Obsidian hydration dating by infrared spectroscopy: method and calibration

Low temperature (90–190 °C) hydrothermal experiments have been conducted on seven obsidians where composition of the glass varies significantly in the concentration of structural water within the unhydrated bulk material. Infrared transmission spectroscopy was used to track the diffusion of molecular water into the glass surface as a function of time and temperature. Long-term (60–360 days) hydration sequences at 90 °C show a t^0.6 time dependence for the mass uptake of molecular water that forms the hydration layer. The structural water concentration of the unhydrated bulk obsidian is highly correlated with the pre-exponential and activation energy and may be used to estimate the Arrhenius constants. In addition, secondary ion mass spectrometry (SIMS) hydrogen profiling of Napa Glass Mountain obsidian hydrated at 90 °C reveals that the early stages of diffusion exhibit a dynamic behavior that includes a fluctuating hydrogen concentration and a changing diffusion coefficient that slows with time.     

Induced hydration of obsidian: a simulation study of accuracy requirements

Determination of the hydration rate constant of obsidian is basic to the use of obsidian for establishing chronologies. The constant can, in principle, be determined in either of two ways: by correlations with archaeological sequences, or by laboratory experiments using induced hydration. Induced hydration holds promise of great accuracy, but results reported to date have been disappointing. This paper is based on the hypothesis that the outcomes are the result of error build-up in the induced hydration protocol, and describes an analysis based on a Monte Carlo simulation of the measurement and analysis process. Data are presented which show that the poor results are due to errors inherent in optical measurement of hydration rim thickness. It is concluded that successful use of induced hydration requires an order of magnitude improvement in accuracy of hydration rim measurement over the accuracies currently claimed for optical microscopy. The results do not affect the validity of hydration dating based on archaeological correlations.     

Strofilas (Andros Island,Greece): new evidence for the cycladic final neolithic period through novel dating methods using luminescence and obsidian hydration

The recently excavated coastal prehistoric settlement of Strofilas on Andros Island (Cyclades, Greece) in the Aegean sheds new light on the transitional phase from the Final Neolithic to Early Cycladic period regarding masonry, fortification, and richly engraved rock art. The fortification possesses early evidence of preserved defensive architecture, as evidenced from the plethora of scattered finds from within and around the settlement. Important features are carvings on rock walls which mainly depict ships, animals, and fish. Initial archaeometric dating via the application of luminescence dating of two samples from the fortified wall bearing engraved ships, and by obsidian hydration of two blades employing the new SIMS-SS method (secondary ion mass spectrometry via surface saturation), has been undertaken to determine the site's chronology. The former yields an average date of 3520 (±540) BC and the latter an average date of 3400 (±200) years BC, both of which, within overlapping errors, suggest the main settlement occurred during the Final Neolithic.     

Obsidian hydration at high elevation: Archaic quarrying at the Chivay source,southern Peru

We examine obsidian hydration as a means to date archaeological sites at high elevation in the central Andes, and in particular quarry sites that are difficult to date by radiocarbon means. The Chivay obsidian source lies in a volcanic depression above the Colca Valley in Arequipa, Peru (71.5355° S, 15.6423° E) at 4950 masl. We compare obsidian hydration readings from one quarry and two workshop locations. Ninety-one flakes from the quarry pit, and 61 and 33 flakes from the workshops were analyzed for hydration bands. Of these, 68 from the quarry, and 54 and 33, respectively from the workshops produced at least one culturally meaningful hydration band. As expected, obsidian appears to hydrate slowly at this high elevation. Yet, variation in hydration readings is low within stratigraphic contexts, suggesting relatively narrow windows of knapping activities in each excavation level. A small number of radiocarbon dates allow us to develop a preliminary hydration rate for Chivay obsidian in this high elevation location. Hydration data indicate that intensive quarrying began by 3800 cal. BC and stopped ca. 2300 cal. BC. By contrast, the two workshops appear to have been deposited 2900 and 1200 cal. BC, and 2700 and 2400 cal. BC. The data are consistent with an uptick in obsidian use by at least the Terminal Archaic period.     

Obsidian provenance studies in Colombia and Ecuador: obsidian sources revisited

The field occurrences, elemental compositions and formation ages of Colombian and Ecuadorian obsidians are revisited. It is shown that the regional sources of this raw material are linked to two major volcanic structures: the Chacana and the Paletara calderas, localised on the eastern cordillera of Ecuador and on the central Andean cordillera of south Colombia respectively. Seventy-two samples were analysed by inductively coupled plasma-atomic emission spectroscopy (ICP-AES), inductively coupled plasma-mass spectrometry (ICP-MS) and/or particle induced X-ray emission (PIXE). The same 10 types of elemental compositions were identified independently from ICP and PIXE. Four of these types were previously unknown. The formation ages of these obsidians previously determined by fission tracks dating are in the range 0.17–1.58 Ma at Chacana and 3.46–4.27 Ma at Paletara. Most Colombian and Ecuadorian pre-Hispanic artefacts present elemental compositions compatible with a Chacana- or Paletara-derived origin of the raw material. However, some of them present fission track ages discordant with the present-day known obsidian occurrences, which implies that the regional source inventory is not yet exhaustive.     

Obsidian sources and distribution systems in Island Southeast Asia: a review of previous research

This paper summarises research on obsidian findings across the region of Island Southeast Asia (ISEA), from the first reporting of obsidian on Sumatra as a result of cave excavations in the early 1900s through to the latest published discoveries in 2009. These results are the background for the first region-wide research project focussing on obsidian characterisation and its role in prehistoric inter-island exchange. It is commonly held that distribution of obsidian in ISEA was only localised and inter-island transportation limited. The review, however, suggests that this hypothesis derives from an incomplete knowledge of obsidian distribution in the region rather than typifying prehistoric social patterns. Obsidian sourcing has been carried out only intermittently in ISEA since the 1970s and has generally been focussed only at the single site level, thus explaining this very partial understanding.     

Late Pleistocene/Early Holocene seafaring in the Aegean: new obsidian hydration dates with the SIMS-SS method

Archaeological evidence regarding the presence of obsidian in levels that antedate the food production stage could have been the result of usage or intrusion of small obsidian artifacts from overlying Neolithic layers. The new obsidian hydration dates presented below employing the novel SIMS-SS method, offers new results of absolute dating concordant with the excavation data. Our contribution sheds new light on the Late Pleistocene/Early Holocene exploitation of obsidian sources on the island of Melos in the Cyclades reporting dates c. 13th millennium - end of 10th millennium B.P.     

Prehistoric settlement chronology on Rapa Nui,Chile: obsidian hydration dating using infrared photoacoustic spectroscopy

The prehistoric Polynesian inhabitants of Rapa Nui (Easter Island) utilized obsidian for nearly 700 years in many activities connected with daily life. The near ubiquitous occurrence of the natural glass in both domestic residences and religious structures makes the application of obsidian hydration dating highly suitable for the investigation of cultural change. We have applied previously developed calibrations that estimate hydration rates for obsidian based upon the structural water content of the glass as determined by infrared spectroscopy. The archaeological ages estimated by this method were compared with accelerator mass spectrometry (AMS) dates using short-lived woody species endemic to the island. The convergence between the two dating methods is strong and we suggest that obsidian hydration dating may be used on Rapa Nui to reliably date contexts where suitable material for AMS dating may not be available.     

On the intrinsic accuracy and precision of luminescence dating techniques for fired ceramics

Luminescence dating techniques have been used extensively for archaeological and geological samples. Such techniques are based on thermally or optically stimulated signals. This paper presents simulations of several luminescence techniques for equivalent dose (ED) estimation for ceramic materials containing quartz. The simulations are carried out using a recently published comprehensive kinetic model for quartz, consisting of 11 electron and hole traps and centers. The complete sequence of the experimental protocols for several thermoluminescence (TL) and optically stimulated luminescence (OSL) techniques are simulated using the same set of kinetic parameters. The specific simulated protocols are: additive dose TL protocol, predose technique (both additive and multiple activation versions), phototransfer protocol, single aliquot regenerative optically stimulated luminescence (SAR-OSL) protocol, and SAR thermoluminescence protocol (SAR-TL). One hundred random variants of the natural samples were generated by keeping the transition probabilities between energy levels fixed, while allowing simultaneous random variations of the concentrations of the 11 energy levels. The relative intrinsic accuracy and precision of the protocols are simulated by calculating the equivalent dose (ED) within the model, for a given natural burial dose of the sample. The intrinsic accuracy of these techniques is estimated by simulating natural irradiation of the samples with a known burial dose, followed by simulation of the luminescence method used to recover the estimated dose ED. The percent difference between the burial dose and the ED value represents the simulated accuracy of the luminescence technique. The relative intrinsic precision of these techniques is estimated by fitting Gaussian probability functions to the ED values obtained with the 100 model variants. It is found that the various techniques can reproduce natural paleodoses in the range 10 mGy–10 Gy with a typical intrinsic accuracy of +1 to 10%. Techniques based on single aliquot protocols were found in general to be more precise than techniques requiring the use of multiple aliquots. In addition, techniques based on interpolation of experimental data were found to be consistently both more precise and accurate than those based on extrapolation of experimental data.     

Obsidian sources and distribution systems in Island Southeast Asia: new results and implications from geochemical research using LA-ICPMS

This paper discusses new evidence of long-distance interaction networks in Island Southeast Asia obtained from geochemical analyses using SEM-EDXA and LA-ICPMS of 101 obsidian samples from 25 locations including seven obsidian sources and 19 archaeological sites. Given that there are obsidian sources distributed throughout much of Island Southeast Asia, the potential for obsidian studies to provide greater understanding of patterns of mobility and exchange in the Pre-Neolithic and Neolithic periods would seem to be considerable. This potential, however, remains largely unrealised as obsidian sourcing has hitherto only been carried out intermittently in Island Southeast Asia using PIXE-PIGME, XRF and other methods.     

Obsidian from Pulo di Molfetta (Bari,Southern Italy): provenance from Lipari and first recognition of a Neolithic sample from Monte Arci (Sardinia)

Twenty-four obsidian artefacts of the Neolithic Age were found at the large karstic doline of Molfetta (near Bari) along the Southern Italian Adriatic coast. Non-destructive chemical analyses of the glass, by SEM-EDS, allowed their source rock regions to be determined. Twenty-three of the studied artefacts had been traded from the island of Lipari. Only one sample had a glass composition and microphenocrysts (biotite, pyroxene and feldspar) that indicate provenance from the Monte Arci area of Sardinia, in particular from the Perdas Urias (SC) outcrops. The attribution of this artefact to Sardinia enlarges the geographical pattern of Monte Arci obsidian exploitation and distribution from island to Southern Italy during the Middle to Late Neolithic.     

Obsidian use at the Ushki Lake complex,Kamchatka Peninsula (Northeastern Siberia): implications for terminal Pleistocene and early Holocene human migrations in Beringia

A study of the movement of people within Northeast Asia at the end of the Pleistocene is critical for understanding how and when some of the first human populations entered North America. Chemical source studies of obsidian may provide the evidence necessary to document people's migrations between these regions. Sixty two obsidian artifacts from the late Pleistocene and Holocene Ushki Lake sites in Kamchatka Peninsula were analyzed by instrumental neutron activation analysis (INAA). Data generated demonstrate that multiple obsidian sources throughout Kamchatka were exploited by the inhabitants of Ushki Lake, and allow us to document long-distance population movements during the late Pleistocene and Holocene. It is reasonable to expect that obsidian from Kamchatka might have been transported to Alaska. This is true for the Chukotka region of Northeastern Siberia; obsidian from Chukotka has been found in late Holocene archaeological sites in Alaska. Ultimately, an expanded study that includes all areas of Northeast Asia and Alaska may provide the data necessary to document the earliest movements of people in these regions.     

Forensic Ar/Ar dating: a provenance study of Middle Stone Age obsidian artifacts from Ethiopia

Obsidian sourcing based on geochemistry is widely applied to reconstruct commerce patterns and dissemination of early hominid groups. Due to problems concerning potential intra-source variability or homogeneity of a geological source over large areas, parameters additional to this classical approach are desirable. Here we present the first ⁴⁰Ar/³⁹Ar investigation of Middle Stone Age (MSA) obsidian artifacts (i.e. debitage pieces) for this purpose, as well as of potential geological obsidian sources from Ethiopia. With the present pilot study we demonstrate that ⁴⁰Ar/³⁹Ar geochronology represents a reliable and powerful tool for archaeological provenance studies complementary to the geochemical approach and more recently applied techniques like fission track counting or Mössbauer spectroscopy. Two independent sets of debitage and potential source rock samples were dated by the ⁴⁰Ar/³⁹Ar method. Debitage pieces from the Kulkuletti excavation site and obsidian samples from the nearby obsidian outcrop Worja (central Ethiopia) exhibit basically identical age ranges as well as similar Ca/K and Cl/K ratios, supporting the debitage/source rock relationship previously inferred on geochemical grounds. A second small set of geochemically characterized debitage samples from the Porc Epic cave and potential source rocks from an obsidian outcrop at Kone (Eastern Ethiopia) however have different ⁴⁰Ar/³⁹Ar ages and Ca/K and Cl/K ratios. These results contradict the previous conclusion about a debitage/source rock relationship of the Porc Epic and Kone samples made on the basis of geochemistry [A. Negash, M.S. Shackley, Archaeometry 48 (2006) 1]. Additional sampling at the Kone outcrop as well as of other obsidian occurrences in the greater area is needed to unambiguously pinpoint the origin of these obsidian tools.     

Chronologies in wood and resin: AMS C dating of pre-Hispanic Caribbean wood sculpture

This paper establishes a chronological framework for selected pieces of Caribbean (Taíno/Lucayan) wooden sculpture, enabling previously ahistoric artefacts to fit back into the wider corpus of pre-colonial material culture. Seventy-two ¹⁴C AMS determinations from 56 artefacts held in museum collections are reported, including 32 ceremonial duhos, or seats. Far from being constrained to the last few centuries prior to contact, the dates for these objects extend back to ca. AD 250, and include the artistic legacies of various cultures. Duhos in both low and high back styles are present from about AD 600, if not earlier, in a distribution that spans the Antillean island chain from Trinidad to Cuba. Complex, drug-related paraphernalia and elaborate ancestral reliquaries are in evidence by AD 1000, as are some distinctive regional styles – such as the unique iconography from the Bahamas and Turks and Caicos islands. This paper explores relevant methodological issues – from the challenges of working with museum pieces (e.g., uncertain provenance, discrete sampling techniques, impact of previous conservation treatments on dating results), to dealing with potential ‘in-built’ age in tropical hardwoods.     

Combining an archaeomagnetic and radiocarbon study: dating of medieval fireplaces at the Mühlegasse,Zürich

During the restoration of the Radium cinema located in the old Town of Zürich, a stratigraphic sequence of medieval fireplaces came to light. Based on ceramic finds, a preliminary age of about 1000 AD was assigned. In this paper we show the results from archaeomagnetic and radiocarbon dating, which combined with the stratigraphic information yield a better constrain of the period of use of these fireplaces. Whilst the radiocarbon technique continues to be the most widespread methodology for dating young archeological artifacts, archaeomagnetic dating is becoming increasingly more established in Europe thanks to the increased number of available measurements. A Bayesian model on the period of use of these fireplaces was produced with OxCal, by a combination of magnetic and radiocarbon ages, together with the stratigraphic information. The results show that the fireplaces were probably used during 1 to 2 generations (e.g. 20–40 years each), and are in good agreement with the archaeological context of this site. To make use of the magnetic measurements for future reconstructions of the field, we carried out an additional age model using only the radiocarbon and the stratigraphic information. Although some of the structures show large directional scatter due to poor baking in antiquity, the results confirm the trend of the geomagnetic field around 1000 AD.     

Subterranean transport and deposition of quartz by ants in sandy sites relevant to age overestimation in optical luminescence dating

An artificial layered sandy site was created using a combination of native sand and colored sand (3 parts native uncolored quartz, 1 part colored quartz) in Apalachicola National Forest near Tallahassee, Florida. Twelve layers of sand, each 1 by 1 m in horizontal extent by 10 cm in thickness were emplaced to a depth of 2 m followed by implantation at the surface of a Florida harvester ant (Pogonomymrex badius) colony (the lower two layers were 50 cm thick). The colony excavated a nest, and after 7 months, the sand layers were excavated to the base to test the hypothesis that sand grains were moved upward within the ant nest without reaching the surface. The ants penetrated 11 of the 12 colored layers reaching a depth of 130 cm. Thirty nine sticky-acetate peels of ant chamber floors were collected and colored sand grains were counted under a microscope. More than 16,000 grains were identified in layers that did not originally host them. Of these, more than 80% were unambiguously moved upward. This means that possibly as many as 54,000 upwardly mobile grains were present (ratio of 3:1 uncolored to colored). In relation to optical luminescence (OSL) dating, this means that grains that would not have been optically zeroed by transport to the surface (defined here as subterranean-transported) were present in abundance, and that if the site was ancient, there would have been found many grains that were older than the layers they presently reside in, even if only one colony of harvester ants had disturbed the layers. This is in addition to the fact that backfilling of chambers and tunnels may contribute even more significantly to the presence of a subterranean-transported component of an OSL sample. We conclude that ants can significantly affect the age distributions in sandy archaeological sites. Multiple examples of such disturbances have been documented in the literature. Most relevant to our results are recent studies of the OSL chronology of Pre-Clovis-age and Palaeoindian age archaeological sites in sandy environments in North America that may have been compromised by ant bioturbation of quartz sand grains. Here we have examined in detail the potential effects of one episode of ant nest-building on the age overestimation of affected sediments. From this we found that as few as 12 episodes of bioturbation involving backfilling of chambers in the same volume of sand could lead to the presence of 1 contaminant grain per 50 grains of sample.     

Radiocarbon dating of prehistoric hearths in alpine northern Sweden: problems and possibilities

The chronology of prehistoric Sami settlement sites has previously been established by conventional radiocarbon dating of bulk charcoal samples associated with hearths from sunken hut floors (stállo-foundations). Here we present results of a comprehensive dating exercise of stállo-foundations in the alpine area of northern Scandinavia using Accelerator Mass Spectrometry (AMS) radiocarbon dating of charcoal. Over a 3 km² study area, AMS calibrated ages of hearth charcoal from 22 stállo-foundations across 12 sites securely date these features to between cal. AD 640 and AD 1180. Only small variations in age were found between charcoal samples from different areas of a given hearth. Statistical analysis of all the charcoal AMS radiocarbon dates obtained reveals that 12 stállo-foundations across nine sites are contemporaneous and date to the Viking Period (AD 800–AD 1050). The tightly constrained AMS-based chronology of stállo-foundations contrasts with the existing chronology based on conventional radiocarbon analysis, which places these features within a significantly greater time-frame of between AD 600 and AD 1900, with most dates ranging between AD 800 and AD 1350.This discrepancy is likely to result from the necessity of collecting composite hearth charcoal particles, which may originate from different phases of occupation, in order to achieve the required final carbon content for conventional radiocarbon analysis. We argue that the new AMS-based radiocarbon chronology of stállo-foundations presented here supersedes the existing chronology based on conventional (Gas Proportional counting) radiocarbon analysis and we advocate the use of AMS radiocarbon dating in future hearth investigations.     

The water question in feminism: water control and gender inequities in a neo-liberal era

The current neo-liberal moment in water policy appears to offer possibilities for realizing feminist ambitions. Several feminist scholars see the individualization and privatization of resource rights as offering possibilities for confronting gender inequalities rooted in, and reproduced by, historic and structural male favoured access to productive resources such as land and water. But we seriously doubt a progressive feminist potential of neo-liberal reforms in the water sector. We focus on water used for agricultural purposes, because neo-liberal water proposals are premised on taking water out of agriculture to uses with higher marginal economic returns. A first set of doubts involves water as a specific resource, largely because of its propensity to flow. Rights to water are less fixed and more prone to be contested at various levels and in different socio-legal domains than rights to other natural resources. The second set stems from our disagreement with the ideological underpinnings of the neo-liberal project. It reflects our concern about how water reforms articulate with wider political-economic structures and historical dynamics characterized by new ways of capitalist expansion. Furthermore, mainstream neo-liberal water policy language and concepts tend to hide precisely those issues that, from a critical feminist perspective, need to be questioned. Feminist reflections about tenure insecurity and social inequities in relation to water clash with the terms of a neo-liberal framework that invisibilizes, naturalizes and objectifies the politics and powers involved in water re-allocation. A feminist response calls for challenging the individualization, marketization and consumer/client focus of the neo-liberal paradigm.     

Climate change,conflict, and cooperation: Global analysis of the effectiveness of international river treaties in addressing water variability

Climate-driven water variability is a natural phenomenon that is observed across river basins, but one that is predicted to increase due to climate change. Environmental change of this kind may aggravate political tensions, especially in regions which are not equipped with an appropriate institutional apparatus. Increased variability is also likely to challenge regions with existing institutional capacity. We argue that our best attempts to assess the ability of states to deal with variability in the future rest with considering how agreements have fared in the past. In this paper, we explore treaty effectiveness, or treaty resilience, by investigating whether particular water allocation and institutional mechanisms help mitigate inter-country tensions over shared water. We use water-related events from the Basins at Risk events database as a dependent variable to test particular hypotheses regarding the impact of treaty design on conflict and cooperation over time. A broad set of climatic, geographic, political, and economic variables are used as controls. The analysis is conducted for the years 1948–2001 using the country dyad as the level of observation. Findings pertaining to our primary explanatory variables suggest that country dyads governed by treaties with water allocation mechanisms exhibiting both flexibility and specificity evince more cooperative behavior. Country dyads governed by treaties with a larger sum of institutional mechanisms likewise evince a higher level of cooperation, although certain institutional mechanisms appear to be more important than others.     

Paying for water: water pricing and equity in England and Wales

Over the past three decades, the business of water supply in England and Wales has been gradually transforming from the supply of a service to citizens, to the sale of a commodity to customers. The paper provides a genealogy of concepts of efficiency and equity in water regulation over the past thirty years, prior to evaluating the implications for water consumers of one aspect of this process – the shift away from policies prioritizing inter- and intra-regional equalization (implying a principle of social equity) towards policies prioritizing economic efficiency (implying a principle of economic equity) in water charging. In closing, alternatives to the current arrangements for domestic consumers are proposed.