THE ORIGIN AND GEOCHEMICAL CHARACTERIZATION OF RED OCHRES FROM THE TITO BUSTILLO AND MONTE CASTILLO CAVES (NORTHERN SPAIN)*

Ochres were the most common source materials for pigments used in Palaeolithic rock art paintings. This work analyses the petrographic and geochemical signatures of different ochre samples from outcrops inside Tito Bustillo Cave and the Monte Castillo Caves using the most common techniques (petrography, XRD, SEM–EDS and ICP–MS) in archaeological pigment characterization studies. The results obtained permit the identification and characterization of the different source ochre types and, furthermore, allow the establishment of mineralogical and geochemical proxies for the study of questions related to ochre characterization, formation processes and provenance.     

Applications of integrated geophysical method in archaeological surveys of the ancient Shu ruins

The Jinsha site is one set of excavated ruins of the ancient Shu state, late Neolithic, early Bronze Age. The archaeological survey of the site is especially important for study of Shu culture, because there is hardly any written record of this period. As technology progresses, more and more advanced techniques and equipment have been used to conduct archaeological surveys. In this study, four nondestructive methods of geophysical detection were used to locate ancient relics at the site. The validity of these different types of archaeological detection methods (method of high-density resistivity, induced polarization, multi-frequency electromagnetic, ground-penetrating radar and so on) and techniques were analyzed. And a multi-scale, multi-method detection system to non-destructive detection of cultural relics was established.     

Decorated prehistoric pottery from Castello di Annone (Piedmont,Italy): archaeometric study and pilot comparison with coeval analogous finds

Prehistoric pottery decorated with incisions or impressions filled with white and seldom coloured inlays is well documented in the archaeological literature, but the related in-depth archaeometric studies are sporadic. 43 decorated ceramic shards, dating from the Neolithic to the Bronze Age, and an Iron Age fibula from the archaeological site of Castello di Annone (Piedmont, North-Western Italy) were analysed with FTIR, Raman and XRPD for characterization of the ornamental pigments forming these inlays. Few white components were used as fillers, namely talc and bone ash (hydroxyapatite – Bone White), often as a mixture and seldom accompanied by other pigments (i.e. kaolinite and presumably secondary calcite). Comparison with freshly-heated biogenic hydroxyapatite proved that ancient Bone White pigment was calcined at about 900 °C. Such a process was kept separate from pottery firing as these white mixtures show absence of talc degradation by-products and sporadic presence of kaolinite, implying these ceramics were decorated only after firing in furnace. Actual presence of fluorapatite in bone ash could allow dating with the Fluorine Method, but lack of fluorine detection with SEM-EDS causes such an attempt to be impracticable so far. A pilot comparative study with a restricted but representative group (11) of coeval finds from other sites of Piedmont suggests that while recurrence of talc prevails in Castello di Annone from the Neolithic throughout the Bronze age, massive use of bone ash (Bone White) becomes widespread in the close Iron Age settlements, possibly consequent to a more efficient handling of its production technology.     

In‐situ Sourcing of Hematite Paints on the Surface of Hohokam Red‐on‐Buff Ceramics Using Laser Ablation – Inductively Coupled Plasma – Mass Spectrometry (LA–ICP–MS) and Instrumental Neutron Activation Analysis

Worldwide applications of ochre analysis continue to develop at a rapid pace, highlighting a number of analytical and interpretative issues. As regional source databases continue to grow, researchers have turned to the thornier issues of source allocation. In this study, we utilize LA–ICP–MS and NAA to examine archaeological pigments, ceramic paints and experimental tiles from geological sources and Hohokam ceramics in central Arizona. Archaeological pigments and paint on sherds are successfully source matched based on trace element content, with implications for understanding paint production, sociocultural relations governing trade in pigment and the use of different resource landscapes over time.     

敦煌石窟艺术应用颜料的产地之谜

论述了敦煌石窟彩绘艺术颜料的研究背景、科学分析方法和结果。并根据史料所载以及现代科学的实际勘探考察,结合颜料的科学分析,对敦煌石窟艺术所用的朱砂、铅丹、赭石、绛矾、雄黄、雌黄、密陀僧、金粉、金箔、石绿、铜绿、石青、青金石、群青、铅粉、石膏、白垩、云母、二氧化铅等主要矿物质颜料的化学成分、应用及其产地进行了探索。     

Hematite sources and archaeological ochres from Hohokam and O’odham sites in central Arizona: an experiment in type identification and characterization

The use of ochre is a defining characteristic of populations living in the Sonoran Desert of the American Southwest. Red pigments and paints were used for craft production, bodily adornment, rock art, and in mortuary contexts. Hematite and other iron-oxides are common components of this pigment that frequently appear in the archaeological record in a variety of forms and in various stages of production. Beyond this, very little is known about these materials. This paper describes the collection of potential geological sources of ochre in the Phoenix Basin and presents a methodology for the identification of processed paints. Geological sources samples are characterized using instrumental neutron activation analysis (INAA) and compared to raw materials recovered archaeologically from the Gila River Indian Community reservation. This preliminary study indicates that iron-oxide sources can be distinguished from each other and that artifacts can be matched to these sources, revealing local procurement along the Gila River by Hohokam and O’odham artisans and continuity in use of one source from the prehistoric period to the present.     

Analytical study of Roman and Arabic wall paintings in the Patio De Banderas of Reales Alcazares’ Palace using non-destructive XRD/XRF and complementary techniques

A portable XRD/XRF system and complementary laboratory techniques were employed to improve the knowledge of the procedures used to create Roman and Arabic wall paintings. Integrated physico-chemical investigations were conducted on fragments of artworks collected from the archaeological excavation of the Patio de Banderas in the Reales Alcazares’ Palace of Seville (Spain), and a comparative study on the pigments from both historical periods was performed. As a result, pigments such as vermilion, red ochre, yellow ochre, green earth, Egyptian blue, carbon and phosphor-based black pigments were detected in Roman samples; however, in the Arabic fragments, only haematite was observed. In addition, the size and shape of the particles of the wall paintings were studied with an XRD 2-dimensional detector and SEM-EDX.     

Diffusion in the Studies of the African Past: Reflections From New Archaeological Findings

Diffusionist theories have often been invoked to explain how ancient African cultures were formed and developed. Explanations were either in terms of waves of migrations or by infiltration by people of less African origin or people alleged to have had a high culture. This article provides new evidence for a Neolithic cultural sequence on the islands and coast of East Africa. It proposes that archaeological cultural horizons such as these should be re-examined using a revised diffusionist theory. On this basis, it can be shown that the people who were smelting iron in Sub-Saharan Africa around the first century a.d. were not marauding communities of Bantu peoples with no inclination to settle and build up empires, but of people who were well settled, and had a long history of building stable settlements and trading from Neolithic times.     

PREHISTORIC WALL PAINTINGS: THE CASE OF THE DOMUS DE JANAS NECROPOLIS (SARDINIA,ITALY)*

The Domus de Janas (Home of the Fairies, or Home of the Witches) are Neolithic hypogea located throughout Sardinia (Italy) and decorated with red and black wall paintings. The objective of this study was to define the painting technique through the analytical characterization of the pigments and binding media. Samples of painting film from different graves have been examined by means of various analytical techniques. XRD, Raman and SEM–EDX analyses identified the red and black pigments respectively as red ochre rich in hematite and carbon black, while GC–MS analyses characterized the organic binder as egg.     

Characterization of a black residue in a decorated Neolithic pot from Dikili Tash,Greece:an unexpected result

A black depositional layer on the inner surface of a Neolithic carinated vessel from the archaeological site of Dikili Tash in Eastern Macedonia was examined scientifically. The layer was initially considered as decomposed organic matter and interest was focused on identifying the original organic contents. The scientific investigation, which included FTIR spectroscopy, analytical SEM examination and optical microscopy, revealed that the black substance was not organic but a pure iron oxide layer deposited on the vessel’s inner surface, and reduced in places to black iron oxides, during a destructive fire. The conclusion is that this layer represents the remnants of the vessel’s original content, which was a red hematite pigment. This unexpected find provides, for the first time, a missing link in the evidence of pigments used in Neolithic times, previously attested to only by finished products.     

Reassessment and new data on the diachronic relationship of Thassos Island with its indigenous metal resources: a review

The extraction of mineral ores and its associated metal production has been a persistent element of the economy on Thassos Island since prehistoric times. As early as the Upper Palaeolithic, around 20,000 years ago, ochre had been mined and used for painting, while early silver extraction is attested during the Final Neolithic (early fourth millennium BC). Copper production and alloying becomes an important activity in the coastal settlements of the island during the third and second millennia. The inception of iron metallurgy has been seen in association with copper smelting as confirmed by analyses on slag found in Early Iron Age upland cemeteries. With the arrival of the Greek colonists around 650 BC, intensification in silver and gold extraction became paramount for further economic expansion. This deep history in the use of Thassian metals is being reviewed based on archaeological findings and archaeometallurgical research of the last three decades, while new analytical data on Early Bronze Age copper smelting at Aghios Antonios are being presented.     

Elemental analysis and characterization of ochre sources from Southern Arizona

Iron oxides and other associated minerals (ochre) were widely used in ancient times, however, the use and procurement of these materials is not well understood and there has been little research on the elemental characterization of the material compared to other artifact classes. To assess the possibility of identifying ochre differences between locations, the original potential geological sources should be thoroughly characterized. This paper describes the collection of potential geologic sources of ochre in the Tucson basin of Arizona, sampling of those sources, instrumental neutron activation analysis (INAA), and subsequent multivariate analysis of the data. This paper has several goals, including characterizing geochemical trends within and between ochre sources, identifying the important elements in geochemical characterization of ochre, and establishing a database for further investigations. This preliminary study indicates that the inter- and intra-source variations in geological sources of ochre in the Tucson basin region can be differentiated. Future analysis of iron oxide artifacts will be performed to examine correlations between artifacts and sources and provide a basis for further deductions concerning ancient ochre procurement.     

One Colour, (at Least) Two Minerals: A Study of Mulberry Rock Art Pigment and a Mulberry Pigment ‘Quarry’ from the Kimberley,Northern Australia

Distinctive mulberry paintings found in northern Australia, particularly those of the Kimberley region, have been argued to represent some of the oldest surviving rock art on the continent. Significant research efforts continue to focus on resolving the age of these motifs, but comparatively little attention has been given to understanding their physical composition and potential source(s). In a pilot investigation, we conclude that (at least) two mineralogically distinct mulberry pigments occur in Gwion motifs and demonstrate that their major components can be indicatively chemically differentiated, non‐invasively. Characterization of a ‘quarried’ mulberry ochre source demonstrates that these pigments occur locally as natural minerals.     

Economic Change in the Prehistoric Hexi Corridor (4800–2200 bp), North‐West China

It is widely known that the Hexi Corridor in North‐West China lies at a hub of trans‐Eurasian cultural exchange. Its role became increasingly important during the late prehistoric period, particularly as the ancient Silk Road began to be used. While the profound transformation of local cultural characteristics in the late Neolithic and the Bronze Age is well documented, the detailed economic dynamics of cultural evolution have not yet been clearly illustrated. In this paper, we report on significant new zooarchaeological and faunal isotopic data from the Neolithic and Bronze Age sites in the Hexi Corridor. The primary objective is to systematically reconstruct the prehistoric economic context of this area by combining these new data with previous archaeological studies and radiocarbon dates. We argue that the primary economic activities of local inhabitants changed dramatically in the prehistoric Hexi Corridor. This was marked by agricultural production at c.4800–4000 bp , agro‐pastoral production at c.4000–3000 bp and animal husbandry at c.3000–2200 bp , respectively. The major subsistence strategies of these three periods show considerable variation. It is very likely that these transformations of economic patterns in the prehistoric Hexi Corridor were primarily triggered by transcontinental cultural exchange and, to a lesser extent, by climate change.     

PREHISTORIC ANTIGORITE PROCUREMENT IN CYPRUS

The Canadian Palaipaphos Survey Project in the Paphos district of south-western Cyprus investigated extensive areas of the Esouzas, Xero, and Dhiarizos River valleys, locating hundreds of archaeological sites spanning the nine millennia from the aceramic Neolithic period to the recent era (Rupp et al. s1984 and 1986). Antigorite artefacts were recovered from Neolithic, Chalcolithic and Bronze Age settlements. A number of geological sources have been proposed for the material from which these artefacts were manufactured. The results of neutron activation analyses of archaeological and geological specimens suggest that the Troodos ophiolite/Kouris River secondary deposits were the primary source of antigorite for the prehistoric populations of the study area. Extreme care must be taken when analysing antigorite samples to avoid material with grey-black magnetite-rich inclusions. since these have radically different trace element chemistries from the pure antigorite.     

陕西安康紫阳北五省会馆壁画颜料分析研究

陕西安康紫阳北五省会馆壁画是目前陕西省境内发现的最大的一处建筑壁画,为了解其颜料组成,本工作采用X射线荧光、偏光显微镜、X射线衍射、激光显微拉曼光谱及扫描电镜能谱分析相结合的分析方法,对颜料样品进行了分析。结果表明,北五省会馆壁画除正殿发现一处红色染料外,其他均为无机颜料;红色颜料主要是铅丹、朱砂、铁红;绿色颜料为氯铜矿、石绿、斜氯铜矿;蓝色颜料的主要成分是普鲁士蓝、smalt、石青;黄色颜料为雌黄、铁黄;褐色颜料的主要成分是铁红及铅丹的变色产物二氧化铅;黑色为炭黑;白色颜料主要是铅白,且多使用铅白作为调色颜料。研究结果对于了解清代民间壁画的制作工艺,丰富对陕西建筑壁画的认识具有重要意义。     

新中国成立以来河南新石器时代考古发现与研究

本文简要回顾了新中国成立60多年来河南新石器时代文化遗存的主要调查、发掘工作,对新石器时代早期的李家沟文化、中期的裴李岗文化和晚期的仰韶文化、大汶口文化、屈家岭文化等的主要考古发现和基本研究历程、重要研究成果进行了概述,有些方面还略作评议。在总结以往发现与研究取得的巨大成就的同时,指出今后既要继续重视基础性的文化研究,又要更加广泛深入地运用聚落考古等方法,加强对古代社会多方面、多角度的研究,以期河南新石器时代考古获得新的更大的发展。     

The Source of Iron‐Oxide Pigments Used in Pecos River Style Rock Paints

The likely sources of iron‐oxide pigments used in prehistoric rock paintings in the Lower Pecos Archaeological Region were identified on the basis of chemical fingerprinting using LA–ICP–MS. The chemical signatures of 13 red rock paint samples collected from two south‐west Texas sites were compared with three potential source materials (ochre, siltstone and rhyolite), and two pigment cakes (crayons) that were excavated near the sampling sites. The significant chemical similarities between the paint and siltstones suggest that siltstone was used as the source of the colour. The overlapping chemical signatures for one of the pigment cakes and siltstone further suggests that some of the prehistoric people inhabiting the area 3000–4000 years ago had acquired the skills to extract iron oxide from siltstone and process it into paint pigments.     

Deficiencies and challenges in the study of ancient tuberculosis DNA

We explore the standards of research and reporting needed to justify the destructive analysis of archaeological human bone for biomolecular studies of ancient tuberculosis (TB). Acceptable standards in osteological interpretation have been met in some biomolecular papers, but there are also cases where insufficient care has been taken in distinguishing between pathognomonic lesions and those that are ‘consistent with’ a diagnosis of TB. Some biomolecular studies have failed to recognize that archaeological bones might be contaminated with environmental mycobacteria whose DNA could give rise to false positives in polymerase chain reactions directed at members of the Mycobacterium tuberculosis complex. The difficulties of applying spoligotyping to ancient DNA have also been underestimated and conclusions drawn from such analyses are often weakly supported. Assumptions that mycobacterial DNA preserves better than human DNA, and that contamination with modern DNA is less of a problem, has led in some cases to a laxity in research standards with insufficient attention paid to the need to authenticate ancient DNA results. We illustrate our concerns by reference to a recent paper reporting biomolecular detection of ancient TB DNA in skeletons from the eastern Mediterranean Neolithic settlement of Atlit-Yam. We are unconvinced that the skeletal evidence presented in this paper gives sufficient indication of TB to warrant destructive analysis, and we are concerned that during the biomolecular part of the project inadequate attention was paid to the possibility that results might be due to laboratory cross-contamination or to amplification of environmental mycobacterial DNA present in the bones.