FACTORS AFFECTING THE VIABILITY OF THERMOLUMINESCENCE DATING OF GLASS

The aim of this study is to achieve a better understanding of some of the factors that limit the thermoluminescence (TL) dating of glass. Using a‘model system’(lithium-disilicate samples having different levels of crystallinity from 0 to 100%), we show, first, that the TL of glass is reproducible only if the glass is not heated above its temperature glass transition and second, that there is a clear connection between the TL sensitivity and the degree of crvstallinity of the sample. We conclude that thermoluminescence is not a general dating method for archaeological glass, but it can be applied to particular glass samples that haue specified characteristics.     

CHARACTERIZATION AND THERMOLUMINESCENCE DATING OF PREHISTORIC POTTERY SHERDS FROM MILENA

This paper reports the results obtained applying absolute dating methodologies and mineralogical, petrographical and micropalaeontological characterization techniques to prehistoric pottery sherds varying in age from the Sicilian Middle Neolithic to Bronze Age. All samples came from the archaeological area of Milena (Caltanissetta, Sicily); those of the Bronze Age were found on a site with a precise stratigraphic succession. The investigation has contributed to the determination of an absolute chronology for the Milena prehistoric period. The data provide, for the first time in Sicily, absolute dates covering a wide spectrum of cultures following one another in the same area and, for the Bronze Age site, correlated to the precise stratigraphic succession. The petrographical and mineralogical analyses allowed not only the identification of the principal constituents of the pottery, but also the formulation of some hypotheses regarding the specific manufacturing techniques of different epochs. The microfacies, obtained from the presence of fossils in the groundmass of the pottery, were also analysed and compared with the microfauna present in the Miocene clays outcropping in the area. The data identified local Messinian clay as the raw material probably used in the manufacture of the pottery and also support the presence, already assumed by archaeologists, of imported Mycenaean pottery, thus supporting the dates obtained on pottery taken from the same stratum.     

EARLY BRONZE AGE TIN PROCESSING AT KESTEL/GÖLTEPE,ANATOLIA

Chemical analysis of statistically significant numbers of samples including minerals, sediments, soil, host rock as well as powdered materials, crucible accretions and metal artefacts revealed information about the distribution of cassiterite at Kestel and the tin smelting processes that took place at Göltepe c. 2600 BC. Using the ancient technique of vanning for the isolation of tin ore (cassiterite), followed by assaying by blowpipe/charcoal block, as well as crucible smelting with a blowpipe, good tin metal suitable for alloying with copper to make bronze was obtained. There is every indication that tin was mined and smelted in the Early Bronze Age at the Kestel/Göltepe sites.     

LUMINESCENCE DATING OF POTTERY FROM LATER PREHISTORIC BRITAIN*

Dating of later prehistoric settlements relies heavily on potter; typologies in England and yet there has been little scientific dating in order to verify these typologies. In this work, luminescence dating techniques were applied directly to the pottery which forms the typological framework. Excellent agreement was obtained between the luminescence ages, and archaeological age ranges for known‐age pottery sherds with diagnostic form and surface decoration. A lower correlation, however, was found in several regions between the luminescence ages for undecorated body sherds and the archaeological assessment which was necessarily based solely on fabric, suggesting the need for reassessment of these fabric chronologies.     

ANALYTICAL INVESTIGATION OF ARCHAEOLOGICAL POWDERS FROM GÖLTEPE (TURKEY)*

Nine powder samples originating from the archaeometallurgical she in Göltepe, southern central Turkey, have been analysed. Bulk analyses, using X-ray fluorescence and X-ruy photoelectron spectroscopy, and single particle analyses, using electron probe X-ray microanalysis, were carried out. The analyses were focused on determining the inorganic elemental composition of the samples and the distribution of particle types in the nine powder samples. In addition, the powder samples were classified on the basis of their elemental composition using multivariate techniques. The objective of this study was to characterize the powder samples and to establish an association with archaeological data from the site     

NEW RADIOCARBON ACCELERATOR DATES ON ARTEFACTS FROM THE EARLY MESOLITHIC SITE OF STAR CARR,NORTH YORKSHIRE*

For the well‐known early Mesolithic site of Star Carr, dating of organic artefacts by accelerator mass spectrometry (AMS) has been hampered by treatment of bone and antler recovered during the original excavations with preservatives. Some, untreated, artefacts were, however, collected after Clark's excavation in 1950. Four of these artefacts were AMS dated in 1995, but two of the dates were significantly younger than the others, and were questionable due to their low collagen yields. These suspect samples have now been re‐analysed, demonstrating that all four artefacts are of similar date. The significance of these dates for the chronology of Star Carr is discussed.     

COPPER AND BRONZE DURING THE ENEOLITHIC AND EARLY BRONZE AGE: A METALLOGRAPHIC EXAMINATION OF AXES FROM THE NORTHALPINE REGION*

This paper presents the results of a metallographic examination of Eneolithic and Early Bronze Age axes from the Northalpine region of central Europe. During this period, different types of copper were in use: arsenical copper, Fahlerz copper and tin bronze. We examine if and to what extent the different properties of the metals used were known to prehistoric metalworkers and actively manipulated in the production of the axes. The development of methods of casting and smithing is discussed. Both aspects contribute to our understanding of the nature of prehistoric technological change. During the Early Bronze Age of the Northalpine region, different traditions of early metallurgy can be identified, which differ in their use of Fahlerz copper, their attitude towards tin alloying and the use made of tin bronze in the production of the axes. These traditions can only be adequately described by reference to both composition—that is, access to different types of copper as well as tin—and knowledge of the production techniques provided by metallographic data.     

THE ISOTOPIC COMPOSITION OF TIN IN SOME ANCIENT METALS AND THE RECYCLING PROBLEM IN METAL PROVENANCING

A recent suggestion that some ancient metallurgical processes might give rise to large changes (> 0.5%) in the isotopic composition of tin gave hope that it might be possible to identify ancient bronze samples which had undergone recycling and mixing processes. This paper describes a method for the analysis of the isotopic composition of tin by thermal ionization mass spectrometry and applies it to analyse a number of ancient bronzes and tin metal objects from the Bronze Age Mediterranean. No observable isotopic fractionation of tin was found above $0.1% in the ratio¹²² Sn/¹¹⁶. Consequently, either recycling of bronze in the Late Bronze Age Mediterranean was not so common as supposed, or the isotopic composition of tin is not fractionated by anthropogenic metallurgical processes to the extent predicted by the Bradford group.     

THE RADIOCARBON CHRONOLOGY OF KOPIA,AN EARLY GLASS MANUFACTURING CENTRE IN INDIA

Right from the time of the Painted Grey Ware (PGW) culture, dating to c. 1200–600 bce , more than 210 archaeological sites in India have provided evidence of glass, but there has been no attempt to date the glass‐yielding layers by radiometric techniques. This has hampered the establishment of a chronology for the beginning and evolution of glass‐making in India. The site of Kopia was excavated by the first author for three seasons from 2004 to 2006 to understand the history, development and technology of glass production in India. The excavation produced evidence of a long period of occupation, covering the Fine Grey Ware (FGW), Northern Black Polished Ware (NBP), Sunga–Kushana and Gupta periods. Twenty accelerator mass spectrometry (AMS) and radiocarbon dates, all derived from charcoal samples and processed independently by three laboratories, are available from the site. The dates range in their calibrated form on average from the ninth to the second century bce in locality I and from the second century bce to the second century ad in locality II.     

SERIPHOS SURFACES: A STUDY OF COPPER SLAG HEAPS AND COPPER SOURCES IN THE CONTEXT OF EARLY BRONZE AGE AEGEAN METAL PRODUCTION

Kephala and Phournoi, on the island of Seriphos, add to a growing number of EBA metal production sites identified in the south‐central Aegean. Analytical examination of samples from the two sites addressed the technological parameters of the copper smelting process, indicating the use of mixed oxidic and sulphidic copper–iron ores to produce unalloyed copper with minute copper sulphide inclusions. A preliminary geological reconnaissance of the island identified several small copper mineralizations, one of them close to the site of Kephala. Nevertheless, the ore sources used remain unclear. Comparisons are made with other contemporaneous neighbouring smelting sites.     

AN EVALUATION OF ANALYTICAL AND INTERPRETATIVE METHODOLOGIES FOR THE EXTRACTION AND IDENTIFICATION OF LIPIDS ASSOCIATED WITH POTTERY SHERDS FROM THE SITE OF SAGALASSOS,TURKEY*

Three lipid analysis methods were applied to extracts of archaeological potsherds from the ancient city of Sagalassos, south‐west Turkey. In the fatty acid methyl ester fraction, obtained by selective transesterification of acylglycerols, the ratio of methyl palmitate to methyl stearate was determined. Secondly, by means of gas chromatography– combustion–isotope ratio mass spectrometry (GC–C–IRMS), stable carbon isotope ratios were measured for the same methyl esters. Finally, triglyceride composition was determined via high‐performance liquid chromatography–mass spectrometry (HPLC–MS). All three methods can be used to trace the origin of animal fat. Agreement between them is reasonable, especially in recognizing ruminant adipose fat. One sample was found to be of dairy origin using both GC–C–IRMS and HPLC–MS. The advantages of the various methods are discussed. Variations in lipid composition were observed between samples from different periods and excavated in diverse areas within the city of Sagalassos.     

ARCHAEOMAGNETIC DATING OF COPPER SMELTING SITE F2 IN THE TIMNA VALLEY (ISRAEL) AND ITS IMPLICATIONS FOR THE MODELLING OF ANCIENT TECHNOLOGICAL DEVELOPMENTS

Site F2 in the Timna Valley, Israel, is a small copper smelting site of ‘primitive’ technology, dated by its excavator to the Pottery Neolithic (sixth to fifth millennium bce ). This early date challenges the common view of the beginning of smelting technology in the Levant and has been contested by various scholars since its publication. In this study, we present results of archaeointensity experiments conducted on slag fragments from the site. The slag yielded an excellent ancient geomagnetic value (64.1 ± 1.1 μT) that, when compared to the Levantine master curve, suggests an age not older than the second millennium and most probably between the 13th and 11th centuries bce . In addition to demonstrating the applicability of geomagnetic archaeointensity experiments to independent dating of slag, we discuss the implications of the current results for the socio‐historical picture of the Timna Valley, and in particular for the way in which technological developments were previously modelled in the archaeometallurgical research on the region.     

ESTIMATION OF THE AGE OF A PRE‐INDUSTRIAL IRON SITE IN KOREA*

A pre‐industrial iron‐smelting site in Korea, whose period of active use is placed on typological grounds between the eighth and 18th centuries ad , has been dated using accelerator mass spectrometry and thermoluminescence. The ages of two charcoal samples were 77 ± 25 and 81 ± 25 years bp , with the calibrated date for both ranging from ad 1700 to ad 1955, while a clay fragment dated to ad 1650 ± 50. The results from typology and radiocarbon seem insignificant due to the considerable uncertainties involved, but in combination with the thermoluminescence result they place the most probable date of the site at around ad 1700.     

PROVENANCING OF LIGHTWEIGHT VOLCANIC STONES USED IN ANCIENT ROMAN CONCRETE VAULTING: EVIDENCE FROM TURKEY AND TUNISIA

The mastery of the use of lightweight rocks in concrete as a means of controlling the thrusts of large‐scale vaults was among the most important contributions of the Roman builders to the development of vaulted architecture. The string of volcanoes along the Tyrrhenian coast of Italy produced a variety of lightweight rocks, which allowed the builders in Rome to develop highly sophisticated ways of manipulating form and mass to create stable structures. The use of lighter rocks in vaults and heavier in foundations occurs from the mid‐first century bc in Rome, but the systematic use of imported lightweight rocks only began in the early second century ad under Trajan ( Lancaster 2005 , 59–64). Soon thereafter, the technique of using lightweight stones to build large vaults spread throughout the empire, usually to areas that had a local source of lightweight volcanic material. However, there was also a seaborne trade in lightweight rocks to areas that did not have local sources of such material. The intention of our analysis is to determine as precisely as possible the provenance of the lightweight stones used in vaulting of two areas of the Mediterranean, modern Turkey (ancient Cilicia) and Tunisia (ancient Africa Proconsularis), and thus to provide a better understanding of the nature of this trade.     

THE CHRONOSTRATIGRAPHY AND GEOARCHAEOLOGICAL SIGNIFICANCE OF AN ALLUVIAL GEOARCHIVE: COMPARATIVE OSL AND AMS 14C DATING FROM GREECE*

The Basin of Phlious in southern Greece is known for its thick colluvial and alluvial deposits from the Holocene. It offers a good opportunity to reconstruct the history of Holocene soil erosion and its interaction with historical farming activities. In this study, we present new results based on optically stimulated luminescence (OSL) dating from the Basin of Phlious. The comparison between OSL and ¹⁴C AMS ages shows good agreement, and demonstrates the need for the detection of insufficiently bleached OSL samples in order to obtain accurate results. The discovery of a Neolithic site, buried under thick alluvial deposits, confirms the hitherto postulated Neolithic human impact on the landscape.     

THE COMPOSITION OF COPPER-BASED SMALL FINDS FROM A WEST PHOENICIAN SETTLEMENT SITE AND FROM NIMRUD COMPARED WITH THAT OF CONTEMPORARY MEDITERRANEAN SMALL FINDS

About 100 Phoenician copper alloy artefacts from Morro de Mezquitilla (Spain) have been analysed by inductively coupled plasma spectrometry and atomic unpublished analyses of contemporary material from Nimrud and with small finds of the same period from several Mediterranean areas. There are no published large-scale analyses of Phonenician metalwork and few analyses of the copper-based, very minor objects of the sort typically recovered from excavation and the comparisons show both similarities and differences in techniques and alloys of the various civilizations and classes of objects.     

CONSTRUCTING CARIBBEAN CHRONOLOGIES: COMPARATIVE RADIOCARBON DATING OF SHELL AND WOOD ARTEFACTS FROM PRE‐COLUMBIAN SITES IN CUBA

The lack of robust chronological frameworks for pre‐Columbian archaeology in the Caribbean limits the interpretive potential of ongoing studies of inter‐site and inter‐island interaction. This paper reviews the dating of 28 wood and shell artefacts from sites in northern Cuba in an attempt to date pre‐Columbian activity in the region and develop dating methodologies for the study of pre‐Columbian interaction in the Caribbean. This research compares dates from wood and shell artefacts from the waterlogged site of Los Buchillones in north‐central Cuba with dates from shell artefacts from sites on eight islands in the Sabana–Camaguey archipelago in the Bahama Channel. In addition to providing a chronological framework based on absolute dates for pre‐Columbian activity in northern Cuba, this paper also considers the methodological issues of using shell for dating pre‐Columbian activity in the Caribbean.     

LASER ARGON DATING AND GEOLOGICAL PROVENANCING OF A STONE AXE FROM THE STONEHENGE ENVIRONS*

The recently-developed laser microprobe ⁴⁰argon-³⁹ argon technique has been used to give a geological date for a rhyolitic tuff stone axe fragment from the Stonehenge environs. The method requires only milligramme-sized samples and gives dates of sufficient accuracy to aid in provenancing artefacts to sources, as well as information on the heating history of samples. The axe sample is of Lower Carboniferous date (341 ± 5 Ma) and this limits possible sources to outcrops within the Scottish Midland Valley and small altered exposures in Dartmoor. X-ray fluorescence analysis of the axe suggests the Scottish Midland Valley as the more likely source. The laser argon analysis also shows that the implement had not been heated in antiquity. Laser argon-argon dating can, therefore, be a useful tool in artefact study.     

THE PETROGRAPHY AND CHEMISTRY OF THIN‐WALLED WARE FROM AN HELLENISTIC– ROMAN SITE AT SEGESTA (SICILY)*

Samples of Roman thin‐walled ware from Segesta (northwestern Sicily), dating back to the early Imperial period, were studied by optical microscopy (OM) and Neutron Activation Analysis (NAA). Up to now, this class of Roman fine tableware has only occasionally been evaluated archaeometrically. Nevertheless, numerous production centres are believed to have been simultaneously active in the western Mediterranean area. Petrographic and chemical data seem to be in agreement with the archaeological hypothesis of local manufacture in Segesta for most of the analysed samples, through a comparison with kiln wasters and local raw materials. The effectiveness of thin‐section petrography for determining the provenance of such a tiny tempered class of pottery and the integrated use of two different grouping procedures (petrography and chemistry) were also tested.