The forest or the trees? Behavioral and methodological considerations for geochemical characterization of heavily-tempered ceramic pastes using NAA and LA-ICP-MS

In this paper, the utility of LA-ICP-MS for instrumentally separating clay and temper within pottery samples is examined through a well-known case study that has been previously characterized through NAA and petrography. Coarse Orange pottery is composed of kaolinitic clays heavily tempered within volcanic ash from the basalt-rich Tuxtla Mountains of southern Veracruz, Mexico. We attempt to address the following topics with analyses on this pottery: 1) can LA-ICP-MS replicate the same groups previously identified by NAA and petrography; 2) can instrumental isolation of the clay fraction within the pottery replicate known patterns in raw clay source geochemistry in the Tuxtla Mountains; 3) can data for both the clay and volcanic ash fractions of each pottery sherd be combined to simulate the bulk INAA data? The results demonstrate that the clay fraction of the pottery sherds can be isolated. Furthermore, the LA-ICP-MS data for the clay fractions display nearly identical chemistry to available NAA data for raw clay samples collected from geological contexts in the region. Instrumentally isolating the clay fraction in this case eliminates the homogenizing effects of adding a common temper and increases the chemical separation among groups making it easier to identify clay procurement strategies for each specimen. However, focusing only on the clay fraction ignores significant tempering variation. Attempts to simulate the bulk NAA by combining LA-ICP-MS data for clays and temper was reasonably successful in reestablishing the tempering variation lost by exclusive focus on clays, but such an approach could not replace the more precise data generated from NAA and petrography.     

A NEW METHOD FOR EXTRACTION,ISOLATION AND TRANSESTERIFICATION OF FREE FATTY ACIDS FROM ARCHAEOLOGICAL POTTERY

This paper presents evidence for increased recovery of organic residues from archaeological pottery through use of a microwave‐assisted liquid chromatography protocol. C_16:0 and C_18:0 saturated fatty acids were obtained from archaeological potsherds recovered from nine Neolithic settlements in the Middle East dating between 4700 and 7300 cal bc , including materials that had not produced evidence for the survival of any lipid species through use of ‘conventional’ solvent extraction techniques. Compound‐specific isotopic analyses of C_16:0 and C_18:0 fatty acids in potsherd extracts subsequently revealed δ¹³C/δ¹²C compositions consistent with modern subcutaneous fats of wild boar and goats pastured on lands adjacent to the Jordan Valley, and residues from a modern pottery vessel used in the manufacturing of butter, cheese and yogurt in central Turkey. These results are presented as an illustration of capabilities of the microwave‐assisted recovery protocol. The reclamation of saturated and unsaturated fatty acids from archaeological pottery fragments recovered from a number of the earliest ceramic horizons in the Middle East is herewith reported, and the extraction methods and instrumental analytical techniques are described.     

Radiocarbon pottery dating: the chemical compounds of organic fractions, the reliability of 14C dates (preliminary results)

In recent times, a large number of radiocarbon dates appeared for the Southern Neolithic on the basis of pottery dating because other organic matter has practically not been preserved. There are two organic fractions of pottery useful for dating: food residues and carbon from the pottery matrix itself. Food residues are often dated, but this material is not always preserved and is prone to being removed during the cleaning of the pottery. The clay mass of the pottery contains carbon, often directly visible upon breaking of the pottery. The article focusses on determining the chemical composition of the organic fractions in the pottery and the origin of the carbon. For this aim we used the nuclear magnetic resonance (NMR) method to identify the chemical compounds in the food residue and in the pottery matrix. As an example we used pottery from the Neolithic sites: Zamost??e (Central Russia) and the Varfolomeevskay sites (Southern European Russia, Low Volga region) from archaeological collections. The results obtained demonstrate that the food residue and the pottery matrix contain practically the same organic compounds, even if the relative abundances of various compounds are different in these materials. The origin of the carbon from pottery is discussed.     

Ceramic production,consumption and exchange in the Banda area,Ghana: Insights from compositional analyses

Ceramic production, exchange and consumption in the Banda area, west central Ghana has been affected by historical developments ranging from recent competition with alternative vessels (made of metal and plastic) to political economic upheavals that altered community relationships within and outside the region. In this study, we explore spatial and temporal patterning in pottery production, exchange and consumption using a combination of analytical techniques. Instrumental neutron activation analysis (INAA) of a large sample (491 specimens) of archaeological and ethnographic pottery, clay and temper samples from sites across the Banda area has led to the identification of seven compositional groups whose differential distribution implies shifts in resource selection through the last thousand years. Laser ablation-ICP-MS analysis was used to explore the effects of distinctive tempering agents (crushed slag) on the bulk chemical signature of a subset of Banda ceramics, while petrographic analysis provides insight into the preparation of ceramic fabrics. We integrate insights from these diverse physical studies to investigate the dynamics of pottery production, exchange and consumption over the course of the last millennium in the Banda area and explore potential linkages with broader political economic transformations.     

Archaeometric study of medieval pottery excavated at Stari (Old) Ras,Serbia

A combined study of a series of polychromatic and monochromatic glazed medieval pottery shards excavated from the archaeological area of Stari (Old) Ras in southern Serbia, including petrographic and chemical analysis, powder X-ray diffraction (PXRD) and Fourier transform infrared (FTIR) spectroscopy, allowed us to clearly distinguish between two groups of ceramics. Ras pottery, made of fine-grained well-cleaned clay and characterised by a rich mineral assemblage, was produced by firing in a temperature range between 800 and 900 °C. Reljina Gradina ceramics were produced at similar temperatures from materials which, with regard to mineralogical and chemical composition, show clear similarity with local clay, suggesting that these samples are of local origin and production. This work is the first systematic archaeometric study of medieval pottery excavated on the territory of Serbia.     

Attempts at thermoluminescence dating of fired materials from the Przeworsk Culture settlements

The thermoluminescence (TL) dating method has a significant measurement error margin reaching almost 10%. Due to this fact it could be considered as little effective in case of such sites from the Roman period as burial grounds with many artefacts useful for archaeological dating. However, for many settlements from this period, where pottery is the only kind of artefacts, the TL method can give notable results. The main purpose of the study was to make an attempt at TL dating of pottery and clay daub samples from the Nieszawa Kolonia and Kręcieszki sites and to compare the obtained dates with the results of archaeological dating of selected features from the Przeworsk Culture settlements. In the Kręcieszki site the fragments of burnt clay daub were dated by the TL method for the first time in the Lublin laboratory. It turned out that clay daub is an equally good dating material as pottery. It can be found that the TL dating of pottery from Nieszawa Kolonia confirms two stages of settlement. The first settlement stage is related to the phases B2-B2/C1-C1a of the Roman period, i.e. from the beginning of the 2^nd to the beginning of the 3^rd century. The second group of TL dates corresponds to the phases C2D that is to the second stage of settlement, from the second half of the 3^rd century to the half of the 5^th century AD. The results of TL dating of pottery and clay daub in the Kręcieszki site are rather similar and correspond to the phase B1/B2 of the period of Roman influence, determined from pottery style, but can also indicate the phase B2/C1.     

Pottery Production, Distribution, and Consumption—The Contribution of the Physical Sciences

The study of the life cycle of pottery, from the selection of raw materials and the production stage through distribution and use to ultimate discard, can make a valuable contribution to archaeological research. The aim of the present paper is to provide a summary and critical assessment of the particular contribution of the physical sciences to the reconstruction and interpretation of this life cycle, in large part through the presentation of selected case studies. The topics covered include the reconstruction of the technology used in pottery production, through a combination of microscopy, radiography, and chemical analysis; the investigation of the extent of craft specialization and the organization of pottery production; the reconstruction of pottery distribution from its production center, using thin-section petrography and chemical analysis, and the interpretation of these data in terms of exchange and trade; the reconstruction of the consumption stage or uses to which pottery was put, from the study of surface wear, organic residues, and performance characteristics; and a discussion of the reasons for the introduction of pottery and for the different technological choices made in pottery production. Throughout, the importance of considering the overall environmental, technological, economic, sociopolitical, cultural–ideological and historical context in which the pottery was produced, distributed, and consumed is emphasized. The paper is concerned, almost-exclusively, with unglazed earthenware spanning prehistory through to circa 1500 AD.     

Gabbroic clay sources in Cornwall: a petrographic study of prehistoric pottery and clay samples

Summary.  This analysis of prehistoric pottery and clay samples from Cornwall demonstrates that the clay used to make Cornish gabbroic pottery in prehistory originated around the gabbro rock outcrop in a small area of the Lizard peninsula. The research uses petrographic and chemical analysis to subdivide the prehistoric pottery into six groups. Owing to the unusual geology of the Lizard these groups can be attributed to specific locations. The most abundant pottery fabric, Typical Gabbroic , was made using coarse clay which is mainly found in a 1 km² area near Zoar. A finer version of this clay, found higher in the soil profile or slightly transported and redeposited, was used to make Fine Gabbroic pottery and an even finer variant called FNS (Fine Non-Sandy) Gabbroic . We identify for the first time here a Loessic/Gabbroic pottery fabric which can be matched exactly to clay found at Lowland Point. Serpentinitic/Gabbroic pottery was made using clay from the gabbro/serpentinite border zone. Pottery made from the Granitic/Gabbroic fabric did not match any clay from the Lizard, showing that gabbroic clay was sometimes removed and made into pottery elsewhere in Cornwall. The main clay source near Zoar was used for clay extraction throughout the Bronze Age and Iron Age for pottery which was traded all over Cornwall. Other gabbroic clay sources produced pottery only during certain periods and exclusively supplied particular settlements, such as the Loessic/Gabbroic fabric which was found only at Gear and Caer Vallack. The results suggest that pottery was produced by several small-scale cottage industries, which may have operated on a seasonal, part-time basis and probably formed only part of a wide range of activities located around the Lizard area.     

北周墓出土彩绘陶器的加固与保护

陕西省考古研究所在西安咸阳国际机场二期建设中抢救性发掘了三座大型高等级北周时期墓葬,出土了数百件精美彩陶俑,形象十分逼真生动。由于彩陶器出土提取于淤泥之中,为了及时有效的保护好这批文物,考古队在第一时间内将出土陶器全部运回所内文保室进行抢救性保护。此次保护的主要任务和难点是,在最佳时间实现土层与彩绘层的成功分离,逐渐降低饱水彩陶器的含水率,使其最终在大气中趋于稳定,最后及时加固和封护彩绘层并采用适合该陶质强度的粘接剂进行粘接复原。经过十年来的时间证明,此次实施的保护方案正确,保护措施得当,保护结果令人满意。     

Evidence of Iberian Bronze Age ‘Boquique’ Pottery in the Balearic Islands: Trade,Marriage or Culture?

Summary.   This paper deals with the recent discovery of Iberian 'Boquique' Bronze Age pottery on the Balearic Island of Mallorca. It marks the 'maritime' spread of this distinctive pottery into a geographic area not previously recorded. It should therefore be of particular interest to mainland investigators and others concerned with its geographical distribution as well as those dealing with long-distance trade and possible kinship links during the period. The find is further supported by the 'micaceous' and 'quartz' composition of the pottery clay fabric, since mica is not known on the island as a component of local clays. The presence of Boquique pottery with 'micaceous' clay properties is demonstrated by microphotographic slab and thin sections as well as chemical clay analysis. This suggests that the pottery was imported, either as a trade item or as personal possessions.
Along with recent evidence of earlier trade in exotic 'elephant' ivory and other items during Bell Beaker times, where the Boquique pottery appears to be a late intrusive element into local Beaker contexts ( Waldren 1998 ), this new evidence represents the first material sign of cultural maritime interaction (Boquique in the present case), either as demographic extension or commercial exchange of these cultural items into the area.
Furthermore, contextual radiocarbon dating surveys strongly indicate a date of 1700–1400 BC for the pottery, in accord both with recent Iberian mainland dates as well as the local archaeological sequence in which it was found.     

DETERMINING POTTERY PROVENANCE: APPLICATION OF A NEW HIGH-PRECISION X-RAY FLUORESCENCE METHOD AND COMPARISON WITH INSTRUMENTAL NEUTRON ACTIVATION ANALYSIS*

A recently developed high-precision X-ray fluorescence (XRF) method, applied for the first time to the study of archaeological pottery, determines the abundances of 13 trace and four major elements from one X-ray spectrum acquired over a 1000 second counting interval. For replicate archaeological samples, the short-term and long-term measurement precisions were close to 1% for the ten elements measured with highest precision. These are comparable to the best results achieved on replicates of clay and pottery standards, and obsidian, using instrumental neutron activation analysis (INAA). High-precision XRF analysis, however, does not require a nuclear facility, and is markedly preferable to INAA in terms of the ease of both sample preparation and analytical procedure. Consequently, element abundance data can usually be provided by a single analyst within a few hours after the start of sample preparation. The accuracy of the method, determined by comparison with data of other workers on eight standard reference materials, averaged 2.4% for the ten best-agreeing elements. The effectiveness of the method for determining pottery provenance is demonstrated for a difficult problem, in which high-precision XRF analysis successfully distinguished the products of two nearby pottery manufacturers in Roman Galilee (Shikhin and Nahif) that had not been clearly differentiated by INAA. The greater effectiveness of high-precision XRF than INAA in this provenance study is a result of the different array of elements measured, and the higher precision obtained for certain elements, by XRF. These results suggest that high precision XRF has potential broad applicability for pottery provenance studies.     

The Latest Objects from Silchester,Hants

THIS paper brings together for the first time a selection of medieval glass and pottery distilling-vessels from British sites. A discussion on the technical aspects of distilling by F. Greenaway (Part I) is followed by a report on two important groups of glass and pottery distilling-apparatus from Selborne and Pontefract priories of the middle and late 15th century respectively (Part II). Part III discusses pottery distilling-vessels from other finds in Britain. Two types of pottery alembic are distinguished and their use in association with bases of either furnace or bowl type is suggested; industrial bottles connected with distilling are also briefly considered. The survey has brought much information to light but has also left many problems unanswered. Coordination of documentary research into techniques, archaeological recognition of vessels, and the chemical analysis of residues is necessary before firm decisions can be made about the uses of the vessels and the types of unit required for specific operations. It is hoped that this paper will stimulate further work in this field.     

Fiat Lux: Functional Analysis of Three Saxo-Norman Pottery Lamps from Berkeley,Gloucestershire

THIS PAPER COMPRISES analysis of three Saxo-Norman pottery lamps recovered during archaeological excavations in 2012 in the Edward Jenner Museum garden, Berkeley, Gloucestershire. While such vessels have been known to archaeologists since the earliest days of Saxon and medieval pottery studies, their specific function, other than general ‘lighting’, has never been considered. Similarly, the composition of the fuel in such lamps has not been scientifically verified. In the following paper, both of these areas are addressed through experimental archaeology and organic residue analysis. The conclusion reached is that the lamps were chosen for use in a late-Saxon industrial workshop as they were ideal for the setting, providing a consistent, stable and bright light source in comparison with other available lighting methods of the period.     

Can the Raman spectrum of anatase in artwork and archaeology be used for dating purposes? Identification by Raman microscopy of anatase in decorative coatings on Neolithic (Yangshao) pottery from Henan,China

Scanning electron microscopy/energy dispersive X-ray analysis has earlier shown that the white background layer (slip) on painted pottery sherds (Yangshao culture, Henan, China, 4200 BC) is composed of kaolinitic clay containing titanium in the assumed form of TiO₂ at just 1 wt%. The same samples of white slip have now been studied by Raman microscopy, revealing bands characteristic of anatase, but none from the majority species, the matrix of kaolinitic clay. These results highlight the extraordinarily intense Raman scattering from even trace amounts of anatase and thus the need to recognise that, although the colours of archaeological artefacts are almost always determined by the nature of the matrix, the Raman spectrum may be determined by a highly scattering trace component such as anatase. The significance of anatase as a potential date-marker pigment on works of art and archaeological artefacts is discussed.     

De-mystifying Pottery Production in the Maya Lowlands: Detection of Traces of Use-Wear on Pottery Sherds through Microscopic Analysis and Experimental Replication

During the Late Classic period at the site of K'axob in Belize, Central America, inhabitants recycled ceramic fragments as tools for the making of pottery. Considering pottery as a tool is by no means an easy task and requires, for its study, significant methodological innovation. The K'axob pottery tools demanded a comprehensive study to determine their use and function within this widespread economic activity. Research presented here incorporated fabrication of replicas of archaeological pottery tools and their experimental use for the making of ceramic vessels. Combined microscopic analysis of archaeological and fabricated tools defined and reproduced wear traces from use activities. Therefore, this investigation entails a methodological innovation to archaeology, yielding a broader perspective into prehistoric technologies.     

Chemical and Petrographic Analysis of Pre‐Hispanic Pottery from the Southern Abaucán Valley,Catamarca, Argentina

Neutron activation (NAA) and petrographic analyses were carried out on Late and Inca Period pottery from 15 archaeological sites and several clay samples in the southern Abaucán Valley, Catamarca, Argentina. The results from the NAA and petrographic analyses provide new data concerning local versus non‐local pottery production and vessel exchange for these two pre‐Hispanic cultural periods. The chemical data demonstrate the use of different clay sources over time until the Inca appearance in the region, when a more structured and controlled production is observed. Petrographic analyses show a similar change in the ceramic paste recipes used by ancient potters.     

Preliminary Characterization of Pottery by Cathodoluminescence and SEM–EDX Analyses: An Example from the Yeha Region (Ethiopia)

Yeha was a political and cultural centre of the Ethio‐Sabaean culture (D’MT) in northern Ethiopia and southern Eritrea. Part of the archaeological research deals with pottery of local, regional and imported origin. The research—investigations and examinations—tries to classify local pottery in two ways: first, by analysing the mineralogy of the temper using light microscopy and cathodoluminescence; and, second, by analysing the main element composition of the clay matrix using a scanning electron microscope with energy‐dispersive X‐ray detection (SEM–EDX). The cathodoluminescence shows that the temper material has differences in the colours of feldspars with a similar mineralogical composition. The results demonstrate that the pottery was produced by using local material that originates from various sources in the Yeha region and that the same raw materials were used in different types of pottery.     

CHALLENGES IN THE ANALYSIS OF HETEROGENEOUS POTTERY BY LA–ICP–MS: A COMPARISON WITH INAA*

Tempers added to pottery have the potential to obscure geographical variation in the chemistry of exploited clay resources when analysed using bulk methods. A pilot study was conducted to assess the possibility of using LA–ICP–MS to analyse clay matrix in pottery with extremely subtle partitions between INAA chemical groups. LA–ICP–MS was used to analyse the clay matrix of 32 pottery samples from seven Middle and Late Woodland period (c. ad 200–800) sites in north‐east Florida and results were compared to data from INAA of the same samples. The results reveal many of the challenges in analysing highly heterogeneous materials with LA–ICP–MS. However, the study also generated data that are potentially useful in the determination of pottery provenance. In some respects, LA–ICP–MS of clay matrix replicated the chemical variation recorded by INAA, and in other respects the results are divergent. The similarities and differences between these results are explained by specific differences between the methods and the materials analysed (matrix versus bulk analysis). Suggestions for improving the method are discussed.     

The persistence of caffeine in experimentally produced black drink residues

Black drink is a native North American caffeinated tea produced from the leaves of Ilex vomitoria. The beverage was an important part of prehistoric Southeastern culture, as it was the only native source of caffeine in North America. The leaves of I. vomitoria were, therefore, a potentially valuable trade resource during the period. As such, the ability to identify archaeological black drink residues is useful to Southeastern archaeologists. In order to determine the plausibility of detecting I. vomitoria in residues, black drink was repeatedly produced in experimental unglazed pottery. The resulting potsherds were buried in several environmental contexts, recovered, and underwent absorbed pottery residue analysis. After two months of burial in three different soil types, plus a control stored in the freezer, caffeine was well-preserved in all sherds, suggesting that caffeine is a potentially useful biomarker for the detection of black drink.     

Report on the pottery from Tell Sufan in Nablus,Palestine

ABSTRACT

This research report aims to give detailed information on the pottery from the 1999 and 2013-16 excavation campaigns taking place at the Tell Sufan site in Nablus, Palestine. These were conducted by the Department of Antiquities at An-Najah National University (ANU) in Nablus. It is of note that this ancient pottery has never previously been the subject of research nor has any literature been published on it. Our methodology consists in: analysing the pottery by identifying it, typifying it, and giving it a function; providing chronological information on the site; comparison of the pottery with that from other sites in Palestine, using archaeological information from the site; and contextualising our findings with other historical and archaeological studies. Examination of the functional use of the pottery allows us to demonstrate human activity at the Tell Sufan site, giving information on the most prosperous phases of occupation in regard to economic aspects, through the late Bronze Age, Iron Age and Byzantine-Early Islamic periods.