A Multidisciplinary Approach to the Study of Archaeological Mortars from the Town of Ammaia in the Roman Province of Lusitania (Portugal)

The Roman town of Ammaia (in Marvão Region) is considered one of the most important recent findings of the Roman presence in Portuguese territory. It was settled in Republican times and abandoned in the seventh century. In this research, 17 masonry mortars and renders from the West Tower (South Gate), the residential area near the West Tower, the macellum, the peristylium, the public bath building, the podium of the temple and the portico of the forum were analysed. The methodology of chemical, mineralogical and microstructural characterization has involved several complementary techniques, including stereomicroscopy, X‐ray diffraction, thermal analysis and scanning electron microscopy coupled with energy‐dispersive X‐ray spectroscopy. The results indicate that the mortars from the beginning of the town's edification were mainly composed of soil (clays). Later, during the main Roman building period, mortars were composed using a calcitic binder and the mortar composition varied according to their use and function. The samples from a period subsequent to the Roman occupation are based on a dolomitic binder. From the present study, relevant information has been acquired about the technological evolution of Roman construction in Ammaia, the historical context of the archaeological structures and guidelines for the conservation and restoration of mortars.     

GEOCHEMICAL CHARACTERIZATION OF ARCHAEOLOGICAL LIME MORTARS: PROVENANCE INPUTS*

Chemical and mineralogical analyses were carried out on historical lime mortars from the parish church of Santa María La Real (Guipúzcoa). The study included various periods ranging from Roman to modern times and allowed the identification of various types of raw materials. In order to obtain pure binder, free of carbonate aggregates and charcoal particles, an innovative binder separation method was implemented. The chemical composition of the binder allows discrimination of different provenance areas for the raw materials, although those areas do not correlate with specific historical periods. In addition, the influence of burial processes on the primeval chemical features has been assessed and reveals that modern mortars display greater chemical modification than the Roman mortars.     

Technology of Medieval Mortars: An Investigation into the Use of Organic Additives

This work proposes a multi‐analytical approach to determine the additives in historical mortars, the use of which is widely described in bibliographical sources, but has rarely been reported in the literature. A protocol to thoroughly analyse mortars was created (optical microscopy, X‐ray diffraction, infrared spectroscopy, thermal analyses and gas chromatography – mass spectrometry). These techniques, which had already been carried out on samples from various sites from the Roman to the modern era, determined that additives had only been used in the mortars from the internal masonry at our sampling site: the medieval military shipyard of Amalfi (Italy). The investigations yielded information on the production technology, and FT–IR and GC–MS revealed a saccharide material‐based additive in the mortars, of plant origin. The FT–IR spectra suggested the presence of a natural gum, which has been used since ancient times to strengthen the cohesion properties of mortars and their resistance to tensile stress.     

Paper 6: Grouting Mortars for Fragmented Bricks and Repair Mortars for Tiles in the Archaeological Site Coudenberg

Abstract

Different grouting and repair mortars were developed and evaluated for the conservation and restoration of fragmented bricks in the walls and floors of the remaining cellars underneath the Aula Magna, the palace’s main banqueting hall, and to fill the lacunae and perform edge repairs of red and blue-grey ceramic floor tiles in the remaining cellars underneath the chapel of the former Palace of Coudenberg in Brussels, Belgium.

To prevent the deposition of lime bloom at the surface of the masonry and to achieve an acceptable colour match of the grout in harmony with the bricks of the Aula Magna, the effect of brick powder added to natural hydraulic lime was studied. The pozzolanic properties and colour match of several historic and modern powdered bricks were investigated. Surprisingly, ancient bricks do not seem to possess higher pozzolanic properties than the more modern ones, although it is supposed that they were fired at lower temperatures. Additional evidence for the pozzolanic reaction of the different brick powder materials was obtained from a simple visual observation of stored samples. After eight weeks all of the samples containing brick powders, fired at low and high temperatures, added to putty lime had hardened under water and were transformed into a remarkably tough material. These results are important, as modern bricks are readily available in large quantities and different colours, which are hence in favour of being used instead of historical material from the site.

For the repair of the ceramic floor tiles different mortars were investigated with mixtures containing talcum, stone or brick powder, pigments, and chalk added to an epoxy binder. The mortars were tested in the laboratory and in situ for their workability and resemblance with the historic floor tiles. The finished mortars showed excellent aesthetic properties with the tiles in situ and good properties to prevent further loss due to human interaction.     

Characterisation of archaeological mortars and plasters from kyme (Turkey)

The present study focuses on the compositional characterisation of Roman, proto-Byzantine and Medieval mortars, sampled in the archaeological site of Kyme (Turkey), an Aeolian city, founded in the middle of the XI century BC by Greek populations. The mortars were studied through elemental (SEM-EDS, XRF), mineralogical (XRPD, De Astis calcimeter) and petrographic (polarised optical microscopy) analysis. The comparison between the samples allowed us to emphasise compositional differences within mortars of the same historical period.In particular, we detected the prevalent use of cocciopesto, which was used as a pozzolanic additive to create hydraulic mortars in the Roman and Byzantine period. The cocciopesto was used to improve the technological properties of an initially slaked lime. Furthermore, compositional similarities allowed us to attribute an unknown sample to the Roman period. Our study also pointed out the fact that the lower quality mortars belonged to the Medieval period. As a matter of fact, the most friable sample belonging to the Middle Ages turned out to be a mixture of clay, lime and volcanic sand.     

Archaeometric study of natural hydraulic mortars: the case of the Late Roman Villa dell’Oratorio (Florence,Italy)

This paper shows the results of a multidisciplinary study carried out on the mortars from the Late Roman Villa dell’Oratorio (fourth-sixth ad), an aristocratic mansion built in the lower Valdarno (Florence, Italy). Thirty-one bedding mortar and plaster samples were analysed through optical microscopy, thermogravimetric analysis, X-ray powder diffraction and scanning electron microscopy with energy-dispersive X-ray spectroscopy for determining the chemical, mineralogical and petrographic characteristics, while their main physical properties were measured by geotechnical procedures. The collected data indicates that the analysed mortars are made up of very fine to coarse river sand aggregate mixed with white to yellowish-white natural hydraulic lime binder mainly consisting of mixtures of prevailing calcite and hydraulic compounds. With regard to the origin of the raw materials, the aggregates were recognized to be selected Arno river sands, and the binders are the burning product of a local marly limestone (ex Alberese). Therefore, the mortars of the Late Roman Villa dell’Oratorio are one of the first uses of natural hydraulic lime in the lower Valdarno.     

Microstructures of Building Materials from Huaca De La Luna,Peru

ABSTRACT

The microstructures of building materials from the archaeological complex of Huaca de la Luna on the northern coast of Peru is assessed for the first time by a multiscale approach. The multiscale microstructural characterization used laboratory techniques including optical microscopy, scanning electron microscopy, X-ray microtomography, and both gas and powder pycnometry. Optical microscopy revealed the presence of organic matter and shell fragments and X-ray microtomography showed differences in the sizes and connectivity of pores. The BET (N₂ gas adsorption) specific surface areas showed greater presence of clayey matrix in the mortars. No significant differences among mortars and brick fragments mineralogy were detected by X-ray diffraction, so the larger amount of fine binding matrix in the mortars suggests that they were produced blending raw material with different grain sizes. The aim of this study is to provide data that can be used for a better understanding of the Moche culture, its construction techniques, and to support conservation strategies of the archaeological heritage.     

Political freedom in Byzantium: the rhetoric of liberty and the periodization of Roman history

ABSTRACT

This paper proposes an intellectual history of the idea that the later Roman empire and, subsequently, the whole of Byzantium were less ‘free’ in comparison to the Roman Republic. Anxiety over diminished freedom recurred throughout Roman history, but only a few specific expressions of it were enshrined in modern thought as the basis on which to divide history into periods. The theorists of the Enlightenment, moreover, invented an unfree Byzantium for their own political purposes and not by examining the facts about its political culture. The second part of the paper proposes that the Byzantines valorized a model of positive freedom as legal-institutional protection against arbitrary oppressive power, including against both barbarian domination and domestic abuses. In contrast to modern thought, which tends to see the imperial position as the chief threat to liberty, the Byzantines viewed it as its bulwark. Yet they too had remedies for oppressive emperors, suggesting that the otherwise well-attested invocations of freedom were not a mere rhetorical trope for them but an actionable cultural norm.     

Paper 5: Historic Mortars from the Coudenberg Archaeological Site: Characterization and Source of Raw Materials

Abstract

The characterization of historic mortars by means of a concise methodology of material analyses can provide crucial information with regard to the origin of the raw materials and the ancient mortar technology. For the analysis of the historic mortars of the Coudenberg archaeological site, the methodology consists of optical and scanning electron microscopy, simultaneous thermal analysis, and an acidic treatment. These analyses were carried out on a total of seventeen samples lifted from various areas in the site, in function of the building chronology resulting from a historic built investigation. The type of binder and aggregate as well as their volumetric ratio were determined.

Both binder and aggregate present distinctive features, which made it possible to identify the probable geological provenance of the raw materials. The observations are verified with available historical records regarding the construction of the main banqueting hall — the Aula Magna — and the use of raw materials such as limestone and sand for the production of lime and construction purposes.     

A hypothesis on different technological solutions for outdoor and indoor Roman wall paintings

The determination of the chemical composition of different parts of wall paintings (pigments, mortars and binders) provides information about technology of preparation of an artefact. Herein, we present a multi-methodological characterisation of wall paintings from a Roman archaeological site in Cuma, focusing on differences between an indoor (domus) and outdoor fabrication (a temple, Tempio con Portico (TCP)). Both pigments, binders and mortars were studied via a combination of destructive/μ-destructive (mass spectrometry, ionic chromatography, ICP-based techniques) and non-destructive (Raman microscopy, small-angle neutron scattering (SANS) and X-ray diffraction) methodologies. Particularly, the systematic presence of dolomite only in mortars from TCP may suggest an intentional use of such limestone for the outdoor fabrication of public interest. Differences between TCP and domus are also related to the composition of the pigment binder. In particular, the detected binders (studied by LC-MS/MS and GC-MS) were proteinaceous in the case of domus (possibly egg and animal glue) and drying oils in the case of TCP. Ultimately, our multi-methodological study provides an overall picture of the material components of paintings from fabrications with different use, proposing a hypothesis on technological choices according to conservative and destination reasons.     

BUILDING MATERIALS OF THE THEATRE OF MARCELLUS,ROME*

The building materials of the Theatre of Marcellus, 44–11 bce , reflect Roman builders' careful selections of tuff and travertine for dimension stone and volcanic aggregates for pozzolanic concretes. The vitric–lithic–crystal Tufo Lionato tuff dimension stone contains a high proportion of lava lithic fragments, which increase its compressive strength and decrease water sorption, enhancing durability. Sophisticated installations of travertine dimension stone reinforce the tuff masonry, which is integrated with durable concrete walls and barrel vaults. The pozzolanic mortars of the concretes contain harenae fossiciae mainly from the intermediate alteration facies of the mid‐Pleistocene, scoriaceous Pozzolane Rosse pyroclastic flow. They have pervasive interpenetrating pozzolanic cements, including strätlingite, similar to high‐quality, imperial era mortars. Concrete walls are faced with refined Tufo Lionato opus reticulatum and tufelli, and opus testaceum of fired, greyish‐yellow brick. The exploratory concrete masonry, which includes some of the earliest examples of brick facings and strätlingite cements in Rome, and the integration of these materials in complex architectural elements and internal spaces, reflect the highly skilled workmanship, rigorous work‐site management and technical supervision of Roman builders trained in republican era methods and materials.     

A Multidisciplinary Approach for the Archaeometric Study of Pozzolanic Aggregate in Roman Mortars: The Case of Villa dei Quintili (Rome,Italy)

This contribution focuses on the study of historical mortars from a Roman archaeological site known as Villa dei Quintili, a monumental villa located in the south‐eastern part of Rome (Italy). The study was carried out on 38 mortar samples, collected from several edifices within the complex. A multi‐analytical approach, including polarized optical microscopy, scanning electron microscopy coupled with energy‐dispersive system and laser ablation inductively coupled plasma mass spectrometry, was used to analyse the pozzolanic material used for the preparation of mortars. Data obtained on both major and trace elements were compared with the compositions of Pozzolana Rossa, Pozzolana Nera and Pozzolanella samples from the Alban Hills volcanic district, collected from a historic quarry nearby, as well as with literature data. The results of such a multidisciplinary approach allowed us to recognize the use of all three pozzolan types for the aggregate fraction of examined mortars from the Villa dei Quintili.     

Archaeological wells in southern France: Late Neolithic to Roman plant remains from Mas de Vignoles IX (Gard) and their implications for the study of settlement,economy and environment

Abstract

A study of plant remains from seven archaeological wells at Mas de Vignoles IX, near Nîmes, southern France, was used to shed light on a current gap in the archaeological record caused by erosion and modern agriculture. The analysis also explored the reliability of these sources for palaeoenvironmental and palaeoeconomical information. Significant results on the spatial organization of human habitation, economic activities, and on the environment and its exploitation were obtained for the Middle Neolithic to Roman periods. Furthermore, the Neolithic wells also provided the first early finds of fig seeds in France. The abundance of weed and ruderal plants up to the Iron Age is consistent with data from other studies and their dramatic decrease during the Roman period may have resulted from radical changes in land management. The study marks the first time, in southern France, that a group of wells from a single site have provided a complete record throughout the later prehistoric and Roman periods.     

Dimensional variations of Roman masonry subjected to wetting-drying cycles

Abstract

Many Roman monuments made of opus caementicium are subjected to wetting and drying phenomena caused by water or/and humidity from the ground. The action of water impregnation on the hypothetical dimensional changes in this Roman concrete has not been considered in the literature and no experimental data are available.

The purpose of this work was the evaluation of the effect of wetting and drying cycles in a number of cores taken from an ancient Roman monument (Domus Tiberiana in the Palatine, Rome). The concrete samples were made of a pozzolanic mortar with large pieces of tuff, marble and bricks.

In spite of some differences in their composition, the behaviour of the cores was similar and, generally, quite constant during the experimental cycles. On the average, the length variation was about 3–4%,or 3–4mm for each metre and, when related to high structural walls and monuments, the possible dimensional changes were quite impressive.     

Byzantine History in late Ottoman Turkish Historiography

Abstract

The present Short Note is intended as a brief introduction to a subject which is part of a wider research project on Greek (ancient, Byzantine, and modern) as well as Roman history and culture as described and discussed in Ottoman literature, particularly in late Ottoman historiography. As an attempt to familiarise the reader with, at this stage, no more than a few aspects of the subject in question, the following sketch does not pretend to be exhaustive. It is hoped, however, that it will provide a general idea of the context, as well as of the relevant sources, some of which will be described in more detail. Our note is, in addition, intended to arouse interest, particularly from the point of view of Byzantine and modern Greek studies, and to invite comments.     

Materials Characteristics of Roman and Arabic Mortars and Stuccoes from the Patio De Banderas in the Real Alcazar of Seville (Spain)

This study discusses the materials and traditional knowledge used in the manufacture and application of lime mortars and stuccoes by Romans and Arabs in Seville (southern Iberian Peninsula). All of the samples studied contain calcite as a binder, combined with aggregates based on river sand from the filling materials of the Guadalquivir River's depression, located in the vicinity of the Real Alcazar Palace in Seville, Spain, where the artefacts were discovered. The Romans used high‐quality production technology, as evidenced by the careful selection of raw materials as well as by the adequate binder‐to‐aggregate ratio and the elevated homogeneity of the mortars and stuccoes. The suitable distribution of aggregates resulted in higher density values for Roman fragments than for Arabic ones. Results derived from Arabic samples suggest a decline in technology manufacture over time. This work provides useful information, particularly regarding the Roman and Arabic periods in the Iberian Peninsula. The analytical techniques employed in this study were X‐ray diffraction (XRD), X‐ray fluorescence (XRF)—using conventional and portable systems, scanning electron microscopy (SEM), petrographic microscopy, differential thermal analysis/thermogravimetry (DTA/TG), particle‐size analysis and mercury intrusion porosimetry.     

Suffering in Silence: The Political Aesthetics of Pain in Antonine Art

Abstract

In this paper, two striking representations of screaming or shouting male barbarians, one on the Column of Marcus Aurelius in Rome and the other on the Pannonian tombstone of the Roman legionary C. Septimus, are analysed and discussed in detail. These two disturbing and provocative images of suffering are situated in the broader context of institutionalised violence in Roman society, as reflected in certain kinds of judicial punishments and in the games in the arena, and of depictions of pain and suffering in other contexts, both ancient and modern.     

Comparing the Old and New: Traditional Building Materials and the Uch Monument Complex,Pakistan

Abstract

The supposition that modern traditionally produced building materials are inherently similar to original building fabric is common in Pakistan. Laboratory analysis on historic and modern samples of fired brick, mud brick, and mud mortars was undertaken for the first time in the region to investigate similarities in basic physical properties and composition of the materials. Simple analytical techniques were used to determine porosity, density, particle size distribution, plastic limit and other properties, as well as chemical composition of the samples. Further analytical methods were used to confirm the results of simpler analyses and further characterize materials. Results indicate that modern locally produced materials were in many ways comparable to their historic counterparts and may be used as intervention materials within the buildings of the Uch Monument Complex. This information will inform the choice and manufacture of proposed intervention materials, while providing preliminary quantitative evidence for continuing traditions.     

Characterization of ancient building lime mortars of Anhui province,China: A multi-analytical approach

The characterization of lime mortars has become of primary importance in order to obtain information about the raw ingredients and building technology of ancient masonry structures. Five different samples from Anhui province, China, representing two types of lime mortar-based materials: joint mortars between the bricks of the city wall and lime mortar sealing a tomb coffin, were collected for analysis. Archaeological information about the samples was reported and studies into the microtextural features and mineralogical compositions of those mortars were performed via a multi-analytical approach. The joint lime mortars between the bricks of city walls, including Mingzhongdu city wall, Mingzhongdu Xihua gate foundation, Zhengyangguan city wall and She county city wall, were found to be aerial lime mortars. The lime mortar from Nanling Tieguai Song dynasty tomb was analysed and found to be a pozzolanic mortar consisting of lime, clay, sand and cocciopesto-like materials. The analytical results serve as a critical reference for the maintenance and restoration of ancient city walls in Anhui province, and as a starting point for searching for ancient Chinese pozzolanic mortars and technology for making those mortars.     

MORTAR STUDIES TOWARDS THE REPLICATION OF ROMAN CONCRETE

The use of strong and durable materials is one essential ingredient leading to the survival of many monumental Roman concrete structures. Replicated concrete mortars with different lime to pozzolan ratios, encompassing the range likely to have been used by the Romans, have been studied here to determine their relative compressive strengths as a function of time. This has been supplemented by the use of the scanning electron microscope to delve into the structure and composition of the binders formed within the strongest and weakest mortars, leading to a deeper understanding of the reasons for the differences in compressive strength.