Differentiation of ceramic chemical element composition and vessel morphology at a pottery production center in Roman Galilee

Cooking pots and bowls from two production locations ca. 200 m from each other at the rural settlement of Kefar Hananya in Roman Galilee were compared employing chemical element composition and vessel-shape analyses. Splits of each pulverized sample, all of which were taken from ceramic wasters, were analyzed by both instrumental neutron activation and high-precision X-ray fluorescence analyses, and computerized vessel-shape analysis was employed for morphological analysis of the same vessel forms from each location. Several statistical techniques (bivariate plots, principal component analysis, cluster analysis and discriminant analysis) were used for analyzing the resultant data. It was found that both the cooking pots and bowls made at each location could be distinguished by employing either chemical composition or morphological analysis. The implications of this work, with regard to investigating both production and consumption sites, and for pottery provenance studies, are discussed. The findings suggest that these analytical techniques can be useful as an aid for chronological differentiations of archaeological pottery.     

Short Note: Provenancing of Pottery— The Need for an Integrated Approach?

The method of chemical provenance determination of pottery is described as a very useful tool, which gives reliable results in most cases, if it is applied correctly and to its full power. Therefore, it is claimed that additional petrographic analysis, the so‐called ‘integrated approach’, should not be considered as a must for each project, but is only needed in cases in which the chemical approach leaves questions to be answered.     

The Source Provenance of Bronze Age and Roman pottery from Cyprus

Archaeological interpretations of ancient economies have been strengthened by chemical analyses of ceramics, which provide the clearest evidence for economic activity, and comprise both the objects of exchange and its means. Pottery is often manufactured from local materials, but its compositional diversity typically prevents significant patterns of resource utilization from being identified. Centrally located and positioned on traditional shipping routes, Cyprus maintained ties with and supplied a variety of distinctive ceramic products to the major commercial centres in the eastern Mediterranean throughout Antiquity. We analysed two Cypriot .ne wares and a variety of utilitarian pottery, as well as samples of extant Cypriot clays to determine source provenance. These chemical analyses provide an objective indication of the origins of ancient (Bronze Age and Roman) ceramics manufactured on Cyprus. The distribution of the probable clay sources and the links between pottery style and the material environment also afford a perspective on the spatial organization of large‐scale pottery production on the island. Compositional analysis provides the means to assemble geographies of pottery production and to unravel the interregional system of exchange that operated in Antiquity, but the ability to accomplish these tasks is predicated on systematic analyses of ceramic products and raw materials that are found far beyond the bounds of individual archaeological sites.     

THE HISTORY OF THE LAWRENCE BERKELEY NATIONAL LABORATORY INSTRUMENTAL NEUTRON ACTIVATION ANALYSIS PROGRAMME FOR ARCHAEOLOGICAL AND GEOLOGICAL MATERIALS

The Lawrence Berkeley National Laboratory pottery provenance group developed standards and instrumental neutron activation analysis (INAA) methods that are used at many archaeometry laboratories around the world. The background and development of ‘Standard Pottery’ and of methods for INAA are described. Early pottery provenance studies are described, and other research programmes, involving obsidian and magmatic mixing, the origin of the stone used for the Colossi of Memnon, and the ‘Plate of Brass’, are mentioned. Research work by the Laboratory included the discovery of the world‐wide iridium anomaly and extensive subsequent research on what has come to be known as the ‘Asteroid Impact Theory’. Characteristics of the analytical programme for pottery provenance work, including overall aims, precision and accuracy, intercalibration, and irradiation and measurement protocols, are discussed. New research areas developed in the past 15 years, to broaden the usefulness of chemical compositional data for archaeological investigation, and examples of recent work, are described. This research, which makes use of high‐precision X‐ray fluorescence analysis in addition to INAA measurements on sample splits, includes distinguishing the products of different workshops located at the same production site, studies on the significance of the distribution of silver in archaeological pottery and the use of high‐precision chemical compositional data as an aid for making chronological distinctions.     

Investigating the production and distribution of plain ware pottery in the Samoan archipelago with laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS)

This paper presents a provenance study of 170 ceramic artifacts and 21 ceramic tiles from three islands in the Samoan archipelago using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Our analyses confirm that LA-ICP-MS can be used to differentiate between clay formations on a single island. We identify different distribution patterns for pottery recovered from lowland and highland sites on Tutuila Island. We also examine evidence for movement of pottery between islands, and find only limited evidence for such movement. Our findings suggest dynamic patterns of prehistoric interaction and site use that need to be evaluated with further data from across the archipelago.     

甘肃新石器时代与青铜代陶器研究的内容和科学意义

综述了现代分析测试方法和数学方法在古代陶器成分分析、年代测定、制作工艺、产地判断、形态分析方面的应用以及甘肃新石器与青铜时代陶器研究的意义。     

Chemical Variability in Clays and Pottery from a Traditional Cooking Pot Production Village: Testing Assumptions in Pereruela*

This paper explores analytically the contemporary pottery‐making community of Pereruela (north‐west Spain) that produces cooking pots from a mixture of red clay and kaolin. Analyses by different techniques (XRF, NAA, XRD, SEM and petrography) showed an extremely high variability for cooking ware pottery produced in a single production centre, by the same technology and using local clays. The main source of chemical variation is related to the use of different red clays and the presence of non‐normally distributed inclusions of monazite. These two factors induce a high chemical variability, not only in the output of a single production centre, but even in the paste of a single pot, to an extent to which chemical compositions from one ‘workshop’, or even one ‘pot’, could be classified as having different provenances. The implications for the chemical characterization and for provenance studies of archaeological ceramics are addressed.     

CORRECTIONS FOR DRILL-BIT CONTAMINATION IN SAMPLING ANCIENT POTTERY FOR NEUTRON ACTIVATION ANALYSIS

The routine measurement of tungsten concentrations in pottery sampled with tungsten-carbide drill bits has enabled the measured concentrations of cobalt, tantalum, and lutetium to be corrected for drill-bit contamination. The corrected data, for cobalt at least, are sufficiently accurate that they regain their value as chemical indicators of pottery provenance.     

Non-destructive fabric analysis of prehistoric pottery using high-resolution X-ray microtomography: a pilot study on the late Mesolithic to Neolithic site Hamburg-Boberg

The characterisation of prehistoric pottery fragments presents a quite complex task. In provenance studies, petrographic and chemical analyses of the ceramic materials are employed to investigate potential production areas in respect to the geolocial background. Moreover, also the production technology of the firing process, as well as the forming techniques used by the prehistoric potters are of great interest. Their investigation is most often accompanied by a destructive preparation of the samples. In this paper, we want to present high-resolution X-ray microtomography (μ-CT), a non-destructive and non-invasive method, as a supplementary research tool in the study of prehistoric pottery.     

The geochemical diversity of neogene clay deposits in Crete and its implications for provenance studies of Minoan pottery*

The determination of provenance probably forms the primary role of geochemical analyses in archaeological ceramic studies. In what has comprised a successful field of study, the ultimate basis for such research has been the comparison of pottery compositions with the geochemical diversity displayed by clay deposits within a given study area. Although such studies are now common, the understanding of chemical and mineralogical variability in ceramic raw materials has been somewhat neglected, with the dominance of assumptions rather than the actual analysis of clays. In this paper, a study is presented of Neogene clays in Crete (Greece), a clay type commonly used in ancient and modern pottery production. Sixty‐one samples were taken from 28 locations in the central and eastern parts of the island, to reveal both intra‐ and inter‐deposit variability. In one deposit chosen for multiple sampling, the 14 samples display great variability in the alkali elements, Fe and Co, and to a lesser extent in the REEs. Many of the geographically separate deposits differ from each other in chemical composition, with Eastern Cretan deposits showing higher REE concentrations and higher Th/Sc ratios, whereas Central Cretan deposits of younger geological stages are characterized by a lower Th/U ratio. Mineralogical analysis by XRD is used to explain aspects of the geochemical variability of the clays.     

Tracing the clay source of Nasca polychrome pottery: results from a preliminary raw material survey

This paper describes the results of the first season of a survey in which clays suitable for the production of Nasca polychrome pottery were collected in an effort to (1) determine the geological variability of clay sources in the Nasca region and (2) match clays compositionally to paste groups from previous provenance analyses. Clays were collected, processed, fired, and analyzed using neutron activation. The results demonstrate that clays in the region were compositionally heterogeneous, and that the clay source for the majority of Nasca polychrome pottery sampled thus far can be traced to lower valleys in the region near the ancient ceremonial center Cahuachi. The results have implications for understanding the nature of polychrome pottery production in the Nasca region, and suggest centralized production near the ceremonial center of the majority of painted ceramics consumed in the Southern Nasca Region.     

THE SUPPLY OF CAMPANIAN‐MADE SIGILLATA TO THE CITY OF POMPEII

Pompeii is an important temporal reference in the study of Roman ceramics, yet until now the origins of red slip tableware or sigillata found in the city have largely been classified by visual evaluations of the pottery. This investigation employs petrographic and elemental analyses to establish the provenance of sigillata found in two pre–ad 79 contexts of Pompeii. In contrast to previous studies, the results suggest that pottery workshops in the vicinity of Somma‐Vesuvius played a vital role in the supply of sigillata to the city.     

Provenance study of early and middle bronze age pottery from Kaman-Kalehöyük,Turkey, by heavy mineral analysis and geochemical analysis of individual hornblende grains

The provenance of Early Bronze Age and early Middle Bronze Age pottery produced between 2100 and 1970 B.C. and excavated from Kaman-Kalehöyük, Turkey was studied using mineralogical methods, including heavy mineral analysis and geochemical study of individual hornblende grains. The relative abundances of heavy minerals in the fabrics of 20 Early Bronze Age (EBA) and early Middle Bronze Age (MBA) pottery sherds, together with 27 local sediments collected within a radius of 25 km of the site were studied. The heavy mineral distributions in the Kaman region were statistically analyzed for consistencies in their occurrence. Amphibole was found to be the most abundant heavy mineral in most of the analyzed samples, followed by titanite and epidote. The amounts of other minerals such as garnet, clinopyroxene, and zircon are subordinate. Different proportions of heavy minerals in the fabrics allow categorization of the EBA and early MBA potteries into 5 groups. Comparative study of heavy mineral assemblages of local sediments and pottery suggests that half of the EBA and most of the MBA potteries were produced from sediment near the excavation site, whereas the other half of the EBA potteries were produced from sediment occurring at 25 km east or more east of the site. The geochemistry of individual amphibole grains was studied by electron-microprobe analysis. Most of the studied amphibole grains are calcic and aluminous, corresponding to hornblende. They can be further characterized into four types based on their chemical composition. The combination of heavy mineral identity and hornblende geochemistry provides diagnostic evidence for the origins of Kaman-Kalehöyük pottery. These and analogous heavy mineral techniques are effective archaeometric tools for determining pottery provenance.     

Re-examining the Egyptian colonial encounter in Nubia through a compositional,mineralogical, and textural comparison of ceramics

Textural, mineralogical, and X-Ray fluorescence (XRF) analyses are used as a cost effective method to distinguish for the first time ancient Egyptian and Nubian-style ceramics found in Nubia. Textural and mineralogical data suggest that Nubian-style sherds are mixtures of sand, silt, and clay sediment that is generally finer grained and poorer in quartz than is the sediment mixture used to produce Egyptian-style pottery. Chemical data also establish a significant difference in the amount of chemical variation found within each style population, but nonetheless supports a considerable overlap in the possible provenance of both styles. Observations and data obtained during this study indicate that standardized, Egyptian-style manufacturing was introduced into Nubia under colonialism, without substantially altering the diversity of native methods of production.     

U-Pb dating of zircon: A sourcing method for pottery from La Morena archaeological site,north-west Colombia*

U-Pb zircon radiometric dating and petrographic thin-section analysis were used for provenance identification of Ferrería and Marrón Inciso pottery styles from La Morena archaeological site in northwestern Colombia. U-Pb dating was applied to zircons recovered from pottery and rock samples from nearby geological units. The results suggest at least three distinct sources: the metamorphic rock unit on which the archaeological site is located, a granodiorite unit that outcrops further away from the site, and a mafic rock that cannot be attributed with certainty. U-Pb in zircons proved to be effective as a provenance method, where ages of the possible source rocks are well constrained, and can be applied to areas where traditional sourcing methods may be problematic.     

广东博罗先秦硬陶的XRF和INAA研究

为揭示广东博罗梅花墩、银岗、横岭山三地古陶器的产源、烧造工艺、技术传播和化交流等方面情况,用波长色散X射线荧光分析(WDXRF)、仪器中子活化分析(INAA)同时测量了广东博罗梅花墩、银岗、横岭山等三地点所出38片西周至春秋、战国硬陶中Al、Ba等元素的含量。并用主成分分析分别处理了测量数据。两套数据的分析结果均表明,梅花墩、银岗和横岭山的硬陶原料互不相同,各地点硬陶可能主要是“自烧自用”。数据分析还表明在南方各省区中,广东硬陶具有Al2O3含量偏高这一明显的地区特征。     

The forest or the trees? Behavioral and methodological considerations for geochemical characterization of heavily-tempered ceramic pastes using NAA and LA-ICP-MS

In this paper, the utility of LA-ICP-MS for instrumentally separating clay and temper within pottery samples is examined through a well-known case study that has been previously characterized through NAA and petrography. Coarse Orange pottery is composed of kaolinitic clays heavily tempered within volcanic ash from the basalt-rich Tuxtla Mountains of southern Veracruz, Mexico. We attempt to address the following topics with analyses on this pottery: 1) can LA-ICP-MS replicate the same groups previously identified by NAA and petrography; 2) can instrumental isolation of the clay fraction within the pottery replicate known patterns in raw clay source geochemistry in the Tuxtla Mountains; 3) can data for both the clay and volcanic ash fractions of each pottery sherd be combined to simulate the bulk INAA data? The results demonstrate that the clay fraction of the pottery sherds can be isolated. Furthermore, the LA-ICP-MS data for the clay fractions display nearly identical chemistry to available NAA data for raw clay samples collected from geological contexts in the region. Instrumentally isolating the clay fraction in this case eliminates the homogenizing effects of adding a common temper and increases the chemical separation among groups making it easier to identify clay procurement strategies for each specimen. However, focusing only on the clay fraction ignores significant tempering variation. Attempts to simulate the bulk NAA by combining LA-ICP-MS data for clays and temper was reasonably successful in reestablishing the tempering variation lost by exclusive focus on clays, but such an approach could not replace the more precise data generated from NAA and petrography.     

CHEMICAL ASSAYS OF TEMPER AND CLAY: MODELLING POTTERY PRODUCTION AND EXCHANGE IN THE UPLANDS NORTH OF THE PHOENIX BASIN,ARIZONA, USA*

A lack of mineralogical variation characterizes the prehistoric pottery in the uplands of central Arizona. Virtually all of the ceramics in that region were tempered with phyllite, which has previously precluded provenance analyses and the investigation of pottery production and distribution in the upland zone. As shown with assays with an electron microprobe, however, both the clay fraction and the temper fragments are chemically diverse and geographically distinct, allowing many of the phyllite‐tempered wares to be sourced, thereby leading to models about the organization of ceramic production and exchange in the upland zone north of the Phoenix Basin.     

CHALLENGES IN THE ANALYSIS OF HETEROGENEOUS POTTERY BY LA–ICP–MS: A COMPARISON WITH INAA*

Tempers added to pottery have the potential to obscure geographical variation in the chemistry of exploited clay resources when analysed using bulk methods. A pilot study was conducted to assess the possibility of using LA–ICP–MS to analyse clay matrix in pottery with extremely subtle partitions between INAA chemical groups. LA–ICP–MS was used to analyse the clay matrix of 32 pottery samples from seven Middle and Late Woodland period (c. ad 200–800) sites in north‐east Florida and results were compared to data from INAA of the same samples. The results reveal many of the challenges in analysing highly heterogeneous materials with LA–ICP–MS. However, the study also generated data that are potentially useful in the determination of pottery provenance. In some respects, LA–ICP–MS of clay matrix replicated the chemical variation recorded by INAA, and in other respects the results are divergent. The similarities and differences between these results are explained by specific differences between the methods and the materials analysed (matrix versus bulk analysis). Suggestions for improving the method are discussed.     

FINGERPRINTING ANCIENT EGYPTIAN QUARRIES: PRELIMINARY RESULTS USING LASER ABLATION MICROPROBE-INDUCTIVELY COUPLED PLASMA-MASS SPECTROMETRY*

Microchemical analysis of minerals present in pottery and stone artefacts may help determine their provenance. Electron microprobe major element analyses of augite suggest that minor elements (Ti0₂,MnO, Aa₂O) are important in fingerprinting basalts. This points to the potential usefulness of trace elements. Augite present in six basalt samples (representing all known/suspected Pharaonic basalt quarries in northern and middle Egypt) and basaltic temper fragments in two New Kingdom pottery sherds was analysed for 28 trace elements (Sr, Ba, Th, U, Zr, Hf, Nb, Ta, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu. Sc, V, Cr, Ni, Ga) by laser ablation microprobe-inductively coupled plasma-mass spectrometry (LAM-ICP-MS, laserprobe). Cluster and discriminant analysis indicate that (1) laserprobe trace element data are more effective at fingerprinting basalts than conventional electron-microprobe data and (2) basaltic temper in the two sherds does not match any of the quarries. Microbeam techniques providing trace element data may represent the future for mineral-based provenance studies.