Non-destructive analysis of amber artefacts from the prehistoric Cioclovina hoard (Romania)

Amber beads from the Cioclovina hoard (Hunedoara County, Romania), dating from the transitional period between the Late Bronze Age and the Iron Age, were analysed by Fourier transform infrared spectroscopy – variable angle reflectance (FTIR-VAR) and Fourier transform Raman spectroscopy (FT-Raman). The aim was to determine if the raw material came from the shores of the Baltic Sea, on the Amber Route which crosses Central Europe, or if it originated from the area of the main amber occurrences in Romania, in Buz?u County, around the village of Col?i. All applied analyses strongly suggest that a large part of the amber from the Cioclovina deposit has a Romanian origin, and thus no connection with the Amber Route.     

Evaluating the efficiency of museums using multiple outputs: evidence from a regional system of museums in Spain

Data Envelopment Analysis is used to evaluate museum efficiency. This approach enables us to create a relative efficiency measure for each museum, taking into account resources used by museums and the performance of their activities based on four well-defined tasks: conservation, research, communication and exhibition. Empirical analysis of data from a regional museum system in Spain is performed, considering a complex production function with several inputs and outputs. The main findings indicate that at least half the museums chosen operate efficiently, with the major cause for inefficiency being inadequate resource management. Only few museums evidenced significant inadequate scaling problems. Major progress, mainly due to improvements in internal efficiency, is evident in the museum system ratios when analysing productivity evolution using the Malmquist Index. By contrast, technological change has less impact, proving that cultural heritage is less receptive to new technologies as compared to other cultural industries.     

Lead isotope analysis as a new method for identifying material culture belonging to the Vázquez de Coronado expedition

Archaeological evidence has become an increasingly important component of efforts to identify the route of the Francisco Vázquez de Coronado expedition through northern Mexico and the southwestern United States (1540-1542). Here, we report the first high-precision lead isotopic measurements of artifacts from two archaeological sites with strong material evidence for the expedition’s presence: Piedras Marcadas Pueblo in New Mexico and the Jimmy Owens Site in Texas. The analysis of lead and copper armaments from both sites reveals that many artifacts have overlapping or extremely similar isotopic ratios. We propose that the narrow range of lead isotopic ratios measured on these artifacts can be interpreted as a geochemical fingerprint for some of the Coronado expedition’s surviving material culture, and provides evidence that we interpret to suggest the expedition derived lead and copper metal from Mexican sources. Such a geochemical fingerprint presents an empirical method for discriminating between artifacts that belonged to the Coronado expedition and those related to subsequent Spanish, historical, or modern activity in the Southwest U.S. Thus, this method could significantly impact the search for and identification of archaeological sites associated with the Coronado expedition.     

Technological traditions inferred from iron artefacts of the Xiongnu Empire in Mongolia

Iron objects excavated from sites of the Xiongnu Empire (3rd century BC–2nd century AD) in Mongolia have been examined using optical and scanning electron microscopy. The results show that the Xiongnu iron tradition may be characterized by the use of low carbon iron and carbon control by carburization. Cast iron was also used in the Xiongnu Empire, but only in very limited applications and with no convincing evidence of its use for the production of low carbon iron. The Xiongnu iron technology seems to have been established on the basis of the bloomery technique, without much influence from the Chinese style of technology, based on cast iron.     

Lead isotope and chemical signature of copper from Oman and its occurrence in Mesopotamia and sites on the Arabian Gulf coast

Lead isotope data, together with an evaluation of previously published results for the chemical composition of Omani ores and copper‐base artefacts are used to define a material signature of Omani copper. Absent from our group of Bronze Age metal (Umm an Nar and Wadi Suq periods) are the signature of ores from Masirah Island and also from the vast deposits in north Oman inland from Suhar. Contemporaneous copper from Bahrain and from Tell Abraq on the Gulf coast is consistent in its material signature with Omani copper; a derivation from Omani ores of this copper is highly likely. A few exceptions at Tell Abraq point to Faynan/Timna in the southern Levant as a possible source region. Among Mesopotamian artefacts the signature of Omani copper is encountered during all cultural periods from Uruk at the end of the fourth millennium BC to Akkadian 1000 years later. Oman/Magan appears to have been particularly important during Early Dynastic III and Akkadian when about half of the copper in circulation bears the Omani signature.     

Stable carbon isotope analysis of subfossil wood from Austrian Alps

The presented studies were carried out in order to check the usefulness of subfossil wood for stable isotope analysis. The aim of research was also to define the optimal method of subfossil samples preparation. Subfossil samples used during the presented studies are a part of the multicentury dendrochronological scale. This chronology originates in an area situated around a small mountain lake — Schwarzersee, in Austria. The obtained results of stable carbon isotope measurements confirmed that the method of α-cellulose extraction by the application of acidic sodium chlorite and sodium hydroxide solutions removes resins and other mobile compounds from wood. Therefore, in the case of the analysed samples, the additional chemical process of extractives removing was found to be unnecessary. Studied wood samples contained an adequate proportion of α-cellulose similar to the values characteristic for the contemporary trees. This proved an adequate wood preservation which is essential for the conduction of isotopic research.     

Towards the application of desorption electrospray ionisation mass spectrometry (DESI-MS) to the analysis of ancient proteins from artefacts

The detection and identification of protein residues from archaeological artefacts has been the subject of considerable controversy over the past two decades, this controversy spurring the application of a range of different analytical methods. Part of the debate surrounds the ability of the methods to uniquely identify original proteins. Another is the apparent contradiction between the ease of extraction in the laboratory of residues that have managed to survive in sediment over millennia; some studies use simple solvents including water, whilst others claim that efficient extraction requires the destruction of the artefact.Desorption electrospray ionisation mass spectrometry (DESI-MS) offers the potential to directly analyse proteins bound to the surface of artefacts. The method permits desorption of analytes under ambient conditions directly from a wide range of surfaces with little or no sample preparation. This has already led to its application in a range of areas, including forensic analysis of trace levels of narcotic drugs. It does not require destruction of the artefact (e.g. by drilling or dissolution) and can work in concert with other methods (for instance it could be used as a screening tool prior to lipid extraction).Here we report the construction of a DESI-MS interface and consider the potential of the method to contribute to the debate surrounding the preservation of proteins on artefacts. The DESI-MS interface was fitted to a conventional ion trap mass spectrometer and tested using peptides and proteins artificially applied to the surface of flint flakes and potsherd samples. A range of intact proteins was analysed; the DESI interface identified test proteins up to a maximum molecular weight of approximately 20 kDa. Peptides generated from these and larger proteins could be detected using DESI-MS following tryptic digestion in situ. The collected data allowed identification of the originating proteins. The potential applications to archaeological science of this new analytical tool are discussed.     

Paleodietary implications from stable carbon isotope analysis of experimental cooking residues

The regional timing of maize introduction in eastern North America is a long-standing topic of archaeological interest. Most recently, Morton and Schwarcz [2004. Paleodietary implications from stable isotopic analysis of residues on prehistoric Ontario ceramics. Journal of Archaeological Science 31, 503–517] investigated the timing of maize introduction in Ontario through isotope analysis of charred cooking residues adhering to the interior of prehistoric ceramic containers. They interpret their results to suggest maize was incorporated into diets after A.D. 600. We assess their approach and conclusions with stable carbon isotope assays on three sets of experimental cooking residues, evaluating the variable combustion of carbon fractions, contributions of fats and carbohydrates, and the contribution of total carbon. We also undertake multiple resource modeling of two part food mixes with green maize and maize flour. Our results suggest that systematic under representation of maize can result depending on residue composition and that some prior knowledge of C3 plant and animal contents is necessary to interpret stable carbon isotope values on cooking residues. We question the independent use of stable carbon isotope analysis of charred cooking residues as a viable technique for extracting paleodietary information.     

An analysis of Late Pre-Islamic copper-base artefacts from Ed Dur, U.A.E.

The article presents the analytical results of a study of copper-base artifacts from ed-Dur, a large site in the United Arab Emirates which was occupied principally during the 1^st century A.D. In addition to identifying a number of pieces with high lead content, the analyses have contributed to an understanding of brass and brass distribtion in the Roman Near East.     

Provenance of prehistoric obsidian artefacts from Kul Tepe,northwestern Iran using X-ray fluorescence (XRF) analysis

Analysis by X-ray fluorescence of 53 obsidian artifacts the main source of obsidian for the workshops in Kul Tepe was Syunik but obsidian sources as far as west as the Lake Van region (Nemrut Da? and Meydan Da?) and as far north as Gutansar were also utilized. These new results indicate a broad network of trade and exchange.     

Stable carbon isotope analysis of human tooth enamel from the Bronze Age cemetery of Ya'amoun in Northern Jordan

Seventy-five teeth from the Bronze Age cemetery of Ya'amoun were sampled for carbon isotope analysis. The sampled teeth represented the transitional period of the Middle/Late Bronze Age. The results showed that the components of the diet that are reflected in the carbon isotope data remained the same during this period with an average δ¹³C of about −11.87‰. This value reflects more C₃ plant consumption.     

Residential mobility and social identity in the periphery: strontium isotope analysis of archaeological tooth enamel from southeastern Arabia

Strontium isotope analysis represents an effective means of assessing mobility and reconstructing geographic residence patterns in archaeological populations. This biogeochemical technique was utilized to test the hypothesis that burgeoning interregional exchange networks and the occurrence of exotic grave goods in local tombs would correspond with a highly mobile population and a considerable immigrant presence during the Umm an-Nar (2700–2000 BC) period in the UAE. This region has been considered peripheral relative to larger civilizations in Mesopotamia and the Indus Valley, but played an important role as a major supplier of copper for the Persian Gulf. Individuals (n = 100) from six monumental Umm an-Nar tombs (Mowaihat; Tell Abraq; Umm an-Nar Island I, II, V; Unar 1) were selected to evaluate the geographic origins of tomb members. Mean ⁸⁷Sr/⁸⁶Sr ratios from local individuals interred at Mowaihat (0.708863 ± 0.000014; 1σ, n = 12), Tell Abraq (0.708873 ± 0.000020; 1σ, n = 27), Umm an-Nar Island (0.708902 ± 0.000079; 1σ, n = 33), and Unar 1 (0.708805 ± 0.000065; 1σ, n = 25) all display little isotopic variability, indicative of a population that was not highly mobile. However, coupled with archaeological evidence, three immigrants from Tell Abraq (n = 2) and Mowaihat (n = 1) identified by deviant strontium values suggest that this region was actively engaged in interregional interaction. Despite claims that these tombs acted as visible markers of territoriality legitimized by local ancestors buried within them, the presence of non-locals suggests that as commerce became increasingly important, definitions of kinship and social identity may have become more flexible to better meet the needs of the local community and those with whom they interacted.     

Stable isotope analysis of humans from Xiaojingshan site: implications for understanding the origin of millet agriculture in China

Millet agriculture originated in Northern China in the early Neolithic period (ca. 8000 BP), however, the actual importance of millet in human diets is still not clear. To determine the relative contribution of millet in human diets in this period we undertook stable isotope analysis of humans from Xiaojingshan site and fauna from Yuezhuang site, both of which are attributed to the Houli Culture and date to about 8000 years ago. The carbon isotope values of human bone collagen showed that millet (as a C₄ plant) only contributed approximately 25% of dietary protein, with the rest from C₃ based plant and animal sources, if a simple mixing model is used. We did not observe any statistical dietary difference between males and females at the site, although it has been argued that the Houli Culture was a matriarchal society. Finally, we compared our data with other published isotopic data from the contemporary Jiahu site and Xinglongwa site and a number of sites from the subsequent Yangshao Culture and found that millet only became a significant source of dietary protein approximately 1000 years later, as human carbon isotope values from these later sites indicated that almost all of dietary protein came from C₄ (i.e. millet) sources.     

Stable isotope analysis of prehistoric populations from the cemeteries of the Middle and Lower Dnieper Basin,Ukraine

This paper presents the results of new stable isotopes (carbon and nitrogen) analysis of human, faunal and fish remains from thirteen cemeteries from the Middle and Lower Dnieper Basin, Ukraine. The results are integrated with earlier analyses, undertaken solely on human samples, in order to provide a comprehensive overview of subsistence across the Upper Palaeolithic through to Eneolithic periods in this region. This is the first time that a combined sample of human, faunal and fish remains has been studied in order to interpret subsistence strategies across these periods in Ukraine. The total dataset comprises 113 samples of human, faunal and fish remains, 59 of which include new analyses of faunal and fish remains that have not previously been made available for study (Table 1). The analysis of the faunal and fish remains allows for a consideration of trophic levels which indicates that the consumption of freshwater fish occurs from the Epipalaeolithic period onwards. Whilst the majority of the cemeteries and the individuals therein cluster in relatively tight groups, there is a significant offset between the human and faunal samples due to the consumption of freshwater resources. The fish samples analysed in the study appear to exhibit a relatively random distribution when compared to the other samples analysed. In general, freshwater resources remain significant through until the end of the Neolithic period and into the Eneolithic period at the sites investigated.     

New light on early caprine herding strategies from isotope analysis: a case study from Neolithic Anatolia

The measurement of stable carbon (δ¹³C) and nitrogen (δ¹⁵N) isotopes of caprine bone collagen from the Neolithic sites of Çatalhöyük and Aşıklı Höyük in south-central Anatolia have allowed examination of exploitation and herding practices of sheep and goats. The isotope values from protodomestic caprines at Aşıklı Höyük suggests that these animals were consuming very similar foods to each other and were all confined to the same or similar environments with no access to C₄ plants. At Çatalhöyük, the results show how the caprine management strategy develops from the strategy seen at Aşıklı Höyük into a more varied practice at an early stage as the site grows with an increasing dietary contribution obtained from C₄ plants. No change in diet is isotopically discernible at Aşıklı Höyük. Interestingly, no distinction could be made between the diets of sheep and goats at either site. Therefore, such studies are a useful method of examining the development of early herding or management strategies of caprines in the Near East.     

Provenance analysis of Olivella biplicata shell beads from the California and Oregon Coast by stable isotope fingerprinting

While Olivella beads are a common component of archaeological sites in California, and were widely traded in prehistory, no method has been developed to trace individual beads to a point of origin. This study examines the potential of stable carbon and oxygen isotopes to source Olivella beads from the Pacific coast. The study shows that 1) the oxygen isotopic composition of modern Olivella biplicata shells faithfully varies with ambient sea surface temperature and local upwelling, lending themselves to sourcing studies; 2) oxygen isotope ratios in modern shells can be used to identify shells that grow north versus south of Point Conception, California; and 3) shell carbon isotope ratios may further subdivide these two regions into more spatially restricted source zones. Analyses on a small sample of 10 beads found at various archaeological sites within the interior of California suggest that all were made in southern California.     

Strontium isotope analysis of human tooth enamel from Barsinia: a late antiquity site in Northern Jordan

The archaeological site of Barsinia represents a model of a mixed subsistence strategy in the late antiquity of Jordan. Contrary to historians' belief that the late antiquity economy was stagnated, archaeological evidence at the site of Barsinia points to wealth accumulation as mirrored by the local wine industry and trade. As the economic growth may enhance population dynamics, the study tests the population mobility at the site using strontium isotope ratios from the human tooth enamel. The study comprised 12 right upper third molars and 12 rodent teeth samples. The results confirm that all of the sampled individuals were local to the area (raised in the area) and whose diets were probably obtained from spatially restricted localities in the region.