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1.
S. Liu K. L. Chen Th. Rehren J. J. Mei J. L. Chen Y. Liu D. Killick 《Archaeometry》2018,60(1):105-117
The origins of the copper, tin and lead for China's rich Bronze Age cultures are a major topic in archaeological research, with significant contributions being made by archaeological fieldwork, archaeometallurgical investigations and geochemical considerations. Here, we investigate a recent claim that the greater part of the Shang‐period metalwork was made using metals from Africa, imported together with the necessary know‐how to produce tin bronze. A brief review of the current status of lead isotopic study on Shang‐period bronze artefacts is provided first, clarifying a few key issues involved in this discussion. It is then shown that there is no archaeological or isotopic basis for bulk metal transfer between Africa and China during the Shang period, and that the copper and lead in Shang bronze with a strongly radiogenic signature is not likely to be from Africa. We call for collaborative interdisciplinary research to address the vexing question of the Shang period's metal sources, focusing on smelting sites in geologically defined potential source regions and casting workshops identified at a number of Shang settlements. 相似文献
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The polychrome glazes from the Processional Way and the Ishtar Gate of Babylon are among the best preserved from antiquity. Yet, little is known about the logistical choices involved in their production. Variations in isotope ratios can be useful for complementing an archaeological investigation of potential geological sources of raw materials. Consistent with archaeological evidence and ancient texts on trade in metals, Turkish ore deposits are thus tentatively proposed as possible sources of the metal oxide colorants used for the investigated polychrome glazes of three Neo‐Babylonian faunal reliefs that are now part of the collection of the Ny Carlsberg Glyptotek, Copenhagen. 相似文献
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This paper explores the possible provenance of ores employed for metallurgical production during the Early Bronze Age in the central Hexi Corridor of north-west China. In total, 78 pieces of copper (Cu) ore samples were collected from five Early Bronze Age sites and one Cu deposit site (the Beishantang Cu deposit) in the Heihe River region of the central corridor. These sites were dated to the late Machang (4100–4000 bp ), Xichengyi (4000–3700 bp ), Qijia (4000–3600 bp ) and Siba (3700–3400 bp ) cultures. After comparing with published lead (Pb) isotopic data from other possible Cu deposits in north-west China, the results show that the Cu ores collected from the Early Bronze Age sites were most likely derived from the adjacent Beishan Cu deposit. More intriguingly, for the first time in Hexi Corridor, a dozen Cu ores were discovered containing highly radiogenic Pb. Though fundamentally different from those in the Central Plains, they illustrate a possible new type of Cu used in Bronze Age western China, and the first-hand materials are significant for further understanding the provenance of raw metals for metallurgical production in the prehistoric Hexi Corridor. 相似文献
4.
Marcus Adrian Roxburgh 《Archaeometry》2023,65(4):798-815
The North Eastern Baltic has no copper resources of its own, meaning that Cu alloy was imported either as raw material or as finished objects. The north-eastern coastline of Estonia during the late pre-Roman and Roman Iron Age was connected to the south by sea to the long-distance ‘amber’ trade route and to the east by Russian river systems. This study quantitatively assesses the direction of the Cu alloy supply in the region before and after brass enters circulation at the beginning of the Roman Iron Age. After an initial portable X-ray fluorescence (pXRF) survey, 18 objects were chosen for Pb isotope analysis. This isotope analysis resolved a group of nine brass artefacts from the Roman Iron Age amongst a ‘melting pot’ of other Cu alloys. The similarity between the isotope ratios found in the Roman world suggests the presence of the same ‘melting pot’ in the North Eastern Baltic, possibly created by a large amount of Roman Cu alloy being traded north. No evidence for Cu alloy from Scandinavia or the Ural Mountains could be found. The hypothesis from this small study is that the Cu alloy entering Estonia was dominated by metal from Southern Europe from the late pre-Roman Iron Age and the Roman period. 相似文献
5.
Jonathan R. Wood 《Archaeometry》2023,65(3):570-586
Although the birth of Classical Greece is often attributed to the constitutional reforms of Cleisthenes (508/507 BCE), the achievement of an economically minded government under the Peisistratid tyrant Hippias (527–510 BCE) potentially paved the way by advancing Athenian silver for exportation in international trade. It is proposed here that new silver technology, which initiated the transition from acquiring silver from ‘dry’ silver ores to silver-bearing lead ores, was introduced to Greece during the time of the Peisistratids (561–510 BCE). Massive exploitation of silver-bearing lead ores at Laurion in Attica, which later financed the construction of a war navy, appears evident in the lead pollution records of Greenland ice, lead isotopic analyses of sixth-century BCE Attic silver coins and late Iron Age Levantine hacksilver, and is reflected in the numbers of lead votive figurines at sanctuaries in Sparta. Against the backdrop of the threat of war with Persia and an imminent Spartan invasion which resulted in the overthrow of Hippias (510 BCE), it is considered that a political transition occurred because Greece was both geologically and politically disposed to adopt this labour-intensive silver technology which helped to initiate, fund and protect the radical social experiment that became known as Classical Greece. 相似文献
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P. D'Imporzano K. Keune J. M. Koornneef E. Hermens P. Noble K. van Zuilen G. R. Davies 《Archaeometry》2020,62(4):796-809
A micro-invasive technique is presented that enables pigment sampling from individual layers of a painting cross-section by obtaining a furrow 10–50 μm wide of chosen length. Combined with increased sensitivity of lead (Pb) isotope analysis using multicollector inductively coupled plasma mass spectrometry (MC-ICPMS) equipped with a 1013 Ω resistor or a Pb double-spike technique, the amount of Pb needed for isotopic analysis is drastically reduced, while maintaining a relative 2 SD precision for 206Pb/204Pb of < 0.02%. The methodology proved able to characterize Pb isotope differences within paint layers. 相似文献
7.
Y.‐K. Hsu J. Rawson A. M. Pollard Q. Ma F. Luo P.‐H. Yao C.‐C. Shen 《Archaeometry》2018,60(1):128-143
The aim of this paper is to apply kernel density estimates (KDEs) to the visualization and interpretation of lead isotope data from bronze assemblages found along the northern border of central China, here designated as the Arc. New lead isotope analyses of 30 leaded tin–bronze artefacts from the Wangdahu cemetery (c.500–300 bc ) in the Ningxia Hui Autonomous Region, north‐west China, provide the basis for the discussion. By using multivariate KDEs and the calculated likelihood of the overlap, the present work shows that the Wangdahu objects feature a unique linear array of isotope ratios, representing an important element of overall bronzes from the Arc in the first millennium bc . This characteristic isotope signature is fundamentally different from that of Dajing ores in north‐east China, as well from that of early Qin bronzes in Shaanxi and Gansu provinces. This suggests that a variety of metal resources were utilized by peoples living in the Arc. The KDE approach thus proves effective at presenting and comparing lead isotope data. 相似文献
8.
S. R. Liu K. L. Chen Th. Rehren J. J. Mei J. L. Chen Y. Liu D. Killick 《Archaeometry》2018,60(5):1040-1044
In this brief response to Sun et al.’s ( 2018 ) comments on our paper, we re‐emphasize that archaeological, chemical and isotopic evidence are all relevant to the discussion about the metal source of the Shang period with highly radiogenic lead isotope ratios. The southern African bronzes have much lower lead contents and quite different lead isotopic signatures than the Shang bronzes. More importantly, there was no metallurgy of any kind in southern Africa before c.200 ce , so southern Africa cannot possibly be the source of Shang bronze, which date to about 1500 to 1000 bce . 相似文献
9.
Heavy stable isotope analysis of mid-late Holocene Neolithic burials from Sarawak (Malaysia) identifies groups not apparent in mortuary treatment or inferred subsistence. Isotope ratios of strontium (87Sr/86Sr) and lead (208Pb/204Pb, 207Pb/204Pb, 206Pb/204Pb) from adult tooth enamel show distinct groups at Niah Cave's West Mouth organized by dietary catchment. Two roughly contemporary sites, Gua Sireh and Lobang Angin, are included to assess regional heterogeneity in northern Borneo. Heavy stable isotope ratios for humans differ from sampled modern plants and archaeological fauna from West Mouth, and suggest a non-local origin for some of the West Mouth human remains. Distinct heavy isotope ratios characterize all three sites and show regional differentiation broadly consistent with geological expectations. Results supplement paleodiet and morphological analyses and have implications for clarifying Niah Cave mortuary use during the mid-late Holocene. Further and more precise geographic placement will follow through additional landscape sampling for strontium and lead isotope values. 相似文献
10.
Nishkarsh Srivastava Amit Kumar Singh Alok Kumar Kanungo Amit Arora Karaigowder Rajan Veerasamy Selvakumar 《Archaeometry》2023,65(6):1246-1259
Iron has been one of the most critical technotraditions that had lasting impact on social formation throughout the Iron Age and historical period. Iron was used in warfare and subsistence economy. Our knowledge on ancient iron smelting and working have generally been derived from ethnography and ethnohistory, which is by all means, time, region, and raw material specific. Scientific analyses of ancient iron have contributed in understanding this heritage to a respectable extent, yet a comprehensive knowledge about the evolution of iron making through time and space in India eludes us. In this work, a comparative study of iron artefacts from two Iron Age/Megalithic-Early Historic sites of Tamil Nadu, south India, that is, Mangadu (burial site) and Ambal (habitation-cum-burial site) is carried out to understand the iron thermal-processing capabilities. The retrieved artefacts were examined using X-ray fluorescence (XRF) for elemental composition. The imaging of the artefacts was done using Scanning Electron Microscopy (SEM), Electron Backscatter Diffraction (EBSD), and Optical Microscopy (OM). In addition, phase identification was performed using X-ray diffraction (XRD) and Energy Dispersive X-ray Spectroscopy (EDS). Combination of these analyses illustrates that inhabitants of Mangadu and Ambal were aware of the iron alloy manufacturing/processing techniques such as forging and hammering. 相似文献
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对于二里头文化的性质问题,学术界已进行了数十年的讨论,然而直到目前,共识却仍未能达成。本文首次从青铜器铅同位素比值分析入手,对二里头文化的性质问题予以探讨。经过对偃师二里头、郑州二里岗、黄陂盘龙城、安阳殷墟等遗址出土青铜器的铅同位素比值数据的分析与讨论,我们支持二里头文化一至三期属夏文化、第四期遗存则已进入了商代纪年的观点。 相似文献
13.
Jane Humphris Michael F. Charlton Jake Keen Lee Sauder Fareed Alshishani 《Journal of Field Archaeology》2018,43(5):399-416
The Royal City of Meroe, ca. 200?km north of Khartoum in the modern-day Republic of the Sudan, was an ancient capital of the Kingdom of Kush. From the 3rd century b.c. to the 4th century a.d., Kushite rulers controlled significant territory from the banks of the Nile at Meroe, in part through their ability to ensure the production of significant quantities of iron. The extensive archaeological remains of Meroitic iron production have been investigated over decades, and recently a series of experimental iron smelts in a replica Meroitic furnace has shed new light on the archaeometallurgical evidence. The data generated during the smelting campaigns has provided an understanding of the type of iron ore used, the construction and operating parameters of the furnace, and the workshop space created by the ancient iron smelters during the later and post-Meroitic times. 相似文献
14.
Isotopic, EPR and petrographic studies aimed at establishing the provenance of sculptural bigio antico are reported, including 18 possible quarry sites and 21 ancient sculptures. The results demonstrate that the Belevi quarry, north‐east of Ephesos, above the more famous white marble quarry, was the major source of this marble. Nineteen artefacts belong to Belevi, whereas the precise origin of the remaining two is unknown, but must probably be found within the same area. The peculiar distribution of δ13C values both for Belevi and artefacts was crucial for inferring the correct provenance, subsequently confirmed by additional analytical and petrographic data. 相似文献
15.
A new method for interpreting lead isotope ratios of artefacts is presented: a numerical and graphical ‘match–no match‘ with possible raw materials. By calculating the definite integral under the kernel density estimate plot of different mining districts, using open-access software and legacy data, the relative probability that an object is made of an ore is indicated. A match with the reference data set may indicate the true origin, while no match indicates an unknown origin, that is, not present in the data set of mineral resources. Likewise, the composite or recycled nature of artefacts can be investigated in a probabilistic manner. 相似文献
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A 13th‐century‐BC shipwreck site, Hishuley Carmel, is described and discussed. It provides direct evidence for marine transport of copper and tin along the Israeli coast and may indicate inland and maritime trade‐routes of metals in the Mediterranean. The shipwreck represents a supply‐system providing the demand for bronze in the Levant. Trace‐elements and lead‐isotope analysis suggest that the copper came from Cyprus, similarly to bun and oxhide ingots from Uluburun. The source of the tin cannot yet be ascertained. The medium‐size ship was probably grounded and wrecked during a storm. Some of the cargo may have been salvaged in Antiquity. © 2012 The Authors 相似文献
19.
Rhonda L. Quinn Scott C. Warnasch Monet Watson Linda Godfrey Jacob B. Setera Jill VanTongeren Richard Mortlock James Wright 《International Journal of Osteoarchaeology》2020,30(2):225-235
In 2011, the mummified body of a Black adult female was discovered in a mid‐19th‐century Fisk iron coffin buried in Queens, New York City. Archival research points to the identity of the woman as Martha Peterson, a domestic worker who lived in the home of William Raymond, the business partner and neighbour of Almond Fisk, the coffin inventor and manufacturer. Here, we apply biogeochemical methods to provide information about the Woman in the Iron Coffin's (WIC's) residence, diet, and health to complement the biological profile and test the archival‐based interpretation of identity. We conducted stable isotopic (δ13C, δ15N, δ18O, 87Sr/86Sr, and 206Pb/207Pb) and elemental (As, Sr, and Pb) concentration analyses of a second premolar and one strand of hair to characterize her lifeways during middle childhood and near the time of death. We interpret WIC's geographic location during the time of tooth formation as local to the New York region, compared with established δ18O and 87Sr/86Sr isoscapes of the United States and 206Pb/207Pb values of regional coal and ore. WIC's δ13C and δ15N values indicate a mixed diet similar to contemporaneous peoples from other Mid‐Atlantic States. Pb concentrations are potentially indicative of acute Pb‐caused health problems in a period of ~1 year during middle childhood. Our biogeochemical results bolster archival‐based interpretations of WIC's identity as a member of the Peterson's, a local free Black family, and provide a glimpse into the life of a Black woman in 19th‐century New York City. 相似文献
20.
Lead isotopes combined with trace element data represent a powerful tool for non‐ferrous metal provenance studies. Nevertheless, unconsidered geological factors and archaeological data, as well as ignored analytical procedures, may substantially modify the interpretation of the isotopic and trace element signature obtained as a potential ore candidate. Three archaeological examples, accompanied by high‐resolution lead isotopic measurements (MC–ICP–MS), are presented here to discuss the above‐mentioned criticisms and to propose some solutions. The first example deals with prehistoric/historical gold/silver‐mining activity from Romania (the Baia Bor?a and Ro?ia Montan? ore deposits). The second one regards the lead/silver metallurgical activity from the Mont‐Lozère massif (France) during medieval times. The third example focuses on the comparison between two batches of lead isotope data gathered on Roman lead ingots from Saintes‐Maries‐de‐la‐Mer, using different SRM 981 Pb values. 相似文献