Differentiation of ceramic chemical element composition and vessel morphology at a pottery production center in Roman Galilee

Cooking pots and bowls from two production locations ca. 200 m from each other at the rural settlement of Kefar Hananya in Roman Galilee were compared employing chemical element composition and vessel-shape analyses. Splits of each pulverized sample, all of which were taken from ceramic wasters, were analyzed by both instrumental neutron activation and high-precision X-ray fluorescence analyses, and computerized vessel-shape analysis was employed for morphological analysis of the same vessel forms from each location. Several statistical techniques (bivariate plots, principal component analysis, cluster analysis and discriminant analysis) were used for analyzing the resultant data. It was found that both the cooking pots and bowls made at each location could be distinguished by employing either chemical composition or morphological analysis. The implications of this work, with regard to investigating both production and consumption sites, and for pottery provenance studies, are discussed. The findings suggest that these analytical techniques can be useful as an aid for chronological differentiations of archaeological pottery.     

Lead isotopic analyses of copper ores in the Early Bronze Age central Hexi Corridor,north-west China

This paper explores the possible provenance of ores employed for metallurgical production during the Early Bronze Age in the central Hexi Corridor of north-west China. In total, 78 pieces of copper (Cu) ore samples were collected from five Early Bronze Age sites and one Cu deposit site (the Beishantang Cu deposit) in the Heihe River region of the central corridor. These sites were dated to the late Machang (4100–4000 bp ), Xichengyi (4000–3700 bp ), Qijia (4000–3600 bp ) and Siba (3700–3400 bp ) cultures. After comparing with published lead (Pb) isotopic data from other possible Cu deposits in north-west China, the results show that the Cu ores collected from the Early Bronze Age sites were most likely derived from the adjacent Beishan Cu deposit. More intriguingly, for the first time in Hexi Corridor, a dozen Cu ores were discovered containing highly radiogenic Pb. Though fundamentally different from those in the Central Plains, they illustrate a possible new type of Cu used in Bronze Age western China, and the first-hand materials are significant for further understanding the provenance of raw metals for metallurgical production in the prehistoric Hexi Corridor.     

Production centers of cooking pots in Iron Age Judah

This paper will present and discuss a multifaceted research project dealing with the production of cooking pots during the Iron Age II (ca. 1,000–586 BCE) Judah (modern Israel). In particular the new compositional analysis of 541 cooking vessels from 11 sites in Iron Age Judah will be presented. The study employs petrographic and chemical (NAA) analysis. The results of this ongoing research have already produced interesting information about production centers and movements of cooking pots in Iron Age II Judah. Apparently, the vast majority of the cooking pots sampled were made of a similar type of clay, related to terra rossa soil. This is true also for sites in the northern Negev and Judean Desert, where the type of soil was not available in the region of the sites. Furthermore, many of the cooking pots distributed around Judah were made in Jerusalem according to a well-located chemical profile (JleB). Other groups may represent Judean Shephelah production centers as the Lachish area as well as production centers in southern Israel or ancient Edom. The implications of the importation patterns of cooking pots by peripheral Judean sites will be discussed.     

商周时期南北方铜矿开采技术比较研究--以鄂赣交界地带和辽西地区为例

本文选取了鄂赣交界地带和辽西地区的4座晚商至西周早中期的古铜矿遗址,分别从探矿技术、开采技术、开采工具、相关配套设施和选矿技术等方面对南北两区域古铜矿的开采技术进行全面比较,并试图从两地的自然环境、矿物品质以及生产组织方式等不同方面来解释出现这种差异的原因。     

A new perspective on Late Holocene social interaction in Northwest Alaska: results of a preliminary ceramic sourcing study

This research examines the evidence for prehistoric ceramic exchange networks over the last 2000 years in northwest Alaska through the use of neutron activation analysis of ceramic artifacts. Results from ceramic analysis on eight coastal and inland archaeological sites identified three source macrogroups and three associated subgroups. Clay source diversity and shared source macrogroups between geographically distant sites suggest the use of multiple sources and/or the movement of pots between production locales, mirroring related patterns in pottery stylistic data. Although additional analytical work is needed to fully understand the changing character of clay procurement and ceramic distribution across this time period, this study provides exploratory data on past ceramic production and distribution that hints at changes in exchange and territoriality in northwest Alaska during the late Holocene.     

‘DE CAERIMONIAE’ TECHNOLOGICAL CHOICES IN COPPER‐SMELTING FURNACE DESIGN AT EARLY BRONZE AGE CHRYSOKAMINO,CRETE*

The excavation of a number of Early Bronze Age sites in the Aegean has recovered perforated ceramic fragments. Archaeometallurgical analysis of slag adhering to these fragments indicates that they are the remains of copper‐smelting furnaces. Despite compelling analytical data supporting this identification, no attempt has been made, thus far, to establish how these unusual furnaces may have operated. The use of perforations is poorly understood and can be considered a counter‐intuitive solution for the reduction of oxidic copper ores. The experiments reported here explore the possible technological choices made by the ancient metalworkers of Chrysokamino to ensure the effective reduction of copper minerals. Temperature data and slag samples were obtained to ascertain the technical performance of the furnace structure with, and without, perforations. Possible reasons are given for the use of a perforated design, and the implications of such technological choices are considered.     

Bronze production in Southwestern Iberian Peninsula: the Late Bronze Age metallurgical workshop from Entre Águas 5 (Portugal)

Archaeological works at Entre Águas 5 (Portugal) uncovered a seasonal LBA settlement with significant metallurgical remains (crucibles, moulds, prills and a tuyere) related to bronze production. Radiocarbon dating ascribes an occupation period (10th–9th century BC) previous to Phoenician establishment in Southwestern Iberia. In spite of the proliferation of metal artefacts during LBA, the production of bronze alloys is still poorly understood. An integrated analytical approach (EDXRF, optical microscopy, SEM–EDS, micro-EDXRF and Vickers microhardness) was used to characterise this metallurgy. Crucibles show immature slags with copious copper nodules, displaying variable tin content (c. 0–26 wt.%), low iron amount (<0.05 wt.%) and different cooling rates. Certain evidences point to direct reduction of oxide copper ores with cassiterite. Scorched moulds with residues of copper and tin indicate local casting of artefacts. Finished artefacts also recovered at the site have an analogous composition (bronze with ∼10 wt.% Sn and low amounts of Pb, As and Fe) typical of coeval metallurgy in SW Iberia. Some artefacts reveal a relationship between typology and composition or manufacture: a higher tin content for a golden coloured ring or absence of the final hammering for a bracelet. An uncommon gilded nail (gold foil c. 140 μm thick; 11.6 wt.% Ag; ∼1 wt.% Cu) attests the existence of evolved prestige typologies. This LBA settlement discloses a domestic metallurgy whose main features are typical in Iberian Peninsula. Finally, it should be emphasized that a collection as comprehensive and representative of a single workshop has rarely been studied, enabling a deeper understanding of the various operations involving the bronze production and manufacture of artefacts.     

Wild or domesticated: DNA analysis of ancient water buffalo remains from north China

Recent zooarchaeological studies on water buffalo (Bubalus sp.) remains from China and south Asia question the traditional view that water buffalo were first domesticated in Neolithic China over 7000 years ago. The results from several recent population genetic studies of modern domesticated buffalo (Bubalus bubalis) are not consistent with each other, placing the original center of buffalo's domestication in south Asia, southeast Asia, or China. This paper reports a study using an ancient DNA approach to analyze water buffalo remains from Neolithic sites in north China to investigate their affinities with modern domesticated water buffalo, and to shed light on the origin of modern domesticated water buffalo in China.A 169 bp fragment of D-loop mitochondrial DNA was successfully amplified and verified for 13 of 24 bone samples obtained from seven archaeological sites along the Wei River valley in Shaanxi Province, China. The bone samples which yielded positive DNA can be dated to 8000–3600 cal. BP. The phylogenetic analysis of the obtained DNA sequences along with modern water buffalo sequences indicated that the ancient water buffalos were not the direct ancestor of modern domesticated water buffalo. However, the phylogenetic analysis, along with BLAST searches of these ancient DNA sequences, did demonstrate their relatedness to water buffalo more so than to any other bovid species, confirming the existence of indigenous wild (but now extinct) water buffalo species (B. mephistopheles) in ancient China.The DNA analysis of these ancient remains failed to establish direct links between modern domesticated water buffalo (B. bubalis) and indigenous water buffalo (B. mephistopheles) from ancient China. If further DNA studies of more ancient remains from other regions of China confirm the observation of solely indigenous water buffalo species in ancient China, it would suggest modern water buffalo might not have been first domesticated in China.     

Paint It Black: The Rise of Metallurgy in the Balkans

This paper integrates archaeological, material, microstructural and compositional data of c. 7,000 years old metallurgical production evidence with the aim to address the knowledge of the world’s earliest metalworkers. The main focus is placed on copper minerals, ores, slags, slagged sherds and metal droplets coming from four Vin?a culture settlements in Serbia and Bosnia and Herzegovina: Belovode, Plo?nik, Vin?a and Gornja Tuzla, all dated between c. 5400 and 4400 BC. Chemical study of copper minerals throughout all sites points at striking uniformity in selecting black and green minerals from the early days of the settlements’ occupation, some of which predate the metal smelting events. Microstructural examination of metal production debris showed convincing technological similarity throughout c. six centuries of copper making in the studied sites, as well as a consistent choice of black and green ores for metal extraction. We argue that black and green ores were intentionally selected as ingredients for the metal smelting ‘recipe’ in the early stages of Balkan metallurgy based on the knowledge related to their characteristic visual aspects. This finding demonstrates how important the adequate combination of colours was for the early copper metalworkers and suggests a unique technological trajectory for the evolution of metallurgy in this part of the world. It also illustrates the capacity that micro-research carries in addressing the how and why of the emergence of metallurgy, and outlines a methodology for future studies of early metallurgies worldwide.     

2003巴东故县坪遗址发掘简报

故县坪遗址发现有汉至六朝时期和明清时期的大批遗迹和遗物,其中汉至六朝时期的灰坑遗迹中出土了大量的石器和陶器,器形主要有石凿、石环、石饼、陶瓮、陶罐等,是恩施自治州内陆腹地保存最好的古文化遗址.     

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPIC AND ISOTOPIC ANALYSIS OF CARBONIZED RESIDUES FROM SUBARCTIC CANADIAN PREHISTORIC POTTERY

Late prehistoric pottery is found in abundance at archaeological sites around Southern Indian Lake. Black residues, found on the two dominant vessel forms, flat plates and round pots, are presumed to be the remains of prehistoric meals. ¹³C cross-polarization magic-angle-spinning nuclear magnetic resonance spectroscopy (CPMAS NMR) and¹³C and¹⁵ N isotopic ratios and C/N ratios are used to reconstruct prehistoric diet and to shed light on possible uses for the plates. Samples of foods were cooked in clay pots, on a wood fire, to simulate the conditions of burning that could have produced the residue. Decomposition of carbohydrates, protein, and fat during cooking is studied with ¹³C CPMAS NMR, and the effect of cooking on isotopic and C/N ratios documented. Predominantly fish and fat were cooked in the pots, whereas the residues from plates contain a greater proportion of fat and could have been used as frying pans or possibly as fat-burning lamps placed on the ashes of a wood fire.     

营城子汉墓出土玻璃耳珰的化学成分与制作工艺研究

营城子汉墓位于辽宁省大连市甘井子区,是我国东北地区一处重要的大型汉墓群。营城子汉墓出土了一批玻璃耳珰,为探讨其成型工艺及来源,采用超景深显微系统进行了表面形貌观察,初步认为是模铸成型,并经过打磨。采用便携式X射线荧光光谱仪(XRF)进行了化学成分分析,结果显示,它们分属铅钡硅酸盐和钾硅酸盐玻璃系统,一件由Cu²⁺着色,其余主要由Co²⁺着色。其为我国自制,所用钴料来源相同,钴料的锰钴比特征与国产钴土矿的类似。并对营城子汉墓出土玻璃耳珰造型与化学成分体系间的关系进行了分析,对玻璃耳珰制作模式进行了初步探讨,进一步加深了对我国古代玻璃耳珰制作与传播的认识。     

Continuity and change in pottery manufacture between the early and middle Neolithic of Romania

This paper provides the first scientific comparison between pottery production in the early Neolithic Star?evo-Cri? and middle Neolithic Vin?a cultures of south-eastern Europe. The author investigates whether Star?evo-Cri? pottery technology was transmitted to the succeeding Vin?a culture, which in other respects was more complex and technologically advanced. The study compares pottery production at two sites, in different regions of Romania, which were occupied in both periods. Samples of 102 pots from the Star?evo-Cri? and Vin?a phases at Par?a, located in Romanian Banat, and Miercurea Sibiului Petri? in Transylvania, were analysed petrographically and geochemically. There are only minor differences found in the pottery technology between the two sites within each phase, but there were significant changes in pottery technology between the Star?evo-Cri? and Vin?a cultures. These changes are more subtle than might have been expected, however, given the rapid developments in other aspects of material culture.     

New data and new issues for the study of origin of rice agriculture in China

China was one of the major centers for the origin of agriculture in the world. The origins of agriculture in China, especially the origin of rice agriculture, made a significant contribution not only to the occurrence of Chinese civilization but also to the development of world history. Recently, the study on the origin of rice agriculture has attracted the attention of the academic community due to the dramatic development of archaeobotanical research in China. In recent years, the flotation technique has widely implemented in archaeological excavations in China. As the result, a tremendous amount of plant remains have been recovered from archaeological sites, including those much related to the study of early rice agriculture. The new data provide direct archaeological evidence for, and raise some new issues about, the origin of rice agriculture in China. For example, the rice remains from the Shangshan site, dated to ca. 10,000 cal. B.P., suggest the beginning of rice cultivation regardless of whether that rice was domesticated or not. The quantitative analysis of plant remains recovered by floatation from the Jiahu site, dated to ca. 8,000 cal. B.P., revealed that the subsistence of the Jiahu people mainly relied on fishing/hunting/gathering, while the products of rice cultivation and animal husbandry were only a supplement to their diet. The ongoing excavation, with floatation and water-sieving, at the Tianluoshan site, dated to 6,000 to 7,000 cal. B.P., suggests that rice farming, though important, was only part of a broader subsistence pattern of the Hemudu Culture, and rice domestication culminated after 6,500 B.P and the beginning of rice domestication remain unclear.     

Archaeometric characterisation of coarse and painted fine ware from <Emphasis Type="Italic">Posta Crusta</Emphasis> (Foggia,Italy): technology and provenance

Coarse and painted fine wares from the Late Antique residential complex of Posta Crusta (Lucera, Foggia, Italy) have been here investigated. The ceramic characterisation was our main concern; even so, the provenance and the production technology have been further investigated, focusing on both ceramic bodies and coatings. Optical microscopy, scanning electron microscopy and a set of bulk chemical analyses (inductively coupled plasma optical emission spectrometry, inductively coupled plasma mass spectrometry, instrumental neutron activation and X-ray fluorescence) were used for the characterisation of 44 samples. Chemical and mineralogical data here obtained were compared with results previously achieved on San Giusto local production, in order to distinguish production areas and identify possible exchanges. As for coarse wares, the characterisation of Posta Crusta pottery shed new light for the reconstruction of the production/distribution framework of this part of northern Apulia. The following trends can be identified: (1) pots from Posta Crusta and San Giusto settlement that can be referred to a single production site, likely located in the nearby territory of one of this two sites; (2) pots from San Giusto kiln exported to Posta Crusta; (3) pots of unknown origin but compatible with the northern Apulian area. Furthermore, it was possible to verify that all Posta Crusta ceramics used the alluvial deposits widely outcropping in northern Apulia as received. As for painted fine wares, Posta Crusta samples enucleated a distinct and homogenous group, including six samples from San Giusto. This result is highly encouraging as it provides the clear evidence of a production group, although it is not possible to refer it to a precise locality. The marine deposits outcropping in northern Apulia can have been surely exploited for raw materials supply. Coatings texture seems to suggest two different ways of application: immersion and painting.     

Remarks on Early Iron Age Burial Sites from Southern Cameroon

For the first time, graves dating to the Early Iron Age between 2000 BP and 1700 BP have been discovered in the southern Cameroonian rain forest. The features in question, from the sites of Akonétye and Campo, were almost identically furnished with iron objects and ceramic pots. Other features with more or less corresponding finds have been discovered at Mouanko–Lobethal, Mouanko–Epolo, Kribi–Mpoengu, and Yaoundé–Obobogo. The spatial distribution of these sites and their near synchronous dating suggest that a particular burial rite was practiced over a considerable area of southern Cameroon during the Early Iron Age.     

Prehistoric copper production and technological reproduction in the Khao Wong Prachan Valley of Central Thailand

This paper concerns the identification and explanation of change in prehistoric extractive metallurgical behaviour in the Iron Age Khao Wong Prachan Valley of central Thailand. This metallurgical complex is amongst the largest in Eurasia and constitutes Southeast Asia's only documented pre-modern copper-smelting evidence. The two Iron Age smelting sites investigated, Non Pa Wai (NPW) and Nil Kham Haeng (NKH), provide a sequence of metallurgical consumption and production evidence from c. 500 BCE to c. 500 CE. The enormous quantity of industrial waste at these sites suggests they were probably major copper supply nodes within ancient Southeast Asian metal exchange networks. Seventy-six excavated samples of mineral, technical ceramic and slag from NPW and NKH were analysed in hand specimen, microstructurally by reflected-light microscopy and scanning electron microscopy and chemically by polarising energy-dispersive X-ray fluorescence spectrometry and scanning electron microscopy with energy-dispersive X-ray fluorescence spectrometry. The analytical data were used to generate detailed technological reconstructions of copper-smelting behaviour at the two sites, which were refined by a programme of field experimentation. Results indicate an approximately 1,000-year trend of Valley copper smelters' improving technical proficiency from what may be an experimental phase of production in the mid-first millennium BCE. This amelioration in production was accompanied by a substantial increase in the human effort of copper extraction. This shift in local ‘metallurgical ethos’ is interpreted as a response to rising regional demand for copper in late prehistory.     

Smalt production in the Ore Mountains: Characterization of samples related to the production of blue pigment in Bohemia

The study deals with the chemical composition of samples related to the production of a blue pigment/smalt. The samples examined come from the regions of Soví huť and Horní Blatná (north-west Bohemia) dating to the 16th and 17th centuries. These locations are often mentioned in relation to the discoverer of smalt production technology: Christopher Schürer. The aim of the study is to evaluate the chemical composition of samples from both localities as well as with respect to the ores occurring in the given regions. The samples can be divided into two basic groups. The first clearly represents smalt (potassium glass coloured with cobalt), while the second apparently constitutes the samples of the so-called ‘speiss’ (an aluminosilicate mass with metallic compounds). The analysis of the smalt confirmed the representation of minor elements bismuth and nickel (always) and uranium and molybdenum (rarely), which are found in Co ores from the Ore Mountains. The paper is the first to present the composition of actual blue pigment finds originating directly from the production sites, while the available literature has so far only reported the results of analyses of the pigments already used when referring to the Ore Mountains.     

Precipitation of lead–zinc ores in the Mississippi Valley‐type deposit at Trèves,Cévennes region of southern France

The Trèves zinc–lead deposit is one of several Mississippi Valley‐type (MVT) deposits in the Cévennes region of southern France. Fluid inclusion studies show that the ore was deposited at temperatures between approximately 80 and 150°C from a brine that derived its salinity mainly from the evaporation of seawater past halite saturation. Lead isotope studies suggest that the metals were extracted from local basement rocks. Sulfur isotope data and studies of organic matter indicate that the reduced sulfur in the ores was derived from the reduction of Mesozoic marine sulfate by thermochemical sulfate reduction or bacterially mediated processes at a different time or place from ore deposition. The large range of δ³⁴S values determined for the minerals in the deposit (12.2–19.2‰ for barite, 3.8–13.8‰ for sphalerite and galena, and 8.7 to ?21.2‰ for pyrite), are best explained by the mixing of fluids containing different sources of sulfur. Geochemical reaction path calculations, based on quantitative fluid inclusion data and constrained by field observations, were used to evaluate possible precipitation mechanisms. The most important precipitation mechanism was probably the mixing of fluids containing different metal and reduced sulfur contents. Cooling, dilution, and changes in pH of the ore fluid probably played a minor role in the precipitation of ores. The optimum results that produced the most metal sulfide deposition with the least amount of fluid was the mixing of a fluid containing low amounts of reduced sulfur with a sulfur‐rich, metal poor fluid. In this scenario, large amounts of sphalerite and galena are precipitated, together with smaller quantities of pyrite precipitated and dolomite dissolved. The relative amounts of metal precipitated and dolomite dissolved in this scenario agree with field observations that show only minor dolomite dissolution during ore deposition. The modeling results demonstrate the important control of the reduced sulfur concentration on the Zn and Pb transport capacity of the ore fluid and the volumes of fluid required to form the deposit. The studies of the Trèves ores provide insights into the ore‐forming processes of a typical MVT deposit in the Cévennes region. However, the extent to which these processes can be extrapolated to other MVT deposits in the Cévennes region is problematic. Nevertheless, the evidence for the extensive migration of fluids in the basement and sedimentary cover rocks in the Cévennes region suggests that the ore forming processes for the Trèves deposit must be considered equally viable possibilities for the numerous fault‐controlled and mineralogically similar MVT deposits in the Cévennes region.     

Pottery production and distribution in prehistoric Bronze Age Cyprus. An application of pXRF analysis

Portable X-ray Fluorescence (pXRF) analysis of over 400 samples of Early and Middle Bronze Age Cypriot pottery from four widely separated sites identifies both local and non-local products at each. A series of analyses of sub-sets of the data highlights differences in the clays used at each site and for some distinctive types and wares. When assessed in the context of general typological, technological and stylistic factors these variations provide the basis for considering patterns of local production and inter-regional relationships across the island. Although the great majority of pots were locally made, particular wares and shapes were brought in from elsewhere. For some sites finer, more highly decorated vessels are mostly imports, but at others both simpler and more complex vessels were made of the same local clays. While small juglets or flasks may have been containers for transporting small quantities of rare substances, larger vessels are likely to have held less precious material. Open vessels, especially small bowls – some of which are plain, utilitarian items – represent another aspect of social behaviour and inter-regional relationships.