EARLY BRONZE AGE TIN PROCESSING AT KESTEL/GÖLTEPE,ANATOLIA

Chemical analysis of statistically significant numbers of samples including minerals, sediments, soil, host rock as well as powdered materials, crucible accretions and metal artefacts revealed information about the distribution of cassiterite at Kestel and the tin smelting processes that took place at Göltepe c. 2600 BC. Using the ancient technique of vanning for the isolation of tin ore (cassiterite), followed by assaying by blowpipe/charcoal block, as well as crucible smelting with a blowpipe, good tin metal suitable for alloying with copper to make bronze was obtained. There is every indication that tin was mined and smelted in the Early Bronze Age at the Kestel/Göltepe sites.     

Rediscovering famous assemblages: A rare Bronze Age crucible from El Argar,Spain

A rare open shallow crucible from the British Museum collection, excavated at the Bronze Age site of El Argar in south-east Spain by Louis and Henri Siret, was studied using X-radiography and scanning electron microscopy. The crucible has relatively thick walls, a spout and a non-refractory fabric. It was used for melting copper alloys for various possible purposes, such as alloying, refining, recycling or before casting, at around 1100°C. Both arsenic and tin were detected in various places and concentrations in the analysed specimens. This crucible could have been used during the period of transition from arsenic-rich copper to tin bronzes in the El Argar culture, or used for the recycling of arsenic-rich copper artefacts being alloyed with tin to produce tin bronzes. This melting crucible is a rare example of its kind to have been investigated scientifically, as most crucibles from contemporary sites on the Iberian Peninsula are generally associated with smelting. This study has also crucially shed more light on the types of alloys and variety of activities undertaken during that transitional period between the use of arsenical copper and tin bronzes in this region.     

ANALYTICAL INVESTIGATION OF ARCHAEOLOGICAL POWDERS FROM GÖLTEPE (TURKEY)*

Nine powder samples originating from the archaeometallurgical she in Göltepe, southern central Turkey, have been analysed. Bulk analyses, using X-ray fluorescence and X-ruy photoelectron spectroscopy, and single particle analyses, using electron probe X-ray microanalysis, were carried out. The analyses were focused on determining the inorganic elemental composition of the samples and the distribution of particle types in the nine powder samples. In addition, the powder samples were classified on the basis of their elemental composition using multivariate techniques. The objective of this study was to characterize the powder samples and to establish an association with archaeological data from the site     

A truly refractory crucible from fourth millennium Tepe Hissar, Northeast Iran

From the Early Chalcolithic to the Late Iron Age, melting and smelting crucibles were usually made from non-refractory ceramic fabrics, which required heating of the charge from within the crucible to avoid collapsing the ceramic itself. In this paper, an unusual melting crucible from Northeast Iran, radiocarbon-dated to the Late Chalcolithic (ca. 3600 BCE), will be presented that significantly changes our understanding of the development of technical ceramics in Southwest Asia. This crucible, made of a highly refractory talc-based ceramic held together by an outer layer of traditional non-refractory ceramic, is to our knowledge unprecedented at such an early date. As will be argued, this ancient crucible was heated from the exterior or from below and not from the interior. This method of firing, combined with the highly-specialized construction technique, makes this crucible so far unique in prehistoric metallurgy, and forces us to re-examine traditional models for the development of technical ceramics and metallurgical practices in the Old World.     

SOURCING OBSIDIAN FROM NEOLITHIC ÇATALHÖYÜK (TURKEY) USING ENERGY DISPERSIVE X‐RAY FLUORESCENCE*

This paper details the chemical sourcing of 42 obsidian artefacts from a single Neolithic structure at Çatalhöyük (central Anatolia), using Energy Dispersive X‐Ray Fluorescence (EDXRF). The chemical signatures of the samples match those of two geological sources in southern Cappadocia: East Göllü Da? and Nenezi Da?. The data provide a counterpoint for previous analyses at the site, and suggest possible intra‐community distinctions with regard to shifts in raw material procurement and technical change.     

Ancient bronze technology and nomadic communities of the Middle Gobi Desert,Mongolia

The Xiongnu period of Mongolian prehistory (ca. 3rd century BC–AD 2nd century) is notable for the emergence of an expansive nomadic state and major changes in metallurgical and ceramic technologies. A number of Xiongnu period and pre-Xiongnu period bronze and bronze-related artifacts from the site at Baga Gazaryn Chuluu in the Middle Gobi province of Mongolia were examined for their chemical compositions and microstructures. They include finished objects, leftovers from casting, and pieces of slag from copper smelting and the assemblage likely represents a combination of local and regional production as well as long-distance exchange items. Results show that the entire bronze manufacturing process, from smelting to fabrication, is represented at BGC sites and bronze working may have been technologically self-sufficient, though ore sources are still uncertain. Our evidence suggests that this bronze assemblage was the result of two different technological traditions characterized by either the dominant use of arsenic, enforced apparently by restriction in tin supply, or the profuse use of both tin and lead. The arsenic-based tradition was observed in the majority of pre-Xiongnu period objects while the tin and lead recipes were verified in most objects dating to the Xiongnu period. This shift in bronze tradition may reflect changes in inter-regional interaction with frontier groups beyond the Gobi Desert and with the early state societies of China.     

Empires and resources: Central Anatolian obsidian at Urkesh (Tell Mozan,Syria) during the Akkadian period

Almost all of the obsidian used to craft stone tools in the Near East from the Palaeolithic onward originated from volcanoes in two geographic regions: Central Anatolia and Eastern Anatolia. Five decades of obsidian sourcing has led to the view that Central Anatolian obsidians largely followed the Mediterranean coast and rarely reached farther east than the Middle Euphrates, whereas Eastern Anatolian sources almost exclusively supplied sites east of the Euphrates. This paper discusses the identification of Central Anatolian obsidian artefacts at the Bronze-Age site of Tell Mozan (Urkesh) in northeastern Syria. Most of the obsidians at Tell Mozan (97%) came from the Eastern Anatolian sources, as expected from established distribution models. Artefacts of Central Anatolian obsidian, however, were excavated from one well-constrained context: the deposits on a palace courtyard that date to the height of the Akkadian empire's influence at this third-millennium Hurrian religious and political centre. In particular, the obsidian came from the Kömürcü source of Göllü Da?. Potential explanations for this exotic obsidian are discussed. This obsidian might have “piggybacked” on the distribution of Central Anatolian metals or arrived at this city as royal gifts or prestige items. Other discussed mechanisms include Akkadian-linked changes in either territoriality involving pastoral nomads responsible for the arrival of Eastern Anatolian obsidians or identity construction of elites based on involvement in Central Anatolian economic and political networks.     

Innovative application of portable X-ray fluorescence (XRF) to identify Göktepe white marble artifacts

An efficient and non-destructive method to classify white marble artifacts by using a hand-held, portable XRF analyzer (pXRF) is here reported. The identification is based on the uniquely high strontium content of this marble and has been verified by testing 32 artifacts, most of which had already been provenanced, using conventional micro-destructive analyses. Besides strontium, other potential provenance indicators, such as manganese and iron, were analyzed and their concentration values obtained after empirical calibration of the instrument by using 17 quarry samples of known composition. The results show that Göktepe/non-Göktepe discrimination is almost always possible (30 artifacts) and that additional analyses are required only when the Sr value is at the lower edge of the Göktepe field (2 artifacts). The success of the method, however, resides in the particular composition relative to trace elements of Göktepe and is not easily extended to other marble varieties. Main reasons are related to insufficient accuracy at low concentration values, intrinsic trace variability of marble artifacts, surface effects that may produce not representative results. Interest in the method therefore is tightly linked to the exceptional importance of Göktepe as a sculptural marble, in which case, detailed data, obtained with a fast and totally non-destructive method, may provide relevant information concerning chronology, workshops, and places of production of the artifacts.     

The Production of Lead–Tin Yellow at Merovingian Schleitheim (Switzerland)*

A Merovingian crucible fragment, with internally adhering yellow glass, and yellow glass beads of the same region and period were investigated by non‐destructive XRF, optical microscopy and SEM‐EDS. Although the microstructure and chemical composition of the yellow pigment (lead–tin yellow type II, ‘PbSnO₃’) are almost identical in both the beads and the crucible, in the latter the pigment occurs in a much higher concentration. However, the glass base in the beads and the crucible is very different, indicating that the beads were not manufactured directly from the crucible. Instead, the crucible most likely served to produce lead–tin yellow, which was subsequently mixed elsewhere with a colourless soda–lime glass to produce yellow glass beads.     

New investigations of the Göllüdağ obsidian lava flows system: a multi-disciplinary approach

The Göllüda? obsidian lava flow system is relatively complex. More than ten different obsidian outcrops and knapping workshops have been identified around this volcano. Their importance for long and short distances obsidian supply has already been demonstrated.One of the main problem encountered when studying the Göllüda? obsidian flows, is the great chemical similarity of some of them. The use of the geochemical approach to solve the problems of obsidian trade around the Göllüda? is therefore insufficient. A multi-disciplinary program joining archaeology, geochemistry and geomorphology, was thus started to understand the relationships between the different obsidian flows and to draw the pattern of the Göllüda? obsidian trade.Our archaeological and geomorphologic approach will help us to understand which obsidian outcrops were available during the Palaeolithic and Neolithic periods.Also our geomorphologic approach, linked to intensive geochemical analyses, will help us to understand the spatial variability of the geochemistry of the obsidian outcrops. Lithic technology will also give information about the different knapping methods used at the workshops.     

On the origins of extractive metallurgy: new evidence from Europe

The beginnings of extractive metallurgy in Eurasia are contentious. The first cast copper objects in this region emerge c. 7000 years ago, and their production has been tentatively linked to centres in the Near East. This assumption, however, is not substantiated by evidence for copper smelting in those centres. Here, we present results from recent excavations from Belovode, a Vin?a culture site in Eastern Serbia, which has provided the earliest direct evidence for copper smelting to date. The earliest copper smelting activities there took place c. 7000 years ago, contemporary with the emergence of the first cast copper objects. Through optical, chemical and provenance analyses of copper slag, minerals, ores and artefacts, we demonstrate the presence of an established metallurgical technology during this period, exploiting multiple sources for raw materials. These results extend the known record of copper smelting by more than half a millennium, with substantial implications. Extractive metallurgy occurs at a location far away from the Near East, challenging the traditional model of a single origin of metallurgy and reviving the possibility of multiple, independent inventions.     

重庆彭水徐家坝遗址出土商周时期的船形杯功能研究

2009年,重庆彭水徐家坝遗址出土了一件船形杯,其用途到底是什么?学术界一直未有一个定论。本工作利用检测手段,从物质成分和结构方面揭示出徐家坝遗址出土船形杯的用途。扫描电镜能谱分析显示船形杯体中含有大量的Cu和Pb以及微量的Sn,杯体表层分离出来的铜块为Cu、Sn和Pb三元合金的铸造组织结构。同时,杯体表面青灰色残留物的X-射线衍射分析显示其中含有锡石(SnO2)、氧化铜(CuO)和碳(C)。实验数据表明巴人在商周时期已经了解到了青铜合金的性质,掌握了青铜冶铸技术,有力证实船形杯可以作为冶铸工具坩埚的观点。     

Technology,chronology and the role of crucible steel as inferred from iron objects of the ancient site at Junnar,India

Ordinary iron objects from an ancient habitation site at Junnar in India, dating to the 2nd BC to AD 2nd century, were examined for their microstructure, chemical composition and age. The objects were mostly made of high carbon steel with a homogeneous microstructure consisting of fine spherical particles of carbide in the ferrite background, free of non-metallic inclusions. Their carbon concentration ranged from 0.7% to over 1.6% with one exception at 0.2%. Some of them contained trace amounts of silicon, manganese and sulfur while one object retained cavities due to volume contraction during solidification reactions. These features indicate that the objects examined constitute an early example of Indian steel making in crucibles. Evidence was found that basic techniques needed for the success of crucible steel technology were mostly available at Junnar at the time. The radiocarbon measurement on carbon samples extracted from one of the iron objects placed its date between 176 BC and AD 20, in agreement with the radiocarbon dates of three charcoal samples from the same site. The forgoing results support that crucible steel was produced in India at a much earlier date than previously supposed, to serve as a material for specific needs arising in daily life.     

Multiple molecular scattering and albedo action on the solar spectral irradiance in the region of the UVB ( ⩽ 320 nm) : a preliminary inventory

Solar UVB, a fundamental element in our environment, was measured with cadmium cells by Paul Götz in Arosa more than sixty years ago and described in his book entitled : Das Strahlungsklima von Arosa [Götz (1926). Springer, Berlin]. Afterwards, in order to ensure uniformity in field experiments, he introduced in his atmospheric measurements a chemical sensor, the Bioclimatic Ultraviolet Dosimeter. This dosimeter, by its cylindrical form, was adapted to an instantaneous measurement of the global UVB radiation at different sites. The global radiation embraces the whole of the group of direct solar irradiances with molecular scattering (sky radiation) and ground reflection (albedo) together with its scattered spectral component.Numerical results from detailed theoretical calculations aimed at evaluating the various absolute effects associated with height, solar zenith angle and surface albedo have been obtained for the standard atmosphere. The variations with solar zenith angles from 0 to 90 and albedos between 0 and 1 are presented for a spherical terrestrial atmosphere at selected wavelengths between 301 and 325 nm in the UVB region     

“Fabelhafte Dinge”: Arzneimittelnarrative zu Coca und Cocain im 19. Jahrhundert

“Fabulous Things”. Drug Narratives about Coca and Cocaine in the 19th Century. This contribution focuses on the history of Coca leaves and Cocaine in the second half of 19^th century Europe. Even though, to date, no direct link has been established between the activities of the Milano physician Paolo Mantegazza, and the Göttingen chemist Friedrich Wöhler, it is not a mere coincidence that both published their findings in the same year, namely, 1859. Mantegazza authored the first treatise claiming that Coca had psychoactive qualities and touted its broad therapeutic faculties; he claimed that it should be introduced into European pharmacotherapy. In Wöhler's laboratory, cocaine was isolated from leaves by his pupil Alfred Niemann; later, Wilhelm Lossen refined and corrected Niemann's results. Narratives about medicinal drugs often streamline history into a story that starts with multiple meanings and impure matters and ends with well‐defined substances, directed at clear‐cut diseases and symptoms. In the case of Coca, however, the pure substance triggered no such process well into the 1880s, whereas the leaves continued to circulate as an exotic, pluripotent drug whose effects where miraculous and yet difficult to establish.     

ARCHAEOMAGNETIC DATING OF COPPER SMELTING SITE F2 IN THE TIMNA VALLEY (ISRAEL) AND ITS IMPLICATIONS FOR THE MODELLING OF ANCIENT TECHNOLOGICAL DEVELOPMENTS

Site F2 in the Timna Valley, Israel, is a small copper smelting site of ‘primitive’ technology, dated by its excavator to the Pottery Neolithic (sixth to fifth millennium bce ). This early date challenges the common view of the beginning of smelting technology in the Levant and has been contested by various scholars since its publication. In this study, we present results of archaeointensity experiments conducted on slag fragments from the site. The slag yielded an excellent ancient geomagnetic value (64.1 ± 1.1 μT) that, when compared to the Levantine master curve, suggests an age not older than the second millennium and most probably between the 13th and 11th centuries bce . In addition to demonstrating the applicability of geomagnetic archaeointensity experiments to independent dating of slag, we discuss the implications of the current results for the socio‐historical picture of the Timna Valley, and in particular for the way in which technological developments were previously modelled in the archaeometallurgical research on the region.     

ESTIMATION OF THE AGE OF A PRE‐INDUSTRIAL IRON SITE IN KOREA*

A pre‐industrial iron‐smelting site in Korea, whose period of active use is placed on typological grounds between the eighth and 18th centuries ad , has been dated using accelerator mass spectrometry and thermoluminescence. The ages of two charcoal samples were 77 ± 25 and 81 ± 25 years bp , with the calibrated date for both ranging from ad 1700 to ad 1955, while a clay fragment dated to ad 1650 ± 50. The results from typology and radiocarbon seem insignificant due to the considerable uncertainties involved, but in combination with the thermoluminescence result they place the most probable date of the site at around ad 1700.     

Paleolithic occupations of the Göllü Dağ, Central Anatolia,Turkey

Abstract

Systematic archaeological surface reconnaissance of the Göllü Da? volcanic complex from 2007 to 2012 documented more than 230 findspots with Paleolithic artifacts, ranging from isolated finds to extensive and dense scatters of artifacts. Most of the activities represented relate to exploitation of the rich obsidian resources in the region. Paleolithic artifacts are attributed mainly to the Middle Paleolithic based on the presence of Levallois technology but there is a substantial Lower Paleolithic component represented by handaxes and other large bifacial tools. Upper and Epipaleolithic sites and artifacts are scarce or absent in the survey sample. The distributions of handaxes and Levallois elements differ substantially, reflecting differences in site preservation and exposure as well as organization of prehistoric activities. Multiple variants of Levallois are represented but centripetal preferential and unipolar flake production dominate. The frequent co-occurrence of different Levallois forms suggests flexible reduction strategies. Distributions of different classes of artifact across the survey area indicate that the Middle Paleolithic occupations of Göllü Da? were not entirely oriented toward workshop activities.     

Obsidian provenance analyses at Göytepe,Azerbaijan: Implications for understanding Neolithic socioeconomies in the southern Caucasus

This study presents a provenance analysis of the Neolithic obsidian assemblages from the early to mid‐sixth millennium bc settlement at Göytepe, Azerbaijan. The study is unique in that (1) it involves a complete, non‐selected obsidian assemblage (901 artefacts) from one particular area of the site; (2) the material is derived from a well‐stratified sequence of 10 securely radiocarbon‐dated architectural levels; and (3) the use of an extraordinarily wide range of sources (more than 20) was identified by provenance analysis using energy‐dispersive X‐ray fluorescence. The results reveal a previously unknown diachronic change in obsidian use in the region, suggesting the occurrence of significant socioeconomic changes during the Late Neolithic of the southern Caucasus.     

Smelting and recycling evidences from the Late Bronze Age habitat site of Baiões (Viseu,Portugal)

Many aspects of bronze production during Late Bronze Age in Western Europe are so far unknown. In the present study selected artefact fragments and metallurgical debris, which include a slag fragment, from the emblematic Late Bronze Age habitat site of Castro da Senhora da Guia de Baiões (Viseu, Portugal) have been studied by optical microscopy, micro-EDXRF, SEM–EDS and XRD. Evidences were found for bronze production involving smelting and recycling. Compositional analysis showed that the artefacts are made of a bronze with 13 ± 3 wt.% Sn (average and one standard deviation) and a low impurity pattern, namely <0.1 wt.% Pb, being comparable with the composition of other bronzes from the same region (the Central Portuguese Beiras). This alloy is generally different from elsewhere Atlantic and Mediterranean bronzes, which show frequently slightly lower Sn contents and higher impurity patterns, namely Pb which is often present as an alloying element. The present study gives further support to early proposals suggesting the exploration of the Western Iberian tin resources during Late Bronze Age, and besides that, it indicates that metalworking and smelting could have been a commonplace activity requiring no specific facilities, being bronze produced at a domestic scale in this Western extreme of Europe.