and stable isotopic study indicate a meteoric origin of the fluids with some degree of water–rock interaction or mixing with another fluid. Temperatures deduced from microthermometry and stable isotope analyses indicate precipitation temperatures around 50°C. These higher temperatures and the evidence for water–rock interaction indicate a flow path long enough to equilibrate with the host–rock limestone and to increase the temperature. The combined study of extension vein‐ and fault‐related calcite precipitates enables determining the origin of the fluids responsible for precipitation in a normal fault setting. Meteoric water infiltrated in the limestones to a depth of at least 1 km and underwent water–rock interaction or mixing with a residual fluid. This fluid was, moreover, tapped during fault activity. The extension veins, on the contrary, were passively filled with calcites precipitating from the downwards‐migrating meteoric water.     

Chlorine stable isotope ratios as tracer for pore‐water advection rates in a submarine gas‐hydrate field: implication for hydrate concentration

At Ocean Drilling Program Site 997 in Blake Ridge gas‐hydrate field in West Atlantic, pore‐water studies revealed a pronounced downward depletion of the heavy chlorine isotope to nearly ?4‰δ³⁷Cl at approximately 750 m below sea floor (mbsf) associated with a 10% downward chlorinity decrease. This is one of the stronger ³⁷Cl depletions hitherto reported for marine pore waters. Chlorinity reductions in hydrate‐bearing sediments commonly result from fresh‐water release by hydrate melting. However, in situ measurements at Site 997 suggest that >50% of the chlorinity reduction occurred prior to hydrate dissociation. Modeling the chlorinity profile shows that advection of a strongly ³⁷Cl‐depleted, low‐chlorinity water (506 mm ) from below the drilled sequence can explain the reduction prior to sampling. Fitting the model to the δ³⁷Cl curve yielded an advection rate of 0.18 mm year^?1. Diffusive mixing with near‐0‰‐δ³⁷Cl paleo‐seawater with maximum chlorinity at shallow subsurface depths (561 mm at approximately 20 mbsf) produced the smooth, steady trend. Separating that part of the freshening caused by advection and diffusion from that due to hydrate dissociation allowed estimation of average hydrate concentrations of 3.8% of the pore space (up to 24.5% in hydrate‐rich layers; near‐100% in rare massive hydrate layers). The deep‐seated source of the ³⁷Cl‐depleted, low‐chlorinity water remains unknown and might be located below the sedimentary section in the oceanic basement.     

3D numerical modeling of hydrothermal processes during the lifetime of a deep geothermal reservoir

Understanding hydrothermal processes during production is critical to optimal geothermal reservoir management and sustainable utilization. This study addresses the hydrothermal (HT) processes in a geothermal research doublet consisting of the injection well E GrSk3/90 and production well Gt GrSk4/05 at the deep geothermal reservoir of Groß Schönebeck (north of Berlin, Germany) during geothermal power production. The reservoir is located between ?4050 to ?4250 m depth in the Lower Permian of the Northeast German Basin. Operational activities such as hydraulic stimulation, production (T = 150°C; Q = ?75 m³ h^?1; C = 265 g l^?1) and injection (T = 70°C; Q = 75 m³ h^?1; C = 265 g l^?1) change the HT conditions of the geothermal reservoir. The most significant changes affect temperature, mass concentration and pore pressure. These changes influence fluid density and viscosity as well as rock properties such as porosity, permeability, thermal conductivity and heat capacity. In addition, the geometry and hydraulic properties of hydraulically induced fractures vary during the lifetime of the reservoir. A three‐dimensional reservoir model was developed based on a structural geological model to simulate and understand the complex interaction of such processes. This model includes a full HT coupling of various petrophysical parameters. Specifically, temperature‐dependent thermal conductivity and heat capacity as well as the pressure‐, temperature‐ and mass concentration‐dependent fluid density and viscosity are considered. These parameters were determined by laboratory and field experiments. The effective pressure dependence of matrix permeability is less than 2.3% at our reservoir conditions and therefore can be neglected. The results of a three‐dimensional thermohaline finite‐element simulation of the life cycle performance of this geothermal well doublet indicate the beginning of thermal breakthrough after 3.6 years of utilization. This result is crucial for optimizing reservoir management. Geofluids (2010) 10 , 406–421     

Molecular transport of methane, ethane and nitrogen and the influence of diffusion on the chemical and isotopic composition of natural gas accumulations

Laboratory experiments have been performed to determine diffusion coefficients of natural gas components (methane, ethane and nitrogen) and isotope fractionation effects under simulated in situ pressure (up to 45 MPa effective stress) and temperature conditions (50–200°C) in water‐saturated pelitic and coarse‐grained rocks. Effective diffusion coefficients of molecular nitrogen (0.39 × 10^?11 to 21.6 × 10^?11 m² sec^?1 at 90°C) are higher than those for methane (0.18 × 10^?11 to 18.2 × 10^?11 m² sec^?1 at 90°C). Diffusive flux rates expressed in mass units are generally higher for N₂ than for CH₄. Both methane and (to a lesser extent) nitrogen diffusion coefficients decrease with increasing total organic carbon (TOC) content of the rock samples because of sorption processes on the organic matter. This effect decreases with increasing temperature. Effective diffusion coefficients increase upon a temperature increase from 50 to 200°C by a factor of four. Effective diffusion coefficients and steady‐state diffusive flux decrease with effective stress. Stationary diffusive fluxes drop by 50–70% for methane and 45–62% for nitrogen while effective diffusion coefficients are reduced by 38% (CH₄) and 32–48% (N₂), respectively. Isotope fractionation coefficients of diffusive transport are higher for methane (?1.56 and ?2.77‰) than for ethane (?0.84 and ?1.62‰). Application of the experimental results to geological systems show that diffusive transport has only a low transport efficiency. Significant depletion of natural gas reservoirs by molecular diffusion is only expected in cases of very poor caprock qualities (in terms of thickness and/or porosity) and over extended periods of geological time. Under these circumstances, the chemical and isotopic composition of a gas reservoir will change and maturity estimates based on these parameters may be deceptive. To account for these potential effects, nomograms have been developed to estimate diffusive losses and apply maturity corrections.     

The politics of water security in southern Saskatchewan

This paper examines long-term water and resource management in Saskatchewan. Agriculture has long sustained Saskatchewan's economy, but the province experienced a resource boom in oil and potash in the 2008–2015 time period. What potential water-related risks are posed by oil and potash? And is the province able to balance the short-term economic gains of these developments with the long-term goal of water security? The research is based on interviews with policy elites in the province of Saskatchewan and argues that four factors explain why the government continues to favour industry over water security: low-issue salience, economic and political interest, ideology, and political culture.     

Origin of deep saline groundwaters in the Vienne granitic rocks (France): constraints inferred from boron and strontium isotopes

As part of a preliminary geological characterization programme to assess the feasibility of an underground laboratory in granitic rock, a series of 17 deep boreholes (maximum depth, 900 m) was drilled by ANDRA in the Vienne district, France. A salinity gradient was demonstrated in the granitic waters with concentrations varying from approximately 1 g L^?1 at 150 m depth at the top of the basement (beneath the sedimentary cover) to 10 g L^?1 in the deeper part (from 400 to 600 m depth). Sr and B isotope ratios were measured in order to better understand the origin of the salinity and to evaluate the degree of water–rock interaction in the system. The results obtained were compared to those of mineral spring waters emerging from the granitic basement in the Massif Central. Evidence in support of a significant marine contribution include: (i) the Cl–Br investigations agree with a marine origin for the saline groundwaters without evolution from seawater; (ii) the ⁸⁷Sr/⁸⁶Sr ratio of the Vienne deep groundwaters (0.7078–0.7084) is in agreement with a palaeo‐seawater isotopic signature; (iii) measured δ¹¹B values for the deepest brine samples are enriched in ¹¹B (up to 36.1‰) relative to the granitic springs. The combined use of δ¹¹B, Cl, B, Br, Sr contents and ⁸⁷Sr/⁸⁶Sr ratios makes it possible to define and quantify a mixing model between marine and crustal end‐members in order to explain the origin of the deep saline groundwaters in the Vienne granitic rocks.     

Effective gas permeability of Tight Gas Sandstones as a function of capillary pressure – a non‐steady‐state approach

Single‐ and two‐phase (gas/water) fluid transport in tight sandstones has been studied in a series of permeability tests on core plugs of nine tight sandstones of the southern North Sea. Absolute (Klinkenberg‐corrected) gas permeability coefficients (k_gas__inf) ranged between 3.8 × 10^?16 and 6.2 × 10^?19 m² and decreased with increasing confining pressure (10–30 MPa) by a factor 3–5. Klinkenberg‐corrected (intrinsic) gas permeability coefficients were consistently higher by factors from 1.4 to 10 than permeability coefficients determined with water. Non‐steady‐state two‐phase (He/water) flow experiments conducted up to differential pressures of 10 MPa document the dynamically changing conductivity for the gas phase, which is primarily capillary‐controlled (drainage and imbibition). Effective gas permeability coefficients in the two‐phase flow tests ranged between 1.1 × 10^?17 and 2.5 × 10^?22 m², corresponding to relative gas permeabilities of 0.03% and 10%. In the early phase of the nonstationary flow regime (before establishment of steady‐state conditions), they may be substantially (>50%) lower. Effective gas permeability measurements are affected by the following factors: (i) Capillary‐controlled drainage/imbibition, (ii) viscous–dynamic effects (iii) and slip flow.     

Gas breakthrough experiments on fine-grained sedimentary rocks

The capillary sealing efficiency of fine‐grained sedimentary rocks has been investigated by gas breakthrough experiments on fully water saturated claystones and siltstones (Boom Clay from Belgium, Opalinus Clay from Switzerland and Tertiary mudstone from offshore Norway) of different lithological compositions. Sand contents of the samples were consistently below 12%, major clay minerals were illite and smectite. Porosities determined by mercury injection lay between 10 and 30% while specific surface areas determined by nitrogen adsorption (BET method) ranged from 20 to 48 m² g ^{? 1}. Total organic carbon contents were below 2%. Prior to the gas breakthrough experiments the absolute (single phase) permeability (k_abs) of the samples was determined by steady state flow tests with water or NaCl brine. The k_abs values ranged between 3 and 550 nDarcy (3 × 10^?21 and 5.5 × 10^?19 m²). The maximum effective permeability to the gas‐phase (k_eff) measured after gas breakthrough on initially water‐saturated samples extended from 0.01 nDarcy (1 × 10^?23 m²) up to 1100 nDarcy (1.1 × 10^?18 m²). The residual differential pressures after re‐imbibition of the water phase, referred to as the ‘minimum capillary displacement pressures’ (P_d), ranged from 0.06 to 6.7 MPa. During the re‐imbibition process the effective permeability to the gas phase decreases with decreasing differential pressure. The recorded permeability/pressure data were used to derive the pore size distribution (mostly between 8 and 60 nm) and the transport porosity of the conducting pore system (10^‐5–10^‐2%). Correlations could be established between (i) absolute permeability coefficients and the maximum effective permeability coefficients and (ii) effective or absolute permeability coefficients and capillary sealing efficiency. No correlation was found between the capillary displacement pressures determined from gas breakthrough experiments and those derived theoretically by mercury injection.     

The Coupled Influence of Relative Density,CSR, Plasticity and Content of Fines on Cyclic Liquefaction Resistance of Sands

In this study, stress-controlled cyclic simple shear tests were performed on sand specimens with up to 10% silt or clay contents, and coupled effects of plasticity, fines content (FC), relative density (D_R) and CSR (cyclic stress ratio) were investigated. The results demonstrated that for sands with low fines content, reasonable trends were obtained when the packing index control parameter was selected as D_R. Also, clean sand specimens demonstrated highest liquefaction strength compared with that of sands with fines up to 10% FC. The effect of fines’ plasticity became apparent as the FC increases and CSR reduces in relatively denser specimens.     

Natural degradation of earthworks,trenches, walls and moats,Northern Thailand

We here investigate the geometry, age, and history of several enigmatic northern Thailand earthwork entrenchments that are mostly located on hills and could not have held water to form moats. The earthworks are either oval or rectangular in plan view and typically encircle 0.3 to 1?sq km areas with no potsherd debris that would indicate former towns. Most trenches are 3–5?m deep with inner walls 4.5–8?m high. Some encircling earthworks are concentric double trenches spaced approximately 10?m apart. Historians have suggested these earthworks enclosed defensible areas where people in outlying villages sought refuge when under attack by neighboring rulers, the Chinese Ho, or the Burmese. We argue that some encircling entrenchments may have been for the capture or containment of elephants. Nearly all of the once near-vertical original walls have degraded to slopes of 32–47°. Fitting calculated curves of the diffusion-based scarp-degradation model to our height-slope data, and assuming most scarps have degraded since the end of La Na Kingdom time a.d. 1558, we derive a diffusion coefficient of 0.002?m² y^?1. Slopes of the rectangular earthwork at Souvannkhomkham, Laos, across the Mekong River from Chiang Saen Noi, are significantly more degraded (approximately 32°), indicating an age of 800–1200 years. Locations of these earthworks are established in hope that they will be preserved as part of the Thai and Lao archaeological legacy.     

Oxygen isotopes in cellulose identify source water for archaeological maize in the American Southwest

Maize (Zea mays) was a primary food crop for aboriginal societies of the arid American Southwest. Water used for maize production in these arid zones could have come from precipitation and runoff during the summer monsoon, from perennial streams and springs, or from stored soil water fed by snowmelt. The oxygen stable isotope ratio (δ¹⁸O) of summer and winter precipitation on the Colorado Plateau naturally differ by more than 10‰ providing a powerful tool for distinguishing winter- from summer-derived water sources used in cultivation of maize. We investigated whether variation in δ¹⁸O of potential source waters is preserved in the δ¹⁸O of cellulose (δ¹⁸O_cellulose) of maize cobs by growing four aboriginal and one modern maize variety in pots irrigated with water of known δ¹⁸O composition. The δ¹⁸O_cellulose values of cobs ranged from 26.8 to 36.4‰ (averaged within varieties) and were highly correlated with δ¹⁸O values of the source irrigation water (−15.8 to −8.2‰). Cob δ¹⁸O_cellulose from five archaeological sites on the Colorado Plateau in southeastern Utah ranged from 27.3 to 34.6‰, closely matching the range of values observed in experimental plants. A δ¹⁸O_cellulose model developed originally for tree rings was parameterized and applied to the archaeological maize cobs. The model indicated that monsoonal precipitation accounted for 0–20% of the moisture for archaeological cob samples from a site adjacent to a perennial stream and 43–98% for samples from an upland site, more distant from a perennial water source. These results reveal the potential for using δ¹⁸O_cellulose to investigate prehistoric irrigation practices and source water used for maize production in the American Southwest.     

The upper continental crust, an aquifer and its fluid: hydaulic and chemical data from 4 km depth in fractured crystalline basement rocks at the KTB test site

Detailed information on the hydrogeologic and hydraulic properties of the deeper parts of the upper continental crust is scarce. The pilot hole of the deep research drillhole (KTB) in crystalline basement of central Germany provided access to the crust for an exceptional pumping experiment of 1‐year duration. The hydraulic properties of fractured crystalline rocks at 4 km depth were derived from the well test and a total of 23100 m³ of saline fluid was pumped from the crustal reservoir. The experiment shows that the water‐saturated fracture pore space of the brittle upper crust is highly connected, hence, the continental upper crust is an aquifer. The pressure–time data from the well tests showed three distinct flow periods: the first period relates to wellbore storage and skin effects, the second flow period shows the typical characteristics of the homogeneous isotropic basement rock aquifer and the third flow period relates to the influence of a distant hydraulic border, probably an effect of the Franconian lineament, a steep dipping major thrust fault known from surface geology. The data analysis provided a transmissivity of the pumped aquifer T = 6.1 × 10^?6 m² sec^?1, the corresponding hydraulic conductivity (permeability) is K = 4.07 × 10^?8 m sec^?1 and the computed storage coefficient (storativity) of the aquifer of about S = 5 × 10^?6. This unexpected high permeability of the continental upper crust is well within the conditions of possible advective flow. The average flow porosity of the fractured basement aquifer is 0.6–0.7% and this range can be taken as a representative and characteristic values for the continental upper crust in general. The chemical composition of the pumped fluid was nearly constant during the 1‐year test. The total of dissolved solids amounts to 62 g l^?1 and comprise mainly a mixture of CaCl₂ and NaCl; all other dissolved components amount to about 2 g l^?1. The cation proportions of the fluid (X_Ca approximately 0.6) reflects the mineralogical composition of the reservoir rock and the high salinity results from desiccation (H₂O‐loss) due to the formation of abundant hydrate minerals during water–rock interaction. The constant fluid composition suggests that the fluid has been pumped from a rather homogeneous reservoir lithology dominated by metagabbros and amphibolites containing abundant Ca‐rich plagioclase.     

Mean winds observed by the Kyoto meteor radar in 1983–1985

Mean winds at 82–106 km altitude have been almost continuously monitored by the Kyoto meteor radar over the period from May 1983 to December 1985. The mean zonal wind becomes eastward with amplitudes as large as 30 m s⁻¹ in the summer months (May–August), maximizing early in July at 95 km altitude, while it is less than 10 m s⁻¹ at all the observed altitudes during the equinoxes. It is normally eastward in winter at low altitudes, although it sometimes becomes westward during sudden stratospheric warmings. The mean meridional wind is usually equatorward and is weaker than the zonal component. A southward wind exceeding 10 m s⁻¹ is detected in July and August. The observed mean winds are compared with the CIRA 1972 model and coincidences with sudden warmings of changes in zonal wind direction are pointed out.     

Syntectonic infiltration by meteoric waters along the Sevier thrust front,southwest Montana

Structural, petrographic, and isotopic data for calcite veins and carbonate host‐rocks from the Sevier thrust front of SW Montana record syntectonic infiltration by H₂O‐rich fluids with meteoric oxygen isotope compositions. Multiple generations of calcite veins record protracted fluid flow associated with regional Cretaceous contraction and subsequent Eocene extension. Vein mineralization occurred during single and multiple mineralization events, at times under elevated fluid pressures. Low salinity (T_m = ?0.6°C to +3.6°C, as NaCl equivalent salinities) and low temperature (estimated 50–80°C for Cretaceous veins, 60–80°C for Eocene veins) fluids interacted with wall‐rock carbonates at shallow depths (3–4 km in the Cretaceous, 2–3 km in the Eocene) during deformation. Shear and extensional veins of all ages show significant intra‐ and inter‐vein variation in δ¹⁸O and δ¹³C. Carbonate host‐rocks have a mean δ¹⁸O_V‐SMOW value of +22.2 ± 3‰ (1σ), and both the Cretaceous veins and Eocene veins have δ¹⁸O ranging from values similar to those of the host‐rocks to as low as +5 to +6‰. The variation in vein δ¹³C_V‐PDB of ?1 to approximately +6‰ is attributed to original stratigraphic variation and C isotope exchange with hydrocarbons. Using the estimated temperature ranges for vein formation, fluid (as H₂O) δ¹⁸O calculated from Cretaceous vein compositions for the Tendoy and Four Eyes Canyon thrust sheets are ?18.5 to ?12.5‰. For the Eocene veins within the Four Eyes Canyon thrust sheet, calculated H₂O δ¹⁸O values are ?16.3 to ?13.5‰. Fluid–rock exchange was localized along fractures and was likely coincident with hydrocarbon migration. Paleotemperature determinations and stable isotope data for veins are consistent with the infiltration of the foreland thrust sheets by meteoric waters, throughout both Sevier orogenesis and subsequent orogenic collapse. The cessation of the Sevier orogeny was coincident with an evolving paleogeographic landscape associated with the retreat of the Western Interior Seaway and the emergence of the thrust front and foreland basin. Meteoric waters penetrated the foreland carbonate thrust sheets of the Sevier orogeny utilizing an evolving mesoscopic fracture network, which was kinematically related to regional thrust structures. The uncertainty in the temperature estimates for the Cretaceous and Eocene vein formation prevents a more detailed assessment of the temporal evolution in meteoric water δ¹⁸O related to changing paleogeography. Meteoric water‐influenced δ¹⁸O values calculated here for Cretaceous to Eocene vein‐forming fluids are similar to those previously proposed for surface waters in the Eocene, and those observed for modern‐day precipitation, in this part of the Idaho‐Montana thrust belt.     

Intra‐individual variation in stable carbon (δ13C) and nitrogen (δ15N) isotopes in mandibles of modern caribou of Qamanirjuaq (Rangifer tarandus groenlandicus) and Banks Island (Rangifer tarandus pearyi): Implications for tracing seasonal and temporal changes in diet

Intra‐individual variations in carbon (δ¹³C) and nitrogen (δ¹⁵N) isotope measurements of dentine collagen in ungulate teeth can be related to diet and environmental changes at different periods during the life of the animal. A protocol of serial sampling of first, second and third molar roots was applied to modern caribou (17–27 months old) of the Qamanirjuaq herd (Rangifer tarandus groenlandicus), Canada. Based on a previous study, we predicted that M2 would reflect winter, M3 summer and M1 a complete year in terms of the isotopic record. Relatively high δ¹⁵N values (ca. 6 to 8‰), previously attributed to winter stress, were found in different molars of different specimens, reflecting a period of growth between April 1966 to April 1967. Previous results on other teeth from the same population confirmed that a high δ¹⁵N_coll value signal corresponded to the winter of 1966/67. This temporary increase in δ¹⁵N value was probably linked to diet and/or environmental change. Collagen from M1 reflects the first winter whereas M2 and M3 reflect the second winter of life of young caribou. A longer time record including summer is represented by the bone collagen of the mandible. Results obtained on molar roots and mandible bone of the modern caribou of Banks Island herd (Rangifer tarandus pearyi) confirmed this seasonal record. Such collagen isotopic analysis on M1, M2 and M3 roots and jawbone can be applied to reindeer found in archaeological sites. Mandibles retaining deciduous premolars are preferable to avoid the possible loss of the winter tooth signal observed in animals older than 2 years. Copyright © 2010 John Wiley & Sons, Ltd.     

The 7th–9th Century Tantura E Shipwreck,Israel: construction and reconstruction

The Tantura E shipwreck was discovered in Tantura lagoon, Israel, in a water depth of 2.8 m, covered by 1 m of sand. It was a coaster that plied the Levant coast, dated to the 7th–9th centuries CE. It was recorded under water, but several components were studied on land, as well as the finds. The hull is of frame‐based construction, with flat floor timbers and a sharp turn of the bilge. The archaeological evidence, as well as modern design tools and regulations, suggests that Tantura E was c.12.5 m long, of 25 tonnes displacement, and could load c.17.5 tonnes.