中国民窑青花论

生产于景德镇民营手工作坊内,供当时民众使用的青花瓷器,在瓷器发展史上具有重要意义。     

Comparison of the Different Types of Qinghua Porcelain from Jingdezhen in the Yuan Dynasty of China (ad 1271–1368) by Micro X‐ray Fluorescence Spectroscopy (μ‐XRF) and Microscopy

The Yuan Qinghua porcelain produced in the city of Jingdezhen, in China, mainly includes the gaudy blue type, a blue–grey or grey‐coloured type and the type featuring a blue colour with a slight amount of grey. For a long time, only the gaudy blue type was focused on and discussed, while the other two types, which contain equally important information with regard to recovering the manufacturing technology of Yuan Qinghua, were always ignored by scientific researchers. In this paper, by using micro X‐ray fluorescence spectroscopy (μ‐XRF), spectrophotometry and optical microscopy, all three different types of Yuan Qinghua porcelain are analysed systemically and, based on the analyses of the body, the glaze and the blue decoration, the differences in the materials and the manufacturing technologies of the three different types are discussed. This not only provides a good basis for the reconstruction of the whole picture of the manufacturing process of Yuan Qinghua porcelains in Jingdezhen, but also contributes to database‐building for the identification of Qinghua porcelain.     

唐宋之际南方的白瓷生产与青白瓷的产生

本文结合考古学与陶瓷工艺学的成果,在梳理唐宋之际南方白瓷生产情况的基础上,认为青白瓷起源于南方地区早期的白瓷生产,并不是仿照青白玉的结果。青白瓷的产生体现了南北瓷业技术的结合,繁昌窑可能是最早大量生产青白瓷的窑场。     

关于青花起源的思考

关于青花的起源,长期来一直有中国起源说和外来技术影响说两种意见。本文着重从低温釉陶生产技术源流和对青料的使用出发,论证了最早出现在巩县窑的唐青花瓷器,只是北魏以来低温釉陶生产技术在新条件下的新产物。认定唐青花的出现是外来绘画理论和绘画技术影响中国艺坛的结果。     

CHARMed PyMca,Part I: A Protocol for Improved Inter‐laboratory Reproducibility in the Quantitative ED‐XRF Analysis of Copper Alloys

This paper describes a protocol for quantification of heritage copper alloys by energy‐dispersive X‐ray fluorescence spectroscopy (ED‐XRF). The protocol, nicknamed CHARMed PyMca, is designed for users who wish to maximize inter‐laboratory reproducibility of quantitative ED‐XRF results for the wide range of copper alloys found in heritage materials. By maximizing reproducibility, this protocol should facilitate collaboration and allow the rigorous use of shared data and databases. The protocol uses free, open‐source, fundamental parameters software called PyMca. PyMca allows for a consistent and transparent application of the fundamental parameters approach independent of the ED‐XRF instrumentation used. The proposed protocol calls for calibration of standardless PyMca results against a set of certified reference materials designed specifically for use with heritage copper alloys, the so‐called copper CHARM set. Finally, this protocol calls for the calibration‐to‐standards to be carried out following a consistent strategy, including error modelling and the incorporation of a validation procedure. A reproducibility study was conducted using CHARMed PyMca and eight different ED‐XRF instruments of six different types. In comparison to a 2010 study conducted according to the same method, CHARMed PyMca showed a dramatic improvement in reproducibility and method sensitivity.     

唐、五代长沙出土白瓷窑口探源

长沙地区出土唐、五代白瓷170余件。`本文根据上手的20件将其分成六大类,其中三类可定出窑口：定窑、安徽泾县晏公窑、繁昌骆冲窑,另三类则来自不明窑口。     

Pottery technology in the Tang dynasty (ninth century ad): archaeometric analyses of a Gongyi sherd found at Siraf,Iran

In 1969–70, a single Tang dynasty blue‐spotted Gongyi sherd was found at Siraf, Iran, the main trading port on the Persian Gulf in the early Islamic period. This is the only known example of Chinese blue‐and‐white ware, whether low‐ or high‐fired, found in the Middle East from such an early date. The sherd provides direct archaeological evidence for the Indian Ocean trade between China and the Middle East in the ninth century ad . The body paste, clear glaze and blue glaze or pigment were analysed by thin‐section petrography, scanning electron microscopy with energy‐dispersive X‐ray spectrometry (SEM‐EDX) and X‐ray fluorescence (XRF). The technological analysis reveals the different steps of the chaîne opératoire: clay mixing, slip and glaze application, and decoration with the cobalt blue glaze before high‐temperature firing. These steps are characteristic of Tang stoneware production at Gongyi in Henan province, China. The use of cobalt blue pigment as part of a simple spotted decoration scheme on the Gongyi sherd, and its find context within the Middle East, provides evidence for the complex interplay and influence occurring between Chinese and Middle East ceramic industries at this time. Closely comparable examples of contemporary low‐fired earthenware ceramics with cobalt blue decoration on a white tin glaze manufactured within the Middle East also occur within the same assemblage from Siraf.     

Compositional Analysis by p‐XRF and SEM–EDX of Medieval Window Glass from Elgin Cathedral,Northern Scotland

Thirty shards of medieval window glass from Elgin Cathedral in north‐east Scotland have been subjected to compositional analysis by portable X‐ray fluorescence and scanning electron microscopy – energy‐dispersive X‐ray spectroscopy. Comparison with previous analytical studies suggests that the majority of the glass was probably produced in France, while a smaller group may have been made in Germany. Significant differences in base glass composition were observed between colours. Two distinct blue glasses compositions were identified. The composition of the grisaille paint differs from paint on the continent, providing the first evidence that it was made using local Scottish lead and iron pigments. This work represents the largest analytical study of Scottish medieval window glass yet undertaken and presents insights into the transfer of medieval materials, technologies and trade routes.     

The Copper CHARM Set: A New Set of Certified Reference Materials for the Standardization of Quantitative X‐Ray Fluorescence Analysis of Heritage Copper Alloys*

This paper introduces a new set of certified reference materials designed to aid scientists and conservators working in cultural heritage fields with quantitative X‐ray fluorescence analysis of historical and prehistoric copper alloys. This set has been designated as the Copper CHARM Set (Cultural Heritage Alloy Reference Material Set). The Copper CHARM Set is designed to be used by a wide range of museum‐, art‐ and archaeology‐oriented scientists and conservators to help improve the accuracy and range of their calibrations for quantitative ED–XRF spectrometry of copper alloys, and also increase the number of elements that can routinely be quantified. In addition, the common use of a single core set of the reference materials is designed to significantly improve inter‐laboratory reproducibility, allowing greater data sharing between researchers and thus furthering possibilities for collaborative study.     

Chemical Analysis of Starch‐Like Mineral Crystals to Eliminate Misidentification in Ancient Residue Research

To clarify issues involved in problematic identification of ancient starch granules, we investigated suspected granules found in residues from a Neolithic grinding stone in north‐east China. The chemical compositions of suspected granules and modern starch granules were tested via SEM–EDS. The results show that the elemental composition of the suspected granules mainly comprises O, S and Ca, which is similar to the composition of calcium sulphate, but quite different from that of real starch granules, which show high levels of C and O, with very low level of other elements. The findings in this study act as a warning that tiny mineral granules may be misidentified as starch, and also indicate that the method of SEM–EDS can be useful to confirm the nature of suspected granules in ancient starch analysis.     

Identification of Pottery‐Forming Techniques using Quantitative Analysis of the Orientation of Inclusions and Voids in Thin Sections

The relationship between forming techniques and orientation of the components of ceramic materials in the context of pottery technology has long been recognized and used for identification of the techniques employed to create archaeological ceramics. The alignment of inclusions is usually characterized by qualitative categories or ordinal scales. This paper evaluates the potential of quantitative orientation analysis for identification of pottery‐forming techniques. A collection of experimental pottery formed using five forming techniques and combined techniques was analysed. The forming techniques were characterized by the intervals of the mean direction and the circular standard deviations of the orientation of the major axes of the ellipses equivalent to the objects representing random sections of inclusions and voids. The most informative criteria for the identification of pottery techniques are the circular standard deviation of the inclusion/void orientations in the core area of the vessel wall in a perpendicular thin section and the mean direction in a tangential section.     

Monitoring to Learn,Learning to Monitor: A Critical Analysis of Opportunities for Indigenous Community‐Based Monitoring of Environmental Change in Australian Rangelands

Indigenous community‐based monitoring has been a central feature in many international attempts to improve monitoring of and local adaptation to environmental change. Despite offering much promise, Indigenous community‐based monitoring has been underutilised in natural resource management in Australia, particularly within the remote, semi‐arid rangelands. This paper discusses contextual social and environmental factors that may help to explain this apparent deficiency, before critically analysing key stakeholder perceptions of the roles for, and challenges of monitoring in the Alinytjara Wilur ara Natural Resources Management region in the north‐west of South Australia. The analysis guides a discussion of responses to better integrate monitoring in general, and Indigenous community‐based monitoring in particular, into regional environmental management approaches. We argue that community‐based monitoring offers a range of benefits, including: better coordination between stakeholders; a heightened ability to detect and respond to climatic trends and impacts; the effective utilisation of Indigenous knowledge; employment opportunities for managing and monitoring natural resources; and improved learning and understanding of rangeland socio‐ecological systems. Identified opportunities for spatial and temporal community monitoring designed for the Alinytjara Wilur ara region could be of value to other remote rangeland and Indigenous institutions charged with the difficult task of monitoring, learning from, and responding to environmental change.     

End‐Member Mixing Analysis (EMMA) Applied to Sediment Grain Size Distributions to Characterize Formational Processes of the Main Excavation Block,Unit 2, of the Rimrock Draw Rockshelter (35HA3855), Harney Basin,Eastern Oregon (USA)

End‐member mixing analysis (EMMA) was conducted on the grain size distributions (GSD) of 13 sediment samples collected from the main excavation block, Unit 2, of the Rimrock Draw Rockshelter, a deeply stratified, multi‐component Palaeoindian rockshelter in the Harney Basin of eastern Oregon, USA. EMMA confirmed the three stratigraphic units (SU) observed in the field and identified three sedimentary end‐members (EM) that account for 95.52% of Unit 2 site formation. EM 1 comprises 70.72% of the total measured grain‐size variation and represents fluvial deposition, correlating with the bottom stratigraphic unit, SU 3. EM 2 comprises an additional 17.74% of the total measured grain‐size variation and represents fluvially reworked aeolian deposition, correlating with the upper stratigraphic unit, SU 1. EM 3 comprises the remaining 7.06% of the total measured grain‐size variation and represents possibly a two‐component aeolian deposition of suspension and short‐term saltation, correlating with the middle unit, SU 2. The results presented demonstrate the ability of EMMA as a technique to (1) unbiasedly distinguish between the SUs identified in the field using only the measured grain size distributions, (2) provide genetically meaningful and quantitative grain‐size end‐members to identify multiple major depositional processes of site formation, and (3) provide a geologically meaningful interpretation of site formation that is capable of facilitating the formulation of more focused hypotheses regarding human and environment interactions at the site.     

Arcangelo Ghisleri and the “Right to Barbarity”: Geography and Anti‐colonialism in Italy in the Age of Empire (1875–1914)

This paper addresses the work of early critics of colonialism and Eurocentrism within Italian geography in the Age of Empire. At that time, a minority but rather influential group of Italian scholars, influenced by the international debates promoted by the anarchist geographers Reclus, Kropotkin and Me?nikov, fumed publicly at Italy's colonial ambitions in Africa. Their positions assumed, at least in the case of Arcangelo Ghisleri, the character of a radical critique of both political and cultural European hegemony. These approaches were linked to a similar critique of “internal colonialism”, both Austrian in the Italian‐speaking regions of Trento and Trieste, and Piedmontese in southern Italy. Based on primary sources, and drawing on the international literature on imperial geography and colonial and postcolonial sciences, this paper conjures up the Italian example to discuss how some European geographers of the Age of Empire were also early critics of racism, colonialism and chauvinism, and how these historical experiences can serve current debates on critical, radical and anarchist geographies.