Charcoal reflectance measurements: implications for structural characterization and assessment of diagenetic alteration

Charcoal is a valuable source of archaeological and palaeoenvironmental proxy data. However growing evidence suggests that production conditions can strongly influence post-depositional alteration of charcoal. Consequently, both reconstruction of production temperature and understanding of the potential for diagenetic alteration are of great interest. Here, we use mean random reflectance (Ro_mean) in conjunction with other chemical characterization methods to address these questions. Ro_mean was obtained for a suite of modern analogue charcoal, produced under controlled conditions, and for a series of natural charcoal samples, obtained from archaeological and palaeoenvironmental deposits. Ro_mean proves to be a robust measure to assess formation temperature for samples produced at 400 °C and above, even after exposure to highly oxidizing conditions. Ro_mean is also useful for samples formed between 300 °C and 400 °C. However, if an assemblage of charcoals has been exposed to oxidizing conditions, lower temperature charcoals may be preferentially lost. It is apparent that charcoal produced at lower temperatures is more highly susceptible to chemical oxidation, and that there is a continuum in charcoal degradation potential, dependant upon fuel material and production conditions.     

Site formation processes in caves: The Holocene sediments of the Haua Fteah,Cyrenaica, Libya

Caves have yielded some of the most globally important archaeological sequences, but often their interpretation has suffered from assumptions about cave sedimentary processes. Caves contain distinctive sedimentary environments: this has major implications for the understanding of contained archaeological materials. This paper describes and analyses the Holocene sediments in the Haua Fteah, a sequence regarded as essentially continuous by the original excavator. 50 years after it was first excavated, the Haua's Epipalaeolithic to post-Classical chronological range and rich finds make it still the key Holocene archaeological site in North Africa. The reassessment shows, however, that the sequence is strongly discontinuous and this has major implications for the reinterpretation of the site, as the highly-resolved archaeological record is thus likely to reflect a series of brief occupations, rather than continuous human activity. As with many caves, the sedimentary record in the Haua Fteah is an extremely sensitive indicator of environments and processes in the wider landscape. Secure understanding of sedimentary process, from analysis of the highly individual records found in caves, is essential for full understanding of their contained archaeology.     

The potential of chironomid (Insecta: Diptera) larvae in archaeological investigations of floodplain and lake settlements

The head capsules of chironomids (Insecta: Diptera) are well preserved in sediments and can be recognised to a high taxonomic level, usually genus and sometimes species. Work on lake sediments has shown that they can be accurate indicators of water temperature, oxygen regimes, and nutrient status (particularly total phosphorus and chlorophyll-a), as well as heavy metal pollution. No systematic chironomid analyses, however, have previously been undertaken on archaeological deposits. In order to address this we assessed the use of chironomids in three types of archaeological deposit; firstly, a lake core at the edge of a lake settlement (crannog), secondly, a palaeochannel infill adjacent to a multi-period settlement site and lastly, a Roman well deposit from a floodplain environment. The chironomid assemblages are shown to vary significantly both between and within the sites and reflect the immediate environment and the adjacent area. The lake sediment assemblage reflects the construction of the crannog through elevated levels of organic detritus, wood and woody debris. The palaeochannel assemblage reveals changing natural conditions and nutrient enrichment probably associated with settlement during the Saxon period. The well assemblage is taxonomically restricted and indicative of organic debris, dead plant material, animal dung and possibly human effluent deposited after abandonment of the well. Dry storage of the palaeochannel and well sediments for several years did not appear to affect the concentration or state of preservation of the head capsules. The chironomid reconstructions are shown to provide an additional indicator of human activity which has the potential to provide quantitative data on the character of aquatic environments associated with archaeological sites.     

Micro-sampling of human bones for mobility studies: diagenetic impacts and potentials for elemental and isotopic research

The nature of long bone formation and the pathways of interaction between bone samples and the burial environment suggest that portions of the bones disconnected from the arterial system are resistant to diagenetic alteration. Preliminary work on femurs from Early Bronze Age hunter-gatherers in Cis-Baikal, Siberia shows that the nature and progression of chemical changes in the bone matrix due to microbial attack can be analyzed using laser ablation inductively coupled plasma mass spectrometry. Intra-osteon variability in elemental concentrations and strontium isotope ratios (⁸⁷Sr/⁸⁶Sr) indicate the presence of unaltered portions of bone within diagenetically modified bone and suggest that useful data remain accessible. These biogenic signals can potentially be useful for mobility research in broad terms and the smaller timescales within an individual's lifetime (months, years), accessible therein. Laser ablation micro-sampling of femur specimens showed that intra-osteon elemental composition of Ba, Re, and Cs varied within and was correlated between multiple osteons of a single bone. Portions of chemically unaffected bone were identified within, and effectively discriminated from diagenetically altered bone tissue. Areas showing visual alterations and erratic or uncorrelated Ca and Sr elemental results also had anomalous Sr isotope ratios, suggesting diagenetic alteration in those places. Compositional and isotopic analysis of intact portions of bone supports the hypothesis that hunter-gatherer groups in Cis-Baikal made numerous major movements during their lives. Microscopic analysis of long bones clarifies aspects of biodeterioration and correlations between trace elemental results and diagenetic alteration. Micro-sampling of intact portions of bone expands the scope of available materials for research on mobility and other aspects of human past behavior.     

Holocene land-use evolution and associated soil erosion in the French Prealps inferred from Lake Paladru sediments and archaeological evidences

A source-to-sink multi-proxy approach has been performed within Lake Paladru (492 m a.s.l., French Prealps) catchment and a 6-m long sediment sequence retrieved from the central lacustrine basin. The combination of minerogenic signal, specific organic markers of autochthonous and allochthonous supply and archaeological data allows the reconstruction of a continuous record of past human disturbances. Over the last 10,000 years, the lacustrine sedimentation was dominated by autochthonous carbonates and the watershed was mostly forest-covered. However, seven phases of higher accumulation rate, soil erosion, algal productivity and landscape disturbances have been identified and dated from 8400 to 7900, 6000 to 4800, 4500 to 3200, 2700 to 2050 cal BP as well as AD 350–850, AD 1250–1850 and after AD 1970. Before 5200 cal BP, soil erosion is interpreted as resulting from climatic deterioration phases towards cooler and wetter conditions. During the Mid-Late Holocene period, erosion fluxes and landscape disturbances are always associated with prehistorical and historical human activities and amplified by climatic oscillations. Such changes in human land-used led to increasing minerogenic supply and nutrients loading that affected lacustrine trophic levels, especially during the last 1600 years. In addition, organic and molecular markers document previously unknown human settlements around Lake Paladru during the Bronze and the Iron Ages.     

From flow to quarry: magnetic properties of obsidian and changing the scale of archaeological sourcing

Previous studies have endeavored to use petrophysical traits of obsidian, particularly its magnetic properties, as an alternative to conventional geochemical sourcing, one of the greatest successes in archaeological science. Magnetic approaches, however, have not seen widespread application due to their mixed successes. In a time when geochemical analyses can be conducted non-destructively, in the field, and in a minute or two, magnetic measurements of obsidian must offer novel archaeological insights to be worthwhile, not merely act as a less successful version of geochemistry. To this end, we report the findings of our large-scale study of obsidian magnetism, which includes 734 geological obsidian specimens and 97 artifacts measured for six simple magnetic parameters. Based on our results, we propose, rather than using magnetic properties to source artifacts to a particular obsidian flow (inter-flow sourcing), these properties are best used to differentiate quarrying sites within an individual flow (intra-flow sourcing). Our results also demonstrate that certain magnetic properties are highly affected by ancient knappers' material selection criteria. Furthermore, depending on the spatial scales of variation, which likely vary from flow to flow, we envision several potential applications of this approach, including integration into minimum analytical nodule analysis (MANA). Magnetic data appear to shift the scale of obsidian sourcing from flows to quarries and, in turn, enable new insights into raw-material procurement strategies, group mobility, lithic technology, and the organization of space and production.     

U-series and radiocarbon dates on mollusc shells from the uppermost layer of the archaeological site of KHB-1, Ra's al Khabbah,Oman

The archaeological site of KHB-1, Oman, has been investigated in order to improve the chronological knowledge of the site, which is dated to the beginning of the fourth millennium B.C. on the basis of the archaeological context. Mollusc shells of the genus Anadara, coming from the uppermost layers of the site, have been dated using two different methods, radiocarbon and U-series technique. The results of the two techniques date the last occupational phase of the site from the end of the fourth millennium B.C. to the beginning of the third millennium B.C.     

Palaeopathology in late Pleistocene and early Holocene Central Plains bison: dental enamel hypoplasia,fluoride toxicosis and the archaeological record

Multiple formative agents are cited for dental enamel hypoplasia (DEH) in modern and fossil mammals. Here, four late Pleistocene-early Holocene bison assemblages from the Central Great Plains are analyzed for DEH and other bone pathologies to investigate the possible influence of chronic fluoride toxicosis, a condition that may have presented a long-term source of duress for prehistoric bison and devalued them as nutritional resources to human hunters. Although DEH is present in all the analyzed assemblages, the lack of corroborating dental and post-cranial anomalies consistent with chronic fluoride toxicosis speaks against it as a primary factor of DEH formation or general ill health in these bison. Rather, maternal nutritional stress, weaning, and seasonal forage condition are invoked as probable promoters of DEH formation. Other identified abnormalities are discussed in reference to their contribution to reduced feeding efficiency and lameness, as are their roles in developing palaeoecological models applicable to archaeological questions about ancient human lifeways.     

The paleolithic site of Longwangchan in the middle Yellow River,China: chronology,paleoenvironment and implications

The Longwangchan Paleolithic site, situated on the Yellow River terraces in the Hukou area, Shaanxi province, China, was found in 2003–2004, and two areas (Localities 1 and 2) of the site were excavated in 2005–2008. Abundant stone artifacts including microliths, a grinding stone fragment and a shovel, with some animal bones and shells, were recovered from Locality 1. In this study, the cultural deposits from Locality 1 were dated using radiocarbon and optical dating techniques, and the sediment properties of the deposits were analyzed. The results show that the age of the deposits ranges from 29 to 21 ka and most of them were deposited between 25 ka and 29 ka. This indicates that corresponds to late Marine Isotope Stage (MIS) 3 and early MIS 2. During the human occupation period, the climate in this area became colder and drier. Sediments from beds where the grinding slab and the shovel were found were dated to ∼25 ka, which is the oldest among the grinding stones found in China. The microliths and the grinding stone are important evidence for an incipient socio-economic process that eventually led to the regional transition from hunting-foraging to farming.     

Alkaline cooking and stable isotope tissue-diet spacing in swine: archaeological implications

In this study we examine the effects of alkaline cooking on carbon and oxygen stable isotopic ratios of mineralized tissues from nine pigs raised on monotonous mixed C3/C4 vegetarian diets. Two sources of collagen (humerus and mandible) and two sources of apatite (humerus and enamel) were analyzed. Within each diet group, humerus and mandible collagens were found to record equivalent δ¹³C and δ¹⁸O ratios; however, enamel apatite was found to be enriched over bone apatite by 2.3‰ in carbon and 1.7‰ in oxygen. Alkaline cooking was found to slightly, but significantly increase the Δ¹³C_{collagen-diet} and Δ¹⁸O_{collagen-diet} of bone collagen. A similar trend towards enrichment was observed in bone and enamel Δ¹³C_apatite-diet and Δ¹⁸O _apatite-diet, but the differences were not significant. Observed isotopic shifts were consistent with increased nutrient utilization of the alkaline-cooked maize as compared to raw maize. In addition, a reexamination of the relationship between diet and tissue carbon isotopic values suggests that species and alimentary type should be considered when interpreting ancient diets.     

Hunting lesions caused by osseous projectile points: experimental results and archaeological implications

The identification of projectile impact traces on archaeological faunal remains is an important issue for understanding prehistoric hunting behavior, especially in the Paleolithic and Mesolithic. From the beginning of the Upper Paleolithic in Europe, and earlier in Africa, projectiles tipped with osseous points were of great importance for subsistence; but thus far, no specific experimental reference has been developed to help identify the traces left by these points. In 2003 and 2004 two series of projectile experiments with antler points of Magdalenian design were organized, involving two ox calves and two female fallow deer as targets for bow and spearthrower shooting. The subsequent study demonstrates that positive identifications of impact traces left by osseous points can be made. The observation of 127 impact traces allowed us to distinguish three main types of traces: notches, punctures and perforations. The relationships between the nature of the impact traces and the (i) target species, (ii) characteristics of the impacted bones, and (iii) type of weapon are presented. Synthesized results are then discussed within the context of the European Upper Paleolithic and Mesolithic.     

Late quaternary alluviation and soil formation in the southern Argolid: its history,causes and archaeological implications

In the context of an archaeological survey of the southern Argolid, Greece, studies have been carried out to elucidate the evolution of the landscape since its earliest known human occupation about 50,000 years ago. One of these studies was a detailed geological mapping of the late Quaternary alluvium and soils in the area. Dated by means of thorium-uranium disequilibria, archaeological finds, and historical information, seven periods of alluviation were identified, each of short duration relative to long intervening periods of stability and soil formation. The three earliest alluvial phases, falling before and during the last glacial interval, range from about 330,000 to 32,000 years in age. No alluviation accompanied the last glacial maximum around 20,000 years ago. In fact, a stable landscape persisted until about 4500 years ago, when debris flows and widespread aggradation in the valleys resulted from major slope destabilization and soil erosion, probably as a result of extensive land clearance in the Early Bronze Age. A subsequent stable period lasted through the many upheavals of the later Bronze Age, the Dark Ages, and the early historical period. It came to an end with a brief phase of alluviation between about 300 and 50 BC. Stability returned through the late Roman period, notwithstanding considerable expansion of the settled area. Another period of destabilization, this one marked by debris flows and hence major soil erosion, is poorly fixed in time, but probably coincides with expanded maquis clearance accompanying the resettlement of the area around AD 1000. Subsequent events of soil erosion and aggradation vary in nature and timing from one drainage to the next and, in some areas, continue today.Nature and chronology of the soil forming and alluviation events show that simple correlations with climatic events do not suffice to explain them. For the latter ones, past about 2500 BC, human activity seems to be the dominant cause, but once again the relation between cause and effect is not straightforward. Land clearing, or neglect of soil conservation efforts during economic downturns, appear to have a more devastating effect upon the landscape than do intensive land use or total land abandonment.     

Differentiating between anthropogenic calcite in plaster,ash and natural calcite using infrared spectroscopy: implications in archaeology

Infrared spectroscopy provides information not only on the type of calcium carbonate polymorph, but also on the extent of atomic order. In calcite, three major infrared absorption peaks are identified: ν₃, ν₂, and ν₄. It was shown that the ratio between ν₂ and ν₄ bands reflects the order of the calcite crystal structure. In this paper we analyse this ratio in geologically formed calcites, archaeological plasters, modern plasters and experimentally prepared plasters. For the geological calcite, the values of the ν₂/ν₄ ratio are around 3, whereas for the experimentally prepared plasters, the values are around 6.5. The ν₂/ν₄ ratio for archaeological plasters varies from 3 to 6. This shows that a high ratio is indicative of disorder in the crystal, and implies that the calcite was formed from calcium oxide at high temperatures. It also implies that this disorder can be preserved for at least 14,000 years. The ν₂/ν₄ ratio of calcite from archaeological sites can thus be used to differentiate between anthropogenic calcite, such as in plaster, mortar and wood ash, from geogenic calcite, such as in limestone. The ratio may also be used to identify plaster or ash that still retains its original crystals and therefore carbon-14 content.     

Measured domestication rates in wild wheats and barley under primitive cultivation,and their archaeological implications

Man's (or, more probably, Woman's) first cereal crops were sown from seed gathered from wild stands, and it was in the course of cultivation that domestication occurred. Experiments in the measurement of domestication rates indicate that in wild-type crops of einkorn, emmer, and barley under primitive systems of husbandry: (a) domestication will occur only if they are harvested when partially or nearly ripe, using specific harvesting methods; (b) exposure to shifting cultivation may sometimes have been required; and (c) under these conditions, the crops could become completely domesticated within 200 years, and perhaps only 20–30 years, without any conscious selection. This paper (a) considers possible delays in the start of domestication due to early crops of wild-type cereals lacking domestic-types mutants; (b) examines the husbandry practices necessary for these mutants to enjoy any selective advantage; (c) considers the state of ripeness at harvest necessary for the crops to respond to these selective pressures; (d) outlines field measurements of the selective intensities arising from analogous husbandry practices applied experimentally to living wild-type crops; (e) summarizes a mathematical model which incorporates the measured selective intensities and other key variables and which describes the rate of increase in domestic-type mutants in early populations of wild-type cereals under specific combinations of primitive husbandry practices; (f) considers why very early cultivators should have used those husbandry methods which, we suggest, led unconsciously to the domestication of wild wheats and barley; and (g) considers whether these events are likely to leave archaeologically recognizable traces.     

Pastoralist iron production on the Laikipia Plateau, Kenya: wider implications for archaeometallurgical studies

Recent research conducted on the Laikipia Plateau in Kenya highlighted several shortfalls in the existing models for understanding and interpreting past iron production technologies. The research was undertaken in order to assess variability in past pastoralist iron production techniques – the first such archaeometallurgical exploration in the region. In all, seven furnaces and one iron production refuse area were excavated across two discrete sites separated by only 3 km: Mili Sita and Cattle Dip, both dating to the second half of the second millennium AD. The recovered archaeometallurgical materials – slag, furnace wall, and tuyères – were analysed using a combination of optical microscopy, SEM-EDS and ED-XRF.The results revealed that the technologies in question were complex and sophisticated, and their reconstruction and interpretation required some special considerations. The exploitation of titania-rich black sand was observed to bear a major influence on the resulting slag compositions at both sites, and use of these specific materials resulted in consistently efficient smelting episodes, demonstrating the technical competence and skill of the past smelters. However, although the slag compositions and microstructures of all the samples were markedly similar between the two sites, striking stylistic variation was apparent in the furnace design. This raised questions not only about the organisation and identity of the smelters who were working in this area at this time, but also of the reliability of assuming that similar slag compositions – peculiar as these might be – reflect similar technological (or sociotechnical) systems (cf. Pfaffenberger, 1992). A further problem encountered was that the consequently ulvite-rich slag was comprised of five, not three, major constituents – titania and lime in addition to iron oxide, alumina and silica. This meant that the operating parameters of these smelting episodes could not be easily interpreted using the usual models, which tend to be based around the assumption of fayalitic slag.As such, this paper will discuss to what extent consistency in technological style, in a broad, sociocultural sense, can be inferred through slag analysis, as well as the need for the formulation of wider reaching models that encompass the full scope of technical variation in iron production.     

Cutmarks on Capsian human remains: implications for Maghreb Holocene social organization and palaeoeconomy

In 1930, the remains of five adults, one subadult, and one infant were excavated from Site 12, a ca. 8000 bp Capsian escargotière in Algeria. Recently, cutmarks were found on several postcranial bones of each of the adult individuals. In an attempt to reconstruct the burial circumstances, archival materials including photographs and field notes were retrieved from the State Historical Society of Wisconsin and the Logan Museum at Beloit College, and a detailed study of the cutmarks was carried out. The cutmarks are associated mostly with long bones and skulls, while two individuals show cutmarks on the thorax. Using theories relating secondary burial practices to a nomadic lifestyle, it is hypothesized that the individuals died away from camp. Initial preparations, while awaiting transport to Site 12, involved limited exposure, followed by decapitation, dismemberment, and possibly defleshing of the thorax and removal of the internal organs. At Site 12, a formal burial ceremony was conducted during which red ochre was used. In some cases the dismembered extremities were placed in the grave with the rest of the body, but several skulls and long bones are missing. It is not known what the missing bones were used for, although Capsian groups are known for modifying human bones for either utilitarian or ritual purposes. This is the first time that cutmarks on human remains are reported for this area and period. The idea that Capsian people practiced decapitation and dismemberment has been suggested before, based on observations on other sites, however. Studies of human skeletal material from the Maghreb, often excavated decades ago, may therefore reveal similar types of evidence. It is suggested that such studies will contribute significantly to our understanding of Holocene Maghreb burial practices, and our ability to reconstruct social organization and palaeoeconomy. Copyright © 1999 John Wiley & Sons, Ltd.     

Stable carbon and oxygen isotopic compositions of wood ash: an experimental study with archaeological implications

Wood ash, composed mainly of the mineral calcite, is an important component in many archaeological sites. Identification of wood ash in the archaeological record is often difficult due to mixing of ash with other calcitic components of geogenic origin and/or due to diagenetic changes. A recent empirical study using the stable isotope compositions of carbon (δ¹³C) and oxygen (δ¹⁸O) in wood ash enabled the identification of mixtures of wood ash with geogenic calcite and to follow diagenetic changes due to partial dissolution and re-precipitation of ash in two prehistoric cave sites in Israel. Little however is known about the processes responsible for the isotopic compositions of wood ash in relation to formation at various temperatures and the influence on isotopic composition of ash from a variety of plant species. Here we present an experimental study of wood ash formed by burning three C3 tree species and one C4 desert bush at different temperatures. The results indicate that there are significant differences in the isotopic compositions of carbon and oxygen between wood ash that forms by combustion at a relatively low temperature (500 °C) and at a higher temperature (900 °C). In addition, we show that the isotopic composition of carbon and oxygen in high temperature wood ash approaches equilibrium over a period of several months and that the carbon isotopic composition of low temperature wood ash may reflect the photosynthetic pathway of the burnt woody species. Lastly, we show that the isotopic compositions obtained from wood ash prepared at different temperatures do not reflect a temperature dependent fractionation process, but a mixing line between calcite that formed by low temperature combustion and calcite formed by high temperature combustion which later underwent re-carbonation with atmospheric CO₂. In addition, we suggest that exchange processes may possibly occur during combustion between decomposing calcium-oxalate and atmospheric O₂, CO₂ and CO. The archaeological implications of this study are discussed in relation to identification of wood ash in the archaeological record, identification of fuel sources and burning temperatures, and diagenetic changes expected in karstic cave environments. The method presented here can be applied at any archaeological site.     

Reconstructing late Holocene palaeoenvironments in Bangladesh: phytolith analysis of archaeological soils from Somapura Mahavihara site in the Paharpur area,Badalgacchi Upazila,Naogaon District,Bangladesh

Palaeoenvironmental reconstruction based on phytolith analysis of late Holocene-aged soils in and around the Somapura Mahavihara archaeological monastery site in the Paharpur area, Badalgacchi Upazila of Naogaon District in northwestern Bangladesh was undertaken. Results indicate five climate zones marked by alternatively cool and temperate events. The phytolith assemblages of Zones 1, 3 and 5 are clearly characterized by a higher proportion of Pooideae phytoliths. The climate indices for these zones are all greater than 50, indicating cooler climatic conditions. In contrast, the phytolith assemblages of Zones 2 and 4 are typified by a higher proportion of Panicoideae phytoliths; their climate indices are 42 and 44, respectively, indicating the presence of a warmer, more temperate climate. In general, the dominance of grasses over broad- leaved trees throughout the sequences suggests that generally cool to temperate and dry conditions with some cyclical variability persisted around Paharpur and the surrounding region throughout the Pala Dynasty from AD 730 to 1080. The question of whether these shifts in vegetation might be linked with El Niño Southern Oscillation events, and whether these might in turn have cultural responses, is raised.