QUICK SURVEY OF THE POSSIBLE CAUSES OF DAMAGE ENHANCEMENT OBSERVED IN SAN GIULIANO AFTER THE 2002 MOLISE,ITALY SEISMIC SEQUENCE

On October 31 and November 1, 2002, two earthquakes of magnitude 5.4 and 5.3 hit the area at the border between the Molise and Puglia regions in Southern Italy. The damage pattern in the epicentral area qualified the quake as an intensity VII MCS event, although providing a notable exception relevant to the small village of San Giuliano di Puglia. Since the first macroseismic survey, it appeared clear that in S. Giuliano the intensity was two degrees higher with respect to three neighbouring villages located within a radius of 3 km. Soon after the quake, our team started a campaign of microtremor HVSR measurements (Horizontal to Vertical Spectral Ratio), then we installed accelerometers and carried out damage and geological surveys. Finally, we performed a geoelectrical tomography and two profiles of Vs velocity with depth using the NASW technique (Noise Analysis of Surface Waves). The preliminary observations indicate that ground motion amplification is present in S. Giuliano within the frequency band that may affect building. A strong velocity contrast 20 m deep causes the predominant peak. More amplification could be due to more complicated, 2D effects. As regards the damage pattern, it divides S. Giuliano in three zones showing different characteristics and seismic behaviour. A building-by-building survey is still under way to better evaluate vulnerability variations in different zones of the village. However, the acquired data so far is sufficient to propose site amplification as a possible cause of the damage enhancement observed in S. Giuliano.     

HINTS ABOUT SITE AMPLIFICATION EFFECTS COMPARING MACROSEISMIC HAZARD ESTIMATE WITH MICROTREMOR MEASUREMENTS: THE AGRI VALLEY (ITALY) EXAMPLE

We approach from a new standpoint the problem of estimating seismic hazard for some towns and villages located in Val d'Agri area (Southern Italy) that in the past have been affected by several seismic events. The estimates are carried out using a method that is based on the analysis of site seismic history extracted from macroseismic catalogues. To study the influence of site effects two different procedures have been performed: in the first, seismic hazard estimates have been deduced from epicentral data only, in the second, intensity data actually observed at the site are also considered. The difference between the two estimates can be correlated with local variations of seismic response due to local geological features which are responsible for possible cases of amplification. In order to validate the presence of such correlation, seismic hazard estimates have been compared to site amplification measurements obtained by using the HVSR (Horizontal to Vertical Spectral Ratio) technique. Our findings reveal a good correlation between seismic hazard enhancements and the presence of site amplification effects. The application of this kind of analysis to the Val d'Agri area has pointed out that the joint estimates of site seismic hazard enhancement and HVSR measurements could be a helpful tool to identify problems related to seismic microzonation.     

Fluids and halogens at the diagenetic–metamorphic boundary: evidence from veins in continental basins, western Norway

Seven vein types are recognized in three continental Devonian molasse basins (the Hornelen, Kvamshesten and Solund basins) in western Norway. These include calcite‐, quartz‐ and epidote‐dominated veins. The salinities of fluid inclusions from quartz‐dominated veins in the Hornelen and Kvamshesten basins are close to or slightly higher than those for modern seawater, whereas the fluids from quartz‐ and calcite‐dominated veins in the Solund basin range from seawater values to 20 wt % NaCl equivalent. Minerals such as biotite, amphibole, titanite, chlorite and epidote are abundant in the latter veins, and are important constituents of the authigenic mineral assemblages. A combination of fluid inclusion and petrological data suggest that at least some of the veins formed at depths around 12–14 km. The Cl/Br ratios and the salinity of the fluid inclusions can be explained by interactions with evaporites, implying that the sedimentary environment forming the basin fill had the strongest influence upon low‐grade metamorphic fluid Cl and Br contents. Differences in the Cl/I and Na/Br ratios between the Solund basin and the Hornelen and Kvamshesten basins are best explained by local mass transfer between pore fluids and the surrounding rock matrix during burial and increasing temperatures.     

Fluids,basin analysis,and mineral deposits

Sedimentary basins are the largest structures on the surface of our planet and the most significant sources of energy‐related commodities. With time, sedimentary successions in basins normally are subjected to increasingly intense diagenesis that results in differential evolution of basin hydrology. This hydrologic structure is in turn vitally important in determining how and where deposition of metals may occur. Fluids in all basins originate and flow as a result of sedimentological and tectonic events, so that fluid histories should reflect the control of both lithology and tectonism on ore deposition. Sandstone lithologies, in particular, reflect fluid‐flow events because they are normally the major aquifers in basins. However, early cementation results in occlusion of primary permeability in some facies (diagenetic aquitards) whereas in others, permeability develops due to the dissolution of unstable grains (diagenetic aquifers). Particularly for ore deposits in Precambrian basins, identification of paleohydrologic systems during basin evolution requires the integration of data derived from tectonics, sedimentology, stratigraphy, diagenesis, geochemistry and geology. Assessment of all these data is a prerequisite for the ‘holistic basin analysis’ needed to guide the search for basin‐hosted ores. Recent results from the Paleoproterozoic Mt Isa and McArthur basins in northern Australia serve as a template for exploring for mineral deposits in basins. Basinal fluids were saline, 200–300°C and evolved primarily from meteoric water in the Mt Isa Basin and from seawater in the McArthur Basin during burial to depths of 4–12 km. The δD_fluid and δ¹⁸O_fluid values in these brines were isotopically identical to those in the Zn‐Pb, Cu and U deposits. Geochemical changes of various lithologies during alteration support detrital minerals as the major source of the U, and volcanic units proximal to diagenetic aquifers as a source for the transition metals. Ages of diagenetic phases extracted from aquifer lithologies reveal that fluid migration from the diagenetic aquifers effectively covers the period of formation for U, Zn‐Pb and Cu mineralization, and that the deposits formed in response to tectonic events reflected in the apparent polar wandering path for the area. Sequence stratigraphic analysis and models of fluid flow also indicate that basinal reservoirs were likely sources for the mineralizing fluids. Thus, diagenetic aquifer lithologies were being drained of fluids at the same time as the deposits were forming from fluids that were chemically and isotopically similar, linking diagenesis and fluid events within the basin to the formation of the deposits.     

Observations Of Water Hardness From Southwest Devon Island, Northwest Territories

Over the thaw period of 1970, the hardness in “Jason's Creek” increased systematically. Waters from other sources in the area, sampled in 1969 and 1970, show increases in hardness with distance of travel downslope, from large flows to small flows, and from flowing water to standing water. The highest total hardness values are from vegetated pools of standing water (as also reported by Smith (1969) in Somerset Island). The hardness of water which has had no contact with regolith or bedrock can be sharply differentiated from that of water which has been in such contact. This observation, together with the increase in hardness with distance of travel, may be consequent upon a slow attainment of chemical equilibrium in these arctic waters. It may also be possible to draw a distinction between the solutional work done by snowmeit water and that done by rainwater. The latter has a lower initial pH and, for comparable volumes of discharge, generates higher values of hardness. These preliminary conclusions are to be tested in future stages of this project, which in 1971 and 1972 will be concerned with the hydrology of a larger stream, the river Mecham, near Resolute on Cornwallis Island. Monitoring of the solute content of waters throughout the Mecham basin is an important part of the proposed research.     

Reactive transport and thermo‐hydro‐mechanical coupling in deep sedimentary basins affected by glaciation cycles: model development,verification, and illustrative example

Deep sedimentary basins are complex systems that over long time scales may be affected by numerous interacting processes including groundwater flow, heat and mass transport, water–rock interactions, and mechanical loads induced by ice sheets. Understanding the interactions among these processes is important for the evaluation of the hydrodynamic and geochemical stability of geological CO₂ disposal sites and is equally relevant to the safety evaluation of deep geologic repositories for nuclear waste. We present a reactive transport formulation coupled to thermo‐hydrodynamic and simplified mechanical processes. The formulation determines solution density and ion activities for ionic strengths ranging from freshwater to dense brines based on solution composition and simultaneously accounts for the hydro‐mechanical effects caused by long‐term surface loading during a glaciation cycle. The formulation was implemented into the existing MIN3P reactive transport code (MIN3P‐THCm) and was used to illustrate the processes occurring in a two‐dimensional cross section of a sedimentary basin subjected to a simplified glaciation scenario consisting of a single cycle of ice‐sheet advance and retreat over a time period of 32 500 years. Although the sedimentary basin simulation is illustrative in nature, it captures the key geological features of deep Paleozoic sedimentary basins in North America, including interbedded sandstones, shales, evaporites, and carbonates in the presence of dense brines. Simulated fluid pressures are shown to increase in low hydraulic conductivity units during ice‐sheet advance due to hydro‐mechanical coupling. During the period of deglaciation, Darcy velocities increase in the shallow aquifers and to a lesser extent in deeper high‐hydraulic conductivity units (e.g., sandstones) as a result of the infiltration of glacial meltwater below the warm‐based ice sheet. Dedolomitization is predicted to be the most widespread geochemical process, focused near the freshwater/brine interface. For the illustrative sedimentary basin, the results suggest a high degree of hydrodynamic and geochemical stability.     

Fracture-fill calcite as a record of microbial methanogenesis and fluid migration: a case study from the Devonian Antrim Shale, Michigan Basin

The Devonian Antrim Shale is an organic‐rich, naturally fractured black shale in the Michigan Basin that serves as both a source and reservoir for natural gas. A well‐developed network of major, through‐going vertical fractures controls reservoir‐scale permeability in the Antrim Shale. Many fractures are open, but some are partially sealed by calcite cements that retain isotopic evidence of widespread microbial methanogenesis. Fracture filling calcite displays an unusually broad spectrum of δ¹³C values (+34 to ?41‰ PDB), suggesting that both aerobic and anaerobic bacterial processes were active in the reservoir. Calcites with high δ¹³C values (>+15‰) record cementation of fractures from dissolved inorganic carbon (DIC) generated during bacterial methanogenesis. Calcites with low δ¹³C values (13C values between ?10 and ?30‰ can be attributed to variable organic matter oxidation pathways, methane oxidation, and carbonate rock buffering. Identification of ¹³C‐rich calcite provides unambiguous evidence of biogenic methane generation and may be used to identify gas deposits in other sedimentary basins. It is likely that repeated glacial advances and retreats exposed the Antrim Shale at the basin margin, enhanced meteoric recharge into the shallow part of the fractured reservoir, and initiated multiple episodes of bacterial methanogenesis and methanotrophic activity that were recorded in fracture‐fill cements. The δ¹⁸O values in both formation waters and calcite cements increase with depth in the basin (?12 to ?4‰ SMOW, and +21 to +27‰ PDB, respectively). Most fracture‐fill cements from outcrop samples have δ¹³C values between ?41 and ?15‰ PDB. In contrast, most cement in cores have δ¹³C values between +15 and +34‰ PDB. Radiocarbon and ²³⁰Th dating of fracture‐fill calcite indicates that the calcite formed between 33 and 390 ka, well within the Pleistocene Epoch.     

Modeling thermal convection in supradetachment basins: example from western Norway

The juxtaposition of fault‐bounded sedimentary basins, above crustal‐scale detachments, with warmer exhumed footwalls can lead to thermal convection of the fluids in the sediments. The Devonian basins of western Norway are examples of supradetachment basins that formed in the hanging wall of the Nordfjord‐Sogn Detachment Zone. In the central part of the Hornelen and Kvamshesten basins, the basin‐fill is chiefly represented by fluvial sandstones and minor lacustrine siltstones, whereas the fault margins are dominated by fanglomerates along the detachment contact. Prominent alteration and low‐greenschist facies metamorphic conditions are associated with the peak temperature estimates of the sediments close to the detachment shear zone. Fluid circulation may have been active during the burial of the sediments, and we quantify the potential role played by thermal convection in redistributing heat within the basins. Different models are tested with homogeneous and layered basin‐fill and with material transport properties corresponding to sandstones and siltstones. We found that thermally driven fluid flow is expected in supradetachment basins as a transient process during the exhumation of warmer footwalls. We demonstrate that the fluid flow may have significantly affected the temperature distribution in the upper five kilometers of the Devonian basins of western Norway. The temperature anomaly induced by the flow may locally reach about 80°C. The sedimentary layering formed by sand‐ and siltstones strata does not inhibit fluid circulation at the scale of the basin. The presence of fluid pathways along the detachment has an important impact on the flow and allows an efficient drainage of the basin by channelizing fluids upward along the detachment.     

Fires at Neumark-Nord 2, Germany: An analysis of fire proxies from a Last Interglacial Middle Palaeolithic basin site

Few sites with evidence for fire use are known from the Last Interglacial in Europe. Hearth features are rarely preserved, probably as a result of post-depositional processes. The small postglacial basins (<300?m in diameter) that dominate the sedimentary context of the Eemian record in Europe are high-resolution environmental archives often containing charcoal particles. This case study presents the macroscopic charcoal record of the Neumark-Nord 2 basin, Germany, and the correlation of this record with the distinct find levels of the basin margin that also contain thermally altered archaeological material. Increased charcoal quantities are shown to correspond to phases of hominin presence—a pattern that fits best with recurrent anthropogenic fires within the watershed. This research shows the potential of small basin localities in the reconstruction of local fire histories, where clear archaeological features like hearths are missing.     

EFFECTS OF SOIL LAYERING ON THE CHARACTERISTICS OF BASIN-EDGE INDUCED SURFACE WAVES AND DIFFERENTIAL GROUND MOTION

This paper studies the effects of soil layering in the basin based on the characteristics of basin-edge induced surface waves and associated differential ground motion. Seismic responses of various basin-edge models were simulated using software based on parsimonious finite difference staggered grid approximation of 2.5D eiastodynamic wave equation. Seismic responses of various models with different number of soil/soft rock layers but for a fixed thickness of deposit, fundamental frequency and impedance contrast revealed a decrease of surface wave amplitude with an increase in the number of layers in the basin. Shifting of dominant frequency towards the higher values was obtained with an increase of number of layers. An increase of dispersion of surface waves with an increase of number of soil layers in the basin was observed. A minor increase of Rayleigh wave velocity with an increase of number of soil layers was also obtained, but in the case of Love wave it was almost negligible.

Spectral analysis of the edge-induced surface waves revealed that the anomalous earthquake intensity may arise in a zone of width of 2.5–3.0 km, parallel to basin-edge and at an offset of 0.5–0.7 km from the edge. Maximum horizontal differential ground motion (HDGM) developed by Love wave (≈4.9×10^?2) was more than that of Rayleigh wave (≈9.4×10^?3). Large variation in HDGM caused by the surface waves was obtained with a change in the number of layers in the basin and maximum HDGM was observed when there were only two layers in the basin. It was inferred that the effect of soil layering in the basin was more on the Rayleigh wave as compared to the Love wave. Development of large HDGM near the basin-edge and its dependency on the number of soil layers reveals that basin-edge induced surface waves need special attention during seismic microzonation or seismic hazard prediction.     

Numerical modeling of the origin of calcite mineralization in the Refugio‐Carneros fault,Santa Barbara Basin,California

Many faults in active and exhumed hydrocarbon‐generating basins are characterized by thick deposits of carbonate fault cement of limited vertical and horizontal extent. Based on fluid inclusion and stable isotope characteristics, these deposits have been attributed to upward flow of formation water and hydrocarbons. The present study sought to test this hypothesis by using numerical reactive transport modeling to investigate the origin of calcite cements in the Refugio‐Carneros fault located on the northern flank of the Santa Barbara Basin of southern California. Previous research has shown this calcite to have low δ¹³C values of about ?40 to ?30‰PDB, suggesting that methane‐rich fluids ascended the fault and contributed carbon for the mineralization. Fluid inclusion homogenization temperatures of 80–125°C in the calcite indicate that the fluids also transported significant quantities of heat. Fluid inclusion salinities ranging from fresh water to seawater values and the proximity of the Refugio‐Carneros fault to a zone of groundwater recharge in the Santa Ynez Mountains suggest that calcite precipitation in the fault may have been induced by the oxidation of methane‐rich basinal fluids by infiltrating meteoric fluids descending steeply dipping sedimentary layers on the northern basin flank. This oxidation could have occurred via at least two different mixing scenarios. In the first, overpressures in the central part of the basin may have driven methane‐rich formation waters derived from the Monterey Formation northward toward the basin flanks where they mixed with meteoric water descending from the Santa Ynez Mountains and diverted upward through the Refugio‐Carneros fault. In the second scenario, methane‐rich fluids sourced from deeper Paleogene sediments would have been driven upward by overpressures generated in the fault zones because of deformation, pressure solution, and flow, and released during fault rupture, ultimately mixing with meteoric water at shallow depth. The models in the present study were designed to test this second scenario, and show that in order for the observed fluid inclusion temperatures to be reached within 200 m of the surface, moderate overpressures and high permeabilities were required in the fault zone. Sudden release of overpressure may have been triggered by earthquakes and led to transient pulses of accelerated fluid flow and heat transport along faults, most likely on the order of tens to hundreds of years in duration. While the models also showed that methane‐rich fluids ascending the Refugio‐Carneros fault could be oxidized by meteoric water traversing the Vaqueros Sandstone to form calcite, they raised doubts about whether the length of time and the number of fault pulses needed for mineralization by the fault overpressuring mechanism were too high given existing geologic constraints.     

Thermal convection in faulted extensional sedimentary basins: theoretical results from finite-element modeling

Thermal convection has the potential to be a significant and widespread mechanism of fluid flow, mass transport, and heat transport in rift and other extensional basins. Based on numerical simulation results, large‐scale convection can occur on the scale of the basin thickness, depending on the Rayleigh number for the basin. Our analysis indicates that for syn‐rift and early post‐rift settings with a basin thickness of 5 km, thermal convection can occur for basal heat flows ranging from 80 to 150 mW m^?2, when the vertical hydraulic conductivity is on the order of 1.5 m year^?1 and lower. The convection cells have characteristic wavelengths and flow patterns depending on the thermal and hydraulic boundary conditions. Steeply dipping extensional faults can provide pathways for vertical fluid flow across large thicknesses of basin sediments and can modify the dynamics of thermal convection. The presence of faults perturbs the thermal convective flow pattern and can constrain the size and locations of convection cells. Depending on the spacing of the faults and the hydraulic properties of the faults and basin sediments, the convection cells can be spatially organized to align with adjacent faults. A fault‐bounded cell occurs when one convection cell is constrained to occupy a fault block so that the up‐flow zone converges into one fault zone and the down‐flow zone is centred on the adjacent fault. A fault‐bounded cell pair occurs when two convection cells occupy a fault block with the up‐flow zone located between the faults and the down‐flow zones centred on the adjacent faults or with the reverse pattern of flow. Fault‐bounded cells and cell pairs can be referred to collectively as fault‐bounded convective flow. The flow paths in fault‐bounded convective flow can be lengthened significantly with respect to those of convection cells unperturbed by the presence of faults. The cell pattern and sense of circulation depend on the fault spacing, sediment and fault permeabilities, lithologic heterogeneity, and the basal heat flow. The presence of fault zones also extends the range of conditions for which thermal convection can occur to basin settings with Rayleigh numbers below the critical value for large‐scale convection to occur in a basin without faults. The widespread potential for the occurrence of thermal convection suggests that it may play a role in controlling geological processes in rift basins including the acquisition and deposition of metals by basin fluids, the distribution of diagenetic processes, the temperature field and heat flow, petroleum generation and migration, and the geochemical evolution of basin fluids. Fault‐bounded cells and cell pairs can focus mass and heat transport from longer flow paths into fault zones, and their discharge zones are a particularly favourable setting for the formation of sediment‐hosted ore deposits near the sea floor.     

A Microtremor Survey in the Area Shocked by the ML 5.2 Salò Earthquake (North Italy): An Empirical Approach to Determine the Effects of Ground Motions

In this work, the results of a quick microtremor survey performed in the municipalities situated in the epicentre area of the Ml 5.2 2004 Salò earthquake (North Italy) are presented. The aim of this study is to understand if the large amount of damage caused by the event (about 215 million euros only in the areas near to the epicenter) is correlated more to the local surface geology conditions or to the vulnerability of ancient Italian historical centers.

A preliminary seismic zonation was carried out in 5 villages including about 30 measurements of microtremors analyzed by the Nakamura technique (hereinafter HVNR). The points of measurement were carefully selected considering sites located both near damaged buildings and over different local geology conditions (alluvium deposits, fluvial-glacial deposits, debris fans and rock). In order to strengthen the HVNR results and to evaluate the reliability of the Nakamura analysis, a comparison with spectral ratios calculated on earthquakes (hereinafter HVSR) recorded at the strong motion station of Vobarno was made. In general, the outcomes of the survey highlight a possible correlation between local geology conditions and ground motion amplification for different frequency bands. In order to check if this evidence is linked with the damage, a series of macroseismic intensity values were collected for different zones of the investigated area, and a nonparametric correlation approach was used to establish a possible correlation between damage and ground motion amplification for selected frequency bands. The results show, from a statistical point of view, that in the area surrounding the epicenter of the November 24, 2004 mainshock, the damage pattern is not strongly dependent upon the local surface geology but more correlated to the low quality of the civil structures present in the area, including old buildings of the last century.     

Landscape and Soil Development on Monaro Basalt West of Nimmitabel,New South Wales

Prolonged stability of the southern tableland of NSW, developed on early Tertiary Monaro basalt, is evident from weak landscape dissection and numerous small lakes. However, poorly developed soils and weathered zones are inconsistent with prolonged Cainozoic weathering or formation under climates substantially different to the present. Thin Holocene sediments are also at variance with the sizes of the lake basins. Low depositional landforms, termed ‘lake shadows’, occur on the eastern perimeters of most lakes, and comprise clay pellets blown from basin floors during dry phases. Deflation, dominantly during Quaternary glacial periods, and reactivated today, is responsible for the thin soils and sediment cover. The lake basins are partly solutional and partly deflational features. The modern soil cover reflects the modern climate.     

Maintaining high fluid pressures in older sedimentary basins

High fluid pressures in old geologic basins, where the mechanisms that generate high fluid pressure have ceased to operate, pose the problem of how high fluid pressures are maintained through geologic time. Recent oil and gas exploration reveals that low permeability shales, the source beds for oil and gas, contain large quantities of gas that are now being exploited in many sedimentary basins in North America. No earlier analyses of how to maintain high fluid pressure in older sedimentary basins included a shale bed as a source of adsorbed gas; this is a new conceptual element that will fundamentally change the analysis. Such a large fluid source can compensate for a low rate of bleed off in a dynamic system. If the fluid source is large enough, as the gas within these shale source beds appears to be, there will no appreciable drop in pressure accompanying a low rate of leakage from the basin for long periods. For the dynamic school of basin analysts this may provide the missing piece in the puzzle, explaining how high fluid pressures are maintained for long periods of geologic time in a crust with finite, non-zero permeability. This is a hypothesis which needs to be tested by new basin analyses.     

Observatory validation of Neolithic tells (“Magoules”) in the Thessalian plain,central Greece,using hyperspectral spectroradiometric data

This paper presents the results obtained from field spectroradiometric campaigns over Neolithic tells (“magoules”) located at the Thessalian region in Greece. In each one of the four archaeological sites selected, three sections were carried out using the GER 1500 handheld spectroradiometer. Spectral profiles of the sections and several vegetation indices such as Normalized Difference Vegetation Indices (NDVI) and Simple Ratio (SR) have been examined in this study. This is one of the first times that ground hyperspectral data are evaluated in such context of archaeological research for the spectral characterization of archaeological features. As it was found, ground spectroradiometric measurements can be efficiently used in order to support and validate satellite imagery results for the detection of archaeological sites.     

Conflicts over shared rivers: Resource scarcity or fuzzy boundaries?

Countries that share rivers have a higher risk of military disputes, even when controlling for a range of standard variables from studies of interstate conflict. A study incorporating the length of the land boundary showed that the shared river variable is not just a proxy for a higher degree of interaction opportunity. A weakness of earlier work is that the existing shared rivers data do not distinguish properly between dyads where the rivers run mainly across the boundary and dyads where the shared river runs along the boundary. Dyads with rivers running across the boundary would be expected to give rise to resource scarcity-related conflict, while in dyads where the river forms the boundary conflict may arise because river boundaries are fluid and fuzzy. Using a new dataset on shared water basins and two measures of water scarcity, we test for the relevance of these two scenarios. Shared basins do predict an increased propensity for conflict in a multivariate analysis. However, we find little support for the fuzzy boundary scenario. Support for a scarcity theory of water conflict is somewhat ambiguous. Neither the number of river crossings nor the share of the basin upstream is significant. Dry countries have more conflict, but less so when the basin is large. Drought has no influence. The size of the basin, however, is significantly associated with conflict. Modernization theory receives some support in that development interacted with basin size predicts less conflict, and we find some evidence here for an environmental Kuznets curve. The importance of basin size suggests a possible ‘resource curse’ effect for water resources.     

Geophysical and geochemical evidence of large scale fluid flow within shallow sediments in the eastern Gulf of Mexico,offshore Louisiana

We analyse the fluid flow regime within sediments on the Eastern levee of the modern Mississippi Canyon using 3D seismic data and downhole logging data acquired at Sites U1322 and U1324 during the 2005 Integrated Ocean Drilling Program (IODP) Expedition 308 in the Gulf of Mexico. Sulphate and methane concentrations in pore water show that sulphate–methane transition zone, at 74 and 94 m below seafloor, are amongst the deepest ever found in a sedimentary basin. This is in part due to a basinward fluid flow in a buried turbiditic channel (Blue Unit, 1000 mbsf), which separates sedimentary compartments located below and above this unit, preventing normal upward methane flux to the seafloor. Overpressure in the lower compartment leads to episodic and focused fluid migration through deep conduits that bypass the upper compartment, forming mud volcanoes at the seabed. This may also favour seawater circulation and we interpret the deep sulphate–methane transition zones as a result of high downward sulphate fluxes coming from seawater that are about 5–10 times above those measured in other basins. The results show that geochemical reactions within shallow sediments are dominated by seawater downwelling in the Mars‐Ursa basin, compared to other basins in which the upward fluid flux is controlling methane‐related reactions. This has implications for the occurrence of gas hydrates in the subsurface and is evidence of the active connection between buried sediments and the water column.     

Abnormally pressured beds as barriers to diffusive solute transport in sedimentary basins

Diffusion can drive significant solute transport over millions of years, but ancient brines and large salinity gradients are still observed in deep sedimentary basins. Fluid flow within abnormally pressured beds may prevent diffusive transfer over geologically significant periods, if the abnormally pressured bed is surrounded by normally pressured beds. Analytic solutions based on sediment loading and unloading demonstrate that this effect should be considered in beds with a compressibility exceeding 10^?8 Pa^?1, with a thickness of 100 m or more, or a sedimentation rate exceeding 10^?5 m year^?1. Conditions favourable for our model of abnormally pressured beds appear common in sedimentary basins. Large salinity gradients associated with clay beds have previously been attributed to membrane effects, but flow patterns associated with abnormally pressured beds appear more robust in the presence of heterogeneity and discontinuities than membrane effects. Calculations suggest that thick underpressured shales in the Alberta basin may have allowed ancient evaporatively concentrated brines to be preserved beneath a vigorous topography‐driven flow system over the last 60 My. In the Illinois basin, drained overpressured beds may have limited solute transport across the New Albany shale until approximately 250 Ma. It is unlikely, however, that overpressures could have persisted long enough to explain concentration gradients observed in the modern basin. These gradients may instead reflect relatively recent halite dissolution above the New Albany shale.     

Fluid circulation related to post‐Messinian extension,Thassos Island,North Aegean

In the North Aegean Domain, Thassos Island contains a Plio‐Pleistocene basin controlled by a large‐scale flat‐ramp extensional system with a potential décollement located at depth within a marble unit. Numerous mineralizations associated with normal faults of Plio‐Pleistocene age are the sign of fluid circulation during extension. Two main generations of fluid flow are recognized, related to Plio‐Pleistocene extension. A first circulation under high‐temperature conditions (about 100–200°C) resulted in dolomitization of marbles near the base of the Plio‐Pleistocene basin. The dolomites are characterized by low δ¹⁸O values (down to 11‰ versus Standard Mean Ocean Water). Some cataclastic deformation affected the dolomites. Hydrothermal quartz that crystallized in extension veins above a blind ramp also has low δ¹⁸O values (about 13‰). This shows that high‐temperature fluids moved up from the décollement level toward the surface. A second downward circulation of continental waters at near‐surface temperature is documented by calcite veins in fault zones and at the base of the Plio‐Pleistocene basin. These veins have O isotope values relatively constant at about 23–25‰ and C isotope values intermediate between the high δ¹³C value of the carbonate host rock (about 1–3‰ versus Peedee Belemnite) and the low δ¹³C value of soil‐derived carbon (?10‰). The calcites associated with the oxidative remobilization of primary sulphide Zn–Pb mineralization of Thassos carbonates have comparable O and C isotope compositions. Hot fluids, within the 100–200°C temperature range, have likely contributed to the weakening of the lower marble unit of Thassos and, thus, to the process of décollement.