AN EXPERIMENTAL INVESTIGATION ON LEAD ISOTOPIC FRACTIONATION DURING METALLURGICAL PROCESSES

In this paper, experiments are designed to imitate the non‐equilibrium evaporation metallurgical process of lead. The lead isotope ratios of the remaining lead liquid with different percentage losses were then determined using high‐solution MC–ICP–MS. The results show that this process does alter lead isotopic ratios of the remaining liquid. However, the variations are so much smaller than the speculated values using the theoretical formula that in most ancient metallurgical processes, the lead isotopic fractionation can be neglected.     

A calf for all seasons? The potential of stable isotope analysis to investigate prehistoric husbandry practices

The Early Bronze Age barrows at Irthlingborough and Gayhurst in central England are notable for the large number of cattle (Bos taurus) remains associated with their human Beaker burials. Previous work using strontium isotope analysis has indicated that most of the cattle analysed, and one aurochs (Bos primigenius), were of local origin [Towers, J., Montgomery, J., Evans, J., Jay, M., Parker Pearson, M., 2010. An investigation of the origins of cattle and aurochs deposited in the Early Bronze Age barrows at Gayhurst and Irthlingborough. Journal of Archaeological Science 37, 508–515.]. In this study, stable isotope analysis of enamel and bone was carried out to investigate whether the mature cattle had experienced similar husbandry practices, climate and environment. Bulk carbon, nitrogen and sulphur isotope analysis of collagen suggested most were consuming similar sources of plant protein from environments probably local to the sites and this was supported by high resolution intra-enamel carbon isotope profiles. Oxygen isotope profiles indicated the aurochs and most of the cattle experienced similar climatic regimes: the only exception being an animal with a non-local strontium isotope ratio. However, a comparison of seasonality profiles of the local animals using estimated tooth formation times showed that there was no consistency in season of birth: the animals appeared to have been born throughout the year. Cattle can breed throughout the year but it requires considerable human effort and intervention to successfully overwinter young stock; it is therefore unlikely to have been carried out without good reason and benefit if winters were harsh. One reason is to ensure a continuous supply of milk. Measuring oxygen isotope profiles to identify year-round calving may thus be a potential indicator of dairying economies.     

Andean Ores,Bronze Artifacts,and Lead Isotopes: Constraints on Metal Sources in Their Geological Context

With a focus on bronze production in the south-central Andes during the Middle Horizon, this study reports the first archaeological use of lead isotope analysis to investigate metallic ores and metal artifacts in the Andean zone of South America. Because the vast majority of metal deposits in the Andean cordillera formed in a convergent plate boundary setting, lead isotope compositions of most Andean ore sources are not unique. Lead isotope ratios of central and south-central Andean ores define four geographically distinct ore lead isotope provinces, oriented and elongated parallel or sub-parallel to the trend of the Andean cordilleras. Consequently, ore lead isotope ratios vary strongly from west to east along transects through the coast, highlands, and altiplano, but they exhibit much less variation from north to south. The strong west-to-east variation in ore lead isotope signatures allows discrimination between ore bodies, and ultimately between metal artifacts, as a function of macro-ecozone location: coast, junga-qiswa, puna, and altiplano. We present the most up-to-date database of ore lead isotope signatures for the south-central Andes including those determined for ores we sampled over an approximate 250,000-km² region within Bolivia, northern Chile, and northwest Argentina. Lead isotope signatures of Cu-As-Ni bronze artifacts from Tiwanaku (altiplano capital) and San Pedro de Atacama (desert oasis entrepôt) establish that altiplano and high sierra ore bodies provided the metal for both assemblages. Conchopata (Wari) arsenic bronze artifacts exhibit lead isotope ratios compatible with the Julcani (Huancavelica) copper sulfarsenide deposit.     

Local mining or lead importation in the Roman province of Africa Proconsularis? Lead isotope analysis of curse tablets from Roman Carthage,Tunisia

This study attempts to determine if there was Roman lead mining in Africa Proconsularis, approximately the area of modern day Tunisia, using lead isotope analysis. Another important aspect of the study is the innovative use of electron microprobe analysis (EMPA) as a screening tool to greatly reduce the number of expensive lead isotope analyses needed for the study. The EMPA X-ray mapping for arsenic, antimony, copper, and silver narrowed the sample of curse tablets to those most likely produced from Tunisian ores; these tablets were then tested using thermal ionization mass spectrometry (TIMS) analysis. A total of 96 Roman lead curse tablets from Carthage, Tunisia were screened with EMPA and twenty selected for TIMS to determine the ore sources of the lead used to manufacture the tablets. Comparing the lead isotope ratios of twelve of the sixteen tablets most likely to be made of Tunisian lead to samples of Tunisian ores suggests that the Romans were mining lead in Africa Proconsularis and were not relying solely on imports.     

Stable Lead Isotope Studies of Black Sea Anatolian Ore Sources and Related Bronze Age and Phrygian Artefacts from Nearby Archaeological Sites. Appendix: New Central Taurus Ore Data

The accumulated published database of stable lead isotope analyses of ore and slag specimens taken from Anatolian mining sites that parallel the Black Sea coast has been augmented with 22 additional analyses of such specimens carried out at the National Institute of Standards and Technology. Multivariate statistical analysis has been used to divide this composite database into five separate ore source groups. Evidence that most of these ore sources were exploited for the production of metal artefacts during the Bronze Age and Phrygian Period has been obtained by statistically comparing to them the isotope ratios of 184 analysed artefacts from nine archaeological sites situated within a few hundred kilometres of these mining sites. Also, Appendix B contains 36 new isotope analyses of ore specimens from Central Taurus mining sites that are compatible with and augment the four Central Taurus Ore Source Groups defined in Yener et al. (1991).     

THE PROVENANCE OF IRON ARTEFACTS FROM MANCHING: A MULTI‐TECHNIQUE APPROACH*

Iron finds from the Celtic oppidum of Manching in southern Bavaria (Germany) are analysed in view of their possible provenance. The exceptional size and the location of Manching are usually attributed to the presence of abundant iron ores in its vicinity. After a review of previous approaches for source determination of iron artefacts, we introduce lead isotope analysis as a new approach. However, only by combining the trace element patterns of slag inclusions and iron metal with lead isotope ratios in the metal is it possible to distinguish various iron ore formations near Manching. As a result, it turns out that, indeed, the most obvious ones—namely, bog ores near the Danube—constituted the main resources for iron production at Manching. It was even possible to select one occurrence as the most likely ore source.     

Moving peoples,changing diets: isotopic differences highlight migration and subsistence changes in the Upper Mun River Valley,Thailand

The dramatic growth of dietary isotope studies in archaeological literature attests to the significant potential this technique has for shedding light on past societies. Human diet reflects complex, inter-linked factors such as status, cultural preferences or environmental constraints on food production. In this study dietary isotope analysis is used to examine the human skeletal remains from Ban Non Wat, northeast Thailand. The study aims to use isotopic data to give insight into patterns of migration and subsistence strategy during prehistory. Ban Non Wat is the most comprehensively excavated site in the Upper Mun River Valley (UMRV), and understanding of prehistoric society in this area is crucial to answering questions of how social complexity arose in the region. Carbon isotope analysis has highlighted migrant individuals invisible to strontium isotope analysis and shown links between unusual burial practice and differences in diet. Results also indicate that diet changed substantially through time, with more reliance on rice in the Bronze Age, correlated with an increase in social differentiation. There is a move away from reliance on rice agriculture in the Iron Age, a time when oxygen isotopes show that environmental conditions were becoming drier, possibly resulting in rice agriculture becoming less viable.     

Stable isotopic evidence for diet in a Roman and Late Roman population from Leptiminus,Tunisia

This study investigates the diet of the Roman and Late Roman population of Leptiminus on the Mediterranean coast of Tunisia. Stable carbon and nitrogen isotope analysis of human bone collagen and carbonate samples obtained from individuals buried in four cemeteries at Leptiminus was conducted in order to reconstruct the diet of the population, investigate the relative importance of marine vs. terrestrial resources, explore sex-, age-, and status-based variations in diet, examine temporal changes in the types of foods consumed, and compare the diet at Leptiminus with that of other Roman populations. The results of this study indicate that the residents of Leptiminus consumed a diet that was heavily reliant on terrestrial plant resources with the addition of a significant amount of marine resources. There were no significant sex differences in isotope values. In contrast, distinct dietary differences were seen between the adults and children. Nitrogen isotope values suggest that weaning began before the age of two and was completed by about 3 years of age, a finding consistent with previous isotopic studies of Roman samples. A temporal shift in diet is suggested by the nitrogen isotope values measured in samples from the most recent cemetery. A comparison of the data from Leptiminus with that derived from other Roman sites indicates that regional variability in diet existed within the Empire.     

晚清社会传闻的宏观态势观照

晚清时期的社会传闻,非常盛行并且内容复杂。从时间上看,高潮迭起又延绵不断;从空间上看,存在大范围、大规模的流布场。其承载形式,则呈多类多样性:口头传播为基本形态;书面形式有报刊新闻型、函牍型、书籍载传型、揭帖型、图示型等。内容上重现复杂性,除了题材方面的表现外,还典型地体现在世俗性内容与神异性内容的混合、叙事性内容与评价性内容的交融。     

Stable Isotopic Analysis of Human Skeletons from the Sunhung Mural Tomb,Yeongju, Korea: Implication for Human Diet in the Three Kingdoms Period

This study reports the results of stable isotope analyses (carbon, nitrogen and sulphur) of human bone collagen from the Sunhung mural tomb from the Three Kingdoms Period of Korea (AD 300–668). The stable isotope data indicate that the main source of protein in the diet of the interred seven Sunhung individuals came from C₃‐based terrestrial resources, and there was an isotopic variation between individuals at this site. To investigate dietary patterns in the Three Kingdoms period, we compared our results with reported isotopic data from other southeastern Three Kingdoms sites (Imdang‐dong, Songhyeon‐dong and Yean‐ri). We found that the Sunhung individuals had similar isotope ratios to the people from these other sites. However, there was noticeable isotopic difference among individuals from each study site, although much of the dietary protein in each site was mainly from terrestrial sources. We propose that the most parsimonious explanation for this isotopic pattern is variation in social status during this time period. Copyright © 2012 John Wiley & Sons, Ltd.     

Paleodietary analysis of the sacrificial victims from the Feathered Serpent Pyramid,Teotihuacan

The consumption of different types and quantities of food frequently serves as a practice that expresses and reinforces social distinctions among individuals within complex societies. This study explores the dietary behavior of probable sacrificial victims interred within the offering complex underlying the Feathered Serpent Pyramid as a line of evidence concerning the identities and life experiences of individuals selected for inclusion within one of Teotihuacan’s public monuments. Stable carbon, nitrogen, and oxygen isotope values from rib samples of 12 individuals within the Feathered Serpent Pyramid complex were compared with those of 14 individuals interred in residential contexts within the city. Results provide new information concerning daily subsistence at Classic period Teotihuacan (ca. A.D. 200–600) and highlight the dietary distinctiveness of individuals interred within the Feathered Serpent Pyramid as compared to the general residential population of the site, particularly in terms of the carbon isotope composition of protein sources consumed by a number of the sacrificial victims. Oxygen isotope analysis suggests that most individuals from the Feathered Serpent Pyramid resided within the local Teotihuacan area during the years immediately prior to their deaths, indicating that the unique dietary pattern seen in stable carbon isotope values cannot be attributed to nonlocal residence prior to sacrifice. Rather, these dietary differences may suggest that the group of individuals selected for interment within the Feathered Serpent Pyramid offering complex maintained a distinctive social or economic identity as compared to the rest of the Teotihuacan population during their lives.     

Sulphur isotope evidence for freshwater fish consumption: a case study from the Danube Gorges,SE Europe

To explore the use of sulphur isotopes as an indicator of the consumption of freshwater fish, we undertook sulphur isotope analysis on bone collagen extracted from humans and animals from five archaeological sites from the Danube Gorges region dating from the Mesolithic to the middle Neolithic periods. The results show a difference in the sulphur isotope values between freshwater and terrestrial ecosystems of 8.7‰. To reconstruct human diets, bone collagen from 24 individuals was analysed for carbon, nitrogen and sulphur isotopic values. The nitrogen isotope ratios ranged from 10.3 to 16.5‰ and the carbon isotope ratios ranged from −20.8 to −18.3‰. Low nitrogen isotope values were found for individuals with low sulphur isotope ratios reflecting the low sulphur isotopic values of the terrestrial animals. The highest human nitrogen isotope values coincided with higher sulphur isotope ratios, which are related to the higher sulphur isotope values of the freshwater fish. Intermediate human sulphur isotopic ratios between these two extremes showed mixed diets of both terrestrial and freshwater resources.     

铜同位素分析法在考古研究中的应用探讨

最新地球化学研究发现,自然界不同地质条件和成矿环境中的铜同位素组成存在显著差异。根据铜矿中铜同位素变化规律,考古学家已将铜同位素作为一种新的示踪剂应用于考古探源研究之中。文章介绍了铜同位素地球化学的最新发展、考古应用原理、实验方法及相关的考古应用实例。认为尽管自然界铜同位素的变化较为复杂且铜同位素地球化学还处于形成发展阶段,但铜同位素分析法在含铜器物的产地研究中已显示出了较好的应用前景。随着铜同位素地球化学研究的深入及分析技术的进一步提高,铜同位素分析法将会在考古研究中发挥更大的作用。     

The Last Domicile of the Iceman from Hauslabjoch: A Geochemical Approach Using Sr,C and O Isotopes and Trace Element Signatures

We present Sr, C and O isotope ratios and quantitative ratios of trace element ratios in the rib and the femur of the Tyrolean Iceman “Ötzi”. The results from the rib and the femur are compared with those obtained from pre-industrial historic human skull bone fragments collected in the late 19th century from charnel houses located on different geological backgrounds throughout North and South Tyrol. Comparison of strontium isotope data from the bone fragments locates the Iceman's domicile, during the last 5 to 10 years of his life, to the crystalline part of the Central Alps. Statistical analysis of the trace element ratios, together with oxygen isotope results, suggests that the Iceman probably spent most of his last years in southern elevated part of the Ötztal. However, the results from Iceman only represent those from a single individual and are not a representative average of a group. It cannot therefore be established with absolute certainty that the original trace element signatures were conserved, especially during the first stage of mummification. Our conclusions should therefore be regarded as tentative, but nevertheless the best possible indication his domicile, and a stimulus for further research.     

The children of Kaminaljuyu: Isotopic insight into diet and long distance interaction in Mesoamerica

Known for its spectacular tombs and adobe talud–tablero architecture, the highland Guatemalan city of Kaminaljuyu is key to models of long distance interaction in Mesoamerica. We use stable isotopic data from human bone, dentine and tooth enamel to reconstruct Kaminaljuyu’s dietary history. Stable carbon isotope ratios and alkaline earth ratios of enamel carbonate indicate a decline in maize consumption from Preclassic to Classic periods, perhaps due to the desiccation of Lake Miraflores, which was used to irrigate Late Preclassic fields. Stable oxygen and strontium isotope ratios in enamel shed light on the geographic origin of Early Classic skeletons, and show that the central skeletons in the tombs were local children. However, four decapitated skulls and two peripheral skeletons show enriched oxygen ratios, similar to Lowland Maya sites. Strontium isotope ratios indicate that most of these are from an area underlain by Cretaceous limestones; one is from a metamorphic region. Two individuals may have traveled to or from Central Mexico. The greater evidence for lowland individuals among the tomb skeletons implies that political connections with the Maya area were more significant to elites at Kaminaljuyu than was direct contact with Central Mexico.     

Evidence for “Celtic migrations”? Strontium isotope analysis at the early La Tène (LT B) cemeteries of Nebringen (Germany) and Monte Bibele (Italy)

Strontium isotope analysis on human remains from the Iron Age (4th/3rd century BC) cemeteries of Nebringen, Germany and Monte Bibele, Italy were carried out to investigate the role of residential changes during the period of the historic “Celtic migrations”. From an archaeological perspective, the location of the cemeteries in the Celtic core (Nebringen) and expansion area (Monte Bibele), and the distinctive development of their material culture, suggest that the buried populations had differing mobility rates. On the contrary, the strontium results indicate that only few individuals were mobile or non-local. There is, however, a difference in variation of strontium isotope ratios between the two studied cemeteries, presumably caused by differing geological conditions. In Nebringen changing use of cultivated land in a geologically heterogeneous environment most likely caused varying strontium isotope ratios even within the same jaw, while individual mobility over longer distances can also not be excluded. In Monte Bibele the range of strontium isotope ratios is narrow, and this may be explained by a community living in the same village and using the same agricultural resources. For various prehistoric time periods it has been suggested that some population groups were more mobile than others, for example because they had special social roles. In the two cemeteries studied here, males have slightly more often a non-local birthplace or moved during childhood. In contrast, females had isotope signatures which are more consistent with the local geological environment. Male mobility is, however, not correlated with burial as a warrior, and patrilocal residential patterns were not observed among females. Foreign and local items are found with isotopically local and non-local individuals and objects per se do not indicate descent. The motives for residential changes were, therefore, varied and not constrained to a specific area or population group. The presented dataset provides details on the way of life and land-use in the Celtic communities, for which information is otherwise absent.     

High-resolution sclerochronological analysis of the bivalve mollusk Saxidomus gigantea from Alaska and British Columbia: techniques for revealing environmental archives and archaeological seasonality

The butter clam, Saxidomus gigantea, is one of the most commonly recovered bivalves from archaeological shell middens on the Pacific Coast of North America. This study presents the results of the sclerochronology of modern specimens of S. gigantea, collected monthly from Pender Island (British Columbia), and additional modern specimens from the Dundas Islands (BC) and Mink and Little Takli Islands (Alaska). The methods presented can be used as a template to interpret local environmental conditions and increase the precision of seasonality estimates in shellfish using sclerochronology and oxygen isotope analysis. This method can also identify, with a high degree of accuracy, the date of shell collection to the nearest fortnightly cycle, the time of day the shell was collected and the approximate tidal elevation (i.e., approx. water depth and distance from the shoreline) from which the shell was collected.Life-history traits of S. gigantea were analyzed to understand the timing of growth line formation, the duration of the growing season, the growth rate, and the reliability of annual increments. We also examine the influence of the tidal regime and freshwater mixing in estuarine locations and how these variables can affect both incremental structures and oxygen isotope values. The results of the sclerochronological analysis show that there is a latitudinal trend in shell growth that needs to be considered when using shells for seasonality studies.Oxygen isotope analysis reveals clear annual cycles with the most positive values corresponding to the annual winter growth lines, and the most negative values corresponding to high temperatures during the summer. Intra-annual increment widths demonstrate clear seasonal oscillations with broadest increments in summer and very narrow increments or no growth during the winter months. This study provides new insights into the biology, geochemistry and seasonal growth of S. gigantea, which are crucial for paleoclimate reconstructions and interpreting seasonality patterns of past human collection.     

Strontium isotope analysis in ancient glass from South Asia using portable laser ablation sampling

In order to carry out strontium (Sr) isotope analysis, glass artefacts from South Asia were sampled with portable laser ablation (pLA), a relatively novel sampling technique that leaves damage invisible to the naked eye. Subsequently, thermal ionization mass spectrometry (TIMS) was used to obtain Sr isotope ratios after sample dissolution and separation. In this study, the goal was twofold: to determine whether the measurements of Sr isotope ratios were impacted by using a portable laser as a sample tool; and to assess the pertinence of using Sr isotope ratios to provenance Indian glass. Despite a deterioration in the precision of the measurement of the Sr isotope ratios for artefacts sampled with pLA compared with the traditional sampling method, the Sr isotope ratios of certain Indian glass are so different that this does not affect their separation but a comparison of data sets obtained using standard methods and pLA might be challenging.     

LEAD ISOTOPE ANALYSES OF ISLAMIC POTTERY GLAZES FROM FUSTAT,EGYPT*

Lead isotope analyses have been undertaken on a group of Islamic lead‐glazed pottery artefacts from Fustat, Egypt, spanning the period from the eighth to the 14th century ad , that had previously been the subject of a comprehensive typological, chronological, petrographic and technological study. Comparison of the lead isotope ratios for the glazes with those for lead ores from Egypt, Iran, Tunisia, Anatolia, Greece, Sardinia and Spain provided information on the possible sources of the lead used in the production of the glazes. The results show that the lead used in glaze production by the Islamic potters at Fustat was most probably obtained from distant ore sources in Iran or Tunisia, Sardinia, Spain and the Taurus Mountains. Different ore sources were favoured in different periods and, to a limited extent, for different types of pottery, but at no time did the Fustat potters use the potentially more accessible Egyptian ore sources.     

Food for Rome: A stable isotope investigation of diet in the Imperial period (1st–3rd centuries AD)

During the Empire, the population of Rome was composed mostly of lower-class free citizens and slaves. Viewed from historical records, the Roman diet included primarily olives, wine, and wheat, but poor and enslaved Romans may have eaten whatever they were able to find and afford, leading to significant heterogeneity in the Roman diet. Previous carbon and nitrogen isotope analyses of skeletons from Imperial Italy have begun to reveal variation in diet, but little is known about what people ate in the capital city. This study complements previous work by adding new isotope data from human skeletons found in two Imperial-period (1st–3rd centuries AD) cemeteries in Rome. These data suggest that urban and suburban diets differed, most notably in the consumption of the C₄ grain millet. Comparing these new data with all published palaeodietary data from Imperial Italy demonstrates that significant variation existed in the diet of the common people.