PETROGRAPHIC AND CHEMICAL CHARACTERIZATION OF POTTERY PRODUCTION OF THE LATE MINOAN I KILN AT HAGHIA TRIADA,CRETE*

Pottery from the Late Minoan I kiln at Haghia Triada in the Mesara Plain, southern Crete, was analysed by a range of techniques, comprising thin‐section petrography, scanning electron microscopy, X‐ray diffraction, X‐ray fluorescence and neutron activation analysis. The project characterizes the ceramic fabrics and probable raw materials, correlates paste recipes with shape, reconstructs the firing conditions of the kiln and establishes a chemical reference group, taking into account post‐burial alteration and contamination. Comparison of the reference group formed with that from the neighbouring, broadly contemporary, kiln at Kommos shows an unexpected differentiation of the two kilns.     

The Compositional study of ceramic samples from tombs dating to the Zhou Dynasty at Xiaoshan,Zhejiang Province (China)

Xiaoshan in Zhejiang Province was an important ceramic production area in ancient China. During recent years, local archaeologists have found a number of mound tombs dating to the Zhou Dynasty and the Spring and Autumn period. Many shards of stamped stoneware and proto‐porcelain have been unearthed from these tombs. In this paper, we report how we collected ceramic shards from tombs and samples from local ancient kilns as reference materials in order to clarify their relationship. We have used the energy‐dispersive X‐ray fluorescence technique to analyse the chemical composition of the ceramic samples. The results indicate that some of the tomb artefacts may be imported from other production areas. We infer that the other tomb samples were produced at local kilns, but due to production process–related compositional differences, there are small differences in chemical composition between different categories of samples.     

CERAMIC PRODUCTION,PROVENANCE AND USE—A REVIEW*

The contribution of the physical sciences to the reconstruction of the production technology (i.e., processing of raw materials, forming, surface treatments and firing methods) for earthenwares, stonewares, porcelains and stonepaste bodies are summarized. The organization of production and the reasons for technological choice are considered. Provenance studies based on both chemical analysis and thin‐section petrography are discussed, with the investigation of Minoan and Mycenaean pottery being taken as the case study. The approaches to determining how pottery vessels were used in antiquity are outlined. Finally, future developments in ceramic studies are briefly considered.     

Assessing Ceramic Compositional Data: A Comparison of Total Reflection X‐ray Fluorescence and Instrumental Neutron Activation Analysis On Late Iron Age Spanish Celtiberian Ceramics

A solid‐phase, non‐chemical processing protocol was recently developed as a means of chemically characterizing archaeological ceramics by total reflection X‐ray fluorescence (TXRF). Following this methodology, TXRF can provide semi‐quantitative determinations for 18 elements with comparable levels of precision and accuracy for the majority of them in comparison with a clay reference material analysed by instrumental neutron activation (INAA). In order critically to assess the analytical capabilities of TXRF, a large sample set of Late Iron Age Spanish Celtiberian ceramics and modern clays was analysed both by TXRF and INAA. Semi‐quantitative chemical data provided by TXRF and quantitative data provided by INAA were subjected to commonly used multivariate statistical methods as a way of evaluating the ability of the new technique to discriminate among different compositional groups. The comparison of the two data sets shows no significant discrepancies, thereby allowing support for the same archaeological interpretation. These results suggest that TXRF has potential applicability for compositional characterization of archaeological ceramics, providing data that are useful for provenance studies.     

Technological Choices in Hand‐Made Indigenous Pottery from Western Mallorca (Balearic Islands,Spain) (C.1200–75 bc): An Archaeometric Approach

This paper addresses the technological choices observed in Mallorca (Spain) for the production of hand‐made pottery during the Late Bronze and Iron Age. We have conducted a diachronic analysis of the ceramic assemblages recovered from two archaeological sites placed in the same territory by means of X‐ray fluorescence and optical microscopy by thin‐section analysis. The archaeometric characterization of the hand‐made vessels allows us to establish several compositional groups related to the use of different raw materials and certain paste recipes associated with the archaeological sites and periods considered. Thus, this study evidences different productive strategies in each site and across time in the same geographical area.     

A Bronze Age Quarry in Eastern Crete

Abstract

The sandstone quarry at Mochlos is one of four major quarries in eastern Crete that were worked during the New Palace Period of Minoan civilization (ca. 1700–1450 B.C.) to produce large ashlar blocks for nearby Minoan sites. At that time sandstone, or ammoudha, as it is known locally, was especially valued as a building material, partly because of its distinctive color and texture, but mainly because of the ease with which it could be cut, and the stone was used extensively for exterior façades, for walls around interior courts, and for other architectural features of the more important buildings on these sites. This article describes the quarry at Mochlos in some detail, including the quarrying techniques employed, and argues that the destination of the stone from the Mochlos quarry was the Minoan palace at Gournia. The article ends with a comparison of the four ammoudha quarries in eastern Crete.     

The production and technology of glazed ceramics from the middle ages,found in the saepinum territory (Italy): a multimethodic approach*

A collection of ceramics from the Middle Ages found in Altilia and Terravecchia (the Saepinum area, Campobasso, Italy) were characterized by using different mineralogical analyses to investigate their provenance and production techniques. The body ceramic was investigated using Rietveld phase analysis of X‐ray powder diffraction patterns, X‐ray fluorescence spectrometry and scanning electron microscopy. The chemical compositions of the coatings were measured by scanning electron microscopy and their mineralogical compositions were determined using a particular technique of X‐ray small‐angle scattering (SAS) optimized for studies of thin films. Moreover, the material used for decoration was studied using micro‐Raman spectroscopy. The archaeometric results confirmed the distinction into two different ceramic classes, already individuated from archaeological analysis: the Altilia objects belong to the protomajolica class, whereas the objects from Terravecchia are RMR (ramina‐manganese‐red) ceramics. A comparison between the chemical and mineralogical compositions of good‐quality ceramic objects and those of waste products indicated local production of the ceramics. A sharp distinction was found in the chemical composition of the coatings: the Altilia products have tin‐opacified lead glazes, while the Terravecchia ones have transparent high‐lead glazes. Among the Altilia products, the unsuccessful process that produced a large quantity of discarded materials was attributed to the high lead content of the glazes. In fact, the principal advantage of the high lead content was to make the preparation and application of the glaze suspension easier, but the risk of reduction of lead oxide to metallic lead was greatly increased. Using micro‐Raman spectroscopy, the following minerals were identified as pigments: pyrolusite for the dark colour, malachite for green, lepidocrocite for yellow and hematite for red.     

Contouring the Cataclysm: A Geographical Analysis of the Effects of the Minoan Eruption of the Santorini Volcano

This study is a step forward in understanding the palaeoenvironmental effects of the Minoan eruption of Santorini (1627–1600 BCE). We employ geostatistics to produce a prediction map for the thickness of the tephra fallout over the Eastern Mediterranean, and we reconstruct the effects by comparisons with recent eruption analogues. Based on the geostatistical map, the amount of environmental disruption over so far undocumented areas is estimated by comparison with archaeological sites where emplaced Minoan tephra has been recorded before. Nevertheless, independent field evidence suggest that the environment responded differently in places, occasionally posing challenges to the presented interpolation. A second line of evidence coming from contemporaneous fluvial archives provides clues for a widespread ‘Minoan flood’ over a large part of the Eastern Mediterranean, associated with the eruption itself. This simultaneous hydrological event may have had a counterbalancing effect on the impacts of the Minoan tephra cover, and could explain the sporadic discrepancies between the predicted effects and the palaeoenvironmental evidence. Traces of the effects of this extraordinary volcanic event are also sought in the regional Late Bronze Age literature.     

On the flow characteristics of the conical Minoan pipes used in water supply systems,via computational fluid dynamics simulations

The Minoan Terracotta pipes with their conical shape were widely used in the water distribution system in the ancient Minoan civilization. They remain one of the brightest achievements of the Minoan tribe in water supply technology and raise admiration as well as many questions about the technological advancements of antiquity, that are yet to be understood. The present work aims at answering the following questions: a) what inspired the Minoans to manufacture pipes with such a peculiar shape, that differs greatly not only from later pipe designs of antiquity, but also from contemporary cylindrical pipes and b) why was the design of those pipes abandoned after the fall of the Minoan civilization? It tries to address these questions by investigating the flow physics and dynamics that take place in such pipes, adopting advanced numerical and computational methods. The time-averaged Navier–Stokes equations along with the k − ? turbulence model are solved for a variety of geometrical parameters, pipe orientations and flow rates, in order to produce a comparative picture of the hydraulic efficiency of the conical Minoan pipes. The flow field is visualized and critical flow parameters, such as the head loss, the velocity magnitude and turbulence intensity, are calculated. These calculations show clearly that the conical Minoan pipes exhibit significantly higher pressure drops along their length compared to an equivalent straight pipe. In their widest part an extended recirculation appears, which could wash out impurities that may be present in the water, which at the same time cannot be deposited on the pipe wall. This evidence proves that the Minoan pipes are energetically expensive to operate and consequently their replacing by cylindrical pipes was inevitable. Therefore, it seems that the main advantage and purpose of the particular geometry was that they could be easily connected on site, forming long straight or slowly bending lines without having to add straight or many different fittings in between.     

STUDIES OF CERAMIC TILES ATTRIBUTED TO GABRIEL DEL BARCO

This study reports the mineralogical and chemical characterization of the ceramic body of tiles created by Gabriel del Barco, an important tile painter in Lisbon from the 17th century. Six tile panels were studied: four are signed and two are attributed to the painter. The results obtained from the signed panels revealed that the samples have almost the same characteristics, with a magnesium‐rich phase, meaning that the artist, or the pottery where the tiles were made, kept to the same manufacturing procedure over some time. In contrast to this, the results of samples from the masterpiece Vista de Lisboa showed some heterogeneity, as two patterns were observed. However, one of these patterns matches with the one observed in the signed tile panels. Although a more detailed study still needs to be done, these findings, together with historical sources linked to painting characteristics, suggest that Gabriel del Barco was also the author of the non‐signed tiles.     

For Whom the Bells Fall: Metals from the Cenote Sagrado,Chichén Itzá

Bells of copper and copper alloys and gold–copper alloys were deposited in events at the Cenote Sagrado at Chichén Itzá, Mexico during the site's primary occupation (ad 750–1050) and in later centuries. Housed in three museums in the United States and Mexico, bells (n = 38) were evaluated for traces of fabrication and alteration using Vis–UV–IR optical microscopy. Bulk compositions were determined through p‐ED‐XRF. Phases and compositional variation by depth were characterized through XRD and RBS. The technological styles of bell groups were ascribed to communities of metallurgical practice, from West and Central Mexico to Costa Rica and Panama.     

A Complete Chemical Grouping of the Berkeley Neutron Activation Analysis Data on Mycenaean Pottery

The Perlman–Asaro data bank contains nearly 900 data sets of Mycenaean and Minoan sherds which were sampled in different regions of Greece and Crete. The data were obtained from Neutron Activation Analysis measurements at Berkeley in the 1970s, and for each concentration value a corresponding uncertainty of measurement was also recorded. Parts of the contents of the data bank have been published before. Here, we present the first complete statistical analysis of the whole data bank, considering measurement errors as well as constant shifts of the data due to pottery making practices (“dilutions”). We establish new reference patterns for different regions of Greece and Crete and compare the results with the contents of our own group data bank in Bonn. For those parts of the data which have been published previously, a comparison between these studies and our recent investigation is presented.     

CHEMISTRY VERSUS DATA DISPERSION: IS THERE A BETTER WAY TO ASSESS AND INTERPRET ARCHAEOMETRIC DATA?

Given the common use of chemical concentration data to define ceramic groups that aid in the exploration of ancient technology, trade and provenance, it is important to reflect on how we collectively establish and define both chemical groups and outliers. In this paper, we argue that commonly used data analysis procedures, such as principal component analysis and centred log‐ratio principal component analysis favoured in the examination of ceramic chemical data, although rapid and easy, may overlook existing chemical groups and outliers, especially when the ratio of non‐diagnostic to diagnostic elements is high. To evaluate whether geochemistry is more important than data dispersion in data assessment, we re‐examine chemical concentration data from previously published ceramic, clay and daub samples from the lower Ohio River Valley. We begin by briefly discussing steps we took to ensure that the data set reflects geochemical differences, rather than analytical or data transfer errors. Next, we use bivariate plots, as well as PCA and CLR–PCA, to examine different versions of our altered data, using varying numbers of element combinations. We propose that the careful examination of bivariate plots is critical in establishing the elements that should be included in PCA and other multivariate analyses.     

Technology Transfer at the Periphery of the Mycenaean World: The Cases of Mycenaean Pottery Found in Central Macedonia (Greece) and the Plain of Sybaris (Italy)*

The study of technology transfer in pottery production to the periphery of the Mycenaean world has been addressed by considering two different areas, southern Italy and central Macedonia. Technological features such as ceramic paste, decoration and firing have been determined for different ceramic groups established according to provenance criteria. The studies of technology and provenance have been performed following an archaeometric approach, using neutron activation analysis, petrographic analysis, X‐ray diffraction and scanning electron microscopy. The results have revealed the existence of two different models. On the one hand, southern Italy seems to exhibit a more organized pottery production, which follows a Mycenaean‐like technology, while in central Macedonia production is probably more varied, being based in part on the technology of the local tradition.     

Geoarchaeological tsunami deposits at Palaikastro (Crete) and the Late Minoan IA eruption of Santorini

The explosive eruption at Santorini in the Aegean Sea during the second millennium BCE was the largest Holocene volcanic upheaval in the Eastern Mediterranean region. The eruption was disastrous for the Minoan settlements at Santorini, but the effect on human society in the neighbouring islands and regions is still clouded in uncertainty. Tsunami generation was suggested, but comparatively little evidence was found. The lack of firm tsunami traces is particularly puzzling in Crete with its coastal settlements of the Late Minoan IA period, during which the Santorini eruption occurred. Here, we report the discovery of extensive geoarchaeological tsunami deposits at Palaikastro in north-eastern Crete. These deposits are characterized by a mixture of geological materials, including volcanic Santorini ash, and archaeological settlement debris. Various tsunami signatures were identified: (1) erosional contact with the underlying strata, (2) volcanic ash intraclasts in the lower part of the deposit, (3) reworked building stone material in the lower part of the deposit, (4) individual marine shells, (5) marine micro-fauna, (6) imbrication of rounded beach pebbles, settlement debris, ceramic sherds and even bones, (7) multi-modal chaotic composition. Late Minoan human settlement activities at Palaikastro provided architectural and stratigraphic frameworks in space and time that recorded and preserved tsunami evidence as geoarchaeological deposits. Such stratigraphic resolution and preservation may not occur in the natural landscape. Volcanic ash transported by wind from Santorini south-east to Crete preceded the tsunami. Geological, archaeological and radiocarbon dating criteria all converge, indicating that the tsunami deposits are coeval with the Minoan Santorini eruption. Field evidence suggests that tsunami waves at Palaikastro were at least 9 m high. Inverse tsunami modeling was attempted, based on these newly discovered tsunamigenic deposits. The initial wave in the generation region at Santorini that best fits the stratigraphic data is a wave with +35 to −15 m initial amplitude and a crest length of about 15 km.     

Colour in Minoan faience

The microstructures and chemical compositions of some 15 faience objects from Crete spanning the period from Middle Minoan IIIA through to Late Minoan IA are determined using analytical scanning electron microscopy. The Minoan faience is compared with replicate faience beads produced in the laboratory using various combinations of manganese, copper and iron as colorants. The alkali contents of the replicate beads are varied so that the colorants are present both as ions in a glass phase and as particulate oxides. These data are then used to try to infer the original colour of the Minoan faience, the great majority of which has suffered severe weathering during burial. The results suggest that instead of the present day “hallmark greys and browns” and “subtle greens and blues”, Minoan faience originally exhibited a wide range of colours, including bright turquoise blue, purple and violet, and pale yellow-green and greenish turquoise.     

THE WESTERN CYCLADES and CRETE: A "SPECIAL RELATIONSHIP"

Summary: This paper examines the idea that in the Later Bronze Age a regular exchange network linked Crete to the Western Cyclades and assured them of preferential treatment. Comparison of the degree of Minoan influence on Keos, Melos and Thera with that on the other Cycladic islands confirms that the former group had a special relationship with Crete; but the evidence is insufficient to prove that they acted as secondary distribution centres for Minoan goods. the substantivist view is that in a non-monetary economy exchange was effected through reciprocity and redistribution, while early trade was always motivated by imports, not exports. But documentary evidence for the Near East warns against oversimplification. For the Western Aegean, precise data are lacking, but evidence suggests that foreign trade was regulated by official agents; there was also freelance private enterprise. the Western Cyclades derived much of their prosperity from the transit dues.     

Investigating ancient technology and ceramic composition at Al-Khidr site (Failaka Island,Kuwait): Geochemical analyses of Bronze Age pottery by pXRF and thin-section petrographic analyses

Pottery assemblages from the site of Al-Khidr on Failaka Island, Kuwait, were analysed in order to reconstruct the chemical composition of Bronze Age wares and to build a mineralogical database of Bronze Age pottery dated from Failaka Periods 1–3B (2000–1650 BCE). A total of 145 ceramic sherds from Al-Khidr, as well as reference groups, were analysed by non-destructive portable X-ray fluorescence (pXRF) spectrometry. Preliminarily petrographic thin-section analysis was applied to four samples to reconstruct possible clay paste recipes and to identify raw materials. The results indicate that geochemical analyses can successfully distinguish subgroups within a typological category of ceramic assemblages. The results identified two subgroups within the Al-Khidr typological category: the Dilmun Barbar tradition and the Mesopotamian tradition. Future comparative compositional studies can be conducted to explore other aspects of craft specialisation, such as ceramic technological choices and possibly the influence of sociopolitical units.     

A preliminary study of ceramic pastes in the copper age pottery production of the Rome area

This paper presents the preliminary results of an analytical study on domestic pottery samples originating from the Copper Age sites of Casetta Mistici, Tor Pagnotta, Osteria del Curato-Via Cinquefrondi, Torre della Chiesaccia and Valle dei Morti, all of which are located in the Rome area (Latium, Italy). The aim of this research is to define the compositional features of the ceramic pastes and to reconstruct the main technological choices characterising pottery production in these contexts. The importance of these archaeological sites lies in their geographic position, being located in an area bounded by the Tiber and Aniene rivers and the Colli Albani volcano, and in their stratigraphic sequence, spanning from the mid-fourth to the end of the third millennium bc. This research, based on a petrographic and chemical investigation of pottery samples, led to the distinction of eight petrographic groups that reflect specific choices in pottery production. Moreover, the analytical results provide indications about the prehistoric pottery production of the Rome area in relation to the ceramic recipes used, the pastes that were obtained and their sourcing areas.     

The Origin of 18th–19th Century Tin‐Glazed Pottery from Lorraine,France

Forty‐eight tin‐glazed ceramic fragments (faiences) from Lorraine, found in excavations or pertaining to objects in collections, were subjected to X‐ray fluorescence analysis to determine the bulk, major, minor and trace element compositions. Sixteen superficially clay layers from the surroundings of Lunéville and Saint‐Clément were also analysed. The faiences are, with four exceptions, MgO rich. The combination of stylistic and chemical arguments allowed the recognition of 28 objects that were attributable to the important faience manufactory of Jacques II Chambrette in Lunéville. This reference group was used to test the provenance of high‐Mg faiences from private collections. The latter are not from the manufactory of Le Bois d'Épense/Les Islettes as commonly assumed, but most probably belong to Lunéville and Saint‐Clément. According to archival sources, the potters mixed three clays for the pastes. Some prospected clays are MgO rich due to the presence of dolomite and other Mg‐bearing minerals, but not as high as the faiences, a fact that can be explained by the sampling of de‐carbonatized layers.