CHEMICAL AND MINERALOGICAL CHARACTERIZATION OF SASANIAN AND EARLY ISLAMIC GLAZED CERAMICS FROM THE DEH LURAN PLAIN,SOUTHWESTERN IRAN*

One hundred and seventy‐five glazed ceramics from Sasanian and Early Islamic period sites located on the Deh Luran Plain in southwestern Iran were examined by instrumental neutron activation analysis for characterizing differences in ceramic pastes and by laser‐ablation inductively coupled plasma mass‐spectrometry for identifying the constituents of the ceramic glazes. The results of the analysis reveal that alkaline‐based glazed ceramics have paste compositions that are distinct from contemporary and later ceramics decorated with alkaline–low‐lead and lead‐based glazes.     

The Faragola Ceramic Collection: Ceramic Production,Consumption and Exchange in Seventh‐Century Apulia

A collection of 30 ceramic samples, 16 of coarse wares and 14 of fine painted wares, have been investigated by optical microscopy, scanning electron microscopy, inductively coupled plasma optical emission spectrometry, inductively coupled plasma mass spectrometry and neutron activation analysis. Further samples of clayey sediments, both locally outcropping and found within the settling tank, have been submitted to the same analytical techniques for comparison with the ceramic collection. The results demonstrated that local clayey sediments were used as received for the production of coarse wares. The same raw materials were sieved and/or refined by decantation for the production of fine painted wares, which, in fact, provided results that were perfectly comparable with those for the clayey raw materials found within the settling tank. The Faragola productions were distinguished from the neighbouring Apulian productions according to petrographic features (the presence of leucite‐bearing volcanic rocks and Mn‐rich wads) and their bulk chemical composition.     

IDENTIFICATION OF POST‐DEPOSITIONAL CHEMICAL ALTERATION OF CERAMICS FROM THE NORTH COAST OF PAPUA NEW GUINEA (SANDUAN PROVINCE) BY TIME‐OF‐FLIGHT–LASER ABLATION–INDUCTIVELY COUPLED PLASMA–MASS SPECTROMETRY (TOF–LA–ICP–MS)*

The measured chemical composition of archaeological ceramics can result from a variety of geological, cultural and taphonomic factors. In the present study, we evaluate the likelihood that elevated barium concentrations in ceramics from the archaeological site of Wom/Aiser, located on the northern coast of Papua New Guinea, result from post‐depositional enrichment. Using time‐of‐flight–laser ablation–inductively coupled plasma–mass spectrometry, we mapped chemical compositional profiles across cut sections of ceramic sherds from four archaeological sites, all previously chemically characterized. We identify the formation of pronounced concentration gradients in samples from Wom/Aiser relative to sherds with low barium concentrations, consistent with post‐burial uptake.     

Identifying a technological style in the making of lime plasters at Teopancazco (Teotihuacan,México)

The aim of this article is to focus on the technology of archeological plasters at Teotihuacan (Central Mexico), from the Classic Period (200–650 A.D.), focusing in the study of Teopancazco, a neighborhood center in the city. Petrographic and chemical analyses by OM, SEM-EDS, and LA-ICP-MS were conducted to characterize samples from different constructive phases and sectors of the neighborhood center, to determine the provenance of the raw materials employed in the manufacturing (e.g., volcanic glass shards) and to assess whether a shift occurred in the manufacturing of plasters and in the procurement strategies of raw materials during the different phases. The results of the analyses show that almost no changes occurred in the making of the plaster during more than four centuries and allow us to consider the presence of a technological style in their manufacture, which is characterized by the making of plaster by mixing lime with volcanic glass shards, which in the case of Teopancazco were derived from the Altotonga (Veracruz) magmatic system. The data at our disposal suggest that this style was developed in Teopancazco and later introduced throughout the city of Teotihuacan in the Early Xolalpan phase (A.D. 350), although we still do not know whether the provenance of the raw materials is the same. The wide distribution of this technological tradition could be due to the technological properties of the materials and/or the influence of the intermediate elite who ruled over Teopancazco. The paper confirms that the study of material culture and technology sheds light on broader cultural aspects of ancient societies.     

COOKING AND PAINTED WARE FROM SAN GIUSTO (LUCERA,FOGGIA): THE PRODUCTION CYCLE,FROM THE SUPPLY OF RAW MATERIALS TO THE COMMERCIALIZATION OF PRODUCTS*

Archaeological excavation at the San Giusto site (Lucera, Italy) has unearthed a Late Antique kiln that was most certainly dedicated to the production of cooking ware. An archaeometric study of numerous specimens of cooking and painted ware found at this site was carried out using optical microscopy, scanning electron microscopy, micro‐Raman spectroscopy, X‐ray diffraction, X‐ray fluorescence, inductively coupled plasma mass and optical emission spectrometry and instrumental neutron activation analysis. The integration of historical–archaeological data with archaeometric data has revealed that these specimens can be attributed to the San Giusto site. Furthermore, the production cycle of this ware can thus be reconstructed: from the diversified supply of raw materials (fluvial and marine sediments), to the relatively complex preparation of the paste, to firing at variable temperatures (600–750°C for cooking ware; 850–1050°C for painted ware).     

First Geochemical ‘Fingerprinting’ of Balkan and Prut Flint from Palaeolithic Romania: Potentials,Limitations and Future Directions

Long‐distance raw material transfers across Romania prior to the Last Glacial Maximum have previously been inferred from either visual and/or petrographic observations of East Carpathian sites. We investigated the potential to ‘fingerprint’ flint from archaeological sites at Mitoc‐Malu Galben and Bistricioara–Lut?rie III in Eastern Romania, using in situ high‐precision analyses of 28 major, minor and trace elements determined by laser ablation – inductively coupled plasma – mass spectrometry (LA–ICP–MS) in combination with multivariate statistical analysis. Our results suggest that geochemical analyses have the ability to distinguish between different geographical sources but are unable to positively associate flint artefacts from archaeological contexts to these geochemical groups. The mismatches of signatures between artefacts and geological materials, however, raise new questions and open unforeseen perspectives.     

Reconstructing Regional Trajectories: the Provenance and Distribution of Archaic to Hellenistic Ceramics in Central Pisidia (South‐west Turkey)

Analytical ceramic studies offer the opportunity to determine cultural development and change on the basis of origin and use of raw materials. In this particular study, an archaeometric approach on ceramics in central Pisidia contributes to the discussion of contact and exchange between indigenous communities and several cultural spheres of influence on a long‐term timescale (eighth to second centuries bce ). Morphological data as well as mineralogical (optical microscopy; n = 273) and chemical composition (by ICP–OES/MS; n = 122) of ceramics and raw materials show distinct resource zones for the production and distribution of ceramics in this connecting region of Anatolia. The use of trace element profiles (REE, HFSE, LILE and TTE) in particular is regarded as instrumental in detailing high‐resolution provenancing of ceramics. The ceramic provenance indicates different patterns of material interactions during the Archaic, Classical and Hellenistic periods. A significant increase in regional interaction occurs coinciding with the development of pottery activities at Sagalassos.     

THE SEARCH FOR THE ORIGIN OF BITUMEN EXCAVATED FROM ARCHAEOLOGICAL SITES IN THE NORTHERNMOST ISLAND IN JAPAN BY MEANS OF STATISTICAL ANALYSIS OF FI–MS DATA*

The origin of bitumen excavated from archaeological sites in Hokkaido, the northernmost island in Japan, was sought by means of field‐ionization mass spectrometry (FI–MS) and gas chromatography – mass spectrometry (GC–MS) of the hydrocarbon components. The field‐ionization mass spectra were decomposed by Z‐numbers into several components, where the Z‐number refers to z in the formula C _n H _2n+z . This is equivalent to the deficit number of H atoms, when compared to the corresponding saturated hydrocarbon, which is related to the number of saturated hydrocarbon rings in alkanes. By use of the spectral intensities of the seven alkane components in each sample, multiple discriminant analysis was employed for the data of raw bitumen samples and excavated samples from archaeological sites. Based on this method and the gas chromatogram type, the following bitumen trade in the prehistoric age of Japan was elucidated: bitumen from Niigata, one of the main sources on the main island of Japan, spread to the north in 2000 bc , probably via the coastal zone, and reached a small island near the north end of Hokkaido. Bitumen from Sakhalin reached the central lowland in Hokkaido, but it went no further. Bitumen from Akita, another main source on the main island, spread over northern Honshu much earlier and reached the Oshima peninsula, the southwestern part of Hokkaido. The Akita bitumen scattered into the central lowland after the Niigata and Sakhalin bitumen. This area is believed to be the place where people from the south and the north met in those periods.     

RELATIONSHIP BETWEEN THE COLORATION AND THE FIRING TECHNOLOGY USED TO PRODUCE SUSA GLAZED CERAMICS OF THE END OF THE NEOLITHIC PERIOD*

Ancient decorated potteries from Susa (Mesopotamia) dating from 4200 to 3700 bc , were studied in order to determine the origin and the nature of the raw materials used, and to identify the technological processes applied to make the ceramic bodies and their decorations. Bulk compositions were determined by particle induced X‐ray emission (PIXE), while the microstructure and the mineralogical phases were studied using scanning electron microscopy (SEM), energy dispersive X‐ray analyses (EDX) and X‐ray powder diffraction (XRD). The results showed that the raw materials used to elaborate these potteries were similar for all the ceramic bodies (carbonates and iron and magnesium‐rich clays containing sand), and for all the decorations (iron oxides, silica, potassic and alumina sources). The variations of coloration of the ceramics and of their decorations were due to different firing temperatures. The ranges of firing temperatures used by potters were evaluated on the basis of mineral stability domains.     

Geochemical Characterization of Lapita Pottery Via Inductively Coupled Plasma–mass Spectrometry (ICP–MS)

We have obtained high‐resolution elemental data on Lapita ceramics (3200–2700 cal year bp ) from Fiji, Tonga and New Ireland using chemistry‐based inductively coupled plasma–mass spectrometry (ICP–MS). These data show clear elemental distinctions between Lapita pottery manufactured in Fiji, Tonga and New Ireland, and demonstrate significant elemental variation in Fijian ceramics collected from settlements in close proximity to one another. Therefore, we anticipate that ICP–MS will become an effective technique for tracking the transfer of Lapita pottery within and between different island groups in Oceania.     

Enhancing Understanding of the Emergence of Global Trade: Analysis of 17th‐ to 19th‐Century Spanish Coins Recovered from Western Australian Shipwrecks Using Laser Ablation – Inductively Coupled Plasma – Mass Spectrometry (LA–ICP–MS)

This research uses legacy data from shipwrecks to further our understanding of global silver movement in the 17th to 19th centuries by analysing a collection of silver coins held by the Western Australian Museum. Three hundred and eighty‐nine silver coins were analysed for their trace element fingerprint in order to identify provenance. The coins are a selection from the ships Batavia, Vergulde Draeck, Zuytdorp, Rapid and Correio da Azia, all wrecked off the coast of Western Australia between 1629 and 1816. Analysis was undertaken using laser ablation – inductively coupled plasma – mass spectrometry (LA–ICP–MS), a relatively non‐destructive technique with a sensitivity of parts per million to parts per billion. Data were interpreted using linear discriminant analysis (LDA), which allowed the coins of known provenance to be sorted into identifiable subgroups on the basis of their trace and minor elemental fingerprints, while 27 unidentified coins were compared with this database and their mint of origin predicted. These results have implications for the provenance determination of archaeological artefacts of many materials.     

A SPECTROSCOPIC INVESTIGATION OF PIGMENT AND CERAMIC SAMPLES FROM COPÁN,HONDURAS*

A combination of micro‐Raman spectroscopy, micro‐infrared spectroscopy and SEM–EDX was employed to characterize decorative pigments on Classic Maya ceramics from Copán, Honduras. Variation in red paint mixtures was correlated with changing ceramic types and improvements in process and firing techniques. We have confirmed the use of specular hematite on Coner ceramics by the difference in intensities of Raman bands. Different compositions of brown paint were correlated with imported and local wares. The carbon‐iron composition of the ceramic type, Surlo Brown, was confirmed. By combining micro‐Raman analysis with micro‐ATR infrared and SEM–EDX, we have achieved a more comprehensive characterization of the paint mixtures. These spectroscopic techniques can be used non‐destructively on raw samples as a rapid confirmation of ceramic type.     

A Roman Egyptian Painting Workshop: Technical Investigation of the Portraits from Tebtunis,Egypt

Roman‐period mummy portraits are considered to be ancient antecedents of modern portraiture. However, the techniques and materials used in their manufacture are not thoroughly understood. Analytical study of the pigments as well as the binding materials helps to address questions on what aspects of the painting practices originate from Pharaonic and/or Graeco‐Roman traditions, and can aid in determining the provenance of the raw materials from potential locations across the ancient Mediterranean and European worlds. Here, one of the largest assemblages of mummy portraits to remain intact since their excavation from the site of Tebtunis in Egypt was examined using multiple analytical techniques to address how they were made. The archaeological evidence suggests that these portraits were products of a single workshop and, correspondingly, they are found to be made using similar techniques and materials: wax‐based and lead white–rich paint combined with a variety of iron‐based pigments (including hematite, goethite and jarosite), as well as Egyptian blue, minium, indigo and madder lake to create subtle variations and tones.     

STONES FROM MEDIEVAL GLASSMAKING: A SUITABLE WASTE PRODUCT FOR RECONSTRUCTING AN EARLY STAGE OF THE MELTING PROCESS IN THE MT LECCO GLASS FACTORY*

The Mt Lecco glass factory was one of the most important production centres in Liguria (Italy) during the 14th and 15th centuries. Archaeological evidence indicates that the whole production cycle took place here. During the glassworking process, production defects such as ‘stones’ were identified and discarded. Stones are partially melted, glass‐coated relics of raw materials or fragments of crucible. The study of the microtexture of stones together with microprobe analyses of phases provides a key for understanding the glassmaking procedure carried out in the Mt Lecco glass factory. The melting rate can be inferred from the compositional variability of glass, which suggests fractional melting of the batch. Glass composition indicates that the Mt Lecco production was a mixed‐alkali one, probably made of quartz‐bearing material as vitrifying agents, plant ashes as fluxing agents and dolomitic limestones as stabilizing agents.     

Archaeometrical study of Khmer stoneware from the Angkorian period: Results from the Cerangkor Project

In the area around Angkor, Cambodia, several ceramics kilns dating from the ninth to 15th centuries ce have been discovered since 1995. The technical, typological and compositional characterization of their production has been one of the main goals of the Cerangkor Project. Samples of green‐glazed ‘Kulen‐type' stoneware and non‐glazed stoneware produced in five kiln sites in the Angkor region were analysed chemically by wavelength‐dispersive X‐ray fluorescence spectrometry (WDS‐XRF) and also petrographically. The data indicate that some workshops used similar raw materials for the same types of ceramics, suggesting the exploitation of the same geological formations in the whole region. Several references groups were established for each type of stoneware offering an important database for future provenance studies of sherds from consumption sites.     

FIELD AND LABORATORY MULTI‐TECHNIQUE ANALYSIS OF PIGMENTS AND ORGANIC PAINTING MEDIA FROM AN EGYPTIAN COFFIN (26TH DYNASTY)

This paper describes the physico‐chemical analyses performed on an Egyptian wood coffin on the occasion of its restoration in the hall of the National Archaeological Museum of Parma (Italy), with the aim of investigating the pigments and organic materials originally used. Pigment determination was performed both in situ by a portable energy‐dispersive X‐ray fluorescence (EDXRF) spectrometer and in the laboratory using a micro‐Fourier‐transform‐infrared (micro‐FTIR) and a Fourier‐transform (FT) Raman spectrometer. The identification of organic materials was performed through gas chromatography – mass spectrometry (GC–MS) and micro‐FTIR analysis. Amongst the pigments, special attention was paid to the green, which appeared to be severely degraded and was examined using powder X‐ray diffraction (XRD) and scanning electron microscopy – energy‐dispersive X‐ray (SEM–EDX) in addition to the above‐cited techniques. Other materials used in the polychromatic decorations are Egyptian blue, cinnabar and possibly orpiment, while calcium carbonate was used for the ground layer. The organic materials were identified as beeswax, mastic and gum arabic, sometimes as mixtures.     

PHYSICOCHEMICAL COMPOSITIONAL ANALYSIS OF CERAMICS: A CASE STUDY IN KENTING,TAIWAN*

The composition of ceramics does not just reflect the component of some specific, unprocessed, geological, raw material source, but also certain forms of human behaviour involved in its manufacture. The purpose of this research project is to apply the acid‐extraction chemical method, complemented by a thin‐section petrographic study, to the compositional analyses of certain local ceramic collections (mainly from several sites in the southern Taiwan area). The results present the raw materials that the ceramic manufacturers of the two cultural traditions (O‐laun‐pi Phase II and Phase III–IV), which overlapped temporally, used. These materials came from the same sources, but the ceramics were manufactured in different ways. Particularly, the people of O‐laun‐pi Phase III–IV also procured certain materials from either local sources or from somewhere in eastern Taiwan to make their pots. The results also indicate that there might have been a variation in terms of their manufacture among sites of the same cultural tradition.     

THE ANALYSIS OF SECOND MILLENNIUM GLASS FROM EGYPT AND MESOPOTAMIA,PART 1: NEW WDS ANALYSES*

A recent analytical study by SEM–WDS was carried out on 226 glasses from the Late Bronze Age, analysing each of the glasses for a total of at least 22 elements, the largest such analytical study conducted on these glasses. The aim of the analysis was first to identify which elements were brought in with each of the raw materials and, second, to accurately characterize those raw materials. Since different glassmaking sites in Egypt and the Near East would probably use at least some local raw materials and these raw materials will vary slightly from site to site, this has potential for provenancing the glass. Analysis showed new patterns in the compositions of glass from the various sites and led to new conclusions about the supply of raw materials and personnel for the glass workshops. This forms the basis for further work by LA–ICPMS to be presented in part 2 of this paper.     

Complex raw materials and the supply system: Mineralogical and geochemical study of the jade artefacts of the Longshan Culture (2400–2000 bce) from Sujiacun site in coastal Shandong,China

X‐ray fluorescence (XRF), X‐ray diffraction (XRD) and Raman spectroscopy were employed to analyse the chemical compositions and phase structures of nine pieces of jade artefacts unearthed from Sujiacun, a Longshan Culture (2400–2000 bce ) site in coastal Shandong, eastern China. The results of the analyses indicated these samples were primarily made from multiple raw mineral materials, including antigorite, actinolite, clinochlore, turquoise and muscovite. No nephrite was recovered from the Sujiacun site. This is strikingly different from other top‐ranking settlements of Longshan Culture, such as Dantu, Liangchengzhen and Xizhufeng, in which nephrite was the main material of jade artefacts. This may reflect the distinctions in the supply system of jade raw materials among different rankings of Longshan period sites. In addition, laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) was used to analyse the composition of the rare earth elements of serpentine jade. These preliminary results were compared with published data on the composition of serpentine jade and it was found that the Sujiacun serpentine jade artefacts were likely sourced from the Taishan jade deposit.