THE EMIGRATION OF PREALPINE LAKE MASTERS: A STUDY OF A 17TH‐CENTURY MANTELPIECE ATTRIBUTED TO THE CARLONE FAMILY OF ROVIO (TICINO,SWITZERLAND)*

This work illustrates the possible connections between the phenomenon of the seasonal emigration of lake masters and the production of artistic artefacts. Within the ambit of these dynamics, a stucco mantelpiece was taken into consideration. Nothing was known about the object: neither its origin, nor the artist who produced it, nor the period of execution. Historical, stylistic and formal analyses of the materials and of the technique with which the work was executed allow us to verify that the mantelpiece was produced using the stucco technique in the 17th century, in Rovio (southern Switzerland, Ticino), and that it comes from one of the exponents of the Carlone workshop, whose representatives were important in the tradition of itinerant artistic workers. Due to their good technical and professional specialization, the Carlone workshop served both public and private buyers. Tommaso Carlone is the principal representative artist of the Carlone workshop; it is certain that his workshop produced the stucco mantelpiece. The migrations of the artists were seasonal and they maintained a close bond with their country of origin. When they returned to the country of origin, they produced works of great artistic value, of which the mantelpiece represents a splendid example. Through the employment of conventional analytical techniques (optical and electron microscopy, infrared spectroscopy and porosity measurements), it has been possible to study the technique with which the work was executed, the materials used and the decay. The mantelpiece was produced using the stucco technique by means of a body layer (slaked lime and silicate and carbonate aggregates) and a marmorino finishing layer (slaked lime and pointed calcite crystals). Above this layer, whose thickness varies in relation to the executed result, there is a thin lime plaster whitewash, pigmented with the dispersion of yellow ochre particles; chromatic alterations are an oxalate patina caused by firm adhesion to the marmorino layer, due to the denaturation of the proteic substances employed. The final treatment was made with beeswax, which increased the marmoreal effect. Several additional layers of lime plaster whitewash have also been applied over the centuries. The figurative central square of the plastic decoration was made using red ochre.     

GILDINGS AND FALSE GILDINGS OF THE BAROQUE AGE: CHARACTERIZATION AND CONSERVATION PROBLEMS

This work investigates the decayed decoration of the ‘Vergine del Carmelo’ chapel, with a particular interest in the residual gildings. Samples of the finishing layers were examined by VIS‐UV optical microscopy and scanning electron microscopy coupled with EDX spectrometry, in order to evaluate the unusual degradation phenomena. Mineralogical composition of the stucco substrate was characterized by X‐ray diffraction (XRD) and FTIR spectroscopy. The results showed the unexpected presence of a thick layer of brass flakes, applied without any binder, used as a substitute for the damaged original gold leaf, and highlighting a very uncommon selective corrosion process of the brass.     

Raman microprobe analysis of stucco samples from the buildings of Maya Classic Copan

Micro-Raman spectroscopy has been applied to painted stucco samples from three buildings at the Maya site of Copan, Honduras. The buildings, Clavel (AD 450–550), Ani (AD550–650) and Structure 10L-22 (AD730,) date from three phases of the Classic Period (AD400–820) acropolis construction. The red pigment has been identified as haematite and the stucco as a mixture of calcite particles dispersed throughout a calcite based lime wash stucco. The physical structure of the stucco changed through time, indicating a refining of production techniques over this period. By combining Micro-Raman spectroscopy with other micro-ATR infrared spectroscopy and environmental scanning electron microscopy a detailed investigation of the materials and production techniques used to decorate these buildings has been made. Differences in the mineralogy of the red pigment used on each building indicate a different geological pigment source for each period.     

PROVENANCE OF OBSIDIAN EXCAVATED FROM LATE CHALCOLITHIC LEVELS AT THE SITES OF TELL HAMOUKAR AND TELL BRAK,SYRIA*

X‐ray fluorescence and laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) analyses conducted on 40 obsidian samples from the Late Chalcolithic 2 levels at Tell Hamoukar and Tell Brak in north‐east Syria have shown trends towards the exploitation of obsidian sources in the eastern Taurus. While the Bingöl region appears to provide the majority of obsidian to both sites, there is also evidence of more minor exploitation of a source in the Lake Van area and an altogether unknown source (X). This paper presents the data acquired from the analyses of the archaeological obsidian and situates these results within their chronological and regional contexts.     

COOKING AND PAINTED WARE FROM SAN GIUSTO (LUCERA,FOGGIA): THE PRODUCTION CYCLE,FROM THE SUPPLY OF RAW MATERIALS TO THE COMMERCIALIZATION OF PRODUCTS*

Archaeological excavation at the San Giusto site (Lucera, Italy) has unearthed a Late Antique kiln that was most certainly dedicated to the production of cooking ware. An archaeometric study of numerous specimens of cooking and painted ware found at this site was carried out using optical microscopy, scanning electron microscopy, micro‐Raman spectroscopy, X‐ray diffraction, X‐ray fluorescence, inductively coupled plasma mass and optical emission spectrometry and instrumental neutron activation analysis. The integration of historical–archaeological data with archaeometric data has revealed that these specimens can be attributed to the San Giusto site. Furthermore, the production cycle of this ware can thus be reconstructed: from the diversified supply of raw materials (fluvial and marine sediments), to the relatively complex preparation of the paste, to firing at variable temperatures (600–750°C for cooking ware; 850–1050°C for painted ware).     

Early Islamic pigments at Nishapur,north-eastern Iran: studies on the painted fragments preserved at The Metropolitan Museum of Art

Pigments appearing on ninth–twelfth-century AD-carved stucco, wall painting, and terracotta friezes excavated at Nishapur in north-eastern Iran were investigated by optical reflectance spectroscopy, micro X-ray fluorescence spectrometry (μ-XRF), X-ray diffractometry (XRD), micro-Raman spectroscopy (μ-Raman), and scanning electron microscopy (SEM). Many of the pigments identified including vermilion, red lead, hematite, limonite, carbon black, atacamite, calcite, and gypsum have been identified in previous studies of pigments used in later Islamic periods. However, a series of unusual pigments such as wulfenite, pyromorphite, phoenicochroite, and jarosite were also found in the present study. The association of kaolinite and alunite with limonite and other Fe-bearing yellow pigments points to a local provenance for these pigments. In addition, the presence of orpiment in the vermilion may be indicative that the vermilion was artificially manufactured. These findings suggest that pigment use and manufacturing during the ninth to eleventh centuries in Nishapur was still in a trial-and-error stage and the palette known from the twelfth century onwards had not yet been systematized.     

ANALYSIS OF ROMAN WALL PAINTINGS FROM THE THERMAE OF ‘IULIA CONCORDIA’

Twenty‐six wall painting fragments and some plaster, ‘intonachino’ and stucco samples, discovered at Iulia Concordia, have been studied by different analytical techniques to gain information about the pigment nature and the composition of the materials. The presence of calcite, dolomite and aragonite allow the distinction of four groups of wall samples varying in the nature of pigments and in the application technique. These differences can be attributed to different execution times or, more probably, to the arrangement of the rooms in the building structure. The nature of the pigments found in the Thermae of Iulia Concordia appears similar to that found in other Roman villas of Venetia et Histria, with the use of precious pigments such as Egyptian blue and cinnabar.     

CHEMICAL AND PHYSICAL CHARACTERIZATION OF STUCCOS FROM A MEXICAN COLONIAL BUILDING: EL MUSEO DEL CALENDARIO OF QUERETARO*

Restoration requires the use of appropriate characterization methods and suitable new material preparation processes permit the reproduction of the original material to be as similar as possible in order to be an appropriate application method. The combination of these factors will facilitate a good restoration process. Different stuccos were taken from El Museo del Calendario, a building located in Querétaro, Mexico which was built in the 16th century. All the stucco samples were studied using the characterization process which is proposed in this article. The characterization method consisted of the use of analytical techniques, such as X‐ray diffraction, Fourier transform infrared and scanning electron microscopy. This characterization method made reproduction of the original material possible. The new material combined with new application techniques developed in situ will result in a high‐quality restoration process.     

LA–ICP–MS,SEM–EDS AND EPMA ANALYSIS OF EASTERN NORTH AMERICAN COPPER‐BASED ARTEFACTS: IMPACT OF CORROSION AND HETEROGENEITY ON THE RELIABILITY OF THE LA–ICP–MS COMPOSITIONAL RESULTS*

This study discusses the relevance of compositions obtained using laser ablation – inductively coupled plasma – mass spectrometry (LA–ICP–MS) for the purpose of identifying the provenance of copper‐based artefacts found in Virginia at Native American sites dated from the 16th to the 18th centuries. Ten artefacts were investigated by scanning electron microscopy – energy dispersive spectrometry (SEM–EDS) to visualize the corrosion and characterize the heterogeneities in the metal and electron probe micro‐analysis (EPMA) to determine separately the compositions of the intact metal and of the corrosion product. It is shown that the corroded surfaces are highly depleted in zinc but that representative concentrations can be determined by sampling the deeper, uncorroded metal. In contrast, lead values are highly variable because of the heterogeneous distribution of this metal within the bulk copper. Despite these problems, brass is easily identifiable and American native copper and European smelted copper can be unambiguously distinguished with LA–ICP–MS on unprepared artefacts using As, Ag, Ni and Sb trace elements.     

基于地理学视角的中国山水画分析

本文从美术地理学的角度出发阐述了中国山水画的地域差别,指出地理环境对山水画的影响主要表现在几方面:即对山水画作品面貌的影响,对山水画家创作灵感的影响,对作品风格和地域特色的影响,对山水画派和地域人才形成的影响。因而,地理环境是艺术家创作的对象和源泉,也是决定美术风格的关键因素,对山水画派和地域人才的形成具有重要影响。     

GEOCHEMICAL ANALYSIS OF VITREOUS ROCKS EXPLOITED DURING THE FORMATIVE PERIOD IN THE ATACAMA REGION,NORTHERN CHILE*

Petrographic analysis and geochemical characterization studies were carried out on vitreous dacite and/or rhyodacite artefacts from Formative period archaeological sites in the upper Salado River Basin in the Atacama Desert, northern Chile. These were compared with samples taken from two source areas located within the subregion, named Linzor and Paniri. Source samples and archaeological specimens were analysed by inductively coupled plasma – mass spectrometry (ICP–MS) combined with optical emission plasma – mass spectrometry (ICP–OES) and atomic absorption spectroscopy (AAS). Results from the limited number of samples analysed indicate that the Linzor source seems to have been the primary source exploited during the Early and Late Formative periods in the Salado River Basin.     

CHANGES IN THE METAL CONTENT OF HUMAN HAIR DURING DIAGENESIS FROM 500 YEARS,EXPOSURE TO GLACIAL AND AQUEOUS ENVIRONMENTS

Scanning electron microscopy, inductively coupled plasma mass spectroscopy and time‐of‐flight secondary ion mass spectrometry have been used to examine the extent and possible mechanisms by which the metal content of human hair is altered by exposure to aqueous environments. The results, using both modern hair and samples from 500‐year‐old hair associated with glacier‐entombed remains, show that the metal content has been altered sufficiently so that the interpretation of the metal signature in terms of diet or disease is problematic. While endogenous information is difficult to glean from these data, interesting observations have been made of possible early stages of mineral authigenic deposition. The chemistry of the outer hair surface was found to be consistent with deposition of Fe and Al silicates, as well as other mineral phases. The ancient hair was analysed at the root region and included a comparison of the internal versus external composition to assist in identifying the diagenetic processes.     

A MULTI‐ANALYTICAL APPROACH FOR THE CHARACTERIZATION OF COMMODITIES IN A CERAMIC JAR FROM ANTINOE (EGYPT)*

This paper describes a multi‐analytical chemical study performed on the original, almost totally conserved, content of a small ceramic jar from the Antinoe archaeological site (fifth to seventh centuries ad, Roman Egypt) and now belonging to the archaeological collection of the Istituto Papirologico ‘Girolamo Vitelli’ (Florence, Italy). Scanning electron microscopy with an energy‐dispersive X‐ray spectrometer (SEM–EDX), Fourier transformed infrared spectroscopy (FTIR) and X‐ray diffraction (XRD) were all used to characterize the inorganic components of the archaeological material. The organic substances were analysed using FTIR, direct exposure mass spectrometry (DE–MS) and gas chromatography – mass spectrometry (GC–MS). The inorganic component essentially consisted of halite (NaCl). Among the NaCl crystals, lamellar elements were identified. They were chemically characterized by carbonato‐apatite and showed a concentric morphology typical of the scales of small fish. The most prevalent organic constituents of the sample were monocarboxylic acids, α,ω‐dicarboxylic acids, and cholesterol and its oxidation products. The organic material composition was consistent with the occurrence of lipids of animal origin. In addition, diterpenes related to pine pitch were also identified. The overall results suggest that the material recovered in the small ceramic jar found in Antinoe is a residue of fish‐based pickles such as garum, muria, allex and liquamen, which were commonly used in Roman times.     

THE SEARCH FOR THE ORIGIN OF BITUMEN EXCAVATED FROM ARCHAEOLOGICAL SITES IN THE NORTHERNMOST ISLAND IN JAPAN BY MEANS OF STATISTICAL ANALYSIS OF FI–MS DATA*

The origin of bitumen excavated from archaeological sites in Hokkaido, the northernmost island in Japan, was sought by means of field‐ionization mass spectrometry (FI–MS) and gas chromatography – mass spectrometry (GC–MS) of the hydrocarbon components. The field‐ionization mass spectra were decomposed by Z‐numbers into several components, where the Z‐number refers to z in the formula C _n H _2n+z . This is equivalent to the deficit number of H atoms, when compared to the corresponding saturated hydrocarbon, which is related to the number of saturated hydrocarbon rings in alkanes. By use of the spectral intensities of the seven alkane components in each sample, multiple discriminant analysis was employed for the data of raw bitumen samples and excavated samples from archaeological sites. Based on this method and the gas chromatogram type, the following bitumen trade in the prehistoric age of Japan was elucidated: bitumen from Niigata, one of the main sources on the main island of Japan, spread to the north in 2000 bc , probably via the coastal zone, and reached a small island near the north end of Hokkaido. Bitumen from Sakhalin reached the central lowland in Hokkaido, but it went no further. Bitumen from Akita, another main source on the main island, spread over northern Honshu much earlier and reached the Oshima peninsula, the southwestern part of Hokkaido. The Akita bitumen scattered into the central lowland after the Niigata and Sakhalin bitumen. This area is believed to be the place where people from the south and the north met in those periods.     

COMPLEMENTARY COMPOSITIONAL ANALYSIS OF FORMATIVE PERIOD CERAMICS FROM THE TEOTIHUACAN VALLEY

During the Classic Period, Teotihuacan was an economic centre of central Mexico, but little is known about the development of this system. This paper presents a pilot study in multi‐method analysis of Formative Period (1500/1400 bc –ad 150) ceramics from the Teotihuacan Valley. Pottery was characterized by instrumental neutron activation analysis, laser ablation inductively coupled plasma mass spectrometry, thermal ionization mass spectrometry and petrography. It appears that most pottery was made from local raw materials that differ from later Postclassic materials. Some inter‐village interaction is suggested by stylistic choices, and one settlement had a group of ceramics made from unequivocally distinct raw materials. The study demonstrates how complementary methods can be used to draw greater anthropological meaning from compositional differences.     

ANALYSIS OF NASRID POLYCHROME CARPENTRY AT THE HALL OF THE MEXUAR PALACE,ALHAMBRA COMPLEX (GRANADA,SPAIN), COMBINING MICROSCOPIC,CHROMATOGRAPHIC AND SPECTROSCOPIC METHODS*†

The pigments, binders and execution techniques used by the Nasrids (1238–1492) to polychrome carpentry in the Hall of the Mexuar Palace at the Alhambra (Granada, Spain) were studied using optical microscopy, scanning electron microscopy with EDX analysis, selective staining techniques and gas chromatography – mass spectrometry. This pioneering investigation presents the first results of a research project devoted to filling gaps in the knowledge of Nasrid art, traditionally approached by stylistic studies. Moreover, it is essential for the polychromy conservation of the studied artworks, and will help to clarify historical and painting uncertainties in the Alhambra monument. The palette consists of a limited range of colours: white (lead‐base pigment), red (cinnabar and red lead), blue (lapis lazuli), black (carbon‐based) and false gold (golden tin). Tempera grassa was the painting technique identified. Two types of grounds were used: (i) gypsum in calligraphy decoration for the false gold technique, and (ii) synthetic minium in geometric drawings in carpentry. Organic insulating layers of linseed oil were used between paint strata. Artists applied synthetic minium to protect the wood (Juglans regia and conifer) against attack by xylophages. To lighten the surface darkened by this ground layer, powdered tin was added to achieve a metallic lustre.     

AN EVALUATION OF ANALYTICAL AND INTERPRETATIVE METHODOLOGIES FOR THE EXTRACTION AND IDENTIFICATION OF LIPIDS ASSOCIATED WITH POTTERY SHERDS FROM THE SITE OF SAGALASSOS,TURKEY*

Three lipid analysis methods were applied to extracts of archaeological potsherds from the ancient city of Sagalassos, south‐west Turkey. In the fatty acid methyl ester fraction, obtained by selective transesterification of acylglycerols, the ratio of methyl palmitate to methyl stearate was determined. Secondly, by means of gas chromatography– combustion–isotope ratio mass spectrometry (GC–C–IRMS), stable carbon isotope ratios were measured for the same methyl esters. Finally, triglyceride composition was determined via high‐performance liquid chromatography–mass spectrometry (HPLC–MS). All three methods can be used to trace the origin of animal fat. Agreement between them is reasonable, especially in recognizing ruminant adipose fat. One sample was found to be of dairy origin using both GC–C–IRMS and HPLC–MS. The advantages of the various methods are discussed. Variations in lipid composition were observed between samples from different periods and excavated in diverse areas within the city of Sagalassos.     

RECONSTRUCTING ANCIENT YEMENI COMMERCIAL ROUTES DURING THE MIDDLE AGES USING STRUCTURAL CHARACTERIZATION OF TERPENOID RESINS*

Following the discovery of items that look like resins at the medieval site of Sharma (Hadramawt coast, Yemen, c. 11th century ad ), chemical investigations were carried out in order to determine their nature and geographic origin. By combining visual observation, infrared spectroscopy, direct inlet electron ionization – mass spectrometry (DI EI–MS) and pyrolysis gas chromatography – mass spectrometry (Py GC–MS) or gas chromatography – mass spectrometry (GC–MS) analyses, it was demonstrated that 84% of the samples were harvested from Hymenaea trees growing in Madagascar and East Africa. Contrary to what was thought previously, frankincense, identified with certainty in only two samples, was thus not the main resin exploited at Sharma. These results are of prime importance for reconsidering the trading routes of resins passing through Sharma, a site that was obviously strongly connected with Africa during the Middle Ages.     

THE CHARACTERIZATION OF PAINTS AND WATERPROOFING MATERIALS FROM THE SHIPWRECKS FOUND AT THE ARCHAEOLOGICAL SITE OF THE ETRUSCAN AND ROMAN HARBOUR OF PISA (ITALY)*

This work presents the results of a diagnostic survey on the shipwrecks from the archaeological site of the ancient harbour of San Rossore (Pisa, Italy). The original waterproofing, caulking and painting materials were characterized by Fourier transform infrared spectroscopy (FTIR), gas chromatography – mass spectrometry (GC–MS), energy‐dispersive X‐ray microanalysis (EDX) and X‐ray diffraction (XRD). The major constituents of the waterproofing and caulking materials detected on the planks were tricyclic abietanes showing a high degree of aromatization. These compounds are indicative of a pitch obtained from the wood of trees of the Pinaceae family. The analysis of the organic components of the paint samples revealed diterpenoid acids characteristic of Pinaceae resins together with linear long‐chain alcohols and fatty acids, highlighting the presence of beeswax. Noticeably, the characteristic odd carbon number alkanes that are normally present in beeswax were not detected. The EDX and XRD analyses showed that hematite, calcite, cerussite and kaolinite were employed as pigments to paint the ships’ hulls.     

BAYESIAN MODELING OF THE OCCUPATION SPAN OF THE AVERBUCH SITE IN THE MIDDLE CUMBERLAND DRAINAGE,TENNESSEE

Abstract

The application of Bayesian models to suites of radiocarbon dates can provide important refinements over standard approaches toward calibration and seriation of dated feature contexts. We have modeled a number of older radiocarbon dates submitted in the 1980s along with a recent set of accelerator mass spectrometry dates from the Averbuch site (40DV60), a Mississippian village in the Middle Cumberland Region of Tennessee occupied in the fourteenth and fifteenth centuries A.D. The results of these analyses demonstrate that even within its short lifespan of ca. 200 years, the village underwent fundamental organizational changes. These shifts appear to be responses to climatic deterioration and an upsurge in regional violence.