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1.
The lead isotope compositions of many different samples from lead ingots of Roman age from two relicts (from Cabrera, and from Saintes‐Maries‐de‐la‐Mer) of the Western Mediterranean have been measured. Other lead isotope analyses of ores, metals or lead ingots from mines of Sierra Morena and from Cartagena and Sardinia have been accomplished. All the lead isotope measurements have been performed at the Joint Research Centre of the European Union, Ispra (Va), Italy. The samples have been prepared in a class 100 clean room, using only ultrapure reagents and FEP materials. In view of the archaeological arguments, it was possible to believe that the Roman lead ingots of the Saintes‐Maries‐de‐la‐Mer 1 wreck came from Spanish lodes, as well as those of the Cabrera 5 wreck. In fact, while the comparison between the first group of ingots (Cabrera 5) and the lead from Sierra Morena is consistent, the correspondence between the second group of ingots (Saintes‐Maries‐de‐la‐Mer 1) and the Cevennes ores (southern France) gives rise to several problems concerning the archaeological and physical origins. These problems are discussed.  相似文献   

2.
The Pine Point region is a classic metallogenic mining camp that produced over 58 million short tons of Zn–Pb ore from approximately 40 base‐metal mineralized deposits hosted by Middle Devonian carbonates. The ore deposits are localized in paleokarstic features found in the epigenetic ‘Presqu'ile’ dolomite that preferentially replaced some of the upper barrier limestones. The main ore‐stage sulfides include galena, sphalerite, marcasite, and pyrite. A bulk fluid inclusion chemistry study was carried out on sulfide, coarse non‐saddle and saddle dolomite and calcite samples from the Pine Point and Great Slave Reef deposits, and unmineralized coarse non‐saddle and saddle dolomite samples from Hay West, Windy Point and Qito areas. Molar Cl/Br ratio data from Pine Point indicate the presence of four fluids at different stages of the paragenesis. The fluids trapped in sulfides and ore‐stage dolomites predominately consist of a Br‐rich fluid with a composition similar to that of evaporated seawater (fluid A), and a very Br‐enriched fluid of unknown origin (fluid B). Both these fluids are CaCl2–NaCl (Na to Ca ratios of 1:10)‐rich brines and have compositions unlike the modern formation waters in the Devonian aquifers in the basin today. A third, relatively Cl‐rich (or Br‐poor), fluid (fluid C) was identified in two samples and may have acquired some chlorinity by dissolving halide minerals. Mixing between the Br‐rich fluid A and a dilute fluid also occurred in the later stages of the paragenesis, resulting in the formation of calcite and native sulfur. Saddle and coarse dolomites not associated with significant sulfide mineralization have a narrow range of halogen compositions similar to fluid A. There is no evidence of fluid B or C in the unmineralized samples. Relative to a modern‐day seawater compositions all the fluids have had some modification of their cation compositions. There is some weak evidence for interactions with clastic units or crystalline basement rocks. It is also possible however, that the evaporative brines could have formed from a relatively CaCl2‐rich, NaCl‐depleted Devonian seawater, unlike the composition of modern‐day seawater.  相似文献   

3.
The origin of large‐scale ancient dolomite is one of the most hotly debated topics in sedimentology. The Loushanguan group of the upper 3rd‐Furongian Cambrian series on the south‐eastern margin of the Sichuan Basin consists of numerous dolomites, and the origins of these dolomites have never been reported previously although they are probably good hydrocarbon reservoirs. Based on a systematic analysis of petrology, fluid inclusions, carbon and oxygen isotopes, trace elements and rare earth elements (REEs), this study provides some unique insights into the origins of the dolomites. Four dolomite types have been identified in the study area: dolomicrite, fabric‐retentive oolitic dolomite, fabric‐obliterative dolomite and saddle dolomite cement. In the dolomicrite and fabric‐retentive oolitic dolomite, high Sr contents (with respect to the fabric‐obliterative dolomite) and the lack of two‐phase aqueous inclusions suggest that they formed at shallow‐to‐intermediate burial depths at low temperatures (<50–60°C). Carbon and oxygen isotopes and seawater‐like REE+Y characteristics of the dolomicrite and fabric‐retentive oolitic dolomite indicate that the dolomitizing fluids were evaporated seawater or slightly modified seawater. The obliteration of the original sedimentary fabric and relatively low δ18O and Sr values compared to the fabric‐retentive dolomite indicate that fabric‐obliterative dolomite formed at intermediate‐to‐deep burial diagenesis. The chemical composition approaches pure dolomite and the REE+Y characteristics are similar to those of the fabric‐retentive dolomite, indicating that the fabric‐obliterative dolomite was formed due to the recrystallization of the previously formed fabric‐retentive dolomite at elevated burial depths and temperatures. High fluid inclusion homogenization temperatures (115–150°C), low δ18O values, nonplanar‐a crystals and seawater‐like REE+Y characteristics suggest that saddle dolomite cement formed by reprecipitation of dolomite that related to seawater‐driven and deep burial fluid. In the study area, dolomicrite and fabric‐retentive oolitic dolomite may have been formed by penecontemporaneous or seepage‐reflux dolomitization during early‐stage diagenesis. Subsequently, during progressive burial, most of the fabric‐retentive dolomite was converted into fabric‐obliterative dolomite by recrystallization. This study confirms that fabric‐obliterative dolomite was the main dolomite type, and although deeply buried, these Cambrian dolomites most likely have preserved coeval seawater geochemical signals.  相似文献   

4.
H. TSIKOS  J. M. MOORE 《Geofluids》2005,5(4):264-271
Petrological and geochemical evidence is presented on the occurrence of aegirine in the Palaeoproterozoic Hotazel iron‐formation, which hosts the giant manganese deposits of the Kalahari manganese field, South Africa. The mineral has an essentially pure Na end‐member composition and occurs sporadically in iron‐formation immediately bordering the manganese ore beds. The development of aegirine appears to have taken place due to the action of late‐infiltrating, saline hydrothermal fluids at the expense of a pre‐existing, binary quartz–hematite assemblage. It is proposed that such a process would have overprinted (and therefore post‐dated) a spatially more extensive, low‐temperature alteration event which brought about thorough carbonate leaching, oxidation and residual enrichment of metals in the Hotazel iron–manganese rocks.  相似文献   

5.
Eight sherds of ninth–tenth century ad Abbaesid blue‐and‐white glazed earthenware, excavated in 1931 at Hira in western Iraq, were analysed using, variously, quantitative wavelength‐dispersive spectrometry (WDS) and energy‐dispersive spectrometry (EDS) in association with scanning electron microscopes (SEM), and semi‐quantitative X‐ray fluorescence spectrometry (XRF). In order to compare the compositions of the cobalt pigments used, the glazes of seven complete vessels of eighth century ad Chinese Tang blue‐and‐white sancai were also analysed semi‐quantitatively using XRF. The Abbasid wares were shown to have used traditional Mesopotamian alkali–lime glazes applied to calcareous clay bodies. Half the glazes examined were opacified with tin oxide. Three types of blue decoration (i.e., raised; spreading; and flat, non‐spreading) were produced using a variety of formulations, including a mixture of cobalt pigment with lead oxide. The sources of the ores used for the cobalt pigments have not been identified. However, the analytical data showed that the cobalt ore used for the Abbasid blue‐and‐white ware could be distinguished from that used for the Tang blue‐and‐white sancai by its higher iron content and by the presence of a significant amount of zinc. The use of cobalt‐blue decoration on the ninth–tenth century ad Abbasid ware was anticipated in China by eighth century ad Tang blue‐and‐white sancai wares. However, whether its introduction by the Abbasid potters should be seen as an independent invention that followed the introduction of tin‐opacified glazes in Iraq, or whether it was influenced in some way by Chinese originals, is still unresolved.  相似文献   

6.
Q. Wang 《Archaeometry》2021,63(1):105-121
In this paper six bronze artefacts of the Eastern Zhou period to Han dynasty (770 BC ‐ 220 AD) with tin‐rich surface decoration in the British Museum collection were studied using a variety of analytical techniques. The decoration patterns include trellis patterns (菱形纹) on two swords of the Yue state, tiger's striped patterns (hu‐ban‐wen, 虎斑纹) on two swords from the Ba‐Shu region, a hexagonal star pattern (六角星纹) on a spearhead of the Wu state, and a cloud‐like pattern on a garment hook. The tin‐rich decorations on those objects were produced by deliberate tinning processes; at least three different tinning techniques were used, including the use of tin‐rich pastes for the trellis pattern of a Yue state sword and for the mottling decoration on the Ba‐Shu swords, amalgam tinning for the hexagonal star pattern on the spearhead of the Yue state, and hot tinning for the cloud‐like pattern of the garment hook. Different tinning techniques could have been applied to produce similar tin‐rich decoration patterns, and vice versa, a single tinning technique could have been used to produce different tin‐rich patterns on different objects.  相似文献   

7.
A review of the Khufu I vessel (c.2566 BC) and contemporary Egyptian iconography (c.2613–2345 BC) suggest this vessel was originally fitted with six pairs of quarter‐rudders, instead of one pair. Furthermore, quarter‐rudders may have been mounted on knob‐shaped thole‐pins, instead of crossbeams. The iconography also suggests that each quarter‐rudder was fitted with a loom‐line and specialized grommet, and rowers may have used a similar system to mount their oars. Finally, a recently published depiction of Sahure sailing a boat may show an anchor secured on the stern deck. © 2011 The Author  相似文献   

8.
ABSTRACT. Both Will Kymlicka (1995) and David Miller (1995) have defended the value of national self‐determination and have argued that a properly organised self‐determining nation respects rather than undermines the equal treatment of all of its members, including ethnic, religious and cultural minorities. I argue that their respective attempts to defend national self‐determination and the equal treatment of all members of the nation are saddled with a serious tension. It is actually quite difficult to coherently argue both that (a) national self‐determination fulfils ethically valuable ends, and that (b) a self‐determining nation can treat all members equally. The equality‐respecting requirement is in tension with the claim that nations secure ethically valuable goods for their members.  相似文献   

9.
Using comprehensive and original data derived from a recent major public opinion survey, this study examines an under‐investigated aspect of the Kurdish issue in Turkey: the dynamics and factors behind Kurdish ethno‐nationalism at a mass level. The empirical findings disprove the conventional socio‐economic peace and Islamic‐peace hypotheses around this issue, and our statistical analyses provide strong support for the relative deprivation hypothesis, i.e. that those who think the Turkish state discriminates against Kurds are more likely to have ethno‐nationalist orientations. Multivariate analyses further show that religious sectarian differences among Kurds (i.e. the Hanefi‐Shafi division) matter: the more religious Shafi Kurds have a stronger ethnic consciousness and a higher degree of ethno‐nationalism. The study also provides a discussion of the broader theoretical and practical implications of the empirical findings, which may provide insights into conflict resolution prospects in countries with a Kurdish population.  相似文献   

10.
The chronological sequence of a major reference site for Neolithic periods in southeastern Europe and the Aegean, Dikili Tash (Macedonia, Greece), has been reassessed by TL. Baked adobe material samples extracted from domestic ovens, directly associated with specific occupational levels, have been studied. The fine‐grain technique has been used for equivalent dose determination. K, U and Th contents and the equilibrium state of U‐series have been measured by low‐background gamma spectroscopy. Since the archaeological levels were already partly excavated, the environmental dose‐rate was evaluated by a reconstruction technique combining laboratory analysis and on‐site measurements. The TL results (weighted average of multiple age determination, oven 400, middle of the Dikili Tash I (DT‐I) phase, 5500 ± 320 bc ; oven 600, end of DT‐I, 4920 ± 310 bc ; house 3, DT‐II, 4260 ± 280 bc ; house 4, DT‐II, 4510 ± 410 bc ) are in general agreement with the timeframe deduced from previous radiocarbon dates. This convergence strengthens the settlement's chronology, established now by independent dating methods.  相似文献   

11.
By utilizing today's web‐based technologies, people can act as sensors and share their perceptions, emotions and observations in a variety of data forms, such as images, videos, texts, Global Positioning System (GPS) trajectories and maps. These forms are collectively called user‐generated content (UGC). These data are in different domains and have a multi‐modality nature. Although recent efforts have probed the acquisition of local knowledge by using single‐domain UGC data in specific applications, such efforts have not thus far presented a model considering multi‐domain UGC specifically to enrich road network data. This article aims at presenting such a model wherein, with the help of each data domain of UGC, one aspect of people knowledge about the road segment is obtained. These different aspects of knowledge are integrated using a Skyline operator to support multi‐criteria route finding. We name this model ERSBU (enriching road segments based on UGC). In ERSBU, road segments are basic spatial units, and their subjective properties have been extracted by using available UGC. The scenic score for each road segment was computed by using geo‐tagged Panoramio photos. The accessibility level of each road segment to different facilities was calculated based on data captured from Wikimapia and OpenStreetMap. Moreover, for measuring the movement popularity of each road segment, Wikiloc and Everytrail GPS trajectories were utilized. For the implementation of the ERSBU model, Tehran region 6 was considered the case study area. The Evaluation of the results proved that road segments that achieved a high score based on knowledge extracted from UGC also mostly gained top scores by analyzing traditional maps. ERSBU allows users to accomplish more‐qualitative path finding by considering the multi‐view characteristics of road segments.  相似文献   

12.
Four Nabataean samples collected in some of the monumental tombs of Madâ’in Sâlih, ancient Hegra, in Saudi Arabia, have been studied by gas chromatography coupled with mass spectrometry. These samples are textile fragments that are either covered with a black layer or bound together with some black amorphous substance. Fatty acids and triterpenoic compounds were detected. Eight triterpenic compounds were identified: ursa‐9(11),12‐dien‐3‐ol, ursa‐9(11),12‐dien‐3‐one, olean‐9(11),12‐dien‐3β‐ol, β‐amyrone, β‐amyrin, α‐amyrone, α‐amyrin and lupeol. The resinous chemical composition and these pentacyclic alcohols, in considerable proportion, indicate a resin of the Burseraceae family, possibly of the genus Canarium.  相似文献   

13.
Large‐scale conical and saucer‐shaped sand injectites have been identified in the Upper Miocene sediments of the Lower Congo Basin. These structures are evidenced on the 3D high‐resolution seismic data at about 600 ms TWT (two‐way traveltime) beneath the seabed. The conical and saucer‐shaped anomalies range from 20 to 80 m in height, 50 to 300 m in diameter, and 10 to 20 ms TWT in thickness. They are located within a sedimentary interval of about 100 m in thickness and are aligned over 20 km in dip direction (NE‐SW), above the NW margin of an underlying Upper Miocene submarine fan. We have interpreted the conical and saucer‐shaped anomalies as upward‐emplaced sand injectites sourced from the Upper Miocene fan because of their discordant character, the postsedimentary uplifting of the sediments overlying the cones and saucer‐shaped bodies, the alignment with the lateral fringe of the Upper Miocene submarine fan, and the geological context. Sand injection dates from the Miocene–Pliocene transition (approximately 5.3 Ma). The prerequisite overpressure to the sand injection process may be due to the buoyancy effect of hydrocarbons accumulated in the margins of the fan. Additionally, overpressure could have been enhanced by the lateral transfer of fluids operating in the inclined margins of the lobe. The short duration of sand injection and the presence of many sandstone intrusions suggested that the process of injection was triggered by an event, likely due to a nearby fault displacement related to diapiric movements. This is the first time that sand injectites of seismic scale have been described from the Lower Congo Basin. The localized nature of these injectites has led to a change in the migration path of fluids through the sedimentary cover. Consequently, the sand intrusions are both evidence and vectors of fluid migration within the basin fill.  相似文献   

14.
L. Gentelli 《Archaeometry》2021,63(1):156-172
This paper details the application of a statistical method for the chronological discrimination of silver coins using counts per second trace elemental, inter‐elemental ratios. The statistical method described is based on a method that has been applied to similar archaeological materials to determine their provenance. The method makes use of the inter‐element association patterns of multi‐element analytical data determined using laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS). The majority of the 266 coins analysed for this study have already been successfully identified by their mint markings. The data from LA‐ICP‐MS analyses, together with what is known about the coins through visual identification, were used to discriminate the reigning sovereign, and in the case of Mexico, the year of minting, of individual coins within the elemental fingerprint of different mints. Subsequently, unidentified coins can be placed in the confusion matrix, and their trace element information used to identify their year of minting when compared with other, identified coins from the same mint. The interpretational statistical technique linear discriminant analysis (LDA) was used to explore an identification of year of minting of coins that have previously not been identified by other means based on a statistical comparison against a database of compositional analysis of silver coins of known year of minting.  相似文献   

15.
This analysis of the patterns of change in the use of incarceration by the American states from 1890 through 2008 focuses on multiple themes particularly relevant to an understanding of policy arenas in which the social constructions of target populations play an important role. Specifically, the study examines whether the states have adopted more similar incarceration levels over time (converged), whether they tend to change in the same direction at the same time (synchronous change), and whether they tend to stay in the same relative positions vis‐à‐vis one another, such that the historical policy position has long‐term implications for later policy positions (“feed‐forward” effects). The results indicate that, in spite of a century of social, political, and economic integration, the policy positions of the states have not exhibited a sustained convergence toward a common level of incarceration, but have undergone cycles, with some periods of convergence followed by periods of divergence. Change has generally been synchronous—as states tend to move in the same direction at the same time as if propelled by national forces even though incarceration levels are determined by state and local policy and the use of discretion by criminal justice officials. The results also indicate a profound “feed‐forward” effect in that the position of the states vis‐à‐vis one another historically has substantial predictive power for their position in subsequent years.  相似文献   

16.
The US‐led post 9/11 ‘intervention’ in Afghanistan was, by definition, not a humanitarian intervention. The intervention in Afghanistan was defined as an act of self‐defence by the US and it was one of the first steps in the ‘war on terror’ by the US and its allies: it had no intention or clear strategies for long‐term stabilization, state‐building or development. The US‐led international coalition failed to ‘find’ Al‐Qaeda in the short term and new arguments had to be made to justify continued international presence. The initial agenda was quickly blurred by a mismatch of intentions including those of long‐term stabilization and state‐building. The ideas developed through the Bonn Agreement (2001–5) and continued through the Afghanistan Compact (2006–10) have focused on building a centrally governed state (sometimes defined as democratic) that has a monopoly on the use of force. Their shortcomings are already well‐documented: the urgency of the Bonn Conference and of the adoption of the Bonn Agreement ostensibly meant trading expediency and stability for accountability and a clean slate, which is not to say that there were no good intentions at Bonn from stakeholders, but that Afghans and the international community put power‐sharing before progress. The choices made at Bonn may have contributed to the culture of impunity and the entrenched poverty that is gripping Afghanistan today. This article responds to the claims that state‐building and all that goes with it are not the responsibility of the ‘international community’ by addressing the accountability and humanitarian paradoxes. The question remains, however, about who should be responsible for reform and politically accountable in the aftermath of non‐humanitarian (and indeed even humanitarian) interventions?  相似文献   

17.
World‐class unconformity‐related U deposits in the Athabasca Basin (Saskatchewan, Canada) are generally located within or near fault zones that intersect the unconformity between the Athabasca Group sedimentary basin rocks and underlying metamorphic basement rocks. Two distinct subtypes of unconformity‐related uranium deposits have been identified: those hosted primarily in the Athabasca Group sandstones (sediment‐hosted) and those hosted primarily in the underlying basement rocks (basement‐hosted). Although significant research on these deposits has been carried out, certain aspects of their formation are still under discussion, one of the main issues being the fluid flow mechanisms responsible for uranium mineralization. The intriguing feature of this problem is that sediment‐hosted and basement‐hosted deposits are characterized by oppositely directed vectors of fluid flow via associated fault zones. Sediment‐hosted deposits formed via upward flow of basement fluids, basement‐hosted deposits via downward flow of basinal fluids. We have hypothesized that such flow patterns are indicative of the fluid flow self‐organization in fault‐bounded thermal convection (Transport in Porous Media, 110, 2015, 25). To explore this hypothesis, we constructed a simplified hydrogeologic model with fault‐bounded thermal convection of fluids in the faulted basement linked with fluid circulation in the overlying fault‐free sandstone horizon. Based on this model, a series of numerical experiments was carried out to simulate the hypothesized fluid flow patterns. The results obtained are in reasonable agreement with the concept of fault‐bounded convection cells as an explanation of focused upflow and downflow across the basement/sandstone unconformity. We then discuss application of the model to another debated problem, the uranium source for the ore‐forming basinal brines.  相似文献   

18.
In polyorogenic regions, the superposition of structures during a protracted tectonic history produces complex fractured bedrock aquifers. Thrust‐faulted regions, in particular, have complicated permeability patterns that affect groundwater flow paths, quantity, and quality. In the Appalachian foreland of northwestern Vermont, numerous bedrock wells that are spatially related to the Paleozoic Hinesburg thrust have elevated naturally occurring radioactivity and/or low yields. The association of groundwater quality and quantity issues with this thrust was a unique opportunity to investigate its structural and hydrogeologic framework. The Hinesburg thrust juxtaposed metamorphic rocks of the hanging wall with sedimentary rocks of the footwall during the Ordovician. It was then deformed by two orthogonal Devonian fold sets and was fractured during the Cretaceous. Median well yields in the hanging wall aquifer are significantly lower than those of the footwall aquifer, consistent with the respective permeability contrast between metamorphic and carbonate rocks. For wells drilled through the Hinesburg thrust, those completed closest (vertically) to the thrust have the highest median yields, whereas others completed farther below have yields in the footwall range. The geochemical signature of the hanging wall and footwall aquifers correlates with their whole‐rock geochemistry. The hanging wall aquifer is enriched in alpha radiation, Na+K‐Cl, Ba, and Sr, whereas the footwall aquifer is enriched in Ca‐Mg‐HCO3 and alkalinity. Wells that penetrated the Hinesburg thrust generally have hanging wall geochemical signatures. A simple hydrogeologic model for the permeability evolution of the Hinesburg thrust involves the ductile emplacement of a low‐K hanging wall onto a high‐K footwall, with subsequent modification by fractures.  相似文献   

19.
Jerash in northern Jordan was, despite a focus on its classical heritage, also active in the Middle Islamic period, but little is known about actual developments during this period. This study represents the first study on the Middle Islamic glazed pottery from the site using scanning electron microscopy energy‐dispersive spectrometry (SEM‐EDS) and thin‐section petrography. The results show that two production traditions existed, each with different provenances. The local production is characterized by a non‐calcareous ceramic body and the use of a high‐lead glaze coloured with iron and copper oxides, whereas the turquoise‐glazed samples, likely imported from Mesopotamia, have a calcareous ceramic body and alkali or alkali‐lead glaze.  相似文献   

20.
Fractures are important conduits for fluid flow in the Earth's crust. To better understand the spatial and temporal relations among fracturing, fracture sealing, and fluid flow, we have studied fractures, faults, and veins in a large dome (Jabal Akhdar) in the Oman mountains. Our work combines the results of meso‐ and microstructural analyses and stable isotope analyses. Seven generations of fractures and veins have been identified in the carbonate‐dominated dome. The earliest generations of veins developed during extension and subsidence of the Mesozoic basin. These veins formed in the inclined segments of bedding‐parallel stylolites and in extensional fractures that are perpendicular to bedding (#1 and #2, respectively). These extension‐related veins are truncated by bedding‐parallel veins (#4) that formed during top‐to‐north bedding‐parallel shear of both the northern and southern limbs of the dome. These veins are consistent with a change in stress regime and may be related to an earlier generation of strongly deformed pinch‐and‐swell veins (#3) that are exposed locally on the southern limb of the dome. Normal faults contain a set of en‐echelon tension gashes (#5) and veins emplaced in dilational jogs along the fault planes (#6). In the northern part of the dome, veins (#7) associated with thrusts post‐date the normal faults. Samples of veins and their host rocks were analyzed to provide information on fluid‐rock interaction in the dome and the scale(s) of fluid movement. Oxygen isotope values range from +16.2 to +29.3‰; carbon isotope values range from 0 to +3.6‰. The results of the structural and isotopic analyses are consistent with the early veins (#2–#5) having precipitated from overpressured fluid in a isotopically rock‐buffered system. During normal faulting (#5 and #6), a more open system allowed external fluid to infiltrate the dome at drained conditions and precipitate the youngest sets of veins (#6 and #7).  相似文献   

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