The influence of poorly interconnected fault zone flow paths on spring geochemistry

Thermal springs commonly occur along faults because of the enhanced vertical permeability afforded by fracture zones. Field and laboratory studies of fault zone materials document substantial heterogeneities in fracture permeabilities. Modeling and field studies of springs suggest that spatial variations in permeability strongly influence spring locations, discharge rates and temperatures. The impact of heterogeneous permeability on spring geochemistry, however, is poorly documented. We present stable isotope and water chemistry data from a series of closely spaced thermal springs associated with the Hayward Fault, California. We suggest that substantial spatial variations observed in δ¹⁸O and chloride values reflect subsurface fluid transport through a poorly connected fracture network in which mixing of subsurface waters remains limited. Our measurements provide insight into the effect of fracture zone heterogeneities on spring geochemistry, offer an additional tool to intuit the nature of tectonically induced changes in fault zone plumbing, and highlight the need to consider local variations when characterizing fracture zone fluid geochemistry from spring systems with multiple discharge sites.     

The Freshwater-Supply Problems of Mankind

Four Soviet hydrologists stress the usefulness of the water-balance principle in estimating the volume of water resources available to mankind. They carefully distinguish between the stable subsurface component of runoff, which has been mapped for the USSR at 1:5 million (and is now being mapped at 1:2.5 million) and the surface runoff, or flood, component. Measures are recommended to increase subsurface runoff at the expense of the surface component. These measures include autumn plowing to reduce sheetwash of snowmelt waters in spring, snowpack management in winter and windbreak planting. Other meliorative measures are irrigation and swamp drainage, both of which need to be placed on a more scientific basis with properly worked-out principles and norms. In discussing the world water-supply problem, the authors rule out recourse to new water sources, such as seawater desalination and glacier melting, and insist that mankind must preserve existing water resources by curbing the discharge of waste waters into natural bodies of water. The proposed recycling principles would increase consumptive use for water-supply needs, but would substantially reduce total withdrawals below the level that can be expected if present water-use practices continue to be followed.     

故宫养心殿燕喜堂古建筑琉璃构件的釉面损毁研究

故宫建筑琉璃构件面临最主要的病变是琉璃釉层的大面积脱落,以养心殿燕喜堂最为典型的琉璃筒瓦为研究对象,分析釉层和胎体的成分、形貌以及热性能等,同时进行不同条件下的模拟循环试验发现:环境温湿度变化剧烈,会引起琉璃样品的釉层脱落,其中样品釉层越厚、胎釉与胎体的热扩散性能和热膨胀性能差异越大,样品釉层脱落的速率会越快。分析原因主要在于琉璃样品从高温急剧降到低温等循环过程发生的“淬火”,样品从高温下降至冷冻室冰水混合物中表面釉层的温度下降速率相对最大,这种温度的急剧变化会引起釉层张应力以及胎釉界面热应力的分布不均,釉层脱落破坏最为严重。对比琉璃样品发生破坏时的模拟实验条件和实际环境条件,与夏季的高温/暴雨最为相似,推测可能成为破坏古建筑琉璃釉面脱落的最主要因素之一。研究成果可为后期文物保护和修复方案的提出提供科学依据。     

The Water Problem in the Deserts of the USSR

A regional review of existing and planned irrigation projects in the desert zone of the Soviet Union envisages the use of water from the Siberian streams in the northern section of the desert zone. For increased water supplies in the south, the author looks to other potential sources such as artificial increases of precipitation in the mountains of Central Asia, elimination of wild growths of water-loving plants, and technological advances that will make possible the economical desalting of water from salt lakes and of mineralized subsurface waters.     

Response of Alum Rock springs to the October 30, 2007 Alum Rock earthquake and implications for the origin of increased discharge after earthquakes

The origins of increased stream flow and spring discharge following earthquakes have been the subject of controversy, in large part because there are many models to explain observations and few measurements suitable for distinguishing between hypotheses. On October 30, 2007 a magnitude 5.5 earthquake occurred near the Alum Rock springs, California, USA. Within a day we documented a several‐fold increase in discharge. Over the following year, we have monitored a gradual return towards pre‐earthquake properties, but for the largest springs there appears to be a permanent increase in discharge. The Alum Rock springs discharge waters that are a mixture between modern (shallow) meteoric water and old (deep) connate waters expelled by regional transpression. After the earthquake, there was a small and temporary decrease in the fraction of connate water in the largest springs. Accompanying this geochemical change was a small (1–2°C) temperature decrease. Combined with the rapid response, this implies that the increased discharge has a shallow origin. Increased discharge at these springs occurs both for earthquakes that cause static volumetric expansion and for those that cause contraction, supporting models in which dynamic strains are responsible for the subsurface changes that cause flow to increase. We make a quantitative comparison between the observed changes and model predictions for three types of models: (i) a permanent increase in permeability; (ii) an increase in permeability followed by a gradual decrease to its pre‐earthquake value; and (iii) an increase of hydraulic head in the groundwater system discharging at the springs. We show that models in which the permeability of the fracture system feeding the springs increases after the earthquake are in general consistent with the changes in discharge. The postseismic decrease in discharge could either reflect the groundwater system adjusting to the new, higher permeability or a gradual return of permeability to pre‐earthquake values; the available data do not allow us to distinguish between these two scenarios. However, the response of these springs to another earthquake will provide critical constraints on the changes that occur in the subsurface and should permit a test of all three types of models.     

The Water Balance of the World's Continents and a Balance Estimate of the World's Freshwater Resources

The results of several years of investigation of the water balance of continents and the world's freshwater resources are presented. Through the use of interpolation relationships to make up for data gaps, maps are compiled for the basic elements of the water balance of the world: total runoff, including its surface and subsurface components, evaporation, gross wetness (soil moisture) and the coefficient of subsurface alimentation of streams, which reflects much of the stable component of streamflow. Revised estimates for the water-balance elements are offered for continents on the basis of revised data. The per capita water supply of continents is calculated, with separate listing of the stable component of runoff, consisting not only of the subsurface flow to streams but also the portion of surface streamflow that is regulated through lakes and reservoirs.     

干冰清洗技术应用于陶瓷文物清洗的探索研究

在文物修复的过程中,首先的工作就是对器物进行清洗,虽然现阶段清洗工艺的效果不错,但使用的试剂与手段造成污染较大,对人体与环境都会造成损害.因此,寻找新的清洗材料与清洗手段,对于文物修复工作的持续发展非常重要。为此,本研究应用干冰清洗技术,工业级清洗机器对在一件晚清胎质较厚、釉质较好的瓷器上进行了清洗实验,并对清洗工艺进行了实验与评估。实验结果表明,干冰清洗技术应用在清除瓷器表面的环氧树脂及污迹效果显著,可谓立竿见影,对瓷器的釉面未造成损害,并且整个清洗流程非常的环保、无污染,清洗完毕只剩下污迹。虽然深层次的环氧树脂清洗效果不明显,但随着今后进一步改善操作技术与清洗工艺,为最终实现环保而可持续的文物修复流程提供经验。     

Origins of formation waters in the Llanos foreland basin of Colombia: geochemical variation and fluid flow history

Wells located in the Colombian Andean foreland often produce biodegraded hydrocarbons and relatively fresh water (total dissolved solids concentrations of 2000 mg l^?1 dominate across most of the basin). The ratio of water to hydrocarbon in the produced fluids is high and has often been interpreted by explorationists and simulation engineers as being due to massive meteoric water invasion. To challenge this hypothesis, previously published and existing data are compiled here, along with 68 new water samples collected from both the surface (rivers) and subsurface (production wells), which are analyzed for major elements, salinity, and stable isotope compositions. The data indicate a mixed origin for the water, which involves formation water, meteoric water, and a third source that we interpret as being related to diagenetic processes (such as clay dehydration). Analyses of the variation of the parameters from north to south and west to east allow us to define the mixtures as coming from waters of different origins and make it possible to determine the relative contribution of each source.     

Changes in the Ice Boundary of the Vestfold Hills,East Antarctica, 1947 to 1990

The position of the ice boundary around the Vestfold Hills, East Antarctica (68°30'S, 78°00'E) was observed using a 43 year record of aerial photography from 1947 to 1990. The southern boundary, formed by Sørsdal Glacier, showed two main areas of ice retreat and no areas of advance. Stagnation and retreat of this boundary is interpreted to be contraction to former limits following the Chelnok Glaciation which occurred 7lt; 700 years BP. The eastern or continental ice sheet boundary showed five sites of rapid, localised incision and downwasting around supraglacial gullies. While no area of continental ice was noted to advance, continued accumulation and firnification of wind-drifted snow in the proglacial zone of the ice sheet in the southeastern corner of the hills may signify a locally positive ice mass balance. Until ice mass balance studies are carried out in the ablation zone surrounding the hills, evidence concerning whether the ice sheet boundary is retreating, stable or advancing will remain equivocal.     

Radiation Conditions in the Territory of the USSR in Various Geological Periods

The components of the radiation balance and the heat balance are computed for Lat. 45°, 60° and 75°N for various geological periods. Cloud cover is estimated for each geological period on the basis of continentality, the character of the underlying surface, type of climate and landscape as well as the known mean magnitude during the present geological period. Albedo is based on the character of the underlying surface indicated by paleogeographic data. Effective outgoing radiation is also based on the character of the underlying surface as well as cloud cover and atmospheric moisture. The disposition of net radiation at the earth's surface is broken down into sensible and latent heat fluxes, the soil heat flux being ignored. The resulting mean data on radiation and heat-balance components are then used to reconstruct the probable range of climatic situations that may have existed in what are now the polar, middle, and subtropical latitudes of the territory of the USSR.     

Desalting of Water by Natural Freezing for Farm use

The author proposes methods for desalting brackish or salty groundwater in the arid zone for use in animal husbandry and crop raising. Stock-raising needs would be met by storing freshwater obtained in winter for year-round use. Crop production would be made possible by freezing a layer of ice over prospective cropland and saturating the soil with meltwater in the spring as in the basin system of once-a-year irrigation.     

Discussion on the variation characteristics of water content of Quaternary soil cover on the top of Yungang Grottoes and the problem of water seepage in caves北大核心

为研究云冈石窟顶部土壤覆盖层的含水率变化情况,建设了土壤环境监测网收集云冈石窟土壤含水率实时监测数据,并分析其时空变化特征及影响因素。结果表明,平坦地形条件下云冈石窟顶部第四纪土壤覆盖层含水率时空变化特征明显:年变化具有周期性,垂向上随深度逐层降低(冬季除外)。春、夏季土壤含水率抬升、储水,秋、冬季下降、失水;在春、夏日土壤含水率呈白天上升、夜晚下降趋势,秋、冬日则呈白天下降、夜晚也下降趋势。土壤含水率时刻处于不停的运动变化之中,受温度、大气降水、微地形等众多因素影响,山体边坡浅层土壤可能为侧向饱和流的入渗通道。降雨对土壤含水率的影响深度与实际入渗深度不一致。云冈窟内顶板及岩壁上部、中部含水率主要受降雨渗透窟顶土壤层、沿岩体裂隙通道进入洞窟的渗漏水控制,而岩壁底部含水率更多受窟前不饱带和与地下毛细水的影响。多年的防水实践也证明云冈洞窟渗漏水主要来自于石窟顶部及附近区域。防渗排水始终是云冈洞窟渗漏水治理的主导思路,建议应根据窟顶土壤厚度、地形地貌和遗址分布等分区治理,充分发挥土壤的防渗作用,减少对土壤覆盖层的过度干预。防渗层材料在具有防渗作用的前提下,应具备一定的透气性,满足“洞窟—覆盖层—大气环境”之间的水汽循环。     

Barite–pyrite mineralization of the Wiesbaden thermal spring system, Germany: a 500-kyr record of geochemical evolution

Barite–(pyrite) mineralizations from the thermal springs of Wiesbaden, Rhenish Massif, Germany, have been studied to place constraints on the geochemical evolution of the hydrothermal system in space and time. The thermal springs, characterized by high total dissolved solids (TDS) contents and predominance of NaCl, ascend from aquifers at 3–4 km depth and discharge at a temperature of 65–70°C. The barite–(pyrite) mineralization is found in upflow and discharge zones of the present‐day thermal springs as well as at elevations up to 50 m above the current water table. Hence, this mineralization style constitutes a continuous record of the hydrothermal activity, linking the past evolution with the present state of this geothermal system. The sulphur isotope signatures of the mineralization indicate a continuous decrease of the δ³⁴S of sulphate from +16.9‰ in the oldest barite to +10.1‰ in the present‐day thermal water. The δ³⁴S values of barite closely resemble various recently active thermal springs along the southern margin of the Rhenish Massif and contrast strongly with different regional ground and mineral waters. The mineralogical and isotopic signatures, combined with calculations based on uplift rates and the regional geological history, indicate a minimum activity of the thermal spring system at Wiesbaden of about 500 000 years. This timeframe is considerably larger than conservative models, which estimate the duration of thermal spring systems in continental intraplate settings to last for several 10 000 years. The calculated equilibrium sulphur isotope temperatures of coexisting barite and pyrite range between 65 and 80°C, close to the discharge temperature of the springs, which would indicate apparent equilibrium precipitation. Kinetic modelling of the re‐equilibration of the sulphate–sulphide pair during water ascent shows that this process would require 220 Myr. Therefore, we conclude that pyrite is formed from precursor Fe monosulphide phases, which rapidly precipitate in the near‐surface environment, preserving the isotope fractionation between dissolved sulphate and sulphide established in the deep aquifer. Equilibrium modelling of water–mineral reactions shows slight supersaturation of barite at the discharge temperature. Pyrite is already strongly supersaturated at the temperatures estimated for the aquifer (110°C) and processes in the near‐surface environment are most probably related to contact of the thermal water with atmospheric oxygen, resulting in formation of oxidized intermediate sulphur species and precipitation of Fe monosulphide phases, which subsequently recrystallize to pyrite.     

Paleo-Eskimo kitchen midden preservation in permafrost under future climate conditions at Qajaa,West Greenland

Remains from Paleo-Eskimo cultures are well-documented, but complete preservation is rare. Two kitchen middens in Greenland are known to hold extremely well-preserved organic artefacts. Here, we assess the fate of the Qajaa site in Western Greenland under future climate conditions based on site characteristics measured in situ and from permafrost cores. Measurements of thermal properties, heat generation, oxygen consumption and CO₂ production show that the kitchen midden can be characterized as peat but produces 4–7 times more heat than natural sediment. An analytical model from permafrost research has been applied to assess future thawing of the midden. Results show that the preservation conditions are controlled by freezing temperatures and a high water/ice content limiting the subsurface oxygen availability. Threats to the future preservation are related to thawing followed by drainage and increasing subsurface oxygen availability and heat generation. The model predicts that the unique 4000-year-old Saqqaq layer below more than 1 m of peat is adequately protected against thawing for the next 70 years.     

Hydrologic response of a small forested swamp complex,Seymour Valley,British Columbia

Wetlands are common in Coastal Western Hemlock forests yet the hydrologic processes that generate runoff from small swamps are not completely understood. Direct field observations, hydrologic, and electrical conductivity data were collected from a gently sloping forested swamp complex from July to November 2009. Swamps occupied depressions between raised mounds (0.1 to 3 m high) and were connected by an ephemeral creek. Runoff was controlled by antecedent moisture conditions and influenced by basin microtopography. Two hydrologic regimes occurred during the study period and different runoff processes dominated each regime. Runoff was generated by subsurface flow during dry antecedent conditions as swamps remained hydrologically disconnected from each other. Runoff was generated by surface outflow from hydrologically connected swamps during wet antecedent conditions as ponded water spilled out of the depressions. The forested swamp complex produced a faster but limited hydrologic response during dry antecedent conditions compared to a slower but greater hydrologic response during wet antecedent conditions. Stormwater runoff and runoff ratios were up to two orders of magnitude higher in wet conditions than during similarly sized events in dry conditions. These factors should be considered when designing monitoring programs or runoff models in forested swamps with significant microtopography. Field surveys and estimates of hydrologic inputs and outputs may be useful in predicting the potential hydrologic connectivity of isolated forested swamps.     

Mathematical modeling of phase separation of seawater near an igneous dike

We provide a simplified treatment of phase separation of seawater near an igneous dike to obtain rough estimates of the thickness and duration of the two‐phase zone, the volume fractions of vapor and brine formed, and their distribution in the subsurface. Under the assumption that heat transfer occurs mainly by thermal conduction we show that, for a 2‐m wide dike, the maximum width of the two phase zone is approximately 20 cm and that a zone of halite is initially deposited near the dike wall. The two‐phase zone is mainly filled with vapor. For a value of thermal diffusivity of a = 10^?6 m² sec^?1, the two‐phase zone begins to disappear at the base of the system after 13 days, and disappears completely by 16 days. For a lower value of thermal diffusivity, the width of the two‐phase region does not change appreciably but its duration increases as a^?1. The width of the two‐phase zone determined by this simplified model agrees reasonably well with transient numerical solutions for the analogous two‐phase flow in a pure water system; however the duration of two‐phase flow is matched better using a smaller value of a. We compare the seafloor values of vapor salinity and temperature given by the model with vapor salinity data from the ‘A’ vent at 9–10°N on the East Pacific Rise (EPR) and argue that either non‐equilibrium thermodynamic behavior or near‐surface mixing of brine with vapor in the two‐phase region may explain the discrepancies between model predictions and data.     

Scottish landform examples 45: Sgriob na Caillich: a landslide-sourced medial moraine on the Isle of Jura

ABSTRACT

Medial moraines deposited by former glaciers and ice sheets are rare in Scotland. The most prominent example is the Sgriob na Caillich moraine, which consists of two to four parallel belts of angular quartzite boulders that extend northwestwards for over 3.5?km from the SW flank of Beinn an Oir on the Isle of Jura. The boulder belts extend to within 300?m of the present coastline, where they are truncated by a low bluff and raised marine terrace. The source of the moraine coincides with bedrock gullies and cliffs that represent the scars of former rock-slope failure(s), indicating that the moraine debris was sourced by one or more rockfalls or rockslides onto the ice surface after Beinn an Oir had emerged from the thinning ice cover as a nunatak. Exposure dating of boulders on the moraine indicate that it formed at 16.6?±?0.8?ka, consistent with the timing of ice-sheet retreat in this sector. The alignment of the moraine indicates ice-margin retreat to the SE; as regional ice-sheet retreat across the adjacent offshore shelf was to the NE, this anomaly implies that a residual icefield became stranded on Jura during ice-sheet retreat.     

An Initial Analysis of River Discharge and Rainfall in Coastal New South Wales,Australia Using Wavelet Transforms

In many coastal catchments of south eastern New South Wales, Australia, changes in river morphology are a response to human impact superimposed on spatial and temporal patterns of variability in precipitation and discharge. Understanding, and preferably quantifying, spatial and temporal patterns of hydrologic variability are essential to understanding natural changes, and to separate these from artificial changes in river systems. Prediction and management of water resources are also dependent upon this understanding. We assess the variability in precipitation and discharge using the wavelet transform which projects the time series of data into a three dimensional surface of frequency, amplitude and time. The analysis reveals that changes across time often reflect changes in individual seasons and may be linked to changes in particular seasonal atmospheric circulation systems. Strong perturbations in the analysis of one catchment are consistent with documented, geomorphically‐effective, flooding sequences. The characteristics of the series in the transformed data reveal interesting differences at certain times and scales which may be a reflection of changes in larger scale atmospheric processes.     

MODIS‐derived NDVI Characterisation of Drought‐Induced Evergreen Dieoff in Western North America

Vegetation stress or mortality can be the result of many factors including drought‐induced water deficit, insect infestations and failures of, or fluctuations in, precipitation sources typical to an area. Reduction of cover and reduced health are identifiable in remotely‐sensed multispectral satellite images. A suite of images from NASA's MODIS sensor was used to calculate the Normalised Difference Vegetation Index (NDVI) during the 2000–2006 North American growing seasons. Fluctuations in NDVI over this period show a significant decline in vegetative health in the region with specific areas showing changes linked to moisture sources, prevailing wind patterns, slope aspect and solar radiation receipt. Ground‐truthing of these areas has confirmed the extent and magnitude of the dieoff signal. Historically, dieoff has been reversed through regeneration as climate conditions return to a normal regime. However, quantification of recent vegetative change in western North America suggests that the degree of change may be too severe for regrowth to occur and may have far‐reaching impacts on a scale unseen in modern times. The loss of vegetative habitat and native species in semi‐arid regions and lack of regeneration in these marginal ecosystems due to prolonged drought are growing global problems. Similar drought stress impacts on marginal ecotypes have also been observed in semi‐arid regions of Australia, South America, Asia and Africa. Observations of the spatial pattern of temperate forest vegetation globally can be used to develop a precise picture of vegetative health in these regions and how they are reacting to global climate change.     

Optical Coherence Tomography for the non-invasive investigation of the microstructure of ancient Egyptian faience

Optical Coherence Tomography (OCT) is a non-invasive subsurface 3D imaging technique based on the Michelson interferometer. The non-invasive nature of OCT and its speed of acquisition makes it possible to image large volumes of intact objects to yield a complete overview of the microstructure. The production methods for ancient Egyptian faience were first investigated using scanning electron microscopy (SEM) imaging of the microstructure in polished sections and microprobe analysis of the composition of the glass phases. These studies were based on original Egyptian faience objects and laboratory reproductions of faience beads made using three different production methods. The microstructure of the same laboratory samples and the Egyptian faience objects from the British Museum Research Laboratory Collection are re-examined using OCT. It is found that OCT virtual cross-section images can be used to group ancient faience objects into three categories on the basis of the morphology of the surface glaze layer and the glaze/core interaction layer. The OCT images correspond well with SEM images of polished sections of ancient faience objects and laboratory reproductions. The virtual cross-sections produced by OCT are somewhat limited by the penetration depth, which is affected by the high absorption coefficient of the material and, therefore, cannot always provide information on the presence or absence of interparticle glass that binds together the quartz particles in the core. Nevertheless, the top two layers are well imaged and since OCT images can be obtained rapidly and without the necessity of removing a sample, the method can be applied to a very much wider range of ancient faience objects than is possible by SEM examination of polished cross-sections. In summary, this paper examines to what extent OCT can assist the investigation of the production techniques of ancient Egyptian faience.