Investigation of lime mortars and plasters from archaeological excavations in Hippos (Israel) using Electron Paramagnetic Resonance

This study presents the preliminary results of investigation of the lime mortars and plasters from archaeological excavations in Hippos (Israel), using Electron Paramagnetic Resonance (EPR) spectroscopy. The research was conducted in order to characterize the building material and its reaction to ionizing radiation. The ancient settlement Hippos, situated on the east shore of the Sea of Galilee, functioned from the 3^rd cent. BC until it was destroyed by the earthquake in 749 AD. Lime mortars and plasters show carbonate and locally gypsum character of binder and different kind of aggregate. Samples were γ-irradiated and measured using X-band EPR spectrometer. Computer Resolution Enhancement Method was applied to the complex spectra. Some of the γ-induced EPR signals were attributed to CO₂ ^? and CO₃ ^3? paramagnetic centres. Exponential growth of the dose response curve above 1 kGy and saturation for doses above 20 kGy was observed. For doses lower than 1 kGy the dose response curve has a linear character. The presence of γ-sensitive carbonate paramagnetic centres could indicate that, after further studies, well-chosen samples of mortars and plasters might be suitable for EPR dating, assuming the centres have been sufficiently bleached during the manufacturing process.     

Characterisation of archaeological mortars from Pompeii (Campania,Italy) and identification of construction phases by compositional data analysis

This work describes the compositional characterisation of coccciopesto and natural pozzolanic mortars sampled in the Regio VI area of the archaeological site of Pompeii, with particular reference to the Casa di Pansa in Insula 6 and Casa 17 in Insula 2. Samples were studied by optical microscopy and analysed by XRF, SEM-EDS, LA-ICP-MS and XRPD. The XRF and SEM-EDS data, subjected to multivariate analysis (cluster analysis), identified the three main construction phases involved in building the Casa di Pansa. In addition, mineralogical and petrographic characteristics of the aggregate were determined and found to be compatible with pyroclastic deposits from the volcano Vesuvius. Study revealed C–S–H phases in the binder, due to pozzolanic hydration phemomena of hydrated lime with cocciopesto and natural pozzalana.     

New compositional data on ancient mortars from Hagia Sophia (Istanbul,Turkey)

This study shows the results of a multidisciplinary collaboration between the University of Calabria (Italy) and the National Autonomous University of Mexico (UNAM), about the compositional characterization of some mortars taken from Hagia Sophia in Istanbul (Turkey), one of the most important buildings in antiquity. Twenty samples of joint mortars were analysed by micro-chemical analyses (SEM-EDS), X-ray powder diffraction (XRPD), optical microscopy (OM) and transmission electron microscopy (TEM). The compositional study allowed us to define, with more detail, the construction phases of the fifth, sixth and tenth century. The petrographic analysis in thin section by optical microscopy showed four typologies of sands, used as aggregate, with specific compositional features. SEM-EDS analyses and TEM observations of the binder around the ceramic fragments of the aggregate showed the presence of different morphologies of single C-S-H compounds.     

Mortars in context: An integrated study of mortars and plasters from the so-called Ginnasio in Solunto (Sicily,Italy)

This paper presents a multipronged scientific study of mortars and plasters of the so-called Ginnasio in the Hellenistic–Roman city of Solunto (Sicily, Italy). A selection of 16 well-contextualized samples was collected to represent different functions and building phases of this private house. The results show that a variety of locally available raw materials was used as aggregates and to produce binders. The diversity of raw materials’ sources and production techniques identified in this study reveals the advanced technological knowledge of the builders of Solunto, indicating a complex relationship between the settlement's cityscape and its surrounding landscape.     

Characterisation of microbial attack on archaeological bone

As part of an EU funded project to investigate the factors influencing bone preservation in the archaeological record, more than 250 bones from 41 archaeological sites in five countries spanning four climatic regions were studied for diagenetic alteration. Sites were selected to cover a range of environmental conditions and archaeological contexts. Microscopic and physical (mercury intrusion porosimetry) analyses of these bones revealed that the majority (68%) had suffered microbial attack. Furthermore, significant differences were found between animal and human bone in both the state of preservation and the type of microbial attack present. These differences in preservation might result from differences in early taphonomy of the bones.     

Multi-Isotope Investigations for Scientific Characterisation and Provenance Implication of Banded Travertines from Tripolis Antique City (Denizli–Turkey)

The coloured stones used in buildings and monuments were an indicator of power and wealth during the ancient times. In this study, Tripolis city samples have been compared with Tripolis quarry samples in order to recognise the provenance of the banded travertine blocks in the ancient city. The banded travertine samples have similar mineral compositions and mainly consist of calcite with minor amounts of dolomite, aragonite, clay and iron oxide minerals. These results are also supported by CRS studies. Calcite is in the form of needle-shaped crystals ranging between 0.163–1.418?mm (in city) and 0.303–1.270?mm (in quarry). Tripolis banded travertine samples show the similar compositional spread in terms of major oxide, trace elements. δ¹³C_V-PDB values of banded travertines range from 1.93 to 5.25‰ (in city) and 2.99 to 3.99‰ (in quarry), δ¹⁸O_V-PDB values change between (?16.93)–(?10.08) ‰ and (?15.93)–(?13.01)‰, respectively. The U–Th radiometric ages are determined between ～267 and 9?ka in Tripolis city samples and ～350 and 2?ka in Tripolis quarry samples. The minero-petrographic, geochemical, C–O and U–Th isotope results fairly matched with each other. It seems highly probable that the banded travertines in Tripolis city were extracted from the Tripolis quarry, which is located at the northeast of the antique city with a distance of 3?km.     

New temple discovery at the archaeological site of Nysa (western Turkey) using GPR method

We carried out a ground-penetrating radar (GPR) study at specific sites around the Nysa city (western Turkey) to assess the potential of detection method and imaging of buried archaeological features. As a major educational and cultural Aegean city during the Hellenistic and Roman times, Nysa has been the focus of archaeological investigations for the last 100 yrs. Past and ongoing excavations have revealed major ancient buildings such as theatres, amphitheatres, a library and shops. However, it is suspected that the original city may have extended further and reached a larger size.     

Methods for the extraction of archaeological features from very high-resolution Ikonos-2 remote sensing imagery,Hisar (southwest Turkey)

Archaeological research in the territory of Sagalassos is a multidisciplinary project covering scientific disciplines traditionally linked to archaeology and also new technologies such as very high-resolution remote sensing with sufficient radiometric and spatial resolution (<2.5 m). This paper focuses on the evaluation of GIS-, pixel- and object-based techniques for automatic extraction of archaeological features from Ikonos-2 satellite imagery, which are then compared to a visual interpretation of ancient structures. The study was carried out on the unexcavated archaeological site of Hisar (southwest Turkey). Although all techniques are able to detect archaeological structures from Ikonos-2 imagery, none of them succeed in extracting features in a unique spectral class. Various landscape elements, including archaeological remains, can be automatically classified when their spectral characteristics are different. However, major difficulties arise when extracting and classifying archaeological features such as wall remnants, which are composed of the same material as the surrounding substrate. Additionally, archaeological structures do not have unique shape or colour characteristics, which can make the extraction more straightforward. In contrast to automatic extraction methods, a simple visual interpretation performs rather well. The methods presented in this paper can be applied with variable success to archaeological structures composed of the same material as the surrounding substrate, which is often the case.     

Collagen fingerprinting of archaeological bone and teeth remains from Domuztepe,South Eastern Turkey

We applied a recently developed method of collagen peptide mass fingerprinting for taxonomic identification in faunal remains to 111 specimens from the Neolithic site of Domuztepe in southeastern Turkey. Advances on the published technique allow us to move beyond the key domesticated fauna (sheep, goat, pig and cattle) to include non-domesticates (deer and gazelle, as well as humans). As the animal economy of Domuztepe was dominated by domestic sheep and goats, a large number of the samples tested were morphologically indistinguishable sheep/goat remains. A number of samples represented elements that provide information on age (i.e., mandibles) or sex (pelvis); thus, this represents the first major study to attempt to improve kill-off profiles using collagen fingerprinting. We also show that the collagen extracted from dentine is equally amenable to the proposed methodology as bone collagen.     

New archaeological and epigraphical material from Qana (South Arabia)

Excavations at Qana, the ancient port of the Hadramawt on the Indian Ocean, have been carried out systematically by a Soviet-Yemeni Expedition since 1985. Several houses, a storeroom, and probably a religious building have been excavated in the "Lower City". A rich collection of archaeological material has been obtained, including several hundred bronze coins; painted and inscribed fragments of texts in Greek datable to the fourth century AD; African and Mediterranean pottery. For the first time it is possible to reconstruct the history of a large South Arabian port belonging to the kingdom of Hadramawt. Furthermore, it has been demonstrated that Qana existed until the beginning of the Islamic era.     

Cartography of the archaeological surveys taken from an Ikonos stereo-pair: a case study of the territory of Hierapolis in Phrygia (Turkey)

The paper analyses methods and issues connected with the elaboration of Ikonos stereo high-resolution satellite images to create a large-scale cartography for archaeological research. This methodology has been used on an area of the ancient territory of Hierapolis in Phrygia (Turkey), where archaeological surveys, developed by the Italian Archaeological Mission, are in progress. In particular, the study area is situated between the modern villages of Yeniköy and Küçükdereköy, for which neither cartographies suitable for ground surveys nor aerophotogrammetrical covers were available. In this area there are a lot of archaeological remains; in particular, a large Hellenistic and Roman settlement and its necropolises, and also an old Turkish settlement, now destroyed. An Ikonos image was ortho-rectified to obtain a space-map of the entire area. It was used to extract vectorial thematic elements (modern topography, hydrology, archaeological remains and traces, etc.) for the production of maps for archaeological research in the tolerances of a 1:10,000 scale.     

Characterization of archaeological lime mortars in a Ming dynasty tomb: A multi-analytical approach

Lime mortars have played an important role in constructing ancient Chinese masonry structures, including city walls, buildings, and tombs. A tomb built with lime mortars and stones belonging a Ming high-ranking official, Xu Jie, was discovered in Huzhou City of China. Eight different samples from Xu Jie’s tomb, representing four types of lime-mortar-based materials: joint mortar between stone bricks, bedding mortar, grouting mortar, and plaster mortars were collected for analysis and comparison. The characterization of the construction materials has therefore become of primary importance. The function of each mortar was reported and studies into the micro-textural features and mineralogical compositions of those mortars were performed via a multi-analytical approach. The joint mortars were all found to be aerial lime mortars with predominately lime. The bedding mortar was found to consist of lime, soil and sand, typical of a tabia mortar. The grouting mortar was found to consist of lime and ground contact metamorphosed limestone. Analysis of plaster sample taken from the roof of the main tomb identified the presence of calcium stearate/palmitate, indicating the usage of plant-based tung oil as an additive. The analytical results will promote our understanding of Ming architectural technology and craftsmanship, and provide critical information for the conservation of Xu Jie’s tomb.     

Wine and olive oil permeation in pitched and non-pitched ceramics: relation with results from archaeological amphorae from Sagalassos,Turkey

Pitch compounds are frequently identified inside archaeological ceramic vessels. As their presence might affect the permeation of oil or wine into the ceramic fabric, experiments were conducted in which the diffusion of lipids or polyphenols into pitched and non-pitched modern vessels was followed by chemical analysis. Results show that the polyphenols of wine can intrude into the ceramics even through a pitch layer. Consequently, the absence of polyphenols in archaeological sherds is not due to their inability to reach the ceramic matrix under the pitch layer. By contrast, a pitch layer is quite effective to avoid oil intrusion into the ceramic matrix. Thus, it seems logical that oil amphorae would have been coated with pitch at the inside prior to use. Experiments in which the pitched ceramic was simultaneously exposed to oil and wine, show that the wine makes the pitch more permeable for the lipid compounds. These experimental data are confronted with residue analysis results obtained on amphorae fragments excavated in Sagalassos, Turkey. Pitch and oil were frequently found together. Based on a polyphenol test, indications for wine storage could only be obtained for two vessels. Against this background, the possible uses of the Sagalassos amphorae are discussed, and the traditional association of pine pitch with wine storage in archaeological amphorae is critically assessed.     

Ancient bacterial DNA (aDNA) in dental calculus from archaeological human remains

The purpose of this study was to identify reactive bacterial aDNA in archaeological human dental calculus. Dental calculus was collected from a middle/late Neolithic human skull from Hulbjerg passage grave, Langeland, Denmark and prepared for transmission electron microscopy (TEM) or gold-labeled antibody TEM. TEM showed calcified, as well as non-calcified bacteria. Immunogold labeling occurred over the cytoplasmic portions of the sectioned bacteria. The result demonstrated that it is possible to identify aDNA sequences from bacteria in archaeological material of considerable age by this technique.     

Amino acids in archaeological bone (2)

Amino acid levels were compared in archaeological bone from four prehistoric Pacific populations: two from New Zealand and two from Papua New Guinea. One group from each region showed cribra orbitalia or porotic hyperostosis. The fewest significant differences were found between the two skeletally healthy groups, and the greatest number of significant differences between the two groups showing pathology. However, canonical discriminant analysis revealed a distinctive amino acid profile for each of the four groups. While the pre- and post-mortem environment may influence amino acid profiles, it is premature to draw specific conclusions as to the influence of diet, disease and burial conditions.     

Thermoluminescence (TL) dating of ancient Syrian pottery from six different archaeological sites

Syrian archaeological pottery sherds were collected for TL dating from six different archaeological sites named Al-Shermanieh, Tell Serah, Der Al-Hajar (south of Damascus), Tell Al-Shekdakah, Tell Al-Souwirieh (east of Damascus) and Khurbet Al-Kulieh (south west of Damascus). The samples were prepared by fine grain technique and the annual dose for each sample (pottery sherds and soil sample) was measured using an alpha spectrometer system for uranium and thorium contribution as well as with atomic absorption spectrometry for the potassium contents. The mean ages were found to be 5500 ± 150 years, 2950 ± 50 years, 1200 ± 50 years, 1300 ± 150 years, 3300 ± 100 years and 3400 ± 200 years for the examined pottery from the sites Al-Shermanieh, Tell Serah, Der Al-Hajar, Tell Al-Shekdakah, Tell Al-Souwirieh and Khurbet Al-Kulieh, respectively. The results were in good agreement with the ages estimated by archaeologists except for one sample which belongs to Der Al-Hjar site.     

Provenance of glass shards in archaeological lime plasters by LA-ICP-MS: implications for the ancient routes from the Gulf of Mexico to Teotihuacan in Central Mexico

We present the chemical characteristics of samples collected from the central courtyard of Teopancazco, a neighbourhood centre in Teotihuacan (Mexico), the most important classic Mesoamerican city. The rhyolitic glass shards used as aggregates have a composition comparable to the glass material sourced from the magmatic system of Altotonga (located along the route to the Gulf Coast). People travelling from the Gulf Coast may have transported the glass shards to Teotihuacan during the Xolalpan phase (350–550 AD). However, the reasons for using glass shards as a construction material remain unknown. These new data confirm the close relationship between inhabitants of Teopancazco and the Gulf Coast already revealed by previous archaeological and archaeometric studies.