Chemical modification of pyroclastic rock by hot water: an experimental investigation of mass transport at the fluid–solid interface

Hydrothermal water–(pyroclastic) rock interactions were examined using flow-through experiments to deduce the effect of mass transport phenomena on the reaction process. A series of experiments were conducted over the temperature range 75–250°C, with a constant temperature for each experiment, and at saturated vapour pressure, to estimate the apparent rate constants as a function of temperature.
Based on the chemistry of analysed solutions, the water–rock interaction in the experiments was controlled by diffusion from the reaction surface and by the existence of a surface layer at the rock–fluid interface, which regulated the chemical reaction rate. The reaction progress depended to a high degree on flow velocity and temperature conditions, with element abundances in the fluid significantly affected by these factors. Mass transport coefficients for diffusion from the rock surface to the bulk solution have been estimated. Ca is selectively depleted under lower temperature conditions ( T  < 150°C), whereas Na is greatly depleted under higher temperature conditions ( T  > 150°C), and K reaction rates are increased when flow velocity increases. Using these conditions, specific alkali and alkali earth cations were selectively leached from mineral surfaces. The 'surface layer' comprised a 0.5–1.8 mm boundary film on the solution side (the thickness of this layer has no dependence on chemical character) and a reaction layer. The reaction layer was composed of a Si, Al-rich cation-leached layer, whose thickness was dependent on temperature, flow velocity and reaction length. The reaction layer varied in thickness from about 10⁻⁴ to 10⁻⁷ mm under high temperature/low fluid velocity and low temperature/high fluid velocity conditions, respectively.     

Hydrothermal convection in and around mineralized fault zones: insights from two- and three-dimensional numerical modeling applied to the Ashanti belt, Ghana

Among hydrogeological processes, free convection in faults has been cited as a possible cause of gold mineralization along major fault zones. Here, we investigate the effects of free convection to determine whether it can cause giant orogenic gold deposits and their regular spatial distribution along major fault/shear zones. The approach comprises: (i) coupled two- and three-dimensional numerical heat- and fluid-flow simulations of simplified geological models; and (ii) calculation of the rock alteration index (RAI) to delineate regions where precipitation/dissolution can occur. Then, comparing the deduced alteration patterns with temperature distribution, potential areas of gold mineralization, defined by T  > 200°C and RAI < 0, are predicted. The models are based on the orogenic Paleoproterozoic ore deposits of the Ashanti belt in western Africa. These deposits occur in the most permeable parts of the fault zone, where the lateral permeability contrast is the highest. For a simple geometry, with a fault zone adjacent to a sedimentary basin half as permeable, we note a transition from three-dimensional circulation within the fault to a two-dimensional convective pattern in the basin far from the fault. Moreover, whereas two-dimensional undulated isotherms dominate in the basin, three-dimensional corrugated isotherms result from the preferred convective pattern within the fault, thus enhancing a periodic distribution of thermal highs and lows. In our most elaborate three-dimensional model with an imposed lateral permeability gradient, the RAI distribution indicates that fluid circulation in fault zones gives rise to a spatial periodicity of alteration patterns consistent with field data.     

Modeling fluid flow in a heterogeneous, fault-controlled hydrothermal system

Previous studies have shown that most hydrothermal systems discharging at the land surface are associated with faulting, and that the location, temperature and rate of discharge of these systems are controlled by the geometry and style of the controlling fault(s). Unfortunately, the transport of heat and fluid in fault-controlled hydrothermal systems is difficult to model realistically; although heterogeneity and anisotropy are assumed to place important controls on flow in faults, few data or observations are available to constrain the distribution of hydraulic properties within active faults. Here, analytical and numerical models are combined with geostatistical models of spatially varying hydraulic properties to model the flow of heat and fluid in the Borax Lake fault of south-east Oregon, USA. A geometric mean permeability within the fault of 7 × 10⁻¹⁴ m² with 2× vertical/horizontal anisotropy in correlation length scale is shown to give the closest match to field observations. Furthermore, the simulations demonstrate that continuity of flow paths is an important factor in reproducing the observed behavior. In addition to providing some insight into possible spatial distributions of hydraulic properties at the Borax Lake site, the study highlights one potential avenue for integrating field observations with simulation results in order to gain greater understanding of fluid flow in faults and fault-controlled hydrothermal and petroleum reservoirs.     

Heterogeneity effects on possible salinity-driven free convection in low-permeability strata

Although studies of free convection commonly focus on highly permeable strata, but numerical analyses indicate that density-driven free convection may also occur in heterogeneous low-permeability strata. Traditional Rayleigh number criteria are overly conservative in predicting thermohaline convection in these systems; so, numerical models are used to make inferences on the process. Simulations with stochastic realizations of permeability fields show that dense plumes can take preferential pathways to sink through generally low-permeability strata; patch analysis using percolation theory shows that the threshold permeability for the onset of free convection can be as low as 10⁻¹⁶ m² even with a mean permeability of 10⁻¹⁸ m². Threshold permeability for the percolation pathways decreases with increasing concentration gradient, vertical correlation length and the mean and variance of the permeability. The connectedness of relatively high-permeability zones is important in initiating and controlling plume fingers of free convection in both single-layer and sand-shale sequence models. Permeable units above and below are conducive to free convection through intervening low-permeability strata if buoyancy gradients exist. This heterogeneity is on scales that are difficult to sample by drilling and too localized to be simulated in regional models but may be significant in solute transport in these systems.     

Rapid Na, Cu exchange between synthetic fluid inclusions and external aqueous solutions: evidence from LA-ICP-MS analysis

Three sets of equilibration experiments (Set 1 to Set 3) were performed in cold-seal pressure vessels to investigate the compositional modification of quartz-hosted fluid inclusions after entrapment. Each set of experiment consisted of two stages. In a pre-run, fluid inclusions containing 5–10 wt% NaCl and selected trace elements were synthesized at 700°C/140–200 MPa. These samples were then loaded into new capsules together with Cu-bearing solutions and some mineral buffers, and re-equilibrated at 600–800°C and 70–140 MPa for 6–8 days. LA-ICP-MS analysis of individual fluid inclusions reveals that in re-equilibration experiments in which the outer fluid was composed of KCl (±FeCl₂) up to 83% of the original Na content of pre-existing fluid inclusions were lost, and up to 5660 ppm Cu were gained. Other elements with larger ionic radii (i.e. K, Fe, Ba, Sr) were not exchanged, demonstrating that the inclusions remained physically intact and that Na and Cu were transported through quartz by diffusion. The observed Na loss from pre-existing fluid inclusions correlates positively with Cu gain, with about 1 Cu atom being gained per 10 Na atoms lost. Thus, Na and Cu (plus probably H) were exchanged by interdiffusion. Remarkably, this processes resulted in up to 10 times higher Cu concentrations in re-equilibrated inclusions than were present in the outer fluid, i.e. Cu diffused 'uphill'. Large variations of Cu concentrations relative to the concentration of other elements are common also in natural fluid inclusion assemblages. However, no evidence for a correlation between Cu content and Na content was found so far, suggesting that Cu diffusion in natural samples may be dominated by processes other than Na–Cu interdiffusion.     

The distribution and morphometry of lakes and reservoirs in British Columbia: a provincial inventory

An inventory of provincial lakes and reservoirs has been developed to characterise and assess the distribution and morphometry of standing water bodies in British Columbia. In the province, there are over 241,500 lakes and reservoirs greater than 1,000 m ² in size. These water bodies cover 2.37 percent of the province area and contain an estimated 521 km ³ of water (312 km ³ in natural lakes and 209 km ³ in reservoirs). A hypsometric relation suitable for order-of-magnitude estimates of lake volume from lake area is presented. Based on the distribution and morphometric attributes of lakes, several distinctive limnologic regions were identified, including the northeastern Alberta Plateau (highest proportion of circular lakes), the southwestern Alberta Plateau (lowest lake density/coverage and highest proportion of irregularly shaped lakes) and the Milbanke Strandflat (highest density of lakes). Observed regional and scale-related patterns in lake distribution/morphometry appear to be largely related to geomorphic controls, particularly tectonic and glacial history. Large-scale hydrologic implications of these standing water bodies and potential ecosystem/water resource management applications of the provincial inventory are also discussed.     

Numerical simulation of mylonitization and structural controls on fluid flow and mineralization of the Hetai gold deposit,west Guangdong,China

The Hetai gold deposit (HGD) is a typical altered mylonite type gold mine in a ductile shear zone in western Guangdong, China. Geomechanical simulations of the HGD were carried out in this paper to examine the importance of the dilation‐driven fluid circulation in gold mineralization. The results show that three evenly‐spaced NNE shear zones of enhanced dilation are produced in the study area. The calculated principal compressive stress in the X direction in these zones ranges between ?420 and ?650 MPa, in line with estimates of ore‐forming pressure (fluid pressure). Ore forming fluid is focused into these features, as observed in the field. The calculated differential stress decreases from 275~350 to 148~225 MPa during the formation of mylonite zones. These, together with geological structural analysis and fluid pressure measurements, indicate that the mylonitization zone can provide a place of fluid focusing and a favorable environment for gold mineralization.     

Permeability of the continental crust: dynamic variations inferred from seismicity and metamorphism

The variation of permeability with depth can be probed indirectly by various means, including hydrologic models that use geothermal data as constraints and the progress of metamorphic reactions driven by fluid flow. Geothermal and metamorphic data combine to indicate that mean permeability ( k ) of tectonically active continental crust decreases with depth ( z ) according to log  k  ≈ −14–3.2 log  z , where k is in m² and z in km. Other independently derived, crustal-scale k – z relations are generally similar to this power-law curve. Yet there is also substantial evidence for local-to-regional-scale, transient, permeability-generation events that entail permeabilities much higher than these mean k – z relations would suggest. Compilation of such data yields a fit to these elevated, transient values of log  k  ≈ −11.5–3.2 log  z , suggesting a functional form similar to that of tectonically active crust, but shifted to higher permeability at a given depth. In addition, it seems possible that, in the absence of active prograde metamorphism, permeability in the deeper crust will decay toward values below the mean k – z curves. Several lines of evidence suggest geologically rapid (years to 10³ years) decay of high-permeability transients toward background values. Crustal-scale k – z curves may reflect a dynamic competition between permeability creation by processes such as fluid sourcing and rock failure, and permeability destruction by processes such as compaction, hydrothermal alteration, and retrograde metamorphism.     

Spatial variations in the salinity of pore waters in northern deep water Gulf of Mexico sediments: implications for pathways and mechanisms of solute transport

Spatial variations in the salinity of pore waters in sedimentary basins can provide important insight into basin-scale hydrogeologic processes. Although there have been numerous studies of brine seeps in the deep water Gulf of Mexico, much less is known about porewater salinities in the vast areas between seeps. A study has been made of spatial variation in pore water salinities in sediments in an approximately 500 km by 200 km area of the northern deep water (water depth >500 m) Gulf of Mexico sedimentary basin (GOM) to provide insight into pathways and mechanisms of solute transport in this portion of the basin. A second objective was to document salinities in the upper 500 m of the sedimentary section, the approximate depth to which methane hydrates, a potential future energy resource, may be stable. Elevated salinities would reduce the P – T stability range of hydrates. Salinities were calculated from borehole logs using a dual electrical conductivity model. Even though much of the northern GOM is underlain by allochthonous salt most of the undisturbed shallow sedimentary section has not been permeated by hypersaline waters. These waters are limited to areas near brine seeps. Hypersaline waters having salinities in excess of 100 g l⁻¹ become more common at subseafloor depths of 2 km and greater. A field study at Green Canyon 65 and published numerical simulations of fluid flow above tabular salt bodies suggest that brines produced by salt dissolution migrate laterally and pond above salt and/or within minibasins and that the dominant mechanism of vertical solute transport is a combination of compaction-driven advection and diffusion, not large-scale thermohaline overturn. Superimposed on this diffuse upward flux of dissolved salt is the more focused and localized expulsion of saline fluids up faults.     

Simulation of the impact of faults on CO2 injection into sandstone reservoirs

Numerical simulations of multiphase CO₂ behavior within faulted sandstone reservoirs examine the impact of fractures and faults on CO₂ migration in potential subsurface injection systems. In southeastern Utah, some natural CO₂ reservoirs are breached and CO₂‐charged water flows to the surface along permeable damage zones adjacent to faults; in other sites, faulted sandstones form barriers to flow and large CO₂‐filled reservoirs result. These end‐members serve as the guides for our modeling, both at sites where nature offers ‘successful’ storage and at sites where leakage has occurred. We consider two end‐member fault types: low‐permeability faults dominated by deformation‐band networks and high‐permeability faults dominated by fracture networks in damage zones adjacent to clay‐rich gouge. Equivalent permeability (k) values for the fault zones can range from <10^?14 m² for deformation‐band‐dominated faults to >10^?12 m² for fracture‐dominated faults regardless of the permeability of unfaulted sandstone. Water–CO₂ fluid‐flow simulations model the injection of CO₂ into high‐k sandstone (5 × 10^?13 m²) with low‐k (5 × 10^?17 m²) or high‐k (5 × 10^?12 m²) fault zones that correspond to deformation‐band‐ or fracture‐dominated faults, respectively. After 500 days, CO₂ rises to produce an inverted cone of free and dissolved CO₂ that spreads laterally away from the injection well. Free CO₂ fills no more than 41% of the pore space behind the advancing CO₂ front, where dissolved CO₂ is at or near geochemical saturation. The low‐k fault zone exerts the greatest impact on the shape of the advancing CO₂ front and restricts the bulk of the dissolved and free CO₂ to the region upstream of the fault barrier. In the high‐k aquifer, the high‐k fault zone exerts a small influence on the shape of the advancing CO₂ front. We also model stacked reservoir seal pairs, and the fracture‐dominated fault acts as a vertical bypass, allowing upward movement of CO₂ into overlying strata. High‐permeability fault zones are important pathways for CO₂ to bypass unfaulted sandstone, which leads to reduce sequestration efficiency. Aquifer compartmentalization by low‐permeability fault barriers leads to improved storativity because the barriers restrict lateral CO₂ migration and maximize the volume and pressure of CO₂ that might be emplaced in each fault‐bound compartment. As much as a 3.5‐MPa pressure increase may develop in the injected reservoir in this model domain, which under certain conditions may lead to pressures close to the fracture pressure of the top seal.     

The interplay of permeability and fluid properties as a first order control of heat transport, venting temperatures and venting salinities at mid-ocean ridge hydrothermal systems

While the fundamental influence of fluid properties on venting temperatures in mid-ocean ridge (MOR) hydrothermal systems is now well established, the potential interplay of fluid properties with permeability in controlling heat transfer, venting temperatures, and venting salinities has so far received little attention. A series of numerical simulations of fully transient fluid flow in a generic, across-axis model of a MOR with a heat input equivalent to magmatic supply at a spreading rate of 10 cm year⁻¹ shows a strong dependence of venting temperature and salinity on the system's permeability. At high permeability, venting temperatures are low because fluid fluxes are so high that the basal conductive heating cannot warm the large fluid masses rapidly enough. The highest venting temperature around 400°C as well as sub-seafloor fluid phase separation occur when the permeability is just high enough that the fluid flux can still accommodate all heat input for advection, or for lower permeabilities where advection is no longer capable to transfer all incoming magmatic heat. In the latter case, additional mechanisms such as eruptions of basaltic magma may become relevant in balancing heat flow in MOR settings. The results can quantitatively be explained by the 'fluxibility' hypothesis of Jupp & Schultz (Nature, 403 , 2000, 880), which is used to derive diagrams for the relations between basal heat input, permeability and venting temperatures. Its predictive capabilities are tested against additional simulations. Potential implications of this work are that permeability in high-temperature MOR hydrothermal systems may be lower than previously thought and that low-temperature systems at high permeability may be an efficient way of removing heat at MOR.     

PURPLE-DYE PRODUCTION IN LYCIA – RESULTS OF AN ARCHAEOZOOLOGICAL FIELD SURVEY IN ANDRIAKE (SOUTH-WEST TURKEY)

Summary.   In 2003 a substantial deposit of heavily fragmented shells of purple snails was by chance located at the site of Andriake, the ancient port of the Lycian city of Myra near Demre, in southern Turkey. The archaeozoological and archaeological record of a survey project in 2004 proved the identification of a large installation for the production of purple dye. Adjacent to a well preserved Hadrianic granary and partly superimposing the remains of a U-shaped building, the deposit is wrapped around three sides of a subterranean cistern. Apparently dating to the sixth century AD, the deposit contains approximately 300 m³ of shell debris. The unique chance of examining an undisturbed and well preserved manufacturing place for purple dye provides an excellent opportunity to investigate the processual particularities as well as the ecological impact of purple-dye production in antiquity.     

Supreme Court Activism in Economic Policy in the Waning Days of the New Deal: Interpreting the Fair Labor Standards Act, 1941–1946

Students of the Supreme Court universally agree that it made a dramatic shift in 1937. First, in West Coast Hotel Company v. Parrish, ¹ it retreated from the unbridled use of the Fourteenth Amendment's Due Process Clause to invalidate state economic regulatory legislation. Then, in National Labor Relations Board v. Jones and Laughlin Steel Corporation , ² the Justices widened the reach of congressional power under the Commerce Clause. This looser reading of the Commerce Clause was solidified in 1941 with United States v. Darby Lumber Company ³ and Wickard v. Filburn. ⁴ So decisive were these cases in dividing what went before from what came afterward that Bernard Schwartz has said, "The 1937 reversal marked the accession of what may be considered the second Hughes Court—so different was its jurisprudence from that of the Hughes Court that had preceded it." ⁵ Whereas the defining jurisprudence of the former had been close supervision of economic policy, the latter refused to second guess the economic wisdom of congressional (and state) regulatory initiatives. Alpheus T. Mason summarized Justice Harlan Fisk Stone's approach, which was indicative of the entire Court of this era, as one that would not say that "no economic legislation would ever violate constitutional restraints, [but that] … in this area the court's role would be strictly confined." ⁶ Confirming this approach, between 1937 and 1957 the Supreme Court struck down only four federal statutes as unconstitutional, none of which were economic in nature. ⁷     

Evolution of deformation and fault‐related fluid flow within an ancient methane seep system (Eocene,Varna, Bulgaria)

Faults are often important in fuelling methane seep systems; however, little is known on how different components in fault zones control subsurface fluid circulation paths and how they evolve through time. This study provides insight into fault‐related fluid flow systems that operated in the shallow subsurface of an ancient methane seep system. The Pobiti Kamani area (NE Bulgaria) encloses a well‐exposed, fault‐related seep system in unconsolidated Lower Eocene sandy deposits of the Dikilitash Formation. The Beloslav quarry and Beloslav N faults displace the Dikilitash Formation and are typified by broad, up to 80 m wide, preferentially lithified hanging wall damage zones, crosscut by deformation bands and deformation band zones, smaller slip planes and fault‐related joints. The formation of a shallow plumbing system and chimney‐like concretions in the Dikilitash Formation was followed by at least two phases of fault‐related methane fluid migration. Widespread fluid circulation through the Dikilitash sands caused massive cementation of the entire damage zones in the fault hanging walls. During this phase, paths of ascending methane fluids were locally obstructed by decimetre‐thick, continuous deformation band zones that developed in the partly lithified sands upon the onset of deformation. Once the entire damage zone was pervasively cemented, deformation proceeded through the formation of slip planes and joints. This created a new network of more localized conduits in close vicinity to the main fault plane and around through‐going slip planes. ¹³C‐depleted crustiform calcite cements in several joints record the last phase of focused methane fluid ascent. Their formation predated Neogene uplift and later meteoric water infiltration along the joint network. This illustrates how fault‐related fluid pathways evolved, over time, from ‘plumes’ in unconsolidated sediments above damage zones, leading to chimney fields, over widespread fluid paths, deflected by early deformation structures, to localized paths along fracture networks near the main fault.     

Effects of episodic fluid flow on hydrocarbon migration in the Newport‐Inglewood Fault Zone,Southern California

Fault permeability may vary through time due to tectonic deformations, transients in pore pressure and effective stress, and mineralization associated with water‐rock reactions. Time‐varying permeability will affect subsurface fluid migration rates and patterns of petroleum accumulation in densely faulted sedimentary basins such as those associated with the borderland basins of Southern California. This study explores the petroleum fluid dynamics of this migration. As a multiphase flow and petroleum migration case study on the role of faults, computational models for both episodic and continuous hydrocarbon migration are constructed to investigate large‐scale fluid flow and petroleum accumulation along a northern section of the Newport‐Inglewood fault zone in the Los Angeles basin, Southern California. The numerical code solves the governing equations for oil, water, and heat transport in heterogeneous and anisotropic geologic cross sections but neglects flow in the third dimension for practical applications. Our numerical results suggest that fault permeability and fluid pressure fluctuations are crucial factors for distributing hydrocarbon accumulations associated with fault zones, and they also play important roles in controlling the geologic timing for reservoir filling. Episodic flow appears to enhance hydrocarbon accumulation more strongly by enabling stepwise build‐up in oil saturation in adjacent sedimentary formations due to temporally high pore pressure and high permeability caused by periodic fault rupture. Under assumptions that fault permeability fluctuate within the range of 1–1000 millidarcys (10^?15–10^?12 m²) and fault pressures fluctuate within 10–80% of overpressure ratio, the estimated oil volume in the Inglewood oil field (approximately 450 million barrels oil equivalent) can be accumulated in about 24 000 years, assuming a seismically induced fluid flow event occurs every 2000 years. This episodic petroleum migration model could be more geologically important than a continuous‐flow model, when considering the observed patterns of hydrocarbons and seismically active tectonic setting of the Los Angeles basin.     

Numerical model of pore‐pressure diffusion associated with the initiation of the 2010–2011 Guy–Greenbrier,Arkansas earthquakes

We model pore‐pressure diffusion caused by pressurized waste‐fluid injection at two nearby wells and then compare the buildup of pressure with the observed initiation and migration of earthquakes during the early part of the 2010–2011 Guy–Greenbrier earthquake swarm. Pore‐pressure diffusion is calculated using MODFLOW 2005 that allows the actual injection histories (volume/day) at the two wells to diffuse through a fractured and faulted 3D aquifer system representing the eastern Arkoma basin. The aquifer system is calibrated using the observed water‐level recovery following well shut‐in at three wells. We estimate that the hydraulic conductivities of the Boone Formation and Arbuckle Group are 2.2 × 10^?2 and 2.03 × 10^?3 m day^?1, respectively, with a hydraulic conductivity of 1.92 × 10^?2 m day^?1 in the Hunton Group when considering 1.72 × 10^?3 m day^?1 in the Chattanooga Shale. Based on the simulated pressure field, injection near the relatively conductive Enders and Guy–Greenbrier faults (that hydraulically connect the Arbuckle Group with the underlying basement) permits pressure diffusion into the crystalline basement, but the effective radius of influence is limited in depth by the vertical anisotropy of the hydraulic diffusivity. Comparing spatial/temporal changes in the simulated pore‐pressure field to the observed seismicity suggests that minimum pore‐pressure changes of approximately 0.009 and 0.035 MPa are sufficient to initiate seismic activity within the basement and sedimentary sections of the Guy–Greenbrier fault, respectively. Further, the migration of a second front of seismicity appears to follow the approximately 0.012 MPa and 0.055 MPa pore‐pressure fronts within the basement and sedimentary sections, respectively.     

AN ANGLO-SAXON DISC BROOCH FROM BLETCHINGDON, OXFORDSHIRE, WITH STYLE II ANIMAL ART

Summary.   The brooch was found in 2003 near Bletchingdon, Oxfordshire. ¹ Its gilt Style II animal ornament and garnet setting indicate that it is a high status dress-fastener, datable to the period AD 575–610. Analysis of its form and ornament suggests that it was a local experiment in the application of a new animal style.     

The application of failure mode diagrams for exploring the roles of fluid pressure and stress states in controlling styles of fracture-controlled permeability enhancement in faults and shear zones

Permeability enhancement associated with deformation processes in faults and shear zones plays a key role in facilitating fluid redistribution between fluid reservoirs in the crust. Especially in high fluid flux hydrothermal systems, fracture-controlled permeability can be relatively short-lived, unless it is repeatedly regenerated by ongoing deformation. Failure mode diagrams in pore fluid factor and differential stress space, here termed λ–σ failure mode diagrams, provide a powerful tool for analysing how fluid pressure and stress states drive failure, associated permeability enhancement and vein styles during deformation in faults and shear zones. During fault-valve behaviour in the seismogenic regime, relative rates of recovery of pore fluid factor, differential stress and fault cohesive strength between rupture events impact on styles of veining and associated, fracture-controlled permeability enhancement in faults and shear zones. Examples of vein-rich fault zones are used to illustrate how constraints can be placed, not just on fluid pressure and stress states at failure, but also on the fluid pressurization and loading paths associated with failure and transitory permeability enhancement in faults and shear zones. This provides insights about when, during the fault-valve cycle, various types of veins can form. The use of failure mode diagrams also provides insights about the relative roles of optimally oriented faults and misoriented faults as hydraulically conductive structures. The analysis highlights the dynamics of competition between fluid pressures and loading rates in driving failure and repeated permeability regeneration in fracture-controlled, hydrothermal systems.     

Fluid evolution along multistage composite fault systems at the southern margin of the Lower Palaeozoic Anglo-Brabant fold belt, Belgium

Mineralised vein systems have been investigated at nine localities at the southern margin of the Anglo‐Brabant fold belt in Belgium. During the late Silurian to early Middle Devonian Caledonian orogeny, shear zones formed, inferred to be associated with granitoid basement blocks in the subsurface. The circulation of a metamorphic fluid, possibly originating in the Cambrian core of the fold belt, along these shear zones resulted in the formation of mesozonal orogenic mineralisation at the southern margin of the Anglo‐Brabant fold belt. The fluid had a composition dominated by H₂O–CO₂–X–NaCl–KCl. The shear zones form part of a greater fault zone, the Nieuwpoort–Asquempont fault zone, which is characterised by normal faulting that started before the Givetian and by the reactivation of the shear zones. Two fluid generations are associated with this normal faulting. First, a low salinity H₂O–NaCl(–KCl) fluid migrated through the Palaeozoic rocks after the Silurian. Based on the isotopic composition, this fluid could be a late‐metamorphic Caledonian fluid or a younger fluid that originated from the Rhenohercynian basin and interacted with Lower Devonian rocks along its migration path. Second, a high salinity H₂O–NaCl–CaCl₂ fluid was identified in the fault systems. Similar fluids have been found in southern and eastern Belgium, where they produced Mississippi Valley‐type Zn–Pb deposits. These fluids are interpreted as evaporative brines that infiltrated the Lower Palaeozoic basement, from where they were expelled during extensional tectonism in the Mesozoic.