Heat Treatment of Mineral Pigment During the Upper Palaeolithic in North‐East Italy

The use of red ochre for utilitarian, symbolic and artistic purposes is widely documented in prehistoric contexts. The absence of adequate red‐coloured raw materials influenced the development of technological activities aimed at modifying the original physiochemical properties of yellow ochre. The heat treatment of goethite to obtain hematite was investigated in the western sector of the Lessini Mountains in north‐east Italy, where red ochre was found in the (Proto)Aurignacian levels at Fumane cave and in the Late Epigravettian sequence at Tagliente rockshelter. The combination of X‐ray powder diffraction (XRPD) and transmission electron microscopy (TEM) proved that heat treatment was a common practice in the studied archaeological sites due to the scarce availability of suitable hematite‐based material in the region.     

First large‐scale provenance study of pigments reveals new complex behavioural patterns during the Upper Palaeolithic of south‐western Germany

The use of red iron‐based earth pigments, or ochre, is a key component of early symbolic behaviours for anatomically modern humans and possibly Neanderthals. We present the first ochre provenance study in Central Europe showing long‐term selection strategies by inhabitants of cave sites in south‐western Germany during the Upper Palaeolithic (43–14.5 ka). Ochre artefacts from Hohle Fels, Geißenklösterle and Vogelherd, and local and extra‐local sources, were investigated using neutron activation analysis (NAA), X‐ray diffraction (XRD) and scanning electron microscopy (SEM). The results show that local ochre sources were continuously and systematically accessed for c.29 500 years, with periodic events of long‐distance (about > 300 km) ochre acquisition during the Aurignacian (c.35–43 ka), suggesting higher mobility than previously suspected. The results reveal previously unknown long‐term, complex spatio‐temporal behavioural patterns during the earliest presence of Homo sapiens in Europe.     

ARTIFICIAL OR NATURAL ORIGIN OF HEMATITE‐BASED RED PIGMENTS IN ARCHAEOLOGICAL CONTEXTS: THE CASE OF RIPARO DALMERI (TRENTO,ITALY)

This study concerns those crystallographic and microstructural features that can provide indications on the actual origin of red pigments based on hematite (Fe₂O₃). The main features of natural and artificial hematite are recalled and used to discuss the results obtained from the characterization of red‐ochre samples coming from the Palaeolithic site of Riparo Dalmeri, a rock‐shelter located in northeastern Italy, dated to 13 000 cal. bp , and notorious for the presence, among the other finds, of red‐painted calcareous stones. Painting and the treatment of leather and hides obtained from the intensive hunting activity were the main uses of the hematite‐based red‐ochres at Riparo Dalmeri. It turns out that hematite was mostly obtained from the thermal treatment of goethite, which, unlike hematite, was and still is widely available in the neighbourhood of the site.     

陕西安康紫阳北五省会馆壁画颜料分析研究

陕西安康紫阳北五省会馆壁画是目前陕西省境内发现的最大的一处建筑壁画,为了解其颜料组成,本工作采用X射线荧光、偏光显微镜、X射线衍射、激光显微拉曼光谱及扫描电镜能谱分析相结合的分析方法,对颜料样品进行了分析。结果表明,北五省会馆壁画除正殿发现一处红色染料外,其他均为无机颜料;红色颜料主要是铅丹、朱砂、铁红;绿色颜料为氯铜矿、石绿、斜氯铜矿;蓝色颜料的主要成分是普鲁士蓝、smalt、石青;黄色颜料为雌黄、铁黄;褐色颜料的主要成分是铁红及铅丹的变色产物二氧化铅;黑色为炭黑;白色颜料主要是铅白,且多使用铅白作为调色颜料。研究结果对于了解清代民间壁画的制作工艺,丰富对陕西建筑壁画的认识具有重要意义。     

The Source of Iron‐Oxide Pigments Used in Pecos River Style Rock Paints

The likely sources of iron‐oxide pigments used in prehistoric rock paintings in the Lower Pecos Archaeological Region were identified on the basis of chemical fingerprinting using LA–ICP–MS. The chemical signatures of 13 red rock paint samples collected from two south‐west Texas sites were compared with three potential source materials (ochre, siltstone and rhyolite), and two pigment cakes (crayons) that were excavated near the sampling sites. The significant chemical similarities between the paint and siltstones suggest that siltstone was used as the source of the colour. The overlapping chemical signatures for one of the pigment cakes and siltstone further suggests that some of the prehistoric people inhabiting the area 3000–4000 years ago had acquired the skills to extract iron oxide from siltstone and process it into paint pigments.     

PIGMENTS AND PLASTERS FROM THE ROMAN SETTLEMENT OF THAMUSIDA (RABAT,MOROCCO)

A total of 22 samples were taken both from plasters still in situ and from collapsed material recovered by French, Italian and Moroccan teams at the Roman settlement of Thamusida (Rabat, Morocco). The sample characterization was obtained using optical microscopy, scanning electron microscopy, image analysis and Raman micro‐spectroscopy. Plaster aggregate was made using a mixture of sands and clays that outcrop nearby, while lime was probably produced using the local limestone crust, as was further verified for the mortars. The plasters from the bath complexes (public buildings) and the Temple à trois cellae (sacred building) were very poorly made, while those from areas VII and XX (private buildings) indicated the involvement of more expert masons. The pigments used were cinnabar, red ochre, yellow ochre, Egyptian blue, green earth, chalk white and carbon black. The overall manufacture was of low quality, and hence perfectly comparable to that observed in other Roman Provinces. With respect to Italy and to other Mediterranean Roman sites, Thamusida fits well within an aesthetic and technical koinè that differentiates sites of the Italian peninsula from those in the Provinces.     

THE SEARCH FOR THE ORIGIN OF BITUMEN EXCAVATED FROM ARCHAEOLOGICAL SITES IN THE NORTHERNMOST ISLAND IN JAPAN BY MEANS OF STATISTICAL ANALYSIS OF FI–MS DATA*

The origin of bitumen excavated from archaeological sites in Hokkaido, the northernmost island in Japan, was sought by means of field‐ionization mass spectrometry (FI–MS) and gas chromatography – mass spectrometry (GC–MS) of the hydrocarbon components. The field‐ionization mass spectra were decomposed by Z‐numbers into several components, where the Z‐number refers to z in the formula C _n H _2n+z . This is equivalent to the deficit number of H atoms, when compared to the corresponding saturated hydrocarbon, which is related to the number of saturated hydrocarbon rings in alkanes. By use of the spectral intensities of the seven alkane components in each sample, multiple discriminant analysis was employed for the data of raw bitumen samples and excavated samples from archaeological sites. Based on this method and the gas chromatogram type, the following bitumen trade in the prehistoric age of Japan was elucidated: bitumen from Niigata, one of the main sources on the main island of Japan, spread to the north in 2000 bc , probably via the coastal zone, and reached a small island near the north end of Hokkaido. Bitumen from Sakhalin reached the central lowland in Hokkaido, but it went no further. Bitumen from Akita, another main source on the main island, spread over northern Honshu much earlier and reached the Oshima peninsula, the southwestern part of Hokkaido. The Akita bitumen scattered into the central lowland after the Niigata and Sakhalin bitumen. This area is believed to be the place where people from the south and the north met in those periods.     

A SCIENTIFIC INVESTIGATION ON THE PROVENANCE AND TECHNOLOGY OF A BLACK‐FIGURE AMPHORA ATTRIBUTED TO THE PRIAM GROUP*

The restoration of a Greek black‐figure amphora provided an opportunity to study the provenance and production technology of the vase. The composition of the ceramic body, determined by inductively coupled plasma optical emission spectroscopy (ICP–OES), matches that of Attic products. Investigation by X‐ray diffraction and reflectance spectroscopy suggests a maximum firing temperature around 900°C and a body re‐oxidation temperature around 800°C, respectively. The morphology and composition of black, red and dark red surface areas were studied by scanning electron microscopy and X‐ray energy‐dispersive analysis; the black areas show the features of a typical well‐vitrified black gloss, while the red areas were most probably obtained by simple burnishing of the body; the dark red additions, on the other hand, are the likely result of a partial re‐oxidation of a clay–ochre mixture.     

THE EARLIEST USE OF CORUNDUM AND DIAMOND,IN PREHISTORIC CHINA*

The majority of prehistoric lithic artefacts were fashioned from rocks and minerals no harder than quartz, and there is no prehistoric evidence for the working of harder materials, such as corundum and diamond. The earliest physical evidence for the use of corundum (ruby, sapphire) is thought to be the abrasive grit recovered from Bronze Age Minoan quartz beads (c. 1700–1500 bc ), while diamond is thought to have been used no earlier than 500 bc , in India. Here we show that corundum was worked c. 4000–3500 bc during the Neolithic period in China, in the form of polished axes from the Liangzhu and Sanxingcun cultures. We also present physical evidence that later Liangzhu axes (c. 2500 bc ), made from the same previously undescribed rock whose most abundant component is corundum, were polished to a mirror‐like finish with a diamond abrasive. Our findings, which are the first to support the use of corundum and diamond in a prehistoric context, may also help to explain the trademark feature of the Neolithic in China, vast quantities of finely polished nephrite jade artefacts.     

Two‐needle knitting and cross‐knit looping: early bronze age pottery imprints from anatolia and the caucasus

There is ample evidence for the use of prehistoric loom‐woven, tabby fabric (made by plain warp and weft technique) in the construction of pottery. Ancient potters from the steppe regions of central Asia through to Anatolia and in some parts of Europe sometimes built their wares aided by old fragments of cloth and basketry, which left impressions on and in the walls of their vessels. In the highlands of eastern Turkey at the site of Sos Höyük and at Chobareti, in Georgia, the impressions on Early Bronze Age pottery include an array of textiles and, notably, what appears to be the earliest known evidence for two‐needle knitting and for the continued use of the single‐element, cross‐knit looping (also known as Coptic ‘nalbinding’) made using an eyed‐needle, a craft which has been found in Pre‐Pottery Neolithic contexts of the Levant. Various basketry techniques are also represented.     

Processing ochre in the Middle Stone Age: Testing the inference of prehistoric behaviours from actualistically derived experimental data

The increase in the presence of ‘ochre’ in African Middle Stone Age contexts has been employed, together with changes in human biology and behaviour, to support the hypothesis that ‘modern’ cognitive abilities arose in Africa. The consistent exploitation of ochre is interpreted as evidence for colour symbolism, a proxy for the origin of language and a defining aspect of ‘modern’ human behaviour. That humans attached considerable symbolic value to red ochres in particular is illustrated by ethnographic examples. Research has shown that wear patterns indicative of abrasive processing methods prevail, but many archaeological specimens also exhibit wear traces not derived from grinding or scraping alone. Building on former research, I present here the results of an experimental study devised to infer the methods employed to extract powder from ochre during the African Middle Stone Age. The prospect of ascertaining at least some of the likely uses to which ochre may have been put, is also explored. I conclude that functional data derived from actualistic experiments can be used to enhance our understanding of some aspects of prehistoric behaviour.     

THE USE OF OXYGEN ISOTOPES IN SHEEP MOLARS TO INVESTIGATE PAST HERDING PRACTICES AT THE NEOLITHIC SETTLEMENT OF ÇATALHÖYÜK,CENTRAL ANATOLIA

This paper presents a pilot study designed to test the use of oxygen isotopes for investigating aspects of early herding practices in the Neolithic of western Asia, using the site of Çatalhöyük in central Anatolia as a case study. Time‐sequenced δ¹⁸O values in dental enamel of archaeological sheep are assessed for post‐depositional diagenetic effects and compared with seasonal δ¹⁸O meteoric water values in the region today. The evidence is used to indicate the environmental conditions in which individual sheep spent their first year, enabling management of breeding and birthing seasons, and movement to seasonal pastures, to be investigated.     

RIETVELD X-RAY DIFFRACTION AND X-RAY FLUORESCENCE ANALYSIS OF AUSTRALIAN ABORIGINAL OCHRES*

Rietveld phase analysis of X-ray powder diffraction patterns and chemical analysis by X-ray fluorescence spectroscopy have been used to characterize a series of red and yellow ochre samples from Aboriginal ochre deposits in South and Western Australia. The ochres were found to have diverse mineralogy, being mixtures of up to seven minerals, and also to have complex trace element signatures. The mineralogical characteristics and geochemistry of the ochres can be used to identify the source quarries. Using this combination of analytieal techniques it may be possible to trace the source of ochres in burial sites and on objects back to the original quarries.     

A Lead Seal from the Laodikeia‐Kandilkiri Excavations and an Overall Assessment of Seal Use in South‐Western Anatolia During the Early Bronze Age

Kandilk?r?, one of the two prehistoric settlements of the ancient city of Laodikeia on the Lykos River (Laodicea ad Lycum), was settled during the Early Bronze Age (EBA) 2 and 3 periods. The present study attempts to provide an overall assessment of questions pertaining to seals and sealing practices in south‐western Anatolia, raised due to the discovery of a lead stamp seal at Kandilk?r?. In EBA 2, metal seals appeared alongside the pre‐existing clay ones, and by the end of the EBA 3, negatives of metal seals seem to have been added to the ‘trinket mould’ repertoire of artisans, who mainly cast lead and were active along the trade routes. The custom of seal usage in the Near East seems to have been partially adopted in south‐west Anatolia in the EBA, then passed to mainland Greece from this region. It is proposed that the south‐western corner of Anatolia might have played a more active role in the transport of Near Eastern ideas as a result of its closer proximity to the Mediterranean coast, and that at least a part of this connection might have been established via sea routes.     

APPROACHING THE LANDSCAPE DIMENSION OF THE MEGALITHIC PHENOMENON IN SOUTHERN SPAIN

Although the megalithic phenomenon in southern Iberia has received attention since the mid‐nineteenth century, there has been very little attention paid to the role that megalithic structures played in the organization of prehistoric landscapes. Just as in other areas of Europe, however, southern Iberian megalithic structures must have played complex roles in the social organization of landscapes that go far beyond their use as funerary containers. Using examples from our work in southern Iberia, we employ GIS‐based spatial analysis to explore for the first time various aspects of the landscape dimension of these monuments. We discuss three case‐studies for which fresh field data have been recently made available. In the first (Almadén de la Plata) we find patterns of association between medieval transhumance routes and megaliths, and we use cost‐surface modelling to suggest that medieval routes may reflect earlier, prehistoric patterns of movement which in turn suggest that megalithic structures functioned in this area as waypoints within an emerging mobility system for people and livestock. In the second case (Aroche) we show correlations between the locations of megaliths and theoretical territories defined by isochrones and contrast this pattern with the distribution of non‐megalithic funerary sites of the Early Bronze Age, concluding that the spatial distribution of megaliths in this region may relate to their role as landmarks. Lastly we describe a far more specific relationship which we have encountered in the Antequera region, where we believe we have identified a relationship between the orientation of the megalithic structure of Menga, a prominent natural feature and several newly discovered prehistoric sites. Together, these three examples suggest that the current focus on typology, chronology and contents in the study of Iberian megaliths needs to be matched with efforts to identify and interpret the often highly complex structure of the prehistoric landscapes of which they form an integral part.     

Sensitivity of bulk sedimentary stable carbon isotopes to prehistoric forest clearance and maize agriculture

The stable carbon isotope compositions (δ¹³C) of tropical lake sediments and soils have been used to reconstruct the occurrence of prehistoric maize cultivation and its relative importance through time. This study assesses some of the possible variables affecting the response of lake sediment bulk organic carbon isotope (δ¹³C_TOC) values to variations in the scale of prehistoric maize cultivation and the potential of this proxy to yield quantitative estimates of the scale of prehistoric maize agriculture in small tropical watersheds. High resolution analyses of δ¹³C_TOC values, maize pollen concentrations, and mineral influx were conducted on sediments deposited during a ∼220 year period of prehistoric maize agriculture in the watershed of Laguna Castilla, a small lake in the mid-elevations of the Cordillera Central, Dominican Republic. Close correspondence between δ¹³C_TOC values and maize pollen concentrations in the Laguna Castilla sediment record indicates a close relationship between the isotopic values and the scale of prehistoric maize cultivation. Correlations between the δ¹³C_TOC signature and mineral influx indicate that the isotope record is also sensitive to variations in allochthonous carbon delivery. This study establishes that sedimentary δ¹³C_TOC values can provide a highly sensitive proxy of the spatial scale of prehistoric maize agriculture in small tropical watersheds, but emphasizes the need for a better understanding of sediment dynamics and carbon cycling in anthropogenically modified landscapes before this proxy can be widely employed in diverse archaeological settings.     

SPECTROSCOPIC INVESTIGATION OF RED STAINS AFFECTING THE CARRARA MARBLE FAÇADE OF THE CERTOSA OF PAVIA

The nature of the large red stains exhibited on the Carrara marble elements of the Certosa of Pavia façade was investigated by means of spectroscopic techniques and scanning electron microscopy. Although previous microbiological analysis has demonstrated the presence on the stone of a bacterial strain identified as Micrococcus roseus, that is capable of carotenoid production, it has been ascertained in the present study that an inorganic pigment, namely Pb₃O₄, is responsible for the observed coloration. On small green spots, the presence of photosynthetic micro-organisms has been demonstrated by microbiological analysis and confirmed by resonance Raman spectroscopy.     

OBSIDIAN IN THE MEDITERRANEAN AND THE NEAR EAST: A PROVENANCING SUCCESS STORY

Obsidian provenancing studies comprise one of the most productive and successful research programmes of archaeological science. Obsidian characterization has been successful because workable obsidian is homogeneous on a small scale, analysable by a large number of methods, and is restricted to a small number of mainly readily distinguishable geological sources. Analytical, dating, source, and trade studies within the western Mediterranean, central and eastern Europe, the Aegean, and Anatolia and the Near East during the last 30 years or so are reviewed. Research has shown that distributions are mainly separate in the four regions examined, and that obsidian was traded up to 900km in the prehistoric period. Publications on obsidian in the areas under review reached a peak of frequency in the later 1970s and 1980s, but have now decreased in number. This may reflect changing fashions in archaeometric studies, and a current lack of routine application of the provenancing methods developed.     

THE EMIGRATION OF PREALPINE LAKE MASTERS: A STUDY OF A 17TH‐CENTURY MANTELPIECE ATTRIBUTED TO THE CARLONE FAMILY OF ROVIO (TICINO,SWITZERLAND)*

This work illustrates the possible connections between the phenomenon of the seasonal emigration of lake masters and the production of artistic artefacts. Within the ambit of these dynamics, a stucco mantelpiece was taken into consideration. Nothing was known about the object: neither its origin, nor the artist who produced it, nor the period of execution. Historical, stylistic and formal analyses of the materials and of the technique with which the work was executed allow us to verify that the mantelpiece was produced using the stucco technique in the 17th century, in Rovio (southern Switzerland, Ticino), and that it comes from one of the exponents of the Carlone workshop, whose representatives were important in the tradition of itinerant artistic workers. Due to their good technical and professional specialization, the Carlone workshop served both public and private buyers. Tommaso Carlone is the principal representative artist of the Carlone workshop; it is certain that his workshop produced the stucco mantelpiece. The migrations of the artists were seasonal and they maintained a close bond with their country of origin. When they returned to the country of origin, they produced works of great artistic value, of which the mantelpiece represents a splendid example. Through the employment of conventional analytical techniques (optical and electron microscopy, infrared spectroscopy and porosity measurements), it has been possible to study the technique with which the work was executed, the materials used and the decay. The mantelpiece was produced using the stucco technique by means of a body layer (slaked lime and silicate and carbonate aggregates) and a marmorino finishing layer (slaked lime and pointed calcite crystals). Above this layer, whose thickness varies in relation to the executed result, there is a thin lime plaster whitewash, pigmented with the dispersion of yellow ochre particles; chromatic alterations are an oxalate patina caused by firm adhesion to the marmorino layer, due to the denaturation of the proteic substances employed. The final treatment was made with beeswax, which increased the marmoreal effect. Several additional layers of lime plaster whitewash have also been applied over the centuries. The figurative central square of the plastic decoration was made using red ochre.