Southern African glass beads: chemistry,glass sources and patterns of trade

Three-hundred-and-sixty glass beads from 19 archaeological sites in southern Africa dating between about the 8th and 16th centuries AD were analyzed using LA-ICP-MS, determining 47 chemical elements. The eight different bead series, previously defined on morphological characteristics, possess different glass chemistries. Some bead series were made from plant-ash glasses, others from soda-alumina glasses. Zhizo series beads of the late 1st millennium AD were probably made from Iranian glass. Later bead series were made of glass probably manufactured in South Asia, though there are changes through time in both South Asian glass recipes and bead morphologies.     

LA-ICP-MS analysis of Late Bronze Age blue glass beads from Gurob,Egypt

Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) analysis was undertaken on 37 blue glass beads excavated from a tomb in the southern Faiyum region of northern Egypt. The tomb was undisturbed, contained the remains of seven females and two children, and dated between the reigns of Amenhotep I (1525–1504 bce ) and Tuthmosis III (1479–1425 bce ). The glass beads were coloured by copper and the trace element concentrations were compositionally consistent with glasses from Mesopotamia rather than from Egypt. Therefore, these glass beads represent a rare example of Mesopotamian glass to be discovered in Egypt, in addition to being some of the earliest glass found. Gurob is known to have been the site of a ‘harem palace' established in the reign of Tuthmosis III, the implication being that these beads represent luxury items transported to Egypt by high-ranking foreign women, possibly in connection with the harem palace.     

XRF analysis of glass beads from the Mycenaean palace of Nestor at Pylos,Peloponnesus, Greece: new insight into the LBA glass trade

In recent years there has been a growing interest in Mycenaean glass among archaeologists and scientists. Scholars have traditionally thought that all Mycenaean glass was imported either in finished form or as ingots and simply shaped or worked at the Mycenaean sites. Chemical studies of other Mycenaean glass (50 and 43) support the hypothesis that glass was imported into Mycenaean Greece, but there is also indication for glass production in mainland Greece at the palace of Thebes (Nikita and Henderson, 2006). There is no evidence for glass making or working at the Palace of Pylos, yet there is an abundance of glass beads there. The aim of this paper is to identify the technology and source for the glass of these beads and thus to ascertain how Pylos was connected to the broader Mycenaean and Mediterranean economies. The composition of the glasses was determined by means of portable XRF analysis and compared to that of other Late Bronze Age glasses from Egypt, Mesopotamia and mainland Greece. Four blue beads coloured with cobalt and one blue bead coloured with copper have Ti and Zr compositions consistent with an Egyptian origin of manufacture while five other beads show Ti and Zr concentrations consistent with a Mesopotamian origin (Shortland et al., 2007). Based on the dearth of Egyptian and Mesopotamian imports in Pylos, the presented data support the hypothesis that Pylos was receiving via internal Greek trade routes foreign-produced glass, which may have been worked abroad or in Greece.     

Overseas imports on the Blue Nile: Chemical compositional analysis of glass beads from Soba,Nubia

Archaeological evidence as well as textual sources leave no doubt about Alwa's (Alodia's) intense transcultural connections, further corroborated by understudied overseas glass bead imports found there. This paper presents results of an analysis of 23 glass beads from Soba, the most prosperous capital of medieval Nubia. Compositional analyses using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) have identified glass belonging to a number of broad compositional groups. Three samples were made of soda lime low-alumina glass produced in the Middle East (v-Na-Ca) and Egypt (m/v-Na-Ca). The remaining beads were made of two types of mineral–soda high-alumina glass (m-Na-Al) North Indian in origin. The results of this study provide new evidence for the provenance and chronology of glass beads available in medieval Soba and Northeast Africa, and contribute new data to research on trade contacts of that time.     

广西越州故城遗址玻璃珠饰的科学研究

本研究利用能量色散型X射线荧光光谱分析、共聚焦激光拉曼光谱分析、光学相干层析成像、超景深光学显微观测等多种方法对广西越州故城遗址出土的印度-太平洋玻璃珠饰进行科技分析,获取了玻璃珠的化学成分、物相结构、内部物理结构、表面显微形貌等综合物理化学信息,确定了玻璃珠的玻璃体系、制作工艺(着色工艺、成形工艺)和产地来源,探讨了以丝绸之路为主线的国内发现魏晋南北朝时期印度-太平洋玻璃珠可能的输入路线。广西越州故城遗址发现的印度-太平洋玻璃珠为中外文明交流提供了新实物证据,对深入研究我国南北朝时期中外文明交流具有十分重要的学术价值和研究意义。     

Investigation of Iron Age north-eastern Scottish glass beads using element analysis with LA-ICP-MS

Class 13 and 14 Iron Age Scottish glass beads are a group of highly decorated beads of British origin or design, dating indicatively to the 1st and 2nd century AD and typically found in Aberdeenshire and Moray district (Guido, 1978, 85–9). Their distinctive stylistic characteristics and geographical segregation renders them ideal for the investigation of whether the glasses employed in their manufacture were imported rather than produced locally, and for the assessment of the technology used in the production of the deep colours. Studies performed in the 1980s on different specimens pertaining to the same Classes (Henderson, 1982) showed compositional characteristics differing from Iron Age southern British beads, suggesting a different source of glass for their manufacture. Here, a set of 19 beads which was never investigated before was analysed for 32 major, minor and trace elements using Laser Ablation-Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS). The sample set shows good homogeneity in major and minor element composition, indicating the use of imported natron glass, with standardized composition typical of Roman glass of the period, also reflected in the recipes used for colouration. Evidence for the use of cullet and waste glass was found, which, along with the particularity of the design, suggests a local origin of the beads and possible production by native glassworkers.     

Characterization of some ancient glass beads unearthed from the Kizil reservoir and Wanquan cemeteries in Xinjiang,China

A total of 33 ancient glass beads unearthed from the Kizil reservoir cemetery and Wanquan cemetery in Xinjiang are studied using Raman spectroscopy, scanning electron microscopy with energy‐dispersive spectrometry (SEM–EDS) and other methods. The detailed study of the glassy matrices, the crystalline inclusions and the microstructural heterogeneities for these glass beads has revealed some valuable information to help in the understanding of their possible manufacturing technology and provenance. At least two different types of glass were present in the two cemeteries. For the first time, antimony‐based colourant/opacifier—for example, Pb₂Sb₂O₇ or CaSb₂O₆—was systematically identified in some beads of plant‐ash type soda–lime glass dated to about 1000–500 bc . The limited number of potash glass beads from the Kizil reservoir cemetery, which were dated to about 500–300 bc , used tin oxide as an opacifier. The diverse resources of the soda–lime and potash glasses indicate the existence of a complex trade network between China and the West much earlier than the Western Han Dynasty.     

Pre-Roman coloured glass beads from the Iberian Peninsula: a chemico-physical characterisation study

This paper reports results derived from a chemical and microstructural characterisation study undertaken on a representative sample set of coloured glass beads that recent archaeological fieldwork carried out in the second century BC Celtiberian necropolis of Numantia (Upper Duero Valley, Spain) has provided. The main objectives of the research were to understand the production technology and provide some insights into their probable provenance. In addition, corrosion and decay processes were also assessed to determine the influence of the cremation ritual within the beads structure. The resulting data suggest that both soda-lime-silicate and, probably, alumino-silicate glasses were produced in the making of these glassy materials, using some transition metal oxides as chromophores or colouring agents. The compositional evidence gathered also suggests that Numantian glass beads were the outcome of trade or exchange practices rather than locally produced.     

The beads of Indian Knoll

ABSTRACT

Busycon discs, barrels, rings, and columellas, Leptoxis and Prunum shell beads, and stone and coal beads from Webb and Moore excavations at Indian Knoll (15OH2) are discussed in this paper as the author seeks to determine how beads were deployed to convey social information during the Archaic period. After wrestling with the count of beads (ca. 27,337) and the number of burials (ca. 260) with beads, the types of beads are tallied and measurements given based on the author’s examination of beads. The presence and distribution of beads in the shell-bearing stratum and the hardpan, and their distribution among women, men, and subadults, are explored. The beads appear to have been assembled rather than manufactured as sets. An argument is made that shell beads were used at Indian Knoll as regalia for members of and victims of a hunt god/spirit cult. Leptoxis sashes are identified in 36 burials and discussed as regalia. Bead co-occurrence with atlatls, faunal species, and violent death is examined as part of the hypothesized cult rituals.     

鲁国故城遗址出土蜻蜓眼玻璃珠的科学研究

本研究利用能量色散型XRF、共聚焦激光拉曼光谱分析技术、光学相干层析成像技术、超景深光学显微系统等多种无损分析技术对山东曲阜鲁国故城遗址出土的7颗蜻蜓眼玻璃珠进行了科学研究。基于获取的蜻蜓眼珠化学成分、物相结构、内部物理结构、表面显微形貌等相关信息,确定了这批蜻蜓眼玻璃珠的成分体系、制作工艺、产地来源和器物功能。研究结果表明,蜻蜓眼玻璃珠来自于楚地,是当时社会稀有而珍贵的奢侈品,是鲁国与楚地相互交流与联系的实物证据。     

湖南出土战国时期蜻蜓眼玻璃珠的科学研究

利用便携式能量色散型X射线荧光光谱仪和三维数字显微系统,对湖南出土的11颗战国时期典型的蜻蜓眼玻璃珠进行科学分析。基于获取的蜻蜓眼珠化学成分、表面和断面显微形貌等相关信息,确定了这批蜻蜓眼玻璃珠的成分体系、制作工艺和产地来源。研究结果表明:3颗蜻蜓眼玻璃珠属于泡碱型钠钙玻璃,1颗扁平蜻蜓眼玻璃珠为植物灰钠钙玻璃,均可能产自埃及或东地中海地区；3颗蜻蜓眼玻璃珠属于铅钡玻璃,还有4颗为钾钙玻璃,皆为战国时期典型的中国本土玻璃,应为楚国本地制作。这11颗蜻蜓眼玻璃珠均采用层叠镶嵌工艺,先制作珠体,然后再用不同玻璃条或片在未完全凝固的状态下进行镶嵌而成。     

The stone quarry on Jiddah Island,Bahrain

The surface of the small island of Jiddah lying north‐west of Bahrain is covered in traces of stone quarrying, but although the island probably supplied the limestone ashlars for the second‐millennium BC Dilmun temples at Barbar, the sixteenth‐century AD Bahrain Fort and other eminent buildings, no study has ever been made of the ancient quarry. Information from a geological report and a few photographs may, it is hoped, inspire new research.     

Glass on the Amber Road: the chemical composition of glass beads from the Bronze Age in Poland

The article discusses the chemical composition of 56 glass samples from 52 beads found in Poland at 13 archaeological sites (mainly cemeteries). The artefacts have been dated to the II–V period of the Bronze Age (=phases BzB–HaB; c. 1600–750/700 bc). The LA-ICP-MS method was applied. Two groups were distinguished in this assemblage based on a comparison of the MgO to K₂O ratio in glass: (i) high magnesium glass (HMG)—23; and (ii) low magnesium and high potassium glass (LMHK)—33 (29 matrix glass specimens and 4 decorative). In southern Poland, beads made of HMG and LMHK are often found in the same cemeteries. Analyses have shown that HMG was most probably made in Mesopotamia and that at least one cobalt glass is of Egyptian provenance. LMHK glass was made in Europe, most probably in Italy. Also, Italy was the most probable transit point for artefacts made of HMG en route to East-Central Europe.     

北京昌平沙河镇出土蜻蜓眼玻璃珠的科学分析与研究

为探讨北京昌平沙河镇墓葬出土的三枚蜻蜓眼玻璃珠的质地和来源,利用X射线衍射分析（XRD）、激光拉曼光谱分析（LRS）、便携式能量色散X射线荧光分析（PXRF）三种无损分析方法,对玻璃珠基体和眼珠分别进行了结构和化学组成的无损伤测试。结果表明,这三枚蜻蜓眼珠的基质为玻璃态物质,其化学成分表明该玻璃属于钠钙硅酸盐（Na₂OCaOSiO₂）系统;Cu和Co是主要的着色元素。考虑到三枚珠子采用的钴料成分为高铁低锰的进口钴料,同时通过与国内外相似珠子的对比,推测这三枚蜻蜓眼玻璃珠是外国进口物的可能性较高。蜻蜓眼玻璃珠所在墓葬群虽为清代,但根据初步的分析研究可推断,墓主通过收藏或其他途径获得并将其作为随葬品。