Obsidian hydration at high elevation: Archaic quarrying at the Chivay source,southern Peru

We examine obsidian hydration as a means to date archaeological sites at high elevation in the central Andes, and in particular quarry sites that are difficult to date by radiocarbon means. The Chivay obsidian source lies in a volcanic depression above the Colca Valley in Arequipa, Peru (71.5355° S, 15.6423° E) at 4950 masl. We compare obsidian hydration readings from one quarry and two workshop locations. Ninety-one flakes from the quarry pit, and 61 and 33 flakes from the workshops were analyzed for hydration bands. Of these, 68 from the quarry, and 54 and 33, respectively from the workshops produced at least one culturally meaningful hydration band. As expected, obsidian appears to hydrate slowly at this high elevation. Yet, variation in hydration readings is low within stratigraphic contexts, suggesting relatively narrow windows of knapping activities in each excavation level. A small number of radiocarbon dates allow us to develop a preliminary hydration rate for Chivay obsidian in this high elevation location. Hydration data indicate that intensive quarrying began by 3800 cal. BC and stopped ca. 2300 cal. BC. By contrast, the two workshops appear to have been deposited 2900 and 1200 cal. BC, and 2700 and 2400 cal. BC. The data are consistent with an uptick in obsidian use by at least the Terminal Archaic period.     

Petrographic and geochemical characterization of chert artifacts from Middle,Upper, and Epi-Paleolithic assemblages in the Jebel Qalkha area,southern Jordan

This study conducted petrographic and geochemical analyses of chert artifacts from the Late Middle Paleolithic, the Initial Upper Paleolithic, the Early Upper Paleolithic, and the Epi-Paleolithic assemblages in the Jebel Qalkha area, southern Jordan, to examine their correlations with the visual attributes and diachronic variability. The results revealed two different aspects of the petrographic and geochemical signatures. The first aspect showed some correlations with the visual chert types that were characterized by the abundance/preservation of fossils, the enrichment of several elements (i.e., Ca, Sr, and Ba), and the quartz crystallite size. The second aspect of geochemical signatures, such as Fe, Mn, Ni, Cr, and Co, showed no correlation with the visual types but was correlated with the chrono-cultural groups. Given the chert occurrences and variability in and around the study area, the first aspect of the chert variability likely represents the variations of different chert outcrops as well as the internal variations within the same sources. Whether the second aspect represents chrono-cultural changes in the use of chert sources needs to be clarified in future by our ongoing examination of geological chert samples in the study area.     

Systematic Reworking of Lithics from Earlier Cultures in the Early Holocene of Dakhleh Oasis,Egypt

Abstract

A raw material form scarcely mentioned in the literature on lithic production—chipped stone artifacts manufactured by members of still earlier cultures—is used for a substantial portion of the toolkits in certain industries of Dakhleh Oasis, south-central Egypt. In one group of early Holocene (Masara) sites, the majority of double patinated tools are chunky burins, systematically manufactured from Levallois flakes and similar thick-sectioned older artifacts. Since fresh chert and other workable stone is available in the area, it appears that old, recycled lithics constitute the preferred raw material for these tool classes. The sites in question seem to be field camps where the burins were both made and used.     

Long-distance provenance for obsidian artifacts of Mesoamerica Preclassic and Early Classic periods found in the Los Naranjos Archaeological Park (Honduras)

Los Naranjos is one of the most important pre-Columbian human settlements of Honduras related to the south-easternmost border of the Mayan civilization. Although the archaeological site mostly spans from 850 BC to 1250 AD, the present obsidian study was only focused on the Preclassic and Early Classic periods (Jaral, 800–400 BC and Edén, 400 BC–550 AD) where undamaged blades and/or retouched obsidian flakes are rare. In this way, the INAA analyses of 17 obsidian samples, compared with major-trace elements data of Honduran and Guatemalan obsidian sources, are mostly representative of waste flakes. Lithic artifacts of Los Naranjos such as sandstones, basalts, and quartzites come from local geological outcrops; whereas, obsidian provenance has to be searched from sources which are located within a radius up to 300 km far away. San Luis, La Esperanza, and Güinope obsidian sources are located in Honduras while the three most exploited Highland Guatemalan obsidian outcrops, which have been dominating long-distance trade in the Maya area mostly for the Classic-Postclassic periods, are San Martin de Jilotepeque, El Chayal, and Ixtepeque. An Ixtepeque provenance, for all the investigated obsidian samples of Preclassic and Early Classic periods found in the Los Naranjos Archaeological Park, was established, thus emphasizing a long-distance source (180 km). This also confirms that Ixtepeque represents the most important provenance of the obsidian artifacts found in archaeological sites of Western and Central-Western Honduras. The possible role played by some of the most important rivers of Guatemala and Honduras as waterway networks of transport was finally pointed out. New INAA chemical data from the Honduran obsidian source of La Esperanza (“Los Hoyos”, 4 samples) are also reported in this paper.     

Increasing data (INAA) on Ecuadorian obsidian artifacts: preliminary provenance and a clue for pre-Columbian eastward trade

In this work we carried out INAA major (Na, K, Ca and Fe %) and trace (ppm) elements (plus Mn by FAAS analysis) of 15 obsidian samples (waste flakes) coming from an unknown archaeological site (¹⁴C-AMS age of 1425 AD) located on the south-eastern flank of the back-arc Sumaco volcano (to the east of the Cordillera Real) and from two already known pre-Columbian archaeological localities: La Florida (Quito) and Milan (Cayambe). Literature compositional data of the Ecuadorian obsidian outcrops provide some constraints on the provenance of the analyzed waste flakes, even though different methods of analyses make comparisons a difficult task. Concerning the obsidian artifacts of La Florida and Milan, they come from the well known Sierra de Guamanì obsidian sources (Cordillera Real). By contrast, the obsidian fragments of the Sumaco settlement show some compositional characters compatible with obsidian erratic pebbles recently discovered in some river banks of the Amazonian foothills draining the easternmost flanks of the Antisana volcano in the Cordillera Real as well. In this way, the obsidian artifacts found at the Sumaco site reinforce the opinion that Ecuadorian source inventory is not yet exhaustive. Although the Antisana volcano seems to be the best candidate to find out additional primary outcrops of obsidian sources, it cannot be also excluded that sub-Andean and Amazonian people directly took advantage from obsidian secondary sources (e.g. river banks), rather than procurements from primary outcrops in the Cordillera Real. The new archaeological findings at the Sumaco volcano are really of paramount importance in tracing the ancient routes of a possible obsidian eastward trade toward the Amazonian region.     

Recent Research on Obsidian from Missouri Archaeological Sites

Obsidian has been noted at archaeological sites in the Midwest for over 160 years, although very few artifacts made from this material are recorded in archaeological contexts in Missouri. Background research revealed that only 16 obsidian artifacts from 13 sites had been documented from the state and that only 5 of the specimens had been geochemically analyzed and attributed to a source. Recent excavations at the Droste site (23PI1291), a Late Woodland period site in northeast Missouri, yielded two obsidian artifacts. The two specimens from the Droste site along with two previously unsourced obsidian artifacts from the Burkemper site (23LN104) and two from the Stapleton site (23HD110) were tested for trace element composition via X-ray fluorescence analysis. This article reports the results of these geochemical analyses, reviews the other obsidian artifacts reported from Missouri, and examines the cultural context and source of obsidian artifacts from other states in the upper Midwest.     

Approaching the Hatch Jasper Quarry From a Technological Perspective: A Study of Prehistoric Stone Tool Production in Central Pennsylvania

Abstract

Mitigation of the Hatch jasper quarry, a “prospect site” in Central Pennsylvania, has enabled the reconstruction of a local system of stone tool acquisition and production. Artifacts from the quarry and the nearby Houserville habitation complex were analyzed using an attribute-based stage typology. This technological approach permitted the separation of geofacts from artifacts, and revealed evidence suggesting that Houserville knappers obtained tool stone from the quarry. Attention was also given to the study of how systematic heat treatment was used to enhance the flaking characteristics of the Hatch quarry jasper. This research highlights the benefits that a technological analysis of flake artifacts, in addition to finished tools, can provide for understanding stone tool production at quarry localities.     

Geochemical impacts to prehistoric iron-rich siliceous artifacts in the nearshore coastal zone

In the Middle Atlantic region of the United States, landscapes drowned by sea level rise contain scores of prehistoric archaeological sites. These sites provide archaeologists with a rare opportunity to investigate various geologic processes. During the transition from a terrestrial to an offshore setting, the materials associated with an archaeological site are exposed to a series of geochemical processes inherent to the formation of tidal marsh. The duration of the geochemical exposure to tidal marsh is largely dependent on the rate of marine transgression. Here we describe the stages associated with the sulfidization and sulfuricization scheme and the impact to iron-rich lithic artifacts from naturally drowned archaeological sites. Sulfidization and sulfuricization should also impact buried archaeological materials as a result of anthropogenic dredge spoil dumping and the creation of man-made tidal marshes along modern coastlines. Our results indicate that the surfaces of an iron-rich artifact, as well as its interior are visually and geochemically altered by prolonged exposure to the anaerobic conditions of a tidal marsh. Not only should researchers be cautious about making lithic material identification on artifacts found within coastal tidal marsh areas, but museum curators should be aware of the damaging impact of long-term aerobic storage. The geochemical tidal marsh scheme that has altered or corroded iron-rich lithic artifacts in the nearshore zone is an expression of a process that has impacted numerous earlier prehistoric sites currently located on the continental shelf or beneath the coastal estuaries around the world.     

Lead isotope analysis as a new method for identifying material culture belonging to the Vázquez de Coronado expedition

Archaeological evidence has become an increasingly important component of efforts to identify the route of the Francisco Vázquez de Coronado expedition through northern Mexico and the southwestern United States (1540-1542). Here, we report the first high-precision lead isotopic measurements of artifacts from two archaeological sites with strong material evidence for the expedition’s presence: Piedras Marcadas Pueblo in New Mexico and the Jimmy Owens Site in Texas. The analysis of lead and copper armaments from both sites reveals that many artifacts have overlapping or extremely similar isotopic ratios. We propose that the narrow range of lead isotopic ratios measured on these artifacts can be interpreted as a geochemical fingerprint for some of the Coronado expedition’s surviving material culture, and provides evidence that we interpret to suggest the expedition derived lead and copper metal from Mexican sources. Such a geochemical fingerprint presents an empirical method for discriminating between artifacts that belonged to the Coronado expedition and those related to subsequent Spanish, historical, or modern activity in the Southwest U.S. Thus, this method could significantly impact the search for and identification of archaeological sites associated with the Coronado expedition.     

INAA of pre-contact basalt quarries on the Samoan Island of Tutuila: a preliminary baseline for an artifact-centered provenance study

This project presents a material-centered instrumental neutron activation analysis (INAA) characterization of 120 geologic samples selected from four fine-grained basalt quarries on the Samoan Island of Tutuila. Previous attempts at definitive differentiation of these Tutuilan quarries have utilized x-ray fluorescence (XRF). In this study, clear differentiation of each analyzed quarry was achieved using INAA. Biplots of canonical discriminant analysis (CDA) scores for the INAA data illustrate clear separation based on the variation in chemical composition between each quarry. The samples analyzed not only define quarry separation, but also provide the “core group” for a preliminary baseline necessary for future artifact-centered provenance studies. Inclusion of these “core group” samples in the baseline was confirmed by stepwise discriminant analysis. These findings suggest the ability to determine artifact quarry of origin on the island of Tutuila, which can elucidate the importance of individual Tutuilan quarries in the production, distribution and consumption of fine-grained basalt artifacts in Polynesia.     

Assessing the applicability of portable X-ray fluorescence spectrometry for obsidian provenance research in the Maya lowlands

Recent innovations in portable energy-dispersive X-ray fluorescence (PXRF) spectrometry have increased its utility for the geochemical characterization of obsidian artifacts for archaeological provenance research. However, concerns over the utility of PXRF instrumental analyses have been raised, focused on the validity and reliability of the geochemical data produced. Here we adopt the framework of Richard Hughes (On Reliability, Validity, and Scale in Obsidian Sourcing Research, 1998), whereby reliability addresses instrument stability and issues of measurement while validity pertains to an instrument’s ability to discern geochemical source provenance. This is done in order to test the utility of PXRF instruments for archaeological provenance research. k-Means cluster analysis was used to test the accuracy of PXRF through statistical comparison of data acquired via laboratory and portable energy-dispersive XRF instruments. Multivariate analysis was employed to demonstrate obsidian source representation at two Classic Maya archaeological sites in southern Belize – Uxbenká and Ek Xux – and to test the validity of data obtained from a PXRF instrument in answering archaeological research questions pertaining to regional interactions between lowland Maya polities. Results suggest that portable XRF instruments produce internally consistent results. However, data acquired from a PXRF instrument are not statistically equivalent to other XRF instruments. This is to say that while PXRF is not a reliable technique, it is valid for questions pertaining to geochemical source representation.     

Non-destructive provenance study of chert using infrared reflectance microspectroscopy

In this paper we explore the potential of non-destructive Infrared reflectance microspectroscopy (IRRMS) for the characterization of chert samples from 10 different geological outcrops in North America with emphasis on the Midcontinent. A principle objective of the project is to determine whether IRRMS analysis can provide a mineral-based signature for bedrock sources of chert artifacts. The technique utilizes a Bio-Rad Digilab FTS-40 Infrared spectroscope and microscope attachment that reflects an infrared beam off a chert specimen. Our findings indicate that spectral features from the molecules constituting minor and trace minerals in chert may provide sufficient characterization for chert sourcing.     

Geochemical discrimination of basaltic sources as a tool for provenance analyses of bifacial tools in the southern Levant: first results from the Jezreel Valley,Israel

The determination of groundstone tool sources bears the potential to examine aspects like raw material selection and preference, mobility, trade and exchange patterns, control over resources and long term use of raw material sources. The discovery of the Neolithic/Chalcolithic basanite bifacial quarry of Giv'at Kipod in the Jezreel Valley, Israel, provides the opportunity of raw material centred provenance studies of bifacials in the southern Levant. The basis for reliable provenance analyses is a clear geochemical characterization of the extraction site and its discrimination from other potential sources. To achieve this, the Miocene magmatic rocks of the Jezreel Valley were sampled and analysed by XRF and La-ICP-MS. The geochemical evaluation, combined with cluster analyses, resulted in a clear discrimination of the Giv'at Kipod lava from other basaltic sources in the area. Based on the geochemical field data, a Giv'at Kipod provenance for six bifacial tools found in three archaeological sites dated to the Neolithic and the Chalcolithic periods was established. The results suggest that the quarry was in use for several millennia. This pilot study demonstrates that for provenance analyses lava outcrops in the southern Levant can be geochemically discriminated from each other on a very small spatial scale, on the basis of a detailed field sampling and the application of multivariate methods.     

Multi-Isotope Investigations for Scientific Characterisation and Provenance Implication of Banded Travertines from Tripolis Antique City (Denizli–Turkey)

The coloured stones used in buildings and monuments were an indicator of power and wealth during the ancient times. In this study, Tripolis city samples have been compared with Tripolis quarry samples in order to recognise the provenance of the banded travertine blocks in the ancient city. The banded travertine samples have similar mineral compositions and mainly consist of calcite with minor amounts of dolomite, aragonite, clay and iron oxide minerals. These results are also supported by CRS studies. Calcite is in the form of needle-shaped crystals ranging between 0.163–1.418?mm (in city) and 0.303–1.270?mm (in quarry). Tripolis banded travertine samples show the similar compositional spread in terms of major oxide, trace elements. δ¹³C_V-PDB values of banded travertines range from 1.93 to 5.25‰ (in city) and 2.99 to 3.99‰ (in quarry), δ¹⁸O_V-PDB values change between (?16.93)–(?10.08) ‰ and (?15.93)–(?13.01)‰, respectively. The U–Th radiometric ages are determined between ～267 and 9?ka in Tripolis city samples and ～350 and 2?ka in Tripolis quarry samples. The minero-petrographic, geochemical, C–O and U–Th isotope results fairly matched with each other. It seems highly probable that the banded travertines in Tripolis city were extracted from the Tripolis quarry, which is located at the northeast of the antique city with a distance of 3?km.     

Characterizing Quartz Artefacts: A Case Study from Manitoba's Northern Boreal Forest

Visual and geochemical analyses of 30 pre‐contact quartz tools from the Churchill River basin of northern Manitoba were used to provisionally assess source provenance based on comparison to local quartz quarry data. The results indicate that tools made from quartz acquired from these quarries were transported and eventually deposited into archaeological sites up to 200 km away. Transport of this quartz, which is of relatively moderate quality, over such distances suggests that stone tool–using hunter–gatherer populations that lived in the Churchill River basin of northern Manitoba were highly mobile. It also indicates that higher‐quality raw materials were unavailable in the immediate area.     

New data of 87Sr/86Sr ratio in classical marble: an initial database for marble provenance determination

⁸⁷Sr/⁸⁶Sr ratios are presented for white marbles collected from some of the most famous classical quarry areas of the Mediterranean: Carrara, Paros, Naxos, Pentelikon, Dokimeion, Hymettus, Thasos, and Proconnesus. These ratios range from 0.7071 to 0.7092. The ranges of the different quarry areas are notably superimposed; this prevents a common adoption of this parameter in distinguishing the quarry locations for the classification of the provenance of marbles used during classical times for architectural and sculptural artefacts. However some quarry areas show peculiar distributions of their isotopic values, which could help to assign the provenance to an unknown marble artefact.Adding these new data to the scarce number of strontium isotopic compositions measured on white marbles and available in the relevant literature, permits the creation of an initial database of 11 classical quarry locations. This database confirms that the strontium isotope ratio could be used in marble provenance determination, together with petrographic and geochemical methods, as an ancillary technique.     

From flow to quarry: magnetic properties of obsidian and changing the scale of archaeological sourcing

Previous studies have endeavored to use petrophysical traits of obsidian, particularly its magnetic properties, as an alternative to conventional geochemical sourcing, one of the greatest successes in archaeological science. Magnetic approaches, however, have not seen widespread application due to their mixed successes. In a time when geochemical analyses can be conducted non-destructively, in the field, and in a minute or two, magnetic measurements of obsidian must offer novel archaeological insights to be worthwhile, not merely act as a less successful version of geochemistry. To this end, we report the findings of our large-scale study of obsidian magnetism, which includes 734 geological obsidian specimens and 97 artifacts measured for six simple magnetic parameters. Based on our results, we propose, rather than using magnetic properties to source artifacts to a particular obsidian flow (inter-flow sourcing), these properties are best used to differentiate quarrying sites within an individual flow (intra-flow sourcing). Our results also demonstrate that certain magnetic properties are highly affected by ancient knappers' material selection criteria. Furthermore, depending on the spatial scales of variation, which likely vary from flow to flow, we envision several potential applications of this approach, including integration into minimum analytical nodule analysis (MANA). Magnetic data appear to shift the scale of obsidian sourcing from flows to quarries and, in turn, enable new insights into raw-material procurement strategies, group mobility, lithic technology, and the organization of space and production.     

Measuring prehistoric mobility strategies based on obsidian geochemical and technological signatures in the Owens Valley,California

We compare the organization of obsidian flaked stone technologies in two different time periods at CA-INY-30, a village site in southern Owens Valley, eastern California. Previous archaeological studies suggest a reorganization in settlement patterns between the Newberry (ca. 3500–1500 BP) and Marana (ca. 650-contact) periods, from a highly mobile to a more residentially sedentary one. New geochemical data, based on laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) analyses of obsidian artifacts associated with discrete house floors, support this basic settlement model, but reveal new detail in how people moved across the landscape and accessed, extracted, reduced and used obsidian resources. In the earlier Newberry period, there is no relationship between flake size and distance-to-source, and the falloff curve relating frequency of obsidian against distance is more gradual, as expected, but contrary to our expectations, source diversity is not higher. These factors suggest extremely high mobility, but also selective extraction of particular sources. Newberry obsidian may have been acquired by groups of hunters who embedded quarrying within long-distance trips to distant hunting grounds, and subsequently transported bifacial cores to base camps. By contrast, Marana patterns show strong relationships between flake size and distance from source and steeper fall-off curves, suggesting groups acquired their obsidian primarily from closer sources, likely via exchange networks. At the same time, geochemical diversity, especially among smaller resharpening flakes, is higher in the Marana period, highlighting the wide-ranging conveyance systems through which obsidian moved.     

Energy-Dispersive X-Ray Fluorescence analysis of Haleakalā basalt adze quarry materials, Maui, Hawai‘i

One of Hawai‘i’s major prehistoric basalt adze quarries (SIHP 50-50-11-2510) is located in the summit region of Haleakalā, Maui. Situated at approximately 2750 m above sea level (9000 ft), the quarry shares a similar high-altitude setting with the Mauna Kea adze quarry on Hawai‘i Island. Adding to a growing Energy-Dispersive X-Ray Fluorescence (EDXRF) database for the Hawaiian Islands, we present the results from 255 geological and archaeological lithic samples from the Haleakalā quarry site. We also briefly discuss why this non-destructive XRF technique is particularly applicable in the Hawaiian cultural context.     

A Twenty-First Century Archaeology of Stone Artifacts

Archaeologists today, as in the past, continue to divide their stone artifact assemblages into categories and to give privilege to certain of these categories over others. Retouched tools and particular core forms, for instance, are thought to contain more information than the unretouched flakes and flake fragments. This reflects the assumption that information to be gained from stone artifacts is present within the artifact itself. This study evaluates a continued interest in the final form of stone artifacts by first considering ethnographic accounts of stone artifact manufacture and use in Australia and then by utilizing the patterns observed in these accounts to investigate assemblage patterning within an Australian archaeological case study. Reading the ethnographic accounts provides no indication that Aboriginal people valued more or less complex artifacts, in uniform ways, in every situation. In fact, the opposite is true. Stone artifacts were always valued in some sense but which ones, and in which ways, depended on the situations the people who needed the artifacts found themselves in. Aboriginal people were quite capable of making and using expedient and informal artifacts in complex ways. The significance of these observations is considered for stone artifact studies in general and in relation to a case study from western New South Wales, Australia.