Ethnoarchaeological analysis of Arctic fish processing: chemical characterization of soils on Nelson Island,Alaska

Activity area analysis of archaeological soils using multi-element characterizations can illuminate how subsistence operations are organized and how subsistence behavior has changed over time, and is increasingly common at archaeological sites. However, in many regions it is impossible to examine the elemental signatures in known anthropogenic soil samples in order to compare them with unknown archaeological samples. This ethnoarchaeological study examines the chemical composition of the soils at known fish processing areas in the contemporary community of Tununak on Nelson Island, western Alaska. Using a quadrupole inductively coupled plasma mass spectrometer (Q-ICP-MS), the concentrations of the following elements in the soil extract were recorded in parts per million (ppm): aluminum (Al), barium (Ba), calcium (Ca), iron (Fe), potassium (K), magnesium (Mg), manganese (Mn), sodium (Na), phosphorus (P), strontium (Sr), titanium (Ti), and zinc (Zn). Fish processing area features are elevated in various elements, including sodium, magnesium, phosphorus, potassium, and manganese, and Ba/Sr, Ba/Ca, and Sr/Ca are also useful in distinguishing between fish processing areas and offsite areas.     

Reconstructing site organization in the eastern Aleutian Islands,Alaska using multi-element chemical analysis of soils

This study presents the results of multi-element analysis of weak-acid extractions of 953 soil samples collected by coring on and around pre-historic village sites on two islands, Sanak and Amaknak, in the eastern Aleutians. Concentrations of aluminum (Al), barium (Ba), calcium (Ca), iron (Fe), potassium (K), magnesium (Mg), manganese (Mn), phosphorus (P), strontium (Sr), titanium (Ti), and zinc (Zn) were determined using an inductively coupled plasma-mass spectrometer (ICP-MS). Resultant elemental signatures allow the identification of site features and organization in the absence of large-scale excavation. All the archeological sites showed similar and distinct chemical signatures regardless of the several thousand year date range of the sites or the length of time a site was occupied. However, intensity of occupation does appear to affect concentrations of elements. Site features such as houses, house berms, house floors and middens had distinct anthropogenic signatures and could be distinguished from one another. This approach may be used to identify sites that do not have distinct surface features and to target areas for excavation.     

The soils of an Iron Age farm site ‐bjellands⊘ynæ, SW Norway

Soil investigations have been carried out at an Iron Age farm site lying under natural vegetation. The soils of the area were mapped and described, and soil samples analysed for pH, organic carbon, total nitrogen, acid‐soluble phosphorus, and available sodium, potassium, calcium and magnesium. Two soil types were distinguished on the mineral soils ‐ Brown Podzolic Soils and Iron Humus Podzols. The former are associated with a higher pH, higher phosphorus contents, and a lower carbon‐nitrogen ratio. These differences arc difficult to explain by natural causes, and arc ascribed to cultivation and manuring of the soil during the occupation of the site.     

Publications New Archaeological Books and Journals

Abstract

An electrical resistivity survey and accompanying soil analyses were performed over an exposed but unexcavated prehistoric house in Peoria loess in westcentral Illinois. Positive resistivity anomalies occur along the trenches for the house walls and within the house and distinctive patterns in contoured resistivity data occur over the house.

Soil analyses show that quartz, kaolinite, montmorillonite, illite, and hematite are the main mineral constituents in the soil. Within the house basin, the soil is dark gray in color because of the presence of organic carbon. Prominent positive electrical resistivity anomalies occur where the dark soil is thickest.

Analyses of the resistivity and soil data enable the identification of several anthropogenic features within the house and suggest that electrical resistivity data would be helpful to archaeologists in doing both detailed and reconnaissance work. For example, the mean amplitude and fabric patterns in contoured resistivity are distinctive over the house relative to areas outside the house. This fact suggests that similar analyses of reconnaissance resistivity data might be helpful in exploration for large archaeologic activity areas such as whole villages or camps. Also, detailed analyses of the resistivity and soil data, in conjunction with information already available from other excavated structures at Orendorf village, suggest that the electrical resistivity technique can serve as a valuable, but ancillary, tool to help archaeologists focus their efforts and decide which of the many structures in a village should be excavated.     

Phosphate Analysis of Anthropic Soils

Abstract

The use of phosphate analysis in archaeology is possible because past human occupation and activities increased the amount of soil phosphorus in the areas occupied. The accumulated phosphorus in archaeological deposits tends to remain constant through time and is measurable through soil sampling and chemical analysis, thereby providing archaeology with a valuable tool, applicable to a wide variety of research situations. Phosphate analysis is especially useful in surveying large areas to locate and delimit sites.     

Soil Chemical Analysis Applied as an Interpretive Tool for Ancient Human Activities in Piedras Negras,Guatemala

The applicability of soil chemical analysis to the interpretation of ancient human activity areas in the Maya region was studied for potential implications in anthropogenically modified soils. We studied chemical signatures associated with a horizontally excavated site in Piedras Negras, Guatemala. The focus of this study is on soil phosphate and trace metals as indicators of ancient activity. We compared total phosphate with Mehlich extractable phosphate to see which method was superior. We also compared total (nitric-perchloric) digestion with the DTPA extraction procedure of heavy metal determination to resolve which method most accurately indicates ancient activity areas. We used principal component analysis to compare the metals and give probable locations of ancient activities. Statistical analysis of chemical patterns indicated possible areas of food preparation and craft production as well as sweeping patterns. We found that elevated phosphate, barium and manganese levels indicate areas of organic refuse disposal. Mercury and lead concentrations indicate areas of craft production. These observations are compared with the artifact data. We were also able to determine areas associated with similar activities using chemical analysis. The comparison of the total and extractable element analysis demonstrated that both methods yield important information regarding activity areas. However, because of the resolution obtained, convenience, economy, and safety, we suggest the extractable DTPA and Mehlich methods.     

Methods of soil P analysis in archaeology

Phosphorus (P) is unique among the elements in being a sensitive and persistent indicator of human activity. It has long been of interest to archaeologists because of its potential to inform them about the presence of past human occupation and to offer clues regarding the type and intensity of human activity. A wide variety of methods have been developed in both soil science and in archaeology to extract and measure soil P, resulting in a tremendous amount of data and a wide array of interpretations, but also considerable confusion over appropriateness of methods and terminology. The primary purpose of this paper is to address these issues by clarifying soil P analyses. Anthropogenic additions of phosphorus to the soil come from human refuse and waste, burials, the products of animal husbandry in barns, pens, and on livestock paths, or intentional enrichment from soil fertilizer. Once added to the soil, phosphorus in its common form as phosphate is stable and generally immobile in soils. Soil P comes in many forms, organized for the purposes of this paper on the basis of extraction and measurement procedures as (1) extraction for available P (Pav); (2) portable field techniques (the spot test or ring test); (3) chemical digestion of a soil sample for total P (Ptot); (4) extractions of inorganic P (Pin) for fractionation studies and extractions to look at individual compounds of P; (5) measurements of organic P (Porg); and (6) extractions for total elemental analysis. To compare the suitability of various extractants as the “best” indicator of human input and activity we subjected samples from three very different archaeological sites (Lubbock Lake, TX; Hulburt Creek, IA; British Camp, WA) to four methods of soil P extraction: perchloric acid digestion (Ptot), sulfuric–nitric acid extraction Ptot), hydrochloric acid extraction after ignition (Pin), and citric acid extraction (Pav). Further, methods of measurement were compared via colorimetry vs. Inductively Coupled Plasma (ICP) spectrometry, and the two methods of supposed “total P” were both measured via ICP. In general, the stronger extractants yielded more soil P, but the result are not clear-cut. Likely variables include the intensity of occupation, nature of the parent material, and postdepositional weathering (e.g., the addition of dust).     

The DaVincis of dirt: Geoarchaeological perspectives on Native American mound building in the Mississippi River basin

The complexity of mound construction, as revealed through geoarchaeological analyses, indicates the cultural significance of mounds may be as well reflected in the earthen construction materials and their arrangement, as it is in the artifacts abandoned on their summits. We use geoarchaeological examples from three sites in the Mississippi River basin, Shiloh Mounds, Cahokia, and Poverty Point, to advocate a geoarchaeological approach that considers multiple scales from the regional soils and geomorphology, field observation of lithostratigraphic units, to the micro-scale identification of the mineralogy and soil development in order to decipher the source and processing of the soils and sediments. We focus on the use of five types of construction referred to here as: sod blocks, soil blocks, loaded fills, zoned fills and veneers. Also we address the selection and transportation of soils and sediments used in mound building and what these types of deposits reveal about the methods used to build mounds. These data can be used to evaluate and understand organization of labor, pace of construction, and mound appearance. We hold there is a considerable (although unquantified) difference between earth moving and mound building and that the construction of these important monuments required considerable knowledge, skill, planning, hard work, and attention to symbolic and ritual meaning.     

LEAD ISOTOPE RATIOS AS A MEANS OF SOURCING ANTHROPOGENIC LEAD IN ARCHAEOLOGICAL SOILS: A PILOT STUDY OF AN ABANDONED SHETLAND CROFT*

Results from soil chemical analysis have demonstrated enhanced concentrations of lead (Pb) associated with archaeological sites. However, interpretation of these Pb concentrations is difficult because of the multitude of possible Pb sources. This pilot study of an abandoned croft in Shetland suggests that Pb isotope ratios have the potential to identify sources of anthropogenic Pb. The results highlight two different Pb associations. The first includes hearth, house floor and house overburden soils, with end members of fuel materials and an unidentified material with a low (< 1.126) ²⁰⁶ Pb/ ²⁰⁷ Pb ratio. The second includes byre, kailyard (garden) and arable soils, with end members of hearth materials and local wind‐blown sand.     

Relict Soils and Early Arable Land Management in Lofoten, Norway

Relict arable soils dating fromc.AD700 provide an opportunity to identify early arable land management practices in the agriculturally marginal landscapes of the Lofoten archipelago, northern Norway. Synthesis of field survey and soil thin section micromorphology supported by image analysis suggests that there was deliberate management of erodible sandy soils in sloping locations to create small areas of cultivation terrace, with a range of materials used as soil amendments to stabilize the accumulated soil and enhance fertility. Small areas of sandy soils in more gently sloping locations were also cultivated, again with a range of materials used as amendments and which contributed to a significant increase in soil thickness. The last phase of cultivation commenced during the late 1800s and involved the reclamation of wetter, peaty soils by spade. These patterns of arable land management are repeated in different parts of Lofoten and indicate that despite the climatic and economic marginality of arable activity in Lofoten, land management practices were developed and applied to permit barley production from small areas.     

Soils and vegetation history of abandoned enclosures in the New Forest,Hampshire, England

Soil profiles buried beneath earth banks of five abandoned enclosures, ranging in age from late Bronze Age to early 19th century AD, were compared with unburied profiles inside and outside the enclosures. Soil particle size analyses and micromorphological studies show that the banks were constructed of mixed topsoil and subsoil from adjacent ditches; on some banks the soil has begun to podzolize. At the two oldest sites (Dark Hat and Long Slade Bottom, which are late Bronze or Iron Age) the soils within the enclosures were homogenized, probably by occasional cultivation for cereal growing. At Dark Hat an ironpan has developed on the upper surface of a layer compacted by smearing during cultivation. The later enclosures, at Burley Moor (Anglo-Saxon), East Boldre (mediaeval) and Hatchet Gate (early 19th century AD), were probably used entirely for pasture. Pollen assemblages from the buried soils and overlying banks, and chemical comparisons of the buried soils with profiles inside and outside the enclosures together provide new evidence for a history of soil and vegetation changes over the past 2500–3500 years. Heathland vegetation associated with podzolic soils existed on plateau gravels before the late Bronze Age, but on other parent materials heath vegetation and acidic soils with incipient podzolization appeared only in later periods. The present patchy vegetation pattern of mainly deciduous woodland with open areas of ferny grassland and heath seems to have persisted since before the late Bronze Age. The most obvious human influences on the vegetation during the last 2000 years have been periodic temporary use of open areas and woodland clearings for protected grazing.     

Physical and Geochemical Characteristics of Soils from Angel Mounds State Historic Site,Indiana, including a Case Study of Sherds from Unit A

Abstract

Using physical and chemical characteristics of soil to evaluate archaeological artifacts and their preservation potential along with associated features is well established. The soil characteristics and geochemistry of the Angel Mounds site (12Vg1) indicate the soil geochemistry is very homogenous and composed of loams and silt loams with a range of pH values from 4.69 to 6.17, mean value of 5.40 ± 0.47. The slightly acidic nature of the soil favors the preservation of pollen and soil diatoms, with minor corrosion potential for the bone, shell, and sherd artifacts. A comparison of the geochemistry of the soils from Unit A and site-wide sampling to sherds from Unit A suggests that elevated phosphorus (P) in the sherds is either the result of the addition of a P-rich temper material or from the sourcing of nonlocal clay-rich sediment, and not from use-derived residue or from the soils themselves.     

The Early Bronze Age settlement of Fidvár,Vráble (Slovakia): reconstructing prehistoric settlement patterns using portable XRF

This paper presents first results of chemical analyses of sediment samples from the Early Bronze Age (EBA) settlement Fidvár near Vráble (Slovakia). Large-scale geomagnetic prospection revealed detailed architectural remains of a fortified settlement. Other structures such as an earthwork of the linear pottery culture and at least two Roman march camps were found too. An Auger programme provided sediment samples of different depths, A) from an EBA house and the outer fortification ditch, B) from a potential metal workshop area as indicated by surface finds, and C) from an area located in the settlement's centre. The samples were analysed by a portable X-ray fluorescence (pXRF) spectrometer in order to investigate the vertical and horizontal distribution of chemical signatures. The comparison of geophysical data and three-dimensional chemical patterns gives us the opportunity to determine the human impact and to reconstruct activity patterns. The potentials and limits in the application of pXRF in archaeological soil chemical surveys are evaluated by systematic comparisons with high resolution laboratory measurements, including atomic absorption spectrometry (AAS) and inductively coupled plasma optical emission spectrometry (ICP-OES). The pXRF analyses can be reproduced well and show a good accuracy. Whilst (p)XRF analyses reflect the total composition of archaeological soil samples, the results of the AAS and ICP-OES analyses are fundamentally influenced by the acid digestion or extraction methods used. The pXRF analyses of the Vráble soils showed typical patterns of human occupation. For example, there are strong positive correlations between phosphorous, strontium and calcium. Phosphorous shows an enrichment in pathways and the fortification ditch. It is less strongly enriched within the sediments of house structures. Similar results apply to calcium and strontium distribution. But compared to the respective concentrations in sediment samples from the ditch they show a considerably higher variation in samples associated with house structures; that is, individual samples of sediments from house structures contained high concentrations of both, calcium and strontium. The deposits of an area that according to surface finds was thought to represent a potential metal workshop did not show indicative chemical signatures. Targeted excavations confirmed the absence of such as workshop. Finally it was shown that the refill history of the innermost fortification ditch (sample area D) and the overall cultural occupation sequence at the site correlate strongly with the chemical signatures of the respective ditch profile. The systematic variation of key elements along the profile opens up an entirely new perspective for interpreting the site's history. Overall, the study shows the great potential of pXRF as valuable part of an archaeological survey toolkit.     

Reimagining the Iglu: Modernity and the Challenge of the Eighteenth Century Labrador Inuit Winter House

The Inuit sod winter house or iglu has undergone a host of alterations over the past millennium, as housing styles were accommodated to changing local milieus during the colonization of the Eastern Arctic. Many of these changes relate to subtle shifts in gendered work and household social relations, and in Labrador from the eighteenth century some appear to reflect engagements with a more or less hostile European discourse on architectural modernity. Far from a static form subjected to convulsive contact-era transformations, however, dwellings were gradually remade in the context of a long-running Inuit effort to house work and sociality within a meaningful space.     

Chemical characterisation of anthro-technosols from Bronze to Middle Age in Bologna (Italy)

The aim of this research was the understanding of a peculiarly expanded soil sequence in Bologna (i.e., Roman Bononia, Etruscan Felsina), one of the most important archaeological poles for Etruscan colonisation and settlement in northern Italy. The uppermost part of the chronological sequence dating from the Bronze Age up to medieval and modern times was analysed for the first time from geochemical and pedological viewpoints. The integration of archaeological, stratigraphical and pedological data supported by soil chemical analysis, a fundamental key for reconstructing a correct evolutionary sequence, made it possible to recognise seventeen buried Soil Units (ancient Technosols, Anthrosols and Cambisols) characterised by different kinds and degrees of intensity of anthropogenic influence. In some cases, the results show a relatively severe element concentration (Cu, Sn) mainly characterising the Iron Age (Etruscan and Villanovan) stratigraphic units, representing an ancient industrial pollution linked to local dispersal of melting activity dump products generated in near-site surrounding areas. Therefore, a comparison was possible between natural blank and anthropogenically polluted geochemical values for some local soils.     

Identifying activity areas in archaeological soils from a colonial Virginia house lot using phytolith analysis and soil chemistry

Environmental archaeology methods can uncover both house lot organization and economic adaptation practices when applied systematically in conjunction with traditional archaeological research. This is the first study to employ both phytolith analysis and soil chemistry to interpret activity areas on an archaeological site. The patterning in the phytolith and soil chemistry analyses from the site of Rich Neck Plantation, Williamsburg, Virginia, reveals a set of six activity areas in and around the 17th century house lot, demonstrating a degree of economic diversification generally attributed only to 18th century colonial economic and social transformations.     

From pedologic indications to archaeological reconstruction: deciphering land use in the Islamic period in the Baida district (north-western Sicily)

The aim of this work was to detect imprints on soil properties from former Islamic land use (9th to 11th century) using a multi-method, soil-chemical approach. Four soil profiles (with buried horizons) found in the vicinities of former Islamic settlements in Sicily were analysed for phosphorus (total, organic and inorganic), nitrogen (total, NO₃⁻ and NH₄⁺), carbon compounds (δ¹³C, lipids, polycyclic aromatic hydrocarbons (PAH) and functional groups), physical and chemical C-fractions and the state of soil weathering. Two soil profiles contained ceramic sherds from the Islamic period. Inorganic nitrogen forms, phosphorous and the PAH content indicated strong impacts from traditional agriculture and/or burning. Radiocarbon dating of soil organic carbon (SOC) fractions from buried horizons showed that distinct changes must have occurred during the Islamic epoch. The isotopic composition of SOC indicated that land use was probably different in earlier times. C₄ plant cultivation was expected but surprisingly lipid analyses did not confirm this. A high amount of aliphates and low C/N ratio indicated a good, long-term SOC stabilisation under the native conditions combined with Islamic land use. The irrigation of the soils probably increased the production of weakly-crystalline Fe forms that helped to stabilise SOC.     

Development and application of methods used to source prehistoric Southwestern maize: a review

Archaeological cobs free of mineral contaminants should be used to source the soils in which they were grown. Mineral contaminants often contain much higher concentrations of metals than vegetal materials and can alter a cob’s apparent metal and heavy-isotope content. Cleaning a cob via immersion in an acid solution for more than a few minutes will result in the incongruent and sometimes complete leaching of metals, including strontium (Sr), from the cob. When using ⁸⁷Sr/⁸⁶Sr to determine the location of potential agriculture fields, it is best to either integrate several depth-integrated soil samples or to integrate several vegetation samples from individual fields. Biologically labile Sr in semi-arid Southwestern soils largely originates from eolian source or sources and usually is not derived from underlying bedrock. Existing Sr-isotope data indicate that archaeological cobs from Aztec Ruins came from either the Mesa Verde-McElmo Dome or Totah areas, that Pueblo Bonito and Chetro Ketl cobs, from Chaco Canyon that predate A.D. 1130, probably came from the Rio Chaco corridor, and that cobs from Chaco Canyon, that postdate A.D. 1130, probably came from either the Totah or Zuni areas.     

Geographical and Temporal Weighted Regression (GTWR)

Both space and time are fundamental in human activities as well as in various physical processes. Spatiotemporal analysis and modeling has long been a major concern of geographical information science (GIScience), environmental science, hydrology, epidemiology, and other research areas. Although the importance of incorporating the temporal dimension into spatial analysis and modeling has been well recognized, challenges still exist given the complexity of spatiotemporal models. Of particular interest in this article is the spatiotemporal modeling of local nonstationary processes. Specifically, an extension of geographically weighted regression (GWR), geographical and temporal weighted regression (GTWR), is developed in order to account for local effects in both space and time. An efficient model calibration approach is proposed for this statistical technique. Using a 19‐year set of house price data in London from 1980 to 1998, empirical results from the application of GTWR to hedonic house price modeling demonstrate the effectiveness of the proposed method and its superiority to the traditional GWR approach, highlighting the importance of temporally explicit spatial modeling.     

Revealing the Monastic Kitchen: Chemical Analysis of the Soil Inside the Monastery of Cornellana (North‐West Spain)

The residues deposited on the floor of the kitchen of the monastery of Cornellana (Asturias, Spain), while it was still in use in the 18th century, have been analysed using different techniques, including the Kjeldahl method, phenol – sulphuric acid assay, FT–IR, SEM–EDX and LOI. This has allowed us to determine the areas of concentration of proteins, carbohydrates, fatty acids, phosphorus and carbonates, and thus approach the interpretation of the layout of the different areas of activity related to the treatment and cooking of foodstuffs in the kitchen. In any case, and regardless of the fact that this is the first time that these techniques have been applied to study a monastic kitchen in the Iberian Peninsula, the aim of this research is to demonstrate their applicability to other case studies of this integrated set of analytical techniques, some of which are not used very often in the analysis of concentrations of residues and analysis of areas of activity on archaeological soils.