Diverse origins and timing of formation of basinal brines in the Gulf of Mexico sedimentary basin

A review of five different field areas in the Gulf of Mexico sedimentary basin (GOM) illustrates some of the potentially diverse chemical and physical processes which have produced basinal brines. The elevated salinities of most of the formation waters in the GOM are ultimately related to the presence of the Middle Jurassic Louann Salt. Some of these brines likely inherited their salinity from evaporated Mesozoic seawater, while other saline fluids have been produced by subsequent dissolution of salt, some of which is occurring today. The timing of the generation of brines has thus not been restricted to the Middle Jurassic. The mechanisms of solute transport that have introduced brines throughout much of the sedimentary section of the GOM are not entirely understood. Free convection driven by spatial variations in formation water temperature and salinity is undoubtedly occurring around some salt structures. However, the driving mechanisms for the broad, diffusive upward solute transport in the northern Gulf rim of Arkansas and northern Louisiana are not known. In the Lower Cretaceous of Texas, fluid flow was much more highly focused, and perhaps episodic. It is clear that many areas of the Gulf basin are hydrologically connected and that large‐scale fluid flow, solute transport, and dispersion have occurred. The Na‐Mg‐Ca‐Cl compositions of brines in the areas of the Gulf Coast sedimentary basin reviewed in this article are products of diagenesis and do not reflect the composition of the evaporated marine waters present at the time of sediment deposition. Large differences in Na, Ca, and Mg trends for waters hosted by Mesozoic versus Cenozoic sediments may reflect differences in: (i) the sources of salinity (evaporated seawater for some of the Mesozoic sediments, dissolution of salt for some of the Cenozoic sediments); (ii) sediment lithology (dominantly carbonates for much of the Mesozoic sediments, and dominantly siliciclastics for the Cenozoic sediments); or (iii) residence times of brines associated with these sediments (tens of millions of years versus perhaps days).     

Infiltration of basinal fluids into high-grade basement, South Norway: sources and behaviour of waters and brines

Quartz veins hosted by the high‐grade crystalline rocks of the Modum complex, Southern Norway, formed when basinal fluids from an overlying Palaeozoic foreland basin infiltrated the basement at temperatures of c. 220°C (higher in the southernmost part of the area). This infiltration resulted in the formation of veins containing both two‐phase and halite‐bearing aqueous fluid inclusions, sometimes with bitumen and hydrocarbon inclusions. Microthermometric results demonstrate a very wide range of salinities of aqueous fluids preserved in these veins, ranging from c. 0 to 40 wt% NaCl equivalent. The range in homogenization temperatures is also very large (99–322°C for the entire dataset) and shows little or no correlation with salinity. A combination of aqueous fluid microthermometry, halogen geochemistry and oxygen isotope studies suggest that fluids from a range of separate aquifers were responsible for the quartz growth, but all have chemistries comparable to sedimentary formation waters. The bulk of the quartz grew from relatively low δ¹⁸O fluids derived directly from the basin or equilibrated in the upper part of the basement (T < 200°C). Nevertheless, some fluids acquired higher salinities due to deep wall‐rock hydration reactions leading to salt saturation at high temperatures (>300°C). The range in fluid inclusion homogenization temperatures and densities, combined with estimates of the ambient temperature of the basement rocks suggests that at different times veins acted as conduits for influx of both hotter and colder fluids, as well as experiencing fluctuations in fluid pressure. This is interpreted to reflect episodic flow linked to seismicity, with hotter dry basement rocks acting as a sink for cooler fluids from the overlying basin, while detailed flow paths reflected local effects of opening and closing of individual fractures as well as reaction with wall rocks. Thermal considerations suggest that the duration of some flow events was very short, possibly in the order of days. As a result of the complex pattern of fracturing and flow in the Modum basement, it was possible for shallow fluids to penetrate basement rocks at significantly higher temperatures, and this demonstrates the potential for hydrolytic weakening of continental crust by sedimentary fluids.     

Salinity structure of the central North Slope foreland basin, Alaska, USA: implications for pathways of past and present topographically driven regional fluid flow

Previous studies of the areal variation in heat flow in the National Petroleum Reserve Alaska (NPRA) support the existence of an active topographically driven regional fluid flow regime in this central part of the North Slope foreland basin. Drilling records and wireline logs for over 30 wells drilled in the NPRA provide additional field information, which can be used to further constrain interpretation of the pattern of regional flow of basinal waters within the NPRA. Hydraulic heads estimated from drilling mud weights show that ground water flow occurs generally from south to north, but with divergence to the north‐east and north‐west away from the central part of the NPRA towards coastal areas of elevated shallow heat flow. Salinities calculated from SP logs range from less than 1 g L^?1, to marine values of 35 g L^?1, to hypersaline values of over 150 g L^?1. The entire upper sedimentary section to a depth of 2 km or more in the eastern part of the NPRA has been preferentially flushed with meteoric water through an area corresponding to the sandiest portion of the Nanushuk group. Deeper areas of low salinity occur within the Sadlerochit and Lisburne sections. The pattern of regional flow in the east is complicated, however, by the presence of a large mass of hypersaline water at depth. It is not known whether these brines are being displaced laterally and upward towards the discharge end of the basin or whether fresher waters are simply riding up over the top. Deep, hypersaline waters also occur in fault slices in the Brooks Range and have survived meteoric flushing. The brines were probably formed at the time of deposition of the Lisburne carbonates. The fluid flow regime to the west is different. Low‐salinity waters may be flowing northward underneath this section through the Ellesmerian section and discharging upward nearer the coast. However, sparse well log control severely limits what can be deduced about the details of flow paths in the central and western parts of the NPRA.     

Topography‐driven flow versus buoyancy‐driven flow in the U.S. midcontinent: implications for the residence time of brines

Topography‐driven flow is normally considered to be the dominant groundwater flow system in uplifted sedimentary basins. In the U.S. midcontinent region east of the Rocky Mountains, the presence of brines derived from dissolution of halite suggests that significant topography‐driven flushing has occurred to remove older brines that presumably formed concurrently with Permian evaporites in the basin. However, the presence of evaporites and brines in the modern basin suggests that buoyancy‐driven flow could limit topography‐driven flushing significantly. Here we used numerical models of variable‐density fluid flow, halite dissolution, solute transport, and heat transport to quantify flow patterns and brine migration. Results indicate the coexistence of large‐scale topography‐ and buoyancy‐driven flow. Buoyancy‐driven flow and low permeability evaporites act to isolate brines, and the residence time of the brines was found to be quite long, at least 50 Myr. The modern distribution of salinity appears to reflect near‐steady‐state conditions. Results suggest that flushing of original evaporatively‐concentrated brines occurred tens of millions of years ago, possibly concurrent with maximum uplift ca. 60 Ma. Simulations also suggest that buoyancy‐driven convection could drive chemical exchange with crystalline basement rocks, which could supply significant Ca²⁺, Sr²⁺, and metals to brines.     

Mobilization of ore fluids during Alpine metamorphism: evidence from hydrothermal veins in the Variscan basement of Western Carpathians,Slovakia

Hydrothermal polymetallic veins of the Gemeric unit of the Western Carpathians are oriented coherently with the foliation of their low‐grade Variscan basement host. Early siderite precipitated from homogeneous NaCl‐KCl‐CaCl₂‐H₂O brines with minor CO₂, while immiscible gas–brine mixtures are indicative of the superimposed barite, quartz–tourmaline and quartz–sulphide stages. The high‐salinity aqueous fluid (18–35 wt%) found in all mineralization stages corresponds to formation water modified by interaction with crystalline basement rocks at temperatures between 140 and 300°C. High brominity (around 1000 ppm in average) resulted from evaporation and anhydrite precipitation in a Permo‐Triassic marine basin, and from secondary enrichment by dissolution of organic matter in the marine sediments at diagenetic temperatures. Sulphate depletion reflects thermogenic reduction during infiltration of the formation waters into the Variscan crystalline basement. Crystallization temperatures of the siderite fill (140–300°C) and oxygen isotope ratios of the parental fluids (4–10‰) increase towards the centre of the Gemeric cleavage fan, probably as a consequence of decreasing water/rock ratios in rock‐buffered hydrothermal systems operating during the initial stages of vein evolution. In contrast, buoyant gas–water mixtures, variable salinities and strongly fluctuating P–T parameters in the successive mineralization stages reflect transition from a closed to an open hydrothermal system and mixing of fluids from various sources. Depths of burial were 6–14 km (1.7–4.4 kbar, in a predominantly lithostatic fluid regime) during the siderite and barite sub‐stages of the north‐Gemeric veins, and up to 16 km (1.6–4.5 kbar, in a hydrostatic to lithostatic fluid regime) in the quartz–tourmaline stage of the south‐Gemeric veins. The fluid pressure decreased down to approximately 0.6 kbar during crystallization of sulphides. U‐Pb‐Th, ⁴⁰Ar/³⁹Ar and K/Ar geochronology applied to hydrothermal muscovite–phengite and monazite, as well as cleavage phyllosilicates in the adjacent basement rocks and deformed Permian conglomerates corroborated the opening of hydrothermal veins during Lower Cretaceous thrusting and their rejuvenation during Late Cretaceous sinistral transpressive shearing and extension.     

Fluid inclusion constraints on the origin of the brines responsible for Pb–Zn mineralization at Pine Point and coarse non‐saddle and saddle dolomite formation in southern Northwest Territories

The Pine Point region is a classic metallogenic mining camp that produced over 58 million short tons of Zn–Pb ore from approximately 40 base‐metal mineralized deposits hosted by Middle Devonian carbonates. The ore deposits are localized in paleokarstic features found in the epigenetic ‘Presqu'ile’ dolomite that preferentially replaced some of the upper barrier limestones. The main ore‐stage sulfides include galena, sphalerite, marcasite, and pyrite. A bulk fluid inclusion chemistry study was carried out on sulfide, coarse non‐saddle and saddle dolomite and calcite samples from the Pine Point and Great Slave Reef deposits, and unmineralized coarse non‐saddle and saddle dolomite samples from Hay West, Windy Point and Qito areas. Molar Cl/Br ratio data from Pine Point indicate the presence of four fluids at different stages of the paragenesis. The fluids trapped in sulfides and ore‐stage dolomites predominately consist of a Br‐rich fluid with a composition similar to that of evaporated seawater (fluid A), and a very Br‐enriched fluid of unknown origin (fluid B). Both these fluids are CaCl₂–NaCl (Na to Ca ratios of 1:10)‐rich brines and have compositions unlike the modern formation waters in the Devonian aquifers in the basin today. A third, relatively Cl‐rich (or Br‐poor), fluid (fluid C) was identified in two samples and may have acquired some chlorinity by dissolving halide minerals. Mixing between the Br‐rich fluid A and a dilute fluid also occurred in the later stages of the paragenesis, resulting in the formation of calcite and native sulfur. Saddle and coarse dolomites not associated with significant sulfide mineralization have a narrow range of halogen compositions similar to fluid A. There is no evidence of fluid B or C in the unmineralized samples. Relative to a modern‐day seawater compositions all the fluids have had some modification of their cation compositions. There is some weak evidence for interactions with clastic units or crystalline basement rocks. It is also possible however, that the evaporative brines could have formed from a relatively CaCl₂‐rich, NaCl‐depleted Devonian seawater, unlike the composition of modern‐day seawater.     

The use of soil chemistry data to address post-mortem diagenesis in bone mineral

The soluble and exchangeable ions for a soil profile from the Roonka archaeological site. Lower Murray Basin, South Australia, are compared with the total elemental content of the soils. Since the chemical composition of post-mortem ionic substitution phases and secondary minerals in archaeological bone will depend on the availability of ions to the soil solution under field conditions, it is suggested that models addressing diagenesis in bone employ soluble and exchangeable ions rather than total elemental soil data.     

Making sense out of cents: compositional variations in European coins as a control model for archaeometallurgy

Archaeometallurgy frequently seeks to correlate between the temporal and spatial distribution of ancient metal objects and their chemical composition. In this study, we examined whether and to what extent local or temporal deviations in the content of modern artifacts can be identified as a proxy for archaeological material that is typically less controlled and therefore more difficult to cluster. For this purpose, Euro coins of 10, 20 and 50 cents from Germany, France, Spain, Italy and Belgium, which are made of copper (Cu) with 5% aluminum (Al), 5% zinc (Zn) and 1% tin (Sn), were analyzed using a simple XRF analyzer. The mass ratios Sn/Cu and Zn/Cu were measured with a relative precision c.a. of 5%. The mean content of the coins from each country was then determined for 20–39 of them. The difference of the mass ratio Sn/Cu observed – from 0.0101 to 0.0111. One coin from Luxemburg shows differences in various areas of its surface of up to a factor of 1.5. Thus, the results of this small pilot research show that even in modern metal artifacts we can detect differences in metal content, which can be correlated to their production and utilization places. Therefore, this study can serve as a model for evaluating compositional variations noted in archaeometallurgical studies where the standard deviations are greater and the differences can be linked more readily to spatial and temporal differences.     

The upper continental crust, an aquifer and its fluid: hydaulic and chemical data from 4 km depth in fractured crystalline basement rocks at the KTB test site

Detailed information on the hydrogeologic and hydraulic properties of the deeper parts of the upper continental crust is scarce. The pilot hole of the deep research drillhole (KTB) in crystalline basement of central Germany provided access to the crust for an exceptional pumping experiment of 1‐year duration. The hydraulic properties of fractured crystalline rocks at 4 km depth were derived from the well test and a total of 23100 m³ of saline fluid was pumped from the crustal reservoir. The experiment shows that the water‐saturated fracture pore space of the brittle upper crust is highly connected, hence, the continental upper crust is an aquifer. The pressure–time data from the well tests showed three distinct flow periods: the first period relates to wellbore storage and skin effects, the second flow period shows the typical characteristics of the homogeneous isotropic basement rock aquifer and the third flow period relates to the influence of a distant hydraulic border, probably an effect of the Franconian lineament, a steep dipping major thrust fault known from surface geology. The data analysis provided a transmissivity of the pumped aquifer T = 6.1 × 10^?6 m² sec^?1, the corresponding hydraulic conductivity (permeability) is K = 4.07 × 10^?8 m sec^?1 and the computed storage coefficient (storativity) of the aquifer of about S = 5 × 10^?6. This unexpected high permeability of the continental upper crust is well within the conditions of possible advective flow. The average flow porosity of the fractured basement aquifer is 0.6–0.7% and this range can be taken as a representative and characteristic values for the continental upper crust in general. The chemical composition of the pumped fluid was nearly constant during the 1‐year test. The total of dissolved solids amounts to 62 g l^?1 and comprise mainly a mixture of CaCl₂ and NaCl; all other dissolved components amount to about 2 g l^?1. The cation proportions of the fluid (X_Ca approximately 0.6) reflects the mineralogical composition of the reservoir rock and the high salinity results from desiccation (H₂O‐loss) due to the formation of abundant hydrate minerals during water–rock interaction. The constant fluid composition suggests that the fluid has been pumped from a rather homogeneous reservoir lithology dominated by metagabbros and amphibolites containing abundant Ca‐rich plagioclase.     

Points and prey: a quantitative test of the hypothesis that prey size influences early Paleoindian projectile point form

Understanding the causes of variation within and between projectile point types is an important task for Paleoindian archaeologists since they rely heavily on points to investigate such things as settlement dynamics and hunting practices. One long-held explanation for the variation in early Paleoindian point form is that prey size influenced the size and shape of projectile points. The study reported here evaluated this hypothesis with standard and geometric morphometric data recorded on Clovis and Folsom points from the Southern Plains and Southwest that are associated with mammoth or bison remains. Points used to hunt mammoth were found to be larger and of a different shape than points used to hunt bison, which supports the hypothesis. However, when both point type and prey size were taken into account, the results ran counter to predictions. Potential explanations for this discrepancy are discussed.     

"虚拟"先人与十九世纪新加坡华人社会--兼论海外华人的"亲属"概念

在东南亚殖民地时代,"虚拟血缘"的组织原则对于华人移民社会的重组重建及其运作,具有重要的意义.本文以19世纪的新加坡为个案,考察华人移民如何透过埋葬先人的坟山组织建构"社群共祖"以整合华人社会,讨论东南亚华人虚拟的"先人"或"祖先"概念,进而思考海外华人的亲属研究问题.本文也讨论与比较了"虚拟血缘"组织原则在明代华南宗族"联宗"形态、台湾汉人社会发展早期的"合约式"宗族和东南亚华人坟山组织的不同运用.     

徐州狮子山楚王陵墓主身份及其相关问题的初步研究

作为1995年中国十大考古发现之一的徐州狮子山楚王陵自发掘出土以来,其宏伟的规模,奇特的葬制以及出土的大量精美文物都引起了学术界的广泛关注,但由于此墓年代久远且早年遭到盗扰,其墓主身份也随学者研究角度的不同而产生了多种学说,其中牵扯到的楚王从二代到五代不等,时间跨度长达57年。就目前而言,第三代楚王刘戊为墓主说法较为盛行,但笔者从葬制、礼仪、出土文物及与相关墓葬的关系等方面综合研究后认为:以第二代楚王刘郢(《汉书》作刘郢客)为墓主更为合理。同时,在本文中作者还将对其他三种观点一一进行辨析,并就与此墓及墓主身份的有联系的相关问题,试做初步的探讨。     

Twin Burials in Prehistory: A Possible Case from the Iron Age of Germany

Compared with other mammals, multiple births are rare in humans. The attitude towards multiple births varies widely among cultures. Although expected to be present, evidence for twin burials from prehistoric times is scarce. However, knowledge about the attitude of ancient societies towards twins, as expressed for instance by funeral practices, would provide interesting insights into the spiritual world of these people. In 2001, an Iron Age settlement site was excavated near Ochtendung, Germany. The skeletons of two perinatal individuals were found in situ in shallow depressions close to post‐holes of a house pit in the western part of the settlement. The individuals appear to have been deposited in the depressions without special care, as one of them was face down. No archaeological findings were associated with the skeletons. Age at death of the two individuals was estimated to be between 36 and 40 weeks' gestation. The cusp patterns of the lower left first molars exhibit a similar configuration of the disto‐buccal cusps in both individuals, probably a division of the hypoconid. The investigation of the bones and the teeth revealed a similar stage of development of the individuals and supports the hypothesis of closely related individuals, probably twins. An interpretation as ‘building sacrifices’ seems unwarranted, considering the careless deposition of the bodies and the absence of any grave goods. Copyright © 2012 John Wiley & Sons, Ltd.     

Massive dolomitization of a Messinian reef in the Great Bahama Bank: a numerical modelling evaluation of Kohout geothermal convection

The hypothesis that Kohout thermal convection may have induced the massive dolomitization of the 60 m thick lowest more reefal unit in well Unda [top of Great Bahama Bank (GBB)] is evaluated through numerical modelling. A two‐dimensional (2‐D) section, including lithological and petrophysical data, together with datings for the sediments of the GBB, was used in the basin model TEMISPACK to reconstruct the history of the whole platform, with a focus on the reef unit. Simulations showed that during high sea‐level periods, Kohout convection is a valid mechanism in the settings of the GBB, although the convection cell remains flat in most cases because of high permeability anisotropy. This mechanism induces rapid fluid flow in the superficial as well as in the deeper parts of the platform, with velocities of at least two orders of magnitude higher than with compaction alone. Lithology appears as a strong control of fluid circulations at the margin scale through the permeability anisotropy, for which a critical value lies between values of 10 and 100. The reefal unit in Unda is part of a larger area determined by the lithologic distribution, in which flow velocities are significantly higher than in the rest of the platform. These velocities are high enough to bring the magnesium necessary to precipitate the observed amounts of dolomite, within durations in agreement with the available time of post‐reef deposition high sea level(s). However, neither fluid flow pattern nor flow velocities are able to explain the preferential massive dolomitization of the lower reef unit and the complete absence of dolomite in the upper one.     

论黄河流域先秦时期腰坑墓葬俗文化——兼说与长江流域同类墓葬俗的关系

腰坑墓流行于黄河流域中原地区的墓葬中,学者们多把对其研究的焦点集中在对这一葬俗文化起源问题的讨论上,并较一致地认为该葬俗最早起源于河南地区。本文对发现的有关材料进行梳理,围绕中原地区先秦时期腰坑墓的起源、用途、性质、发展演变等进行了分析,以澄清过去研究中存在的一些模糊认识。认为,腰坑墓的葬俗最早可以追溯到新石器时代,而其起源亦非河南地区。     

The serotonin hypothesis of schizophrenia: a historical case study on the heuristic value of theory in clinical neuroscience

Clinical examination of the reliability and coherence of the evidence concerning modern neurochemical theories of mental disorders has led some scholars to conclude that support for many of these theories is weak. Nevertheless, these theories continue to be widely promoted. One explanation that has been offered for continued adherence to questionable theory is that it stimulates and gives direction to research. The heuristic value of theory is examined in the present paper by tracing the discoveries that followed from an old theory of schizophrenia, which is--by current consensus--false. It is shown that the original serotonin hypothesis of schizophrenia did, in fact, lead to significant advances in neuropharmacology, neurology and psychiatry.     

Climate change and the expansion of the Scythian culture after 850 BC: a hypothesis

In south-central Siberia archaeological evidence suggests an acceleration of cultural development and an increase in the density of nomadic populations around 850 BC. We hypothesize a relationship with an abrupt climatic shift towards increased humidity caused by a decline of solar activity. Areas that initially may have been hostile semi-deserts changed into attractive steppe landscapes with a high biomass production and high carrying capacity. Newly available steppe areas could be invaded by herbivores, making them attractive for nomadic tribes. The central Asian horse-riding Scythian culture expanded, and an increased population density was a stimulus for westward migration towards southeastern Europe.     

Stonehenge rhyolitic bluestone sources and the application of zircon chemistry as a new tool for provenancing rhyolitic lithics

The source of the bluestones at Stonehenge has long been debated, and while there is general consensus that the so-called spotted dolerites are derived from a relatively small number of outcrops exposed in the highest parts of Mynydd Preseli, in southwest Wales the source of the rhyolitic component has attracted relatively little detailed attention. This is largely because unlike the uniqueness of the spots in the coarser grained doleritic rocks, the rhyolites are fine-grained in character and lack any obvious distinctiveness, especially in hand specimen. This makes their provenancing difficult. A recent study, however, suggested that there was a close lithological similarity between the informally-termed ‘rhyolite with fabric’ bluestone component and rhyolitic rocks from the Ordovician Fishguard Volcanic Group exposed in the Pont Saeson area of north Pembrokeshire. This study aims to see if the chemistry of zircons, which are present in both sets of samples, could be used to support the petrographical association. Analyses for certain high field strength elements (including the rare earth elements) obtained by LA-ICP-MS showed that indeed the analyses were nearly identical when compared using a range of statistical approaches, including similarity coefficients, statistical distance, and principal component analysis, while showing clear differences to sample sets which had no reason to be correlated with the Pont Saeson samples. There are two important conclusions arising from this study. Firstly, the identification of the Pont Saeson source of the ‘rhyolite with fabric’ bluestone from outcrops in low ground to the north of the Mynydd Preseli will without doubt lead to fresh debates about the mechanisms of transport of this component of the bluestones to the Stonehenge site. Secondly, the chemistry of zircons may well prove to have a wider application in the provenancing of fine-grained rhyolitic rocks which have an archaeological context.