How the Romans got themselves into hot water: temperatures and fuel types used in firing a hypocaust

Abstract

The remains of hypocausts are noted as being widespread throughout the Roman Empire but, whereas the structure of hypocaust systems has been widely documented, primary knowledge of operating temperatures is limited. The petrographic technique of reflectance microscopy is used here to quantify cell wall reflectance values for charcoals from the hypocaust furnace of a bath suite forming part of small Romano-British villa complex at Groundwell Ridge near Swindon (Wiltshire, UK). The technique utilises material of archaeological origin to infer operating temperatures of the hypocaust furnace using established calibrations. The charcoals recovered from the furnace were identified as being predominantly Quercus (Oak) with some Populus/Salix (poplar/willow). Mean random reflectance of the samples indicated furnace-operating temperatures of 330–410°C. These temperatures fall below that of charcoal fuel production and hence suggest that it was wood that was used to fuel the hypocaust at Groundwell Ridge and not charcoal. Knowledge of the operating temperature of the furnace is a starting point in further calculations to understand, using primary evidence, the operating temperatures throughout the hypocaust system.     

Is vitrification in charcoal a result of high temperature burning of wood?

The term ‘vitrified’ is used to describe the glassy appearance of some charcoals recovered in the archaeological record. It has been generally considered that this phenomenon is a result of wood being subjected to high temperatures similar to the role of temperature in the formation of glass and pottery. Charcoals displaying characteristics of vitrification from three distinct archaeological contexts were analysed using reflectance microscopy to determine their temperature of formation. Charcoal was also generated in laboratory charring experiments at temperatures of 900–1100 °C for durations of 1, 6, 12 and 24 h to determine if subjection to high temperature led to vitrification. None of the laboratory-produced charcoals displayed characteristics of vitrification. Mean random reflectance of the vitrified archaeological fragments indicated temperature of formation from 310 to 530 °C. A charring experiment was also conducted, at 500 °C for 6 h, using green wood with some bark attached, and added sugars, but no evidence of vitrification was seen. Therefore vitrified charcoals do not result from high temperature charring or primarily from the use of green wood.     

Charcoal reflectance measurements: implications for structural characterization and assessment of diagenetic alteration

Charcoal is a valuable source of archaeological and palaeoenvironmental proxy data. However growing evidence suggests that production conditions can strongly influence post-depositional alteration of charcoal. Consequently, both reconstruction of production temperature and understanding of the potential for diagenetic alteration are of great interest. Here, we use mean random reflectance (Ro_mean) in conjunction with other chemical characterization methods to address these questions. Ro_mean was obtained for a suite of modern analogue charcoal, produced under controlled conditions, and for a series of natural charcoal samples, obtained from archaeological and palaeoenvironmental deposits. Ro_mean proves to be a robust measure to assess formation temperature for samples produced at 400 °C and above, even after exposure to highly oxidizing conditions. Ro_mean is also useful for samples formed between 300 °C and 400 °C. However, if an assemblage of charcoals has been exposed to oxidizing conditions, lower temperature charcoals may be preferentially lost. It is apparent that charcoal produced at lower temperatures is more highly susceptible to chemical oxidation, and that there is a continuum in charcoal degradation potential, dependant upon fuel material and production conditions.     

Morphological,chemical and physical changes during charcoalification of wood and its relevance to archaeological contexts

Wood exposed to a heat source can be transformed into charcoal if subject to conditions of carbonisation (in the absence of air) or charring (in restricted air). Charcoal recovered from archaeological sites can yield fundamental information to our understanding of human economic and cultural development over time and (ecological) setting. This work describes the morphological (anatomy, degree of shrinkage), physical (reflectance) and chemical (elemental, molecular composition) properties of charcoal in relation to heat source and wood variables. In this study charcoal and charcoal fuel were experimentally produced whereby temperature (160–1200 °C), time of exposure (2–1440 min), heating rate (high and low) and wood type (angiosperm and conifer) were varied. The results show that charcoal, often described as an inert, black material, has different chemical and physical properties in relation to the investigated variables. By using these different properties it is possible to distinguish between the different types of fires (domestic and industrial) exploited by humans in the past. Morphological analyses and reflectance measurements are effective tools for this purpose and can be used in wood exposed to temperatures of 300 °C and above—temperatures which are relevant to archaeological research. Angiosperm and conifer wood react in different ways when exposed to heat and thus the taxonomic identity of archaeological material needs to be known. Chemical analyses can be used for wood exposed to temperatures below 400 °C whereas elemental analyses of the carbon content can be used for wood exposed to temperatures up to a maximum of 650 °C.     

X-ray microtomographic imaging of charcoal

We assess the potential of X-ray microtomography as a tool for the non-destructive, three-dimensional examination of the internal structure of charcoal. Microtomographic analysis of a series of charcoals produced by the experimental pyrolysis of pine wood at temperatures from 300 and 600 °C in nitrogen only and in nitrogen mixed with 2% oxygen indicates that, despite substantial shrinkage, observed porosity, pore size and pore connectivity are all increased by pyrolysis and also by chemical oxidation. Analysis of a number of altered and unaltered archaeological and geological charcoals has demonstrated the capacity of the technique to identify and map the distribution of authigenic mineral contamination within charcoal fragments. The results are of significance to radiocarbon dating in that they provide insights into the mechanisms by which charcoal can be contaminated by extraneous carbon in the natural environment.     

Charcoal scarcity in Epigravettian settlements with mammoth bone dwellings: the taphonomic evidence from Mezhyrich (Ukraine)

Fuel management during the Paleolithic periods is an important issue to understand past human subsistence. Numerous Palaeolithic sites relate an abundance of burnt bones in hearths and an absence or scarcity of wood charcoals, which leads studies to focus on burnt bone remains and the use of bones in hearths. Few works take into account the micro-residues of wood charcoals which can still be present in hearth areas and excavated sediments. We studied the Epigravettian site with mammoth bone dwellings of Mezhyrich (Ukraine) previously characterized by its high content of burnt bones and an “absence” of wood charcoal during the so-called mammoth steppe. The presence or absence and proportions of both wood charcoals and burnt bones were quantified in macro-, meso- and microscale sediment size fractions by an image analysis method. Our results show that excavations during field-works at Mezhyrich give only a partial image of the original anthracological record and that most charcoal materials are lost with standard archaeological and anthracological approaches. The scarcity of charcoals in this site was possibly due to an important mass reduction accentuated by the addition of bones in hearths. By applying our protocol we recovered a significant amount of wood charcoals which provides the first ¹⁴C dates from charcoals at Mezhyrich. Numerous charcoals are identified contributing subsequent information about vegetation, environment and burning practices. They indicate, by comparison with pollen data already collected, the presence of forest patches in a mammoth steppe landscape, which might have influenced the collecting behavior of Epigravettian populations.     

Alkali extraction of archaeological and geological charcoal: evidence for diagenetic degradation and formation of humic acids

Charcoal forms a crucial source of archaeological and palaeoenvironmental data, providing a record of cultural activities, past climatic conditions and a means of chronological control via radiocarbon (¹⁴C) dating. Key to this is the perceived resistance of charcoal to post-depositional alteration, however recent research has highlighted the possibility for alteration and degradation of charcoal in the environment. An important aspect of such diagenesis is the potential for addition of exogenous “humic acids’ (HAs), to affect the accuracy of archaeological and palaeoenvironmental reconstructions based upon chemical analyses of HA-containing charcoal. However the release of significant quantities of HA from apparently pristine charcoals raises the question whether some HA could be derived via diagenetic alteration of charcoal itself. Here we address this question through comparison of freshly produced charcoal with samples from archaeological and geological sites exposed to environmental conditions for millennia using elemental (C/H/O) and isotopic (δ¹³C) measurements, Fourier Transform Infrared Spectroscopy (FTIR) and proton Liquid-State Nuclear Magnetic Resonance (¹H NMR). The results of analyses show that the presence of highly carboxylated and aromatic alkali-extractable HA in charcoal from depositional environments can often be attributable to the effects of post-depositional processes, and that these substances can represent the products of post-depositional diagenetic alteration in charcoal.     

Preservation potential of charcoal in alkaline environments: an experimental approach and implications for the archaeological record

Charcoalified plant material (usually wood) has been described as being inert with a high preservation potential. Although usually black on both the outside and inside, the physical and chemical properties differ as a function of temperature and time of exposure to a heat source. Post-depositional processes however may exert additional affects on charcoalified material and introduce bias into the archaeological record. This work explores the influence of alkaline conditions, often encountered in the soil environment, on the preservation potential of charcoalified material. Charcoal, experimentally produced at different temperatures, was exposed to a number of solutions of potassium hydroxide and calcium hydroxide with different pHs, to simulate exposure to alkaline soil conditions. Under these conditions chemically mediated physical interactions occur resulting in fragmentation of the charcoal samples into (very) small pieces the size of which depends upon the initial temperature of charcoalification. Moreover further interactions result in a decrease in reflectance relative to samples not exposed to alkaline conditions. Although experimentally driven the potential for physical loss of charcoal from a particular site coupled with the reduction in (expected) reflectance of any resident material, has important implications for any conclusions drawn regarding the archaeological record.     

Charcoal analysis and dendrology: data from archaeological sites in north-western France

During the last 15 years, charcoal analysis of archaeological sites in north-western France has been carried out in conjunction with systematic and detailed dendrological examination. By considering these extrinsic criteria in association with the analytical results, palaeo-ethnographic and palaeo-environmental information can be obtained. The charcoals are classically identified under the microscope on the basis of their cellular structure. This examination is associated with an observation of the ligneous structure on transverse sections using a binocular lens. When charcoal fragments are large enough, the growth ring widths are measured. Tree ring curvature is also noted. Finally, alteration by fusion or radial cracks, the presence of fungal hyphae, and insect degradation are also recorded. Results are thus obtained on the nature of fuel used in domestic fireplaces and kilns. The selection of timbers and their catchment areas are also revealed. The average width of the growth rings in oak charcoal from domestic hearths coming from about forty sites in north-western France shows a significant increase from 6000 to 2000 BP. There is a similar increase in the number of heliophilic taxa used from the Neolithic to the Iron Age. This implies that the environment became more and more open because of use by society. The interpretation of the dendrology results applied to charcoal analyses is obtained through a convergence of criteria. Thus, charcoal analysis can provide more than just an identification of the species used, and can yield fundamental information on the interaction of society with the environment.     

Archaeobotanical inference of Bronze Age land use and land cover in the eastern Mediterranean

Charcoal and charred seeds at five Bronze Age archaeological sites discern ancient land use in the eastern Mediterranean. Seed frequencies of orchard crops, annual cereals and pulses, and wild or weedy plants are used to characterize plant utilization at different archaeological sites on the island of Cyprus, in the Rift Valley of Jordan, and in the Jabbul Plain and along the upper Euphrates River valley in Syria. Seed to charcoal ratios provide proxies to determine the relative usage of dung versus wood for fuel across the ancient Mediterranean landscape. Greater charcoal and lower charred seed values are interpreted to represent a wooded environment, while higher amounts of charred seeds and minimal wood charcoal suggest a much great use of dung as a fuel source. Interestingly, Politiko-Troullia (Cyprus, Cypriot archaeological sites are, by convention, named for the nearest modern village (Politiko), followed by an italicized toponym (Troullia) referring to the plot of land that incorporates the site) has the lowest seed to charcoal ratio, suggesting its residents primarily burned wood and that the landscape surrounding Troullia remained relatively wooded during the Bronze Age. In contrast, villagers at Tell el-Hayyat (Jordan) utilized a mixture of wood and dung, in contrast to Tell Abu en-Ni’aj (Jordan), and especially Umm el-Marra and Tell es-Sweyhat (Syria), where inhabitants relied solely on dung fuel. Comparative analysis and interpretation of seed and charcoal evidence thus illustrates the variety of fuel use strategies necessitated by the dynamic and diverse Bronze Age landscapes of the Eastern Mediterranean.     

The ethnoarchaeology of firewood management in the Fang villages of Equatorial Guinea, central Africa: Implications for the interpretation of wood fuel remains from archaeological sites

In archaeological literature, the study of trees and wood remains is a topic of relatively marginal interest, especially compared to texts on crops and human–animal relations. However, charcoal is the most frequent botanical remain found in archaeological sites. Charcoal analysis can therefore play a major role in the development of studies in both landscape and palaeoethnobotanical reconstruction. The majority of the archaeological charcoal assemblages reflect the exploitation of wood as an energy source (fuel). The archaeological study of firewood selection has been predominantly developed from “eco-utilitarian” or “subsistence economy” perspectives, but has not yet considered fuel collection and use as one of the most enduring categories of human–environment interactions, nor has archaeology looked into its potential as a source of empirical information on past perceptions of, and interactions with, ancient landscapes. The aim of this paper is to expand previous archaeological work on the interpretation of charcoal macro-remains through the study of firewood collection as a historically constituted, socially mediated and archaeologically observable landscape practice. In order to achieve this, we present an ethnoarchaeological case study from the Fang society of Equatorial Guinea (central Africa) aimed at gaining a better understanding of the complex interactions between cultural, ecological and economic variables in firewood collection strategies.     

Firing temperature of a clay core sample in a bronze tripod from Daxinzhuang Site in China using TL techniques

In this paper, we studied the thermal history of a clay core sample from one leg of a bronze tripod unearthed at Daxinzhuang Site, Shandong, China. The properties of the luminescence signals of quartz depend on the maximum temperature at which the quartz was annealed in the past. We examined the feasibility of measuring the thermoluminescence (TL) sensitivity change of quartz for exploring the firing temperature of archaeological materials. The sensitization factor of the 110°C TL peak (S₂/S₁) and the ratio of the 210°C TL peak to the 110°C TL peak at different annealing temperatures were utilized to unveil the firing temperature in the clay core sample. The firing temperature of the clay core sample was approximately 700°C–800°C, proving the clay core has been fired. This result proved that the clay core has been fired by human agencies and indicated on the temperature of the clay core in drying and firing given by the foundry workers before the actual casting step.     

Stable carbon and oxygen isotopic compositions of wood ash: an experimental study with archaeological implications

Wood ash, composed mainly of the mineral calcite, is an important component in many archaeological sites. Identification of wood ash in the archaeological record is often difficult due to mixing of ash with other calcitic components of geogenic origin and/or due to diagenetic changes. A recent empirical study using the stable isotope compositions of carbon (δ¹³C) and oxygen (δ¹⁸O) in wood ash enabled the identification of mixtures of wood ash with geogenic calcite and to follow diagenetic changes due to partial dissolution and re-precipitation of ash in two prehistoric cave sites in Israel. Little however is known about the processes responsible for the isotopic compositions of wood ash in relation to formation at various temperatures and the influence on isotopic composition of ash from a variety of plant species. Here we present an experimental study of wood ash formed by burning three C3 tree species and one C4 desert bush at different temperatures. The results indicate that there are significant differences in the isotopic compositions of carbon and oxygen between wood ash that forms by combustion at a relatively low temperature (500 °C) and at a higher temperature (900 °C). In addition, we show that the isotopic composition of carbon and oxygen in high temperature wood ash approaches equilibrium over a period of several months and that the carbon isotopic composition of low temperature wood ash may reflect the photosynthetic pathway of the burnt woody species. Lastly, we show that the isotopic compositions obtained from wood ash prepared at different temperatures do not reflect a temperature dependent fractionation process, but a mixing line between calcite that formed by low temperature combustion and calcite formed by high temperature combustion which later underwent re-carbonation with atmospheric CO₂. In addition, we suggest that exchange processes may possibly occur during combustion between decomposing calcium-oxalate and atmospheric O₂, CO₂ and CO. The archaeological implications of this study are discussed in relation to identification of wood ash in the archaeological record, identification of fuel sources and burning temperatures, and diagenetic changes expected in karstic cave environments. The method presented here can be applied at any archaeological site.     

Preservation of fungi in archaeological charcoal

During the analysis of wood charcoal remains from archaeological sites, it is common to find different microorganisms and different forms of degradation present in the plant tissue. However, one may encounter difficulties when attempting to identify these microorganisms and determine when their attack occurred. This paper focuses on preservation aspects related to the microorganisms in wood and demonstrates the structural changes that take place in different types of decayed wood after it was converted into charcoal. The study seeks to determine whether the microbial attack found in archaeological woods took place before the burning of the wood or after. Burning experiments were conducted using wood that had been decayed by various types of fungi including white-rot, brown-rot, and soft-rot. The laboratory burnt wood samples showed decay patterns that were comparable to those observed in archaeological charcoal samples, indicating that signs of fungal infestation and features of decay can be preserved after burning with micromorphological details of mycelium and cell wall attack evident. This indication may provide important information related to the gathering of deadwood as fuelwood. In addition, examples of decayed wood preserved in archaeological charcoal assemblages are described. Their relationship to the archaeological context and environmental conditions may suggest different interpretative models concerning wood management strategies applied by past societies.     

An investigation of climatic change in the holocene epoch using archaeological charcoal from Swaziland, Southern Africa

A methodology is described for the analysis of Holocene charcoals excavated from a rock shelter in the Lubombo Mountains of northeast Swaziland. Scanning electron microscopy was used to compare these with modern reference woods. Of the ancient material 96·6% could be identified, in some cases at specific level. It is in such a subtropical area, where the woody flora is so rich, that assemblages of local taxa can be used in palaeoclimatic reconstructions. The changing taxa indicated by the charcoal fragments from the rock shelter clearly reflect minor shifts in Holocene climate, from moist to dry and back to moist in recent times. This is of relevance to the fluctuations in Stone Age populations in southern Africa. The wider use of such evidence to complement other palaeoenvironmental and archaeological data is advocated.     

THE ANCIENT MINE OF SERVETTE (SAINT‐MARCEL,VAL D’AOSTA,WESTERN ITALIAN ALPS): A MINERALOGICAL,METALLURGICAL AND CHARCOAL ANALYSIS OF FURNACE SLAGS*

The Cu–Fe mining district of Servette is located in the valley of Saint‐Marcel (Val d’Aosta) at about 1800 m a.s.l. in the western Italian Alps. A large furnace slag deposit occurs near the Servette mine. Slags are mainly constituted by silicate and oxide in a glassy matrix, with disseminated sulphides and iron–copper alloys, and they record temperatures of 1380–1100°C. Radiocarbon dating of slag charcoals has shown that metallurgy in this site took place around ad 890–980. The charcoal analysis has shown that coniferous wood was mainly utilized, and intensive exploitation over the centuries led to a change in the composition of the local woods.     

Quantifying woodland resource usage and selection from Neolithic to post Mediaeval times in the Irish Midlands

The antiquity and context (site or feature type) are the two principal factors that act as a framework for interpreting charcoal and wood data from archaeological sites in the recreation of past woodland environments. This research addresses these parameters through the analysis of over 18,000 charcoal fragments from 57 archaeological excavations carried out along a 61?km road scheme in the midland region of Ireland. Observations on spatial vegetation dynamics and woodland resource patterns are also reported on. The data were analysed through percentage frequency and multivariate analyses. The results reveal woodland resource usage in terms of wood types selected for use as fuel or as structural wood as well as patterns of change and variability in taxonomic composition in relation to site types, feature types and time periods. Selection was found to be low in prehistoric times and in particular at burnt mound sites/fulachta fiadh but became increasingly important as time progressed. This has important implications when charcoal from archaeological settings is used in environmental reconstructions.     

An ethnoarchaeological study of cooking installations in rural Uzbekistan: development of a new method for identification of fuel sources

Mud constructed cooking installations such as ovens and hearths are common in modern, pre-modern and archaeological domestic contexts in West and Central Asia. Archaeological cooking installations are primarily identified using analogy of shape and size to ethnographic installations. The study presented here establishes direct evidence to the use of fire within mud constructed cooking installations, thus providing means for reducing ambiguity in identification of archaeological cooking installations. In addition, we present here a newly developed method that enables a clear-cut distinction between wood and dung ashes used as fuel materials in many modern and archaeological domestic contexts. The study is based on an ethnoarchaeological research in rural households at the Republic of Uzbekistan that was followed by geoarchaeological analyses of installation walls, wood ash, dung ash and wood and dung standards collected in the study area. Field work included ethnographic observations, interviews with informants and temperature measurements during cooking experiments. We show that changes in the clay mineral structure due to exposure to high temperatures on the interior walls of cooking installations can be detected using FTIR (Fourier Transform Infrared) spectroscopy, providing for the first time direct evidence to the use of fire within such installations. We demonstrate that the temperature recorded by clay alteration on installation walls as well as in the ashes left on installation bottoms does not correspond to baking or cooking temperatures. We also show that the newly developed method, based on the ratio of wood ash pseudomorphs to dung spherulites, separates between wood and dung ashes with very high certainty. Yet, we identify a range of values where differentiation between wood and dung ashes is uncertain, and suggest it results from intensive mixing processes. Lastly, we show that phytolith morphotype analysis is an insufficient tool, if used alone, for distinguishing wood from dung ashes in the study area. The newly developed tools for temperature estimation within mud constructed installations and for fuel origin determination contribute to better understanding of cooking-related practices, and can be applied to archaeological contexts worldwide.     

Auditory Exostoses in Pre‐Hispanic Populations of the Lower Paraná Wetlands,Argentina

Auditory exostosis (AE) has been characterised from the medical and anthropological perspectives as an adaptive biological response to repeated immersion in cold water as well as exposure to cold environmental temperatures and wind chill. At the archaeological level, the highest prevalence has been found in societies living in coastal environments in areas located at 30–45° north or south latitude with a subsistence pattern based on fishing and mollusc gathering. The region of the lower Paraná River wetlands in Argentina is an area dissected by multiple rivers, streams, and lakes, especially in the Paraná delta near Buenos Aires where these features create a landscape composed of many islands. A variety of archaeological analyses performed on faunal remains, stone tools, bone, and ceramic artefacts are consistent with the interpretation that towards the end of the late Holocene (2000–700 BP), this region was inhabited by hunter–gatherer populations with a subsistence pattern based mainly on fishing and hunting along with the gathering of molluscs. In this work, we present an analysis of 176 crania of individuals recovered from 21 archaeological sites in the region. Results indicate the presence of AE in 6.25% of the cases, with all of these corresponding to adult male individuals. This moderate prevalence coincides with the expected levels for populations where contact with water is frequent in regions located at 30–45° latitude. The absence of female individuals showing evidence of AE allows us to suggest a possible sex‐based division of labour. We hope that this work can contribute to ongoing discussion of the economic and social aspects that characterised pre‐Hispanic life in the study area, while also expanding the available information on AE at the worldwide level. Copyright © 2015 John Wiley & Sons, Ltd.     

Multi-element soil prospection aiding geophysical and archaeological survey on an archaeological site in suburban Sagalassos (SW-Turkey)

In order to take full advantage of the archaeological information contained within buried archaeological sites, it is important to apply an integrative approach combining complementary prospection methods. In this study, geochemical prospection data are combined with archaeological and geophysical survey results on an unexcavated site in suburban Sagalassos (SW-Turkey), with the aim of obtaining better insights into the structural shapes and past functionalities of the area. Spatial and multivariate statistical analyses of the chemical data reveal anomalies of K, P and Zn on a location where archaeological and geophysical results suggest the presence of ceramic producing kilns. These elemental enrichments are thought to result from burning wood or dung as fuel for the detected kilns. In addition, local anomalies of Co, Cr, Fe, Mg, Mn and Ni were found to reflect the working and storage of ophiolitic clays, employed as a raw material for ceramic production. Radiocarbon dating of charcoal in a 2.5 m deep drill core in this zone provides ages between AD 120 and 350 at depths of 50 and 60 cm. Al, As, Ba, Ca, Na, Sr, Ti and Pb are considered geogenic elements in this study. The present study supports the theory that geochemical prospection holds potential as a surveying technique, as it was found that chemical data facilitate the interpretation of structures detected by geophysical and archaeological methods, thereby creating an extra dimension to the interpretation of survey data. The results further argue in favour of using strong-acid extractions and the consideration of a large suite of elements when applying chemical soil survey as an archaeological prospection technique, and highlight the importance of considering site lithology. Multivariate statistics proved to be invaluable in distinguishing anthropogenic from lithological soil patterns.