Consideration on the construction process and the sandstone quarries during the Angkor period based on the magnetic susceptibility

Detailed magnetic susceptibility measurement was conducted on the sandstones used for the Angkor monuments constructed in the period spanning the Preah Ko and Angkor Wat styles, and the construction process of the buildings and quarries of the sandstones was considered. Combined with the previous study on the sandstones of the Bayon style [Uchida, E., Cunin, O., Shimoda, I., Suda, C., Nakagawa, T., 2003. The construction process of the Angkor monuments elucidated by the magnetic susceptibility of sandstone, Archaeometry 45, 221–232], the magnetic susceptibility measurement revealed that there were 7 sandstone quarries corresponding to Stages I, II, III, IVa, V, VII and VIIIb during the Angkor period. The sandstones used for the monuments belonging to Stage I show average magnetic susceptibility values ranging from 1.1 to 2.3 × 10⁻³ SI units. In the Bakheng style period (Stage II), the average magnetic susceptibility of the supplied sandstones decreased gradually from around 10 to 1 × 10⁻³ SI units over time. The magnetic susceptibility range of the sandstones used for the monuments of Stage III was from 2.3 to 3.0 × 10⁻³ SI units. In the early Angkor Wat style period (IVb), the average magnetic susceptibility of the supplied sandstones increased over time, reflecting the supply of the sandstones from two different quarries, that is, the quarry corresponding to the Khleang and Baphuon style monuments (Stage IVa), with low average magnetic susceptibilities of 1.1 to 2.4 × 10⁻³ SI units, and the quarry corresponding to the main Angkor Wat style monuments (Stage V), with high average magnetic susceptibilities ranging from 2.8 to more than 4.3 × 10⁻³ SI units. The sandstones of Stage VII show low average magnetic susceptibility around 1 × 10⁻³ SI unit. The sandstones of Stage VId is a mixture of sandstones of Stages V and those of Stage VII. The sandstones with high magnetic susceptibilities are found in the monuments belonging to Stage VIIIb, reflecting the supply from the new sandstone quarry.     

Nature and provenance of the sandstone used for Bayon style sculptures produced during the reign of Jayavarman VII

Under Jayavarman VII (1182/83-ca.1218 CE) the Khmer empire reached its apex, leaving a heritage of major construction works and unique artistic production. The stone materials of several sculptures produced under his reign were characterized and compared to possible geological sources in northern and eastern Cambodia. The data suggest that a specific type of sandstone, rich in volcanic detritus, was deliberately selected and quarried from a Triassic sedimentary sequence exposed far from Angkor, the main political and economic center at that time.     

Salt weathering of sandstone at the Angkor monuments,Cambodia: identification of the origins of salts using sulfur and strontium isotopes

The Angkor monuments in northwestern Cambodia, which are primarily made of sandstone, are suffering from deterioration due to salt weathering. In order to elucidate the sources of the salts and salt weathering process, this paper analyzed bulk chemical compositions and S (sulfur) and Sr (strontium) isotopic ratios for the salts and surrounding environmental materials. At places where bats inhabit the structures, various kinds of sulfate and phosphate salts are formed on the surface of the sandstone. The results of the analysis demonstrate that the S and P (phosphorus) components in the salts are primarily derived from bat guano. Moreover, Ca (calcium), which is the major element in the salts, is suggested to be derived from both bat guano and the sandstone. The isotopic data strongly suggests that bat guano is related to salt weathering. Removal of these animal excrements is essential for future conservation of these monuments. On the other hand, exfoliation of sandstone commonly occurs due to crystallization of calcite (CaCO₃) on platform surfaces of pyramid-type monuments. A large amount of Ca in calcite is suggested to be derived from calcite cement of the building sandstone.     

New insights regarding the Akko 1 shipwreck: a metallurgic and petrographic investigation of the cannonballs

The Akko 1 shipwreck constitutes the remains of a small Mediterranean naval vessel, discovered in Akko harbour, Israel, and excavated over three seasons between 2006 and 2008. Among the finds at the shipwreck site were eleven cannonballs. Two of them, a 9-pdr and a 24-pdr, were retrieved and studied using metallurgical and petrographic methods. The examination of the cast-iron was performed with optical microscopy, SEM–EDS, XRF and microhardness tests. The remains of the casting sand from within the voids in both cannonballs were studied by petrography. Combined with the archaeological evidence and the historical background, the metallurgical and petrographic testing may suggest that Akko 1 was a warship or an auxiliary naval vessel of similar size to, or slightly smaller than, sixth rate, and was in Akko harbour circa 1840.     

INAA of pre-contact basalt quarries on the Samoan Island of Tutuila: a preliminary baseline for an artifact-centered provenance study

This project presents a material-centered instrumental neutron activation analysis (INAA) characterization of 120 geologic samples selected from four fine-grained basalt quarries on the Samoan Island of Tutuila. Previous attempts at definitive differentiation of these Tutuilan quarries have utilized x-ray fluorescence (XRF). In this study, clear differentiation of each analyzed quarry was achieved using INAA. Biplots of canonical discriminant analysis (CDA) scores for the INAA data illustrate clear separation based on the variation in chemical composition between each quarry. The samples analyzed not only define quarry separation, but also provide the “core group” for a preliminary baseline necessary for future artifact-centered provenance studies. Inclusion of these “core group” samples in the baseline was confirmed by stepwise discriminant analysis. These findings suggest the ability to determine artifact quarry of origin on the island of Tutuila, which can elucidate the importance of individual Tutuilan quarries in the production, distribution and consumption of fine-grained basalt artifacts in Polynesia.     

Trace elements in palaeopathology: Quantitative analysis of a case of hypertrophic osteoarthropathy by instrumental neutron activation analysis

Instrumental neutron activation analysis (INAA) of the bones of a 6th century case (AD ) of hypertrophic osteoarthropathy (HOA) showed high levels of Zn, Mn and K in the periosteal new bone. The concentration of Zn in the periosteal new bone appeared to be biogenetic in origin and connected with active mineralization processes in the abnormal bone tissue. Manganese and potassium concentrations were, at least partly, related to diagenetic processes.     

Developing baseline data to understand environmental change: a geochemical study of archaeological otoliths from the Coorong,South Australia

Otoliths are calcium carbonate structures found in the inner ear of teleost fish. While they are routinely studied by marine scientists, analyses of otoliths recovered from archaeological sites in Australia and the Pacific have generally been restricted to identification of species and sometimes the fish age. Otoliths can also provide information on the season of catch, and, through trace element analysis, allow the reconstruction of environmental conditions experienced by fish. In this study, we use otoliths from mid- to late Holocene aged archaeological shell middens at the Coorong (South Australia) to examine species present, season of catch, age of fish and environmental conditions experienced by fish. Results demonstrate that the majority of the fish (identified as Argyrosomus japonicus and Acanthopagrus butcheri) were caught in freshwater environments during the warm season, and had grown to an age and size indicative of their having reached sexual maturity. This study provides data indicating fluctuating levels of salinity in the estuary, which are significantly lower than the hypersaline conditions experienced today. Ultimately, this project highlights the usefulness of conducting more detailed investigations of otoliths, including geochemical analyses, to address a wide range of research questions in archaeology and palaeoenvironmental research.     

Archaeological carved slabs of the Langobard art in churches of Peligna Valley and Spoleto (Italy): provenance of the stones

In this study we investigate the provenance of the limestone and marble used to made carved slabs today placed in three churches located in Raiano and Vittorito (Peligna Valley, Abruzzo, Italy) and in Spoleto (Umbria, Italy). The slabs, representative examples of the Langobard art (Middle Ages), are dated approximately from 8th to 9th centuries A.D. and have the same pattern in terms of decoration, suggesting a progressive expansion of Langobards in central and southern Italy, after the foundation of the Pavia Kingdom.     

Provenancing the rhyolitic and dacitic components of the Stonehenge landscape bluestone lithology: new petrographical and geochemical evidence

The source of the bluestone component found in the Stonehenge landscape has long been the subject of great interest and considerable debate. The bluestones are a mix of lithologies, the standing orthostats being predominantly dolerites, variably ‘spotted’, with only four of them being of dacitic and rhyolitic composition and the Altar Stone being sandstone. However in the 1920s the spotted dolerites were sourced to outcrops which comprise tors in the summit regions of the Mynydd Preseli in north Pembrokeshire, west Wales. There were also speculations about the possible sources of the dacitic and rhyolitic components, ideas which were elaborated on in the early 1990s when the original petrological provenancing was supplemented by whole-rock geochemical analysis. Most recently, new petrographical investigations have been combined with zircon geochemical data to determine the possible source of one type of rhyolite, the so-called ‘rhyolite with fabric’, found abundantly as débitage in the Stonehenge landscape (but not composing the four orthostats) to outcrops in the vicinity of Pont Saeson, especially a large craggy outcrop called Craig Rhos-y-felin, located in low ground to the north of the Mynydd Preseli. In order to test this provenance whole-rock geochemical analysis has been undertaken on samples of débitage from the Stonehenge landscape and from the Pont Saeson area, including Craig Rhos-y-felin. These data are then compared with other new and existing geochemical data for dacitic and rhyolitic lithologies recovered from the Stonehenge landscape, including the four orthostats, as well as geochemical data from outcrops of the same lithologies from the two main volcanic horizons exposed across north Pembrokeshire, namely the Fishguard Volcanic Group and the Sealyham Volcanic Formation, both of Ordovician age. This study concludes that previous, 20th century, attributions of provenance to a number of dacitic and rhyolitic outcrops in the north Pembrokeshire have been in error whilst the new data for the Pont Saeson rhyolite accords well with elemental contents recorded in the ‘rhyolite with fabric’ lithology from the Stonehenge landscape débitage. This study therefore endorses the proposal that the Pont Saeson area is indeed the source of the ‘rhyolite with fabric’ lithology recovered from numerous sites in the Stonehenge landscape, and is the only reliable provenance for any of the dacitic and rhyolitic bluestone material collected to date. It also serves to endorse the use of zircon chemistry as a provenancing tool in archaeopetrological investigations.     

Gabbroic clay sources in Cornwall: a petrographic study of prehistoric pottery and clay samples

Summary.  This analysis of prehistoric pottery and clay samples from Cornwall demonstrates that the clay used to make Cornish gabbroic pottery in prehistory originated around the gabbro rock outcrop in a small area of the Lizard peninsula. The research uses petrographic and chemical analysis to subdivide the prehistoric pottery into six groups. Owing to the unusual geology of the Lizard these groups can be attributed to specific locations. The most abundant pottery fabric, Typical Gabbroic , was made using coarse clay which is mainly found in a 1 km² area near Zoar. A finer version of this clay, found higher in the soil profile or slightly transported and redeposited, was used to make Fine Gabbroic pottery and an even finer variant called FNS (Fine Non-Sandy) Gabbroic . We identify for the first time here a Loessic/Gabbroic pottery fabric which can be matched exactly to clay found at Lowland Point. Serpentinitic/Gabbroic pottery was made using clay from the gabbro/serpentinite border zone. Pottery made from the Granitic/Gabbroic fabric did not match any clay from the Lizard, showing that gabbroic clay was sometimes removed and made into pottery elsewhere in Cornwall. The main clay source near Zoar was used for clay extraction throughout the Bronze Age and Iron Age for pottery which was traded all over Cornwall. Other gabbroic clay sources produced pottery only during certain periods and exclusively supplied particular settlements, such as the Loessic/Gabbroic fabric which was found only at Gear and Caer Vallack. The results suggest that pottery was produced by several small-scale cottage industries, which may have operated on a seasonal, part-time basis and probably formed only part of a wide range of activities located around the Lizard area.     

Provenance study of early and middle bronze age pottery from Kaman-Kalehöyük,Turkey, by heavy mineral analysis and geochemical analysis of individual hornblende grains

The provenance of Early Bronze Age and early Middle Bronze Age pottery produced between 2100 and 1970 B.C. and excavated from Kaman-Kalehöyük, Turkey was studied using mineralogical methods, including heavy mineral analysis and geochemical study of individual hornblende grains. The relative abundances of heavy minerals in the fabrics of 20 Early Bronze Age (EBA) and early Middle Bronze Age (MBA) pottery sherds, together with 27 local sediments collected within a radius of 25 km of the site were studied. The heavy mineral distributions in the Kaman region were statistically analyzed for consistencies in their occurrence. Amphibole was found to be the most abundant heavy mineral in most of the analyzed samples, followed by titanite and epidote. The amounts of other minerals such as garnet, clinopyroxene, and zircon are subordinate. Different proportions of heavy minerals in the fabrics allow categorization of the EBA and early MBA potteries into 5 groups. Comparative study of heavy mineral assemblages of local sediments and pottery suggests that half of the EBA and most of the MBA potteries were produced from sediment near the excavation site, whereas the other half of the EBA potteries were produced from sediment occurring at 25 km east or more east of the site. The geochemistry of individual amphibole grains was studied by electron-microprobe analysis. Most of the studied amphibole grains are calcic and aluminous, corresponding to hornblende. They can be further characterized into four types based on their chemical composition. The combination of heavy mineral identity and hornblende geochemistry provides diagnostic evidence for the origins of Kaman-Kalehöyük pottery. These and analogous heavy mineral techniques are effective archaeometric tools for determining pottery provenance.     

Petrographic and geochemical investigations of the late prehistoric ceramics from Sos Höyük,Erzurum (Eastern Anatolia)

Ceramics from the late prehistoric periods at Sos Höyük, in Eastern Anatolia, located along a thoroughfare that connects the Trans-Caucasus, Iran and central Anatolia, were subjected to petrographic and X-ray fluorescence analysis in order to characterise the clay groups, with a view to determining provenance and production patterns. Dominated by Kura-Araxes Ware, the data from the sequence at Sos Höyük were compared with the previous studies from the neighbouring regions to understand commonalities in pottery production. The analyses reveal a local production of vessels, most probably for household use. Although Sos Höyük potters shared similarities in the procurement pattern of raw clays and production technique with their neighbours, differences can be also recognized.     

Slag inclusions in iron objects and the quest for provenance: an experiment and a case study

Slag inclusions are found within most archaeological bloomery iron artefacts and are remainders of slag created during the smelting and smithing processes. Although they are widely believed to provide data with the potential for provenancing iron artefacts, previous slag inclusion studies have mostly proven inconclusive. The main aim of the work reported here is to analyse experimental smelting and smithing assemblages (including ore, furnace lining, fuel and slag), to compare these to slag inclusions in the resulting bloom and worked objects, and then explore the relationships between ore, slag and slag inclusions. This study has revealed that the composition of slag inclusions most closely relates to the smelting slag produced, whereas provenance to a specific ore would be difficult due to the chemical variability derived from furnace lining, fuel and any fluxes used. Some compounds in the slag inclusions are particularly affected during smithing of the artefact, i.e. those present in the sand flux and fuel used. However, trends are observed in the K₂O/MgO, MnO/SiO₂, Al₂O₃/SiO₂, Al₂O₃/MgO, Al₂O₃/K₂O and Al₂O₃/CaO ratios that allow comparison between slag inclusions and smelting slag in these experiments, and may therefore be used during other provenancing attempts. The knowledge gained from the experimental assemblages was subsequently applied to an archaeological case study, examining objects from the 900 Cal BC smithing site of Tel Beth-Shemesh, Israel and the 930 Cal BC smelting site of Tell Hammeh, Jordan. The analyses suggest that none of the artefacts examined derived from the Hammeh smelting system.     

Geochemical provenance analyses of Roman lava millstones north of the Alps: a study of their distribution and implications for the beginning of Roman lava quarrying in the Eifel region (Germany)

In Roman times, rotary querns and different types of millstones, driven either by horse-capstan or water power, were produced in the lava quarries of the quaternary volcanic Eifel region and exported to many parts of the Empire. The geographic distribution of Roman lava millstones from the Eifel region provides important information about trade patterns and, in cases of well dated millstones, also allows an estimate as to when the Roman lava quarrying in the Eifel region began. Sixty-two millstones from Germany, France and Austria were sampled and analyzed for major and trace elements by X-ray fluorescence. To determine their provenance, the millstone data was evaluated by a combination of geochemical discrimination and cluster and discriminant analyses using an extensive and detailed database of all Roman lava quarries in the Eifel region. An Eifel provenance could be confirmed for forty-four artefacts and, furthermore, determined down to the exact lava flow. The affiliation of the other artefacts to other possible regions where millstones of comparable lava were extracted was carried out on the basis of geochemical data from the literature. However, because of insufficient data, only assumptions about the regional provenance can be made. The origins of the other finds are assumed to be the Vogelsberg region, the Massif Central, Orvieto, and, possibly, the Pannonian Basin. A preliminary map of the distribution of Eifel millstones in Roman times based on these data is presented; the beginning of Roman lava quarrying can be constrained to 8–7 BC.     

Celtic vitrified forts: Implications of a chemical-petrological study of glasses and source rocks

The term “vitrified forts” refers to remnants of stony fortifications of early Iron Age in which constituent rock fragments and boulders have been melted and/or welded together by heat, apparently in situ. The methods used are a matter of controversy, and even the question whether the firing was constructive or destructive is disputed. In this study we present bulk analyses of some twenty source rocks and of fifty glasses (in petrographic thin sections) from eleven sites and attempt to relate these data to the processes (and purposes) producing the observed sintering, welding and melting. The results are consistent with progressive partial, sometimes total, melting of the rocks used. In agreement with most previous investigators we conclude that no exotic rocks (although limited amounts of clays or organic debris cannot be excluded) were used as flux nor were easily fusible materials selected. On the other hand, simply burning an ordinary (of the later murus gallicus type) timber-laced wall cannot account for the evidence of strongly reducing conditions and sustained high temperatures, probably for days and in some cases well above 1000 °C. Rather, the fires seem to have been contained, perhaps by filling the space between the rocks in the timber framework with soil, clay and combustible materials, e.g. peat, brushwood and domestic debris. We cannot conclude whether the firing was accidental, or set by enemies or by the builders. In any case, the builders appear to have used more sophisticated techniques than previously believed to ensure the durability of their constructions.     

Fluid flow and the Heart Mountain fault: a stable isotopic, fluid inclusion, and geochronologic study

Numerous studies have proposed that movement along the 3400‐km² low‐angle (<3°) Heart Mountain detachment fault of north‐western Wyoming and south‐western Montana was facilitated by the presence of lubricating fluids. A recent stable isotope study suggested that the fluids along the Heart Mountain fault originated from large hydrothermal systems associated with Eocene intrusive centers. Herein, we present results from a combined stable isotope, fluid inclusion, and ⁴⁰Ar/³⁹Ar geochronology study of the relationship between shallow crustal fluids from Eocene intrusive centers in the New World Mining district and fluids associated with the Heart Mountain fault. Our results suggest that: (i) Eocene intrusive bodies within the New World Mining District focused hydrothermal fluids along specific units and structures from the ore deposit centers along the Heart Mountain fault detachment surface; (ii) hydrothermal waters were focused along the Heart Mountain fault from the breakaway region near Silvergate, Montana toward Heart Mountain in Cody, Wyoming; and (iii) hydrothermal activity along the Heart Mountain fault occurred at the same time as emplacement of the Eocene intrusives, between 50.1 and 48.1 Ma. These data, taken together, suggest that the hydrothermal activity generated by intrusion of Eocene rhyodacites and dacites provided the source of fluids found along the Heart Mountain fault plane.     

Barite–pyrite mineralization of the Wiesbaden thermal spring system, Germany: a 500-kyr record of geochemical evolution

Barite–(pyrite) mineralizations from the thermal springs of Wiesbaden, Rhenish Massif, Germany, have been studied to place constraints on the geochemical evolution of the hydrothermal system in space and time. The thermal springs, characterized by high total dissolved solids (TDS) contents and predominance of NaCl, ascend from aquifers at 3–4 km depth and discharge at a temperature of 65–70°C. The barite–(pyrite) mineralization is found in upflow and discharge zones of the present‐day thermal springs as well as at elevations up to 50 m above the current water table. Hence, this mineralization style constitutes a continuous record of the hydrothermal activity, linking the past evolution with the present state of this geothermal system. The sulphur isotope signatures of the mineralization indicate a continuous decrease of the δ³⁴S of sulphate from +16.9‰ in the oldest barite to +10.1‰ in the present‐day thermal water. The δ³⁴S values of barite closely resemble various recently active thermal springs along the southern margin of the Rhenish Massif and contrast strongly with different regional ground and mineral waters. The mineralogical and isotopic signatures, combined with calculations based on uplift rates and the regional geological history, indicate a minimum activity of the thermal spring system at Wiesbaden of about 500 000 years. This timeframe is considerably larger than conservative models, which estimate the duration of thermal spring systems in continental intraplate settings to last for several 10 000 years. The calculated equilibrium sulphur isotope temperatures of coexisting barite and pyrite range between 65 and 80°C, close to the discharge temperature of the springs, which would indicate apparent equilibrium precipitation. Kinetic modelling of the re‐equilibration of the sulphate–sulphide pair during water ascent shows that this process would require 220 Myr. Therefore, we conclude that pyrite is formed from precursor Fe monosulphide phases, which rapidly precipitate in the near‐surface environment, preserving the isotope fractionation between dissolved sulphate and sulphide established in the deep aquifer. Equilibrium modelling of water–mineral reactions shows slight supersaturation of barite at the discharge temperature. Pyrite is already strongly supersaturated at the temperatures estimated for the aquifer (110°C) and processes in the near‐surface environment are most probably related to contact of the thermal water with atmospheric oxygen, resulting in formation of oxidized intermediate sulphur species and precipitation of Fe monosulphide phases, which subsequently recrystallize to pyrite.     

“Measure for measure”: a taphonomic reconsideration of the Kebaran site of Ein Gev I,Israel

We present the results of a detailed taphonomic study of the faunal remains from Ein Gev I, a Kebaran open-air site near the Sea of Galilee, Israel. In an earlier study faunal remains were assigned to bone element and species using a rapid method technique based on the identification of teeth and epiphyses only (Davis, 1974). In this study we identified the maximum number of skeletal elements, including fragments of long bone shafts. We also employed a series of taphonomic analyses to reconstruct the depositional history of the bone assemblage and to investigate subsistence, meat procurement and bone processing strategies. We compared the results obtained by a complete bone sampling method with those derived using a rapid method. The bone assemblage is dominated by mountain gazelle (Gazella gazelle), Mesopotamian fallow deer (Dama mesopotamica) and bezoar goat (Capra aegagrus). The assemblage is characterized by significant density-mediated biases, caused by both human bone processing behaviours and in situ post-burial bone attrition. Our attempts to compare species abundance derived from the two different identification protocols revealed no significant difference between the two sampling methods, both in terms of species diversity (richness and evenness) and skeletal element abundance (SEA). These comparisons contrast previous studies that expected to find ubiquitous head-and-foot dominated SEA profiles in zooarchaeological studies that were based on the incomplete identification of faunal remains.     

Characterization and origin of black and red Magdalenian pigments from Grottes de la Garenne (Vallée moyenne de la Creuse-France): a mineralogical and geochemical approach of the study of prehistorical paintings

Pigments sampled from wall paintings and from crayons taken on the floor, at the Grottes de la Garenne (Saint-Marcel – Indre, France) have been analyzed and characterized by infrared spectroscopy, Raman micro-spectroscopy, X-ray diffraction, ICP/MS and analytical TEM. The red pigment used for the wall paintings is mainly composed by hematite, clays, carbon matter and carbonates. Results on the red pigments show that the compositions of the paintings are similar to that of some crayons. Regarding these analyses, their origin is compatible with local siderolithic facieses. Analysis of black pigments shows that they are made of cryptomelane, pyrolusite, clays, carbonates and carbon matter. It shows also that paintings and some crayons compositions are compatible. On the contrary of red pigments, the origin of black pigments is probably allochtonous. Indeed, the traces of thallium detected in cryptomelane, the cerium anomaly and the absence of iron are not compatible with local facieses or other sites from the French Massif Central.     

Musical constructions of nationalism: a comparative study of Bartók and Stravinsky

Abstract. This article argues that music, and in particular the history of music, can make a considerable contribution to the study of nations and nationalism and illustrates it by analysing Béla Bartók and Igor Stravinsky, relating these analyses to significant debates within theories of nations and nationalism. Within studies of nations and nationalism the article concentrates on the different interpretations of the term ‘construction’ expressed in the works of Eric Hobsbawm and Anthony D. Smith.