SYNTHESIS AND ACID RESISTANCE OF MAYA BLUE PIGMENT*

Maya blue is an organo‐clay artificial pigment composed of indigo and palygorskite. It was invented and frequently used in Mesoamerica in ancient times (eighth to 16th centuries). We analyse in this paper one of the characteristics of Maya blue that has attracted the attention of scientists since its rediscovery in 1931: its high stability against chemical aggression (acids, alkalis, solvents, etc.) and biodegradation, which has permitted the survival of many works of art for centuries in hostile environments, such as the tropical forest. We have reproduced the different methods proposed to produce a synthetic pigment with the characteristics of the ancient Maya blue. The stability of the pigments produced using either palygorskite or sepiolite has been analysed by performing acid attacks of different intensities. The results are analysed in terms of pigment decolouration and destruction of the clay lattice, revealed by X‐ray diffraction. Palygorskite pigments are much more resistant than sepiolite pigments. It is shown that indigo does not protect the clay lattice against acid aggression. We show that Maya blue is an extremely resistant pigment, but it can be destroyed using very intense acid treatment under reflux.     

CORRELATION BETWEEN SPECTRAL,SEM/EDX AND ELECTROCHEMICAL PROPERTIES OF MAYA BLUE: A CHEMOMETRIC STUDY*

Visible spectra, composition from SEM/EDX and solid‐state electrochemical data are correlated for a set of 12 Maya Blue samples from different archaeological sites of Campeche and Yucatán (Mexico). In addition to indigo and dehydroindigo, indirubin and other possibly indigo‐type compounds can be detected in Maya Blue samples. Application of hierarchical cluster analysis techniques allows similarity relationships to be established between samples from different sites, confirming prior results which suggest that the preparation of Maya Blue pigment evolved with time during the Maya culture following a ramified scheme.     

Central petén blue pigment: A maya blue source outside of Yucatán,México

Much of the research on Maya Blue has focused on locating palygorskite sources in northern Yucatán, México. To that end, Arnold et al. (2007) reported seven discriminate source mineral locations for palygorskite used in the manufacture of Maya Blue. Recently, a blue pigment was excavated from the archaeological site of Ixlú, El Petén, Guatemala and LA-ICP-MS and INAA analyses were conducted to determine if the pigment had the traditional Maya Blue structure and if it was from one of the seven mineral sources in México. Geochemical analyses demonstrate that the Ixlú pigment has the traditional Maya Blue structure, but it was manufactured from clays in central Petén, Guatemala. These new data suggest that the knowledge of Maya Blue manufacture was transferred and not the actual pigment and they reveal another source for Maya Blue manufacture outside of the Yucatán peninsula.     

A Taphonomic Approach to Late Classic Maya Mortuary Practices at Xuenkal,Yucatán,Mexico

Abstract

Following a brief introduction to mortuary practices in Prehispanic Maya society, we outline the analytical procedures followed during the excavation and laboratory investigation of five burial assemblages from the Late Classic period site of Xuenkal, Yucatán, Mexico. A detailed account of a sequence of primary and secondary interments is provided with a focus on taphonomic and biovital information, emphasizing the importance of an interdisciplinary approach, especially human taphonomy, for the reconstruction of complex Maya mortuary treatments. Our results show that bodies of the dead or their parts followed surprisingly long and complex funerary paths.     

Writing violence in Seventeenth-Century Yucatan: Fray Bernardo de Lizana's Devocionario de nuestra Señora de Izamal y Conquista espiritual de Yucatán (1633)

Although long considered a minor work, Franciscan friar Bernardo de Lizana's Devocionario de nuestra Señora de Izamal y Conquista espiritual de Yucatán (1633) is key for understanding what the author himself termed the ‘spiritual conquest’ of colonial Yucatan. Deploying José Rabasa's concept of ‘writing violence,’ this essay shows how this text works to promote a culture of forceful spiritual conquest, reminiscent of the culture of spiritual conquest of the primitive Yucatecan church (1545–1562), in order to complete the conquest of the last independent Maya on the peninsula.     

Inductively coupled plasma emission spectroscopy and Postclassic Petén slipped pottery: an examination of pottery wares,social identity and trade*

ICP–ES analysis of the clay pastes of Postclassic (c. ad 850–1524) slipped pottery from the central Petén lakes region establishes chemical composition groups that provide information concerning manufacturing traditions and trading patterns. These data demonstrate that manufacturing traditions and trading patterns change throughout the Postclassic period, reflecting possible socio‐political alliances as different ethnic groups migrated to and from the Yucatán peninsula into the central Petén lakes region. The chemical composition groups also demonstrate that some manufacturing traditions imitate those from the Late Classic period and that some clay sources were used throughout the Postclassic period for multiple ceramic groups.     

Haciendas and economic change in Yucatán: Entrepreneurial strategies in the Parroquia de Yaxcabá, 1775–1850

Using archaeological and historical data from eighteenth- and nineteenth-century haciendas in theParroquia de Yaxcabá, Yucatán, this paper demonstrates how documentary records can be employed to create diachronic archaeological explanations. Both the organization of production on the hacienda and the entrepreneurial strategies pursued by the estate owners. contribute to the form of the hacienda. The following analysis suggests quantitative and qualitative explanations for variation in hacienda size and architectural elaboration. The archaeological interpretations offer a reconsideration of processes of economic change in central Yucatán prior to the Caste War of 1847.     

TESTING ASSUMPTIONS OF NEUTRON ACTIVATION ANALYSIS: COMMUNITIES,WORKSHOPS AND PASTE PREPARATION IN YUCATAN,MEXICO*

Contemporary pottery and raw materials (N= 170) from three workshops in Ticul, Yucatán, were analysed by neutron activation to test the hypothesis that individual workshops that used their own clay sources could be identified by their pottery. Although the data failed to confirm the hypothesis, the results reinforced previous conclusions about the relationship of local communities of potters to the chemical patterning of pottery made in these communities.     

The first direct evidence of pre-columbian sources of palygorskite for Maya Blue

Maya Blue, a nano-structured clay–organic complex of palygorskite and indigo, was used predominantly before the Spanish Conquest. It has fascinated chemists, material scientists, archaeologists and art historians for decades because it is resistant to the effect of acids, alkalis, and other reagents, and its rich color has persisted for centuries in the harsh tropical climate of southern Mesoamerica. One of its components, palygorskite, is part of modern Maya indigenous knowledge, and ethnohistoric and archaeological data suggest that its modern sources were probably utilized in Prehispanic times. Yet no direct evidence verifies that palygorskite was actually mined from these sources to make Maya Blue. Here we characterize these sources compositionally, and compare our analyses to those of Maya Blue from Chichén Itzá and Palenque. We demonstrate that the palygorskite in most of these samples came from modern mines, providing the first direct evidence for the use of these sources for making Maya Blue. These findings reveal that modern Maya indigenous knowledge about palygorskite, its mining, and its source locations, is at least seven centuries old.     

ISSUES RELATED TO DETERMINING BURIAL CHRONOLOGY BY FLUORIDE ANALYSIS OF BONE FROM THE MAYA ARCHAEOLOGICAL SITE OF CHAU HIIX,BELIZE*

Fluoride percentage of bone is often used to determine relative dates of burials in archaeological contexts. An analysis of prehistoric Maya burials at Chau Hiix, Belize, identifies taphonomic factors, including soil composition, grave depth, soil disturbance, age at death and cortical bone thickness, that cause variations in the rate of fluoride absorption by altering the access of water to bone. This example demonstrates that fluoride dating is unlikely to be useful at most prehistoric Maya sites because of the inconsistent taphonomy due to typically diverse mortuary practices, and it also serves as a cautionary tale for applications of this methodology in other contexts.     

Evidence from Escalera al Cielo: Abandonment of a Terminal Classic Puuc Maya hill complex in Yucatán,Mexico

Abstract

Excavations at the hilltop site of Escalera al Cielo, located in the Puuc Maya region of Yucatán, Mexico, have uncovered evidence of a planned abandonment at the end of the Terminal Classic period (a.d. 800–950). Six buildings investigated among three residential groups contain rich floor assemblages similar to those known from only a few rapidly abandoned sites in the Maya area. Through an analysis of de facto refuse—most of which was recovered in locations of storage and provisional discard—and midden refuse, this paper illustrates how the assemblages represent an example of household-level abandonment with anticipated return. We also consider Escalera al Cielo in light of our present understanding of the political and environmental history of the Puuc region during the late 9th century a.d.     

The Archaeology of Copán, Honduras

Copán, a major Classic Maya center in western Honduras, has been the focus of archaeological investigation for over a century. An intense period of research since 1975, involving projects and scholars from many institutions, has resulted in a comprehensive understanding of the origin, maturation, and decline of this major Maya polity.     

A prehispanic Maya pit oven? Microanalysis of fired clay balls from the Puuc region,Yucatán,Mexico

Excavations of a kitchen at Escalera al Cielo in the Puuc Maya region of Yucatán, Mexico uncovered a concentration of fired clay balls (ca. 3–5 cm in diameter), in addition to other de facto domestic refuse. The kitchen pertains to an intensively excavated elite residential group that was rapidly abandoned sometime near the end of the Terminal Classic period (A.D. 800–950), resulting in floor assemblages that provide an opportunity to explore the types and distribution of daily household activities. The results of experimental replications and a suite of analyses comprising modal analysis, ceramic petrography, Fourier transform infrared spectroscopy (FTIR), and microbotanical residue analysis reveal aspects of clay preparation, firing temperatures, repeated use of the balls, firing conditions, and specific plant food or fuel residues adhering to them. We show that the fired clay balls were manufactured with local, clay-rich soil and employed by the inhabitants of Escalera al Cielo as heating elements; relatively high concentrations of microbotanical residues from edible plants adhering to them support the hypothesis that they were involved in kitchen activities related to food processing.     

A SPECTROSCOPIC INVESTIGATION OF PIGMENT AND CERAMIC SAMPLES FROM COPÁN,HONDURAS*

A combination of micro‐Raman spectroscopy, micro‐infrared spectroscopy and SEM–EDX was employed to characterize decorative pigments on Classic Maya ceramics from Copán, Honduras. Variation in red paint mixtures was correlated with changing ceramic types and improvements in process and firing techniques. We have confirmed the use of specular hematite on Coner ceramics by the difference in intensities of Raman bands. Different compositions of brown paint were correlated with imported and local wares. The carbon‐iron composition of the ceramic type, Surlo Brown, was confirmed. By combining micro‐Raman analysis with micro‐ATR infrared and SEM–EDX, we have achieved a more comprehensive characterization of the paint mixtures. These spectroscopic techniques can be used non‐destructively on raw samples as a rapid confirmation of ceramic type.     

The Henequen Ports of Yucatan’s Gilded Age

Over the last two centuries, the coast has played a major role in the economy of Yucatán, and has served as a key venue in its growing engagement in the global economy. A prominent chapter in this history took place during the Gilded Age (1860–1915), which saw the emergence of a powerful plantation class whose wealth was based on meeting international demand for the fiber of the agave, or henequen plant, which was used to manufacture rope, cordage, and twine. The cultivation of this plant gave rise to hundreds of plantations, and an accompanying infrastructure of haciendas, fiber processing plants, and an extensive regional network of railways for transporting henequen to the port of Progreso, from whence it was exported to North America and Europe. As part of this infrastructure, several plantation owners laid rail lines from their haciendas to the coast and built small ports for shipping their henequen to Progreso. These ports, which are documented in these pages, represented a substantial capital outlay, and were built under the shadow of the gathering clouds of the Mexican Revolution. Viewed in retrospect, they offer an insightful perspective on the economic outlook of the Yucatecan elites in the dawn of the modern age.     

Prohibido Tocar Este Cenote: The Archaeological Basis for the Titles of Ebtun

Ebtun, Kaua, Cuncunul, Tekom, and Tixcacalcupul are a group of related communities on the Yucatán peninsula described in the corpus of Maya-language documents known as The Titles of Ebtun. In this paper I explore transformations in agrarian practice and material expressions of identity after the Spanish invasion by analyzing archaeological variation in the life histories of places over the last 500 years. As new plants, animals, and technologies were adopted, landscape organization changed, and locales took on new meanings. Ebtun’s landscape reflects a historically contingent process that has transformed place and identity, fostering autonomy of cultural practice and renewal of tradition.     

THE CHEMICAL COMPOSITION OF BLUE PIGMENT ON CHINESE BLUE‐AND‐WHITE PORCELAIN OF THE YUAN AND MING DYNASTIES (ad 1271–1644)*

The chemical compositions of the glazes and pigments of 39 blue‐and‐white porcelains of Ming Dynasty date and three of Yuan date were examined by SR‐XRF. Both the analysis of the Fe/Mn ratio in the light blue areas of the glaze and a comparison of the Fe/Mn values between light blue, dark blue and clear glaze areas reveals that the samples can be divided into three groups. The results indicate that there are two significant changes of provenance of blue pigment during the Ming Dynasty and that some kinds of pigment were most probably imported from the Middle East. Considering literature records and other scholars’ studies, an outline picture of the pigment used on Chinese blue‐and‐white porcelain produced in Jingdezhen in the Yuan and Ming Dynasties is presented.