The archaeology of radiocarbon accelerator dating

Accelerator mass spectrometry (AMS) allows radiocarbon dating to be carried out by direct counting of¹⁴C atoms, rather than the conventional counting of radioactive disintegrations. The result is that samples up to 1000 times smaller can be handled. The approach was tested in principle by 1977 and for archaeological operation by 1983. More than 2000 samples per year are now being dated worldwide. The machines can now operate to about ± 80 years or better. Dates older than 40,000 years have not yet been achieved, but the ability to use small samples has already had considerable impact on dating the period 10,000–30,000 years ago. Bone is an ideal material for the new technique, since amino acids can normally be isolated and purified from gram-size samples. Studies of the origins of domestication are aided by the dating of individual grains and seeds. Because small samples can be mobile in the soil, careful sample selection strategies and procedures are required. The full impact of the technique can be assessed only through the rapid and comprehensive publication of archaeological results.     

Subterranean transport and deposition of quartz by ants in sandy sites relevant to age overestimation in optical luminescence dating

An artificial layered sandy site was created using a combination of native sand and colored sand (3 parts native uncolored quartz, 1 part colored quartz) in Apalachicola National Forest near Tallahassee, Florida. Twelve layers of sand, each 1 by 1 m in horizontal extent by 10 cm in thickness were emplaced to a depth of 2 m followed by implantation at the surface of a Florida harvester ant (Pogonomymrex badius) colony (the lower two layers were 50 cm thick). The colony excavated a nest, and after 7 months, the sand layers were excavated to the base to test the hypothesis that sand grains were moved upward within the ant nest without reaching the surface. The ants penetrated 11 of the 12 colored layers reaching a depth of 130 cm. Thirty nine sticky-acetate peels of ant chamber floors were collected and colored sand grains were counted under a microscope. More than 16,000 grains were identified in layers that did not originally host them. Of these, more than 80% were unambiguously moved upward. This means that possibly as many as 54,000 upwardly mobile grains were present (ratio of 3:1 uncolored to colored). In relation to optical luminescence (OSL) dating, this means that grains that would not have been optically zeroed by transport to the surface (defined here as subterranean-transported) were present in abundance, and that if the site was ancient, there would have been found many grains that were older than the layers they presently reside in, even if only one colony of harvester ants had disturbed the layers. This is in addition to the fact that backfilling of chambers and tunnels may contribute even more significantly to the presence of a subterranean-transported component of an OSL sample. We conclude that ants can significantly affect the age distributions in sandy archaeological sites. Multiple examples of such disturbances have been documented in the literature. Most relevant to our results are recent studies of the OSL chronology of Pre-Clovis-age and Palaeoindian age archaeological sites in sandy environments in North America that may have been compromised by ant bioturbation of quartz sand grains. Here we have examined in detail the potential effects of one episode of ant nest-building on the age overestimation of affected sediments. From this we found that as few as 12 episodes of bioturbation involving backfilling of chambers in the same volume of sand could lead to the presence of 1 contaminant grain per 50 grains of sample.     

Thermoluminescent dating in its application to archaeology: A review

This paper sets out to describe the fundamentals of thermoluminescent (TL) dating and to explain the principles of operation of the different methods at present in use. The various complicating factors associated with TL dating are discussed, together with the measures which can be taken to recognize and as far as possible to correct them. Those materials from archaeological contexts which are suitable for dating by the TL technique are described and the criteria for the selection of suitable samples, and the methods of obtaining the desired ancilliary information relating to the environment of the site, are discussed.     

Optically stimulated luminescence dating of Southern High Plains archaeological sites

The Southern High Plains of North America is rich in archaeological sites, but many are not well constrained chronologically, owing to a lack of material for radiocarbon dating. A program of optically stimulated luminescence (OSL) dating, applying mainly single-grain analyses, was therefore initiated. Many samples have independent age estimates from radiocarbon to check the OSL results, but OSL age estimates are also provided for those sites that otherwise lack secure chronological control. Sediment samples for OSL were obtained primarily from Paleoindian and Archaic localities, though include deposits of more recent age. Through the analysis of single grains, equivalent dose—the numerator of the age equation—is evaluated independently on numerous grains. The distribution of these values is relatively broad for some samples, and this is attributed to post-depositional mixing. Mixing is also evident in some samples with more narrow distributions. Selecting portions of the mixed distributions for age determination allows more accurate dating for some samples, but the nature of the distributions limits the resolution on others, conclusions that cannot be as easily drawn from multi-grain analysis. Where independent age control is available, most OSL results broadly conform; however, some samples show discrepancies that are not readily explained, but may relate to association or dose rate problems. This underscores the desirability of obtaining where possible suites of chronological evidence.     

On the intrinsic accuracy and precision of luminescence dating techniques for fired ceramics

Luminescence dating techniques have been used extensively for archaeological and geological samples. Such techniques are based on thermally or optically stimulated signals. This paper presents simulations of several luminescence techniques for equivalent dose (ED) estimation for ceramic materials containing quartz. The simulations are carried out using a recently published comprehensive kinetic model for quartz, consisting of 11 electron and hole traps and centers. The complete sequence of the experimental protocols for several thermoluminescence (TL) and optically stimulated luminescence (OSL) techniques are simulated using the same set of kinetic parameters. The specific simulated protocols are: additive dose TL protocol, predose technique (both additive and multiple activation versions), phototransfer protocol, single aliquot regenerative optically stimulated luminescence (SAR-OSL) protocol, and SAR thermoluminescence protocol (SAR-TL). One hundred random variants of the natural samples were generated by keeping the transition probabilities between energy levels fixed, while allowing simultaneous random variations of the concentrations of the 11 energy levels. The relative intrinsic accuracy and precision of the protocols are simulated by calculating the equivalent dose (ED) within the model, for a given natural burial dose of the sample. The intrinsic accuracy of these techniques is estimated by simulating natural irradiation of the samples with a known burial dose, followed by simulation of the luminescence method used to recover the estimated dose ED. The percent difference between the burial dose and the ED value represents the simulated accuracy of the luminescence technique. The relative intrinsic precision of these techniques is estimated by fitting Gaussian probability functions to the ED values obtained with the 100 model variants. It is found that the various techniques can reproduce natural paleodoses in the range 10 mGy–10 Gy with a typical intrinsic accuracy of +1 to 10%. Techniques based on single aliquot protocols were found in general to be more precise than techniques requiring the use of multiple aliquots. In addition, techniques based on interpolation of experimental data were found to be consistently both more precise and accurate than those based on extrapolation of experimental data.     

The current state of American archaeology

Meltzer, David J., Don D. Fowler, and Jeremy A. Sabloff. American Archaeology Past and Future: A Celebration of the Society of American Archaeology 1935–1985. Washington, D.C.: Smithsonian Institution Press, 1986. 479 pp. including illustrations and chapter references. $35.00 cloth, $19.95 paper.

Schiffer, Michael B. Advances in Archaeological Method and Theory. Volume 9. Orlando, Florida: Academic Press, 1986. v + 468 pp. including illustrations, tables, chapter references, and index. $75.00.     

A review of rock art dating in the Kimberley, Western Australia

This paper critically reviews the various approaches used to estimate the age of the rock art in the Kimberley region of Western Australia. They include: (i) the relative superimposition of styles; (ii) the use of diagnostic subject matter (depictions of extinct animals, stone tool technology, introduced European and Asian objects and animals); (iii) the recovery of a ‘painted’ slab from a dated archaeological unit; (iv) radiocarbon dating of beeswax figures, charcoal pigments, organic matter in overlying mineral deposits and ‘accreted paint layers’ (oxalate rich crusts and amorphous silica skin), pollen grains from an overlaying mud-wasp nest; and (v) optically stimulated luminescence (OSL) dating of quartz grains from overlying mud-wasp nests. Future directions for rock art dating in the Kimberley include uranium-series dating of overlying and underlying mineral deposits.     

Optically stimulated luminescence dating of the city wall system of ancient Tayma (NW Saudi Arabia)

In addition to a series of chronological markers (artefacts, pottery) in the archaeological contexts of ancient Tayma (NW Saudi Arabia), optically stimulated luminescence (OSL) and radiocarbon dating techniques were applied to generate reliable ages for the city wall system of the oasis. A massive aeolian sand deposit burying the oldest part of the outer wall of Tayma was sampled to obtain a minimum age for the construction of this wall. The sequence of OSL ages from the inactive dune (ID) (4900 ± 300 a, 5100 ± 400 a, 4400 ± 300 a, 3900 ± 200 a, 4000 ± 200 a) is in full accordance with ¹⁴C-AMS ages of charcoal embedded into the same dune (4190–4420 cal BP, 3870–4080 cal BP). Underlying alluvial samples from the inactive gravel sheet (IGS) in contrast give maximum ages for the construction which scatter between 6600 ± 300 a and 4900 ± 400 a. The new dating sequence provides evidence that the oldest part of the ancient city wall system already existed in the 2nd half of the 3rd mill. BC which is earlier than expected thus far from archaeological and architectural interpretation.     

A comparison of the treatment of errors in radiocarbon dating calibration methods

The application of radiocarbon dating to archaeological samples generally requires calibration of ¹⁴C dates to calendar ages and interpretation of dating errors. In this paper, four recent methods of age calibration are assessed, particularly with regard to their quality of error treatment. Recent experimental research has suggested that commonly quoted errors on “raw” ¹⁴C dates may require enlargement to more realistic levels, which, when incorporated in the calibration schemes, produce a considerable increase in the size of the typical calibrated interval. A general decrease in the sensitivity of ¹⁴C dating using single, “normal precision” dates is implied. Thus typical calibrated age intervals range from 300 to 1300 years (approximate 95% confidence level), with little improvement resulting if “high precision” calibration systems are used to correct “normal precision” dates. Of the four methods considered here, that proposed by Neftel is found to provide the most objective, flexible, comprehensive and “easy to use” scheme. This method is particularly recommended for its treatment of errors both on the dates to be calibrated and on the calibration curve itself.     

Higher ground: The archaeology of North American platform mounds

Platform mounds, as forms of monumental architecture, have long been central to inquiries into Native American social complexity. The archaeological literature produced over the last 5 years that pertains to North American platform mounds in the Southeast and Southwest is reviewed. Chronologies, forms, and functions of platform mounds are summarized. There are similarities in the platform mound characteristics and construction sequences found in both regions. It is proposed that these characteristics reflect similar social processes of integration and differentiation.     

Optically stimulated luminescence dating of heated materials using single-aliquot regenerative-dose procedure: a feasibility study using archaeological artefacts from India

Optically stimulated luminescence (OSL) dating of heated/fired materials of archaeological importance from various parts of India was attempted. A single-aliquot regenerative-dose (SAR) procedure was used for palaeodose determination in the quartz grains extracted from the heated materials using the luminescence produced by blue light stimulation. In most pottery samples, the palaeodose obtained using SAR-OSL is ∼6% lower than the palaeodose measured using thermoluminescence (TL) method. Broadly, there is good agreement between the SAR-OSL and TL ages of the artefacts and their archaeologically expected ages. The results suggest that routine dating of heated/fired materials using the SAR-OSL procedure is more practicable, especially when the TL sensitivity of the quartz grains is poor and availability of datable material is limited.     

Timing the Neolithic transition: the application of fluoride dating at Tell Halula,Syria

The study of Near Eastern Neolithic villages provides a unique means of tracing subsistence strategy, population growth, health, and emerging social inequality associated with agricultural origins. However, disentangling these patterns requires a detailed comprehension of the chronological placement of individual households in the site. In this paper, we present a test to determine the reliability and applicability of the fluoride dating method (a relative dating method) on human dentition of 40 samples from 28 Pre-Pottery Neolithic B (or PPNB) burials from the site of Tell Halula, in Syria. This method, applied here for the first time on a Neolithic Near East case study, is an alternative when other dating methods, like radiocarbon dates, do not provide the required temporal resolution to address particular research problems. Nonetheless, the results obtained in the fluoride analysis show how both the age at death of individuals, and the integrity of the burial plug enormously affect the amount of fluoride absorbed by teeth, so that only a small subset of the full dataset was suitable for fluoride dating. Although the distribution of fluoride values of dentine from the small sample of burials from suitable contexts matches the expected chronology, and corroborates the hypothesis that the occupation at Halula extends from the Middle to the Late PPNB, our analysis illustrates the need for a better understanding of the different sources of error in fluoride dating to improve the method itself, and to obtain more reliable fluoride chronologies.     

Walter Taylor and the history of American archaeology

Walter Taylor’s place in the history of archaeology is well secured. Not only is he noted for his uncredited anticipation of the theoretical and methodological innovations of the 1960s and 1970s in his infamous book A Study of Archeology, but he is also well-known for committing professional suicide by short-sightedly attacking numerous key figures in American archaeology for their methodological shortfalls, and yet never publishing a report utilizing his controversial method. Although these statements have inundated the historical literature on American archaeology, they are received wisdom rather than the reality of Taylor’s contributions to the field. Many aspects of Taylor’s conjunctive approach were at odds with the stated aims of processual archaeology. Although Taylor did not live up to his critics’ (or his own) demands for a grand display of his approach, he did on several occasions demonstrate its potential. The irony of Taylor in the history of archaeology is not that he was uncredited for his prescience or that his attacks on the archaeological establishment were a naïve failure; but rather that he receives too much credit for what he didn’t do, and not enough for what he did.     

Pedogenetic dating of loess strata

Loess is an aeolian Pleistocene sediment of periglacial or arid origins, deposited without internal stratification in parcels representing geological periods. The contents of total as well as individual carbonates are comparatively uniform within a specific stratum, but the relative carbonate contents differ significantly between the various glacials as represented by loess facies. There is a consistent increase in the content of dolomite with decreasing age of stratigraphic units, which has traditionally been attributed to postdepositional alteration, notably the gradual removal of the calcite fraction by weathering. The explanation of pedogenetic enrichment in the course of aeolian recycling of glacial and glacio-fluvial deposits could convincingly account for the stepped profile of the dolomite's depth functions. The implication is that such recycled sediments can be attributed to specific cryocratic phases simply by their characteristic dolomite fraction, i.e. they can be dated. In order to test this hypothesis against the competing weathering hypothesis, strata of the Gudenus Cave in Lower Austria were subjected to carbonate differentiation analysis. The results are presented, analyzed and discussed. It is shown that the dolomite contents of the unweathered strata provide a clear trend that is even more pronounced than that found at open-air sites.     

Strofilas (Andros Island,Greece): new evidence for the cycladic final neolithic period through novel dating methods using luminescence and obsidian hydration

The recently excavated coastal prehistoric settlement of Strofilas on Andros Island (Cyclades, Greece) in the Aegean sheds new light on the transitional phase from the Final Neolithic to Early Cycladic period regarding masonry, fortification, and richly engraved rock art. The fortification possesses early evidence of preserved defensive architecture, as evidenced from the plethora of scattered finds from within and around the settlement. Important features are carvings on rock walls which mainly depict ships, animals, and fish. Initial archaeometric dating via the application of luminescence dating of two samples from the fortified wall bearing engraved ships, and by obsidian hydration of two blades employing the new SIMS-SS method (secondary ion mass spectrometry via surface saturation), has been undertaken to determine the site's chronology. The former yields an average date of 3520 (±540) BC and the latter an average date of 3400 (±200) years BC, both of which, within overlapping errors, suggest the main settlement occurred during the Final Neolithic.     

A chronometric tool for Hawaiian archaeology: the hydration dating of Pu'u Wa'awa'a trachytic glass

The Pu'u Wa'awa'a trachytic glass deposit located on the Big Island of Hawai'i was a source of lithic tools for much of Hawaiian prehistory. Routinely encountered at habitation sites, the glass has the potential to provide absolute dates based upon the degree of surface hydration. Infrared photoacoustic spectroscopy and secondary ion mass spectrometry were used to monitor the diffusion of water in archaeological and experimental samples. Accelerated laboratory hydration experiments show that water diffusion in trachytic glass containing a structural water content of 0.16% ± 0.03% is linear with time. Application of the calibration to trachytic glass artifacts from the Kahalu'u habitation cave have produced chronometric dates in the 17th–18th centuries. These age estimates are in agreement with radiocarbon dates and artifactual data that bracket the site occupation. However, the glass dates do not correlate well with site stratigraphy and this suggests that slight sample imperfections that retain water may be one factor that results in ages that are too early for later occupation levels.     

Uranium-series dating rock art in East Timor

At many sites throughout the world rock art paintings have been covered by naturally deposited calcite laminations, which we demonstrate can be individually dated by recently improved uranium-series methods. Here we report the application of multi-collector inductively coupled plasma mass spectrometry to measure the ages for carbonate coatings that bracket red pigment at Lene Hara cave, East Timor, which could be evidence of human painting. These analyses establish the feasibility of dating milligram samples of finely layered calcite deposits associated with archaeological evidence of human occupation. In addition to confirming an age of less then 6300 years for the visible red paintings on the carbonate surface we also report a substantially older age of 24,000 to 29,300 years for a similar, older red pigment lamination providing possible evidence for an earlier painting episode.