Absolute dating of hominids and palaeolithic artifacts of the cave of La Chaise-de-Vouthon (Charente), France

Two adjacent chambers of the cave of La Chaise, Grotte de Bourgeois-Delaunay (B-D) and Grotte Suard, have been studied. Both were partly filled with detrital sediments containing lower and middle Palaeolithic artifacts and skeletal remains of pre-Neanderthalian hominids. Layers of stalagmitic calcite occur interstratified in the sediments of both chambers. Dates obtained by ²³⁰Th/²³⁴U ratios have provided a time scale for hominid and cultural evolution as represented in this cave.In B-D the lower travertine rests on a breccia containing cranial remains of juvenile Neanderthals. The base of the travertine dates to 151 ± 15 Ky (Ky = 1000 years BP); the top of the travertine yields a date of 112±5 Ky. The travertine contains pollen of an interglacial flora. Overlying detrital sediments 1·2 m in thickness contain artifacts transitional from Acheulian to Mousterian industries. They are capped by a travertine (Layer 7) whose base is dated at 100±6 Ky, and which is capped by stalagmites ranging in age down to 58±7 Ky. Overlying the travertine is sediment containing first Mousterian, and then Aurignacian artifacts.Near the base of the sediments filling Grotte Suard is a stalagmite layer dated to 249±30 Ky. It contains interglacial pollen and presumably dates to the beginning of the isotope stage 7 interglacial. Neanderthaloid hominid teeth and cranial fragments are found scattered through the overlying sediments, up to a capping stalagmitic layer whose base is dated at 101±7 Ky. The best described hominids from Suard are from a section that was probably overlying the capping stalagmite. The capping stalagmite is temporally correlated with layer 7 of B-D.     

Multi-Isotope Investigations for Scientific Characterisation and Provenance Implication of Banded Travertines from Tripolis Antique City (Denizli–Turkey)

The coloured stones used in buildings and monuments were an indicator of power and wealth during the ancient times. In this study, Tripolis city samples have been compared with Tripolis quarry samples in order to recognise the provenance of the banded travertine blocks in the ancient city. The banded travertine samples have similar mineral compositions and mainly consist of calcite with minor amounts of dolomite, aragonite, clay and iron oxide minerals. These results are also supported by CRS studies. Calcite is in the form of needle-shaped crystals ranging between 0.163–1.418?mm (in city) and 0.303–1.270?mm (in quarry). Tripolis banded travertine samples show the similar compositional spread in terms of major oxide, trace elements. δ¹³C_V-PDB values of banded travertines range from 1.93 to 5.25‰ (in city) and 2.99 to 3.99‰ (in quarry), δ¹⁸O_V-PDB values change between (?16.93)–(?10.08) ‰ and (?15.93)–(?13.01)‰, respectively. The U–Th radiometric ages are determined between ～267 and 9?ka in Tripolis city samples and ～350 and 2?ka in Tripolis quarry samples. The minero-petrographic, geochemical, C–O and U–Th isotope results fairly matched with each other. It seems highly probable that the banded travertines in Tripolis city were extracted from the Tripolis quarry, which is located at the northeast of the antique city with a distance of 3?km.     

The ESR geochronology and geology of the open‐air Palaeolithic deposits in Bollschweil,Germany*

This paper presents ESR (electron spin resonance) ages of rhinoceros and equine tooth enamel from the open‐air Palaeolithic site of Bollschweil on the western edge of the Black Forest near Freiburg, Germany. Bollschweil is one of very few archaeological sites in southern Germany to yield Lower or Middle Palaeolithic faunal and lithic materials from a buried, open‐air context. The geological context of the archaeological remains indicates that the loessic sediments have been reworked. Excavation at this site yielded a cold‐period fauna characterized by bones of mammoth, horse, large bovids and wooly rhinoceros. In the absence of any clear chronostratigraphic marker horizons, the age of the finds could not be determined without the use of a chronometric dating method. Lithic artefacts from the site, including a handaxe and a side scraper, suggest either a Middle Pleistocene or early Late Pleistocene age. The ESR dating results indicate that the deposit enclosing the archaeological finds should be assigned to oxygen isotope stage (OIS) 6, although there exists some possibility that some teeth were deposited later, in OIS 5.     

‘THERE'S NO PLACE LIKE HOME’—NO ISOTOPIC EVIDENCE FOR MOBILITY AT THE EARLY BRONZE AGE CEMETERY OF SINGEN,GERMANY

The Early Bronze Age necropolis of Singen (Hohentwiel), located near Lake Constance, represents a population from a period of technological transition in southwestern Germany. The site contains several graves with metal artefacts that originated in other parts of Central and Western Europe, and therefore these could be interpreted as being the graves of non‐local individuals. The purpose of this study was to investigate this possibility through the application of isotopic analysis. The ratios of strontium and oxygen isotopes in human enamel reflect the geological origin of food and drinking water consumed during enamel formation in early life stages. Additionally, the ratio of sulphur isotopes from bone collagen reflects the origin of foods consumed during the last 10–20 years of life of an adult individual. We used these three isotope systems to attempt to identify local and non‐local individuals at the site. We found that the isotope ratios of Sr, O and S of the humans were relatively homogeneous and generally correspond to the isotope signature of the local geology, climate and environment. We conclude that the sampled population is of local origin and does not show patterns of individual mobility, even though there is evidence for long‐distance trade and exchange of the metal artefacts at this site.     

Stable Lead Isotope Studies of Black Sea Anatolian Ore Sources and Related Bronze Age and Phrygian Artefacts from Nearby Archaeological Sites. Appendix: New Central Taurus Ore Data

The accumulated published database of stable lead isotope analyses of ore and slag specimens taken from Anatolian mining sites that parallel the Black Sea coast has been augmented with 22 additional analyses of such specimens carried out at the National Institute of Standards and Technology. Multivariate statistical analysis has been used to divide this composite database into five separate ore source groups. Evidence that most of these ore sources were exploited for the production of metal artefacts during the Bronze Age and Phrygian Period has been obtained by statistically comparing to them the isotope ratios of 184 analysed artefacts from nine archaeological sites situated within a few hundred kilometres of these mining sites. Also, Appendix B contains 36 new isotope analyses of ore specimens from Central Taurus mining sites that are compatible with and augment the four Central Taurus Ore Source Groups defined in Yener et al. (1991).     

The Neolithic site of Maddalena di Muccia (Umbria–Marche Apennine,Italy): a tip to reconstruct the geomorphological evolution and human occupation during the Late Pleistocene and the Holocene

The geomorphological evolution of the upper Chienti river basin, during the late Pleistocene and the Holocene, was characterized mainly by numerous landslides, strongly affecting the river dynamics, that produced falls, deviations and in some cases total obstructions with the formation of lakes sometimes extending for some kilometres. Moreover, particularly during the Holocene, phytoclastic and phytohermal travertine deposits were deposited in correspondence of steps along the river bed; one of these deposits, by means of radiocarbon dating, has been dated between 8260 ± 100 yr BP and 7740 ± 80 yr BP. Stromatolithic travertine is also present at the base of Holocene channels, slightly incised on the top of the upper Pleistocene alluvial plain.     

THE ORIGIN of METAL OBJECTS FROM the EARLY BRONZE AGE SITE of THERMI ON the ISLAND of LESBOS

Summary: Lead isotope analysis of metal are deposits in the Mediterranean provides an important database for provenance studies of ancient metal artefacts. the Isotrace laboratory at Oxford has accumulated during the past decade well over 2000 lead isotope data on copper and lead ores and these data (in addition to analyses published by other groups) can be used for comparisons with lead isotope compositions of ancient metal objects. In a search for the roots of Early Bronze Age metallurgy in Europe we have analysed 34 copper-based objects from the Early Bronze Age strata of the town of Thermi on the Aegean island of Lesbos. the results of lead isotope analysis show that the metal objects on this site have a quite varied origin. Some of the objects are made of copper consistent with an origin from the mineral deposits of the Troad whilst others might be made of copper from the Cyclades. However, there are also some objects which are not made of copper from any of the Aegean deposits. These imports have later parallels on the site of Kastri on Syros and amongst the objects excavated by Schliemann at Troy.     

Stable Isotopic Analysis of Human Skeletons from the Sunhung Mural Tomb,Yeongju, Korea: Implication for Human Diet in the Three Kingdoms Period

This study reports the results of stable isotope analyses (carbon, nitrogen and sulphur) of human bone collagen from the Sunhung mural tomb from the Three Kingdoms Period of Korea (AD 300–668). The stable isotope data indicate that the main source of protein in the diet of the interred seven Sunhung individuals came from C₃‐based terrestrial resources, and there was an isotopic variation between individuals at this site. To investigate dietary patterns in the Three Kingdoms period, we compared our results with reported isotopic data from other southeastern Three Kingdoms sites (Imdang‐dong, Songhyeon‐dong and Yean‐ri). We found that the Sunhung individuals had similar isotope ratios to the people from these other sites. However, there was noticeable isotopic difference among individuals from each study site, although much of the dietary protein in each site was mainly from terrestrial sources. We propose that the most parsimonious explanation for this isotopic pattern is variation in social status during this time period. Copyright © 2012 John Wiley & Sons, Ltd.     

URANIUM-SERIES DATING OF FOSSIL BONES FROM ALPINE CAVES

During the course of an investigation of fossil cave bear populations the uranium-series method for absolute age determination has been applied to bone material. The applicability of the method to bone samples from alpine caves could be demonstrated by the concordance of U/Th and U/Pa ages and cross-checks with the radiocarbon method. Stratigraphic agreement between bone ages and carbonate speleothetn ages also indicates the potential of the uranium-series method as a suitable tool for the age determination of fossil bones from alpine cave environments.     

Seasonality and intra-site variation of Neanderthal occupations in the Middle Palaeolithic locality of Payre (Ardèche,France) using dental wear analyses

The reconstruction of Palaeolithic subsistence and settlement systems at the Middle Palaeolithic site of Payre (France) is undertaken through the application of dental wear analyses combined to zooarchaeological, technological, and ecological indicators. Three archaeological levels were investigated. Level D, dated to MIS 5, could correspond to an occupation during the cold season. In levels G and F, dated to MIS 8-7, animals were probably hunted during a warmer season. According to dental wear analyses, it is likely that level F has actually recorded a succession of short occupations, contrary to what is observed in the levels G and D. Those differences in the duration of site occupation are discussed in the light of previous sedimentological, zooarchaeological, and technological studies.     

OSL dating using quartz fine grains extracted from loess in Upper Palaeolithic sites of Nihewan Basin, northern China

Although radiocarbon (¹⁴C) dating, uranium-series dating, and optically stimulated luminescence (OSL) dating have been conducted for Upper Palaeolithic sites in the Nihewan Basin, northern China, there is room for constructing a detailed chronological framework. In this study, loess sediments collected from two Upper Palaeolithic sites, Youfang site and Hutouliang site, were dated using the single-aliquot regenerative-dose (SAR) OSL protocol. OSL measurements for palaeodoses estimation used fine-grained quartz samples extracted from loess. OSL dating results were obtained as 10–17 ka. These OSL ages were consistent with the related stratigraphy of Palaeolithic sites, archaeological evidence and independent ¹⁴C ages.     

Non-ferrous metallurgy from the Phoenician site of La Fonteta (Alicante, Spain): a study of provenance

The lead isotope composition of 22 samples from the excavation of the Phoenician site of La Fonteta (Guardamar del Segura, Alicante, Spain) has been analysed in a preliminary study of their provenance. These materials span chronologically from the first half of the 8th century BC to the middle of the 6th century BC.The samples have been selected to include materials used in lead and silver production, as well as in copper-based metallurgy. Therefore, lead droplets, galena nodules and fragments of litharge have been analysed, together with a fragment of a copper ingot, an object, a melting waste composed of a Cu–Pb alloy, and two fragments of a material that we have provisionally labelled ‘Pb–Cu cupellation debris’.All these materials have been initially analysed by X-Ray Fluorescence-Spectrometry to identify their bulk compositions. Some of them have been also analysed by SEM–EDX and ICP–OES. Subsequently, lead isotope analyses (LIA) have been performed using Thermal Ionization Mass Spectrometry (TIMS). The new LIA data obtained has been compared with published lead isotope data from the Mediterranean area. The identification of different groups suggests a significant complexity of the internal and external trade routes during the Orientalising period. For this reason, the provenance study of these materials is especially important in shedding light on the commercial dynamics that the Phoenicians established with native people to control the raw materials and to commercialise finished products.     

Evolution of fluid chemistry during travertine formation in the Troll thermal springs,Svalbard, Norway

Arctic hydrothermal springs at Bockfjorden, Svalbard, have isotope and trace element signatures indicative of derivation from glacial melt waters with minor contribution from seawater. Downstream gradients in water chemistry, isotopic composition and carbonate precipitation rates have been documented for the Troll spring and travertine terrace system. The main controls on the downstream evolution of these parameters are carbon dioxide degassing, calcite precipitation, evaporation and biological activity. The carbonate precipitation rates not only show an approximately parabolic dependence on the calcite supersaturation levels, but depend also on local hydrodynamics. Downstream loss of light isotopes of oxygen and hydrogen can be explained as an effect of evaporation, as estimated using chloride as a conservative marker. Biological activity affects nitrate and bromide concentrations and influences the morphology of calcite precipitates.     

Oxalate Patinas on Stone Monuments in the Venetian Lagoon: Characterization and Origin

Calcium oxalate patinas have been sampled on architectural elements of two ancient churches located on Torcello Island (Venetian Lagoon) and subsequently analyzed. The site had been selected presenting patinas of exceptional amount and thickness, elsewhere generally found as thin alteration layers covering stone surfaces or within black crusts on monuments in urban environments. Optical and mineralogical analyses suggest that these patinas are not the result of a simple deposition process, but originate as surface “transformations” of the substrate, and are mainly composed of dihydrate calcium oxalate (weddellite) and gypsum. Among the experimental techniques, isotope analyses (C and S) have been specifically carried out aiming at achieving a better understanding of their origin and possible causes of formation. The observed carbon isotopic fingerprint reveals in fact a strong biological fractionation recorded in the oxalate patina (δ¹³C ranging from ?22.3‰ to ?28.0‰), almost exclusively attributable to C3 pathway photosynthesis processes. Slightly negative sulfur isotope ratio values seem to be inversely correlated with patina exposure to atmospheric agents and pollutants. The results obtained prove that calcium oxalate originates from a biomineralization process induced by lichen colonization in specific environmental conditions.     

Exploring the season of mound building through oxygen isotope geochemistry at the Garden Patch site,Gulf Coast Florida,USA

ABSTRACT

The American Southeast saw the development of large ceremonial village centers, the coalescence of households, and monumental architecture integrated into village layout during the Middle Woodland period (ca. AD 1–600). These shifts toward more sedentary lifeways occurred independently of, and prior to, the domestication of plants across the Southeast. This paper examines the seasonality of monumental construction at the Garden Patch site located on the central Gulf Coast of Florida. This site contains evidence for rapid mound construction that followed a predetermined site plan. Here, we present oxygen isotope analyses of archaeological mollusk shells (Crassostrea virginica) to evaluate the seasonality and periodicity of monument construction. We conclude that mound construction occurred during the cooler months of the year. Ultimately, this contributes to an anthropological understanding of the development of these early ceremonial centers in the Southeast.     

ESR Dating of the Last Interglacial Mousterian at Karaïn Cave, Southern Turkey

We have obtained ESR ages on 18 teeth from archaeological levels AH16-AH27 exposed at the east profile in compartment E at Karaïn Cave. This sequence exhibits a transition in lithic assemblage from a Classic Charentian to a Karaïn (Zagros-type) Mousterian between levels AH27 and AH25, and two calcite-cemented soils at levels AH22 and AH16 which have been interpreted as climatic warm phases. Since we found no systematic increase in tooth ages with depth, we assigned this sequence a mean early uptake (EU) age of 108 ± 23 ka and mean linear uptake (LU) age of 121 ± 27 ka, on the basis of 37 subsamples from 16 teeth. In this site, the precision of individual tooth ages suffered little from the problems associated with uranium uptake. However, this advantage was offset due to uncertainties arising from the rather inhomogeneous nature of the enclosing strata which contained various sizes of limestone blocks with intervening sediment. This led to difficulties in ascribing a precise annual gamma radiation dose to individual teeth in such a "lumpy" gamma radiation field. Considerable scattering of the individual tooth ages occurred mainly because the annual gamma dose comprised greater than 50% of the total annual dose to the individual teeth. On the basis of the ESR dating results, we infer that deposition of the two different lithic assemblages and both the penultimate and the final climatic warm phases at Karaïn probably occurred during oxygen isotope stage 5. We also conclude that these lithic assemblages are significantly different than contemporaneous Levantine Mousterian industries which occur about 700 km to the southeast.     

Study on the strontium isotope standard in pig teeth excavated from Zaoshugounao site,Shaanxi Province of China

In archaeology, strontium isotope analysis is developing into an efficient scientific technique for tracing the movement of prehistoric humans and animals. Determining the local bioavailable ⁸⁷Sr/⁸⁶Sr ratio range is the key to distinguishing whether the human or animal is indigenous to the local area. It has been shown that the ⁸⁷Sr/⁸⁶Sr ratio in the enamel of pigs can be an excellent sample to determine the range of local strontium isotope ratio at the site. However, pigs may not be all local at the site, and there is no special study on whether pigs’ different ages and tooth types impact the local strontium isotope characteristics. In this paper, the tooth enamel of 19 pigs from the Zaoshugounao site for strontium isotope ratio (⁸⁷Sr/⁸⁶Sr) by multicollector–inductively coupled plasma mass spectrometry. There were no significant differences in ⁸⁷Sr/⁸⁶Sr ratios of local pigs at different months and different molar types, which did not affect the determination of the local strontium isotope standard. Based on the local strontium isotope ratio range (0.711056–0.711476), we found that five pigs were non-local. The Jing and Wei river basins (in Guanzhong basin) and northern Shaanxi are likely sources of non-pigs.     

Uranium-series dating rock art in East Timor

At many sites throughout the world rock art paintings have been covered by naturally deposited calcite laminations, which we demonstrate can be individually dated by recently improved uranium-series methods. Here we report the application of multi-collector inductively coupled plasma mass spectrometry to measure the ages for carbonate coatings that bracket red pigment at Lene Hara cave, East Timor, which could be evidence of human painting. These analyses establish the feasibility of dating milligram samples of finely layered calcite deposits associated with archaeological evidence of human occupation. In addition to confirming an age of less then 6300 years for the visible red paintings on the carbonate surface we also report a substantially older age of 24,000 to 29,300 years for a similar, older red pigment lamination providing possible evidence for an earlier painting episode.     

The Use of Strontium Isotope Analysis to Investigate Tiwanaku Migration and Mortuary Ritual in Bolivia and Peru

Strontium isotope analysis is applied in South America for the first time in order to investigate residential mobility and mortuary ritual from ad 500 to 1000. While Tiwanaku‐style artefacts are spread throughout Bolivia, southern Peru and northern Chile during this time, the nature of Tiwanaku influence in the region is much debated. Human skeletal remains from the site of Tiwanaku and the proposed Tiwanaku colony of Chen Chen have been analysed to test the hypothesis that Tiwanaku colonies, populated with inhabitants from Tiwanaku, existed in Peru. Strontium isotope analysis supports this hypothesis by demonstrating that non‐local individuals are present at both sites.     

Wood Pseudomorphs From Level I at Abric Romani,Barcelona, Spain

Abstract

Hollow impressions with sharp boundaries reflecting the morphologies of a tree trunk, long sticks, and diverse small wood fragments appeared embedded in the 46–49,000-year-old travertine platform of Level I at the Romani Rockshelter. Biodegradation of the wood may have occurred after a rapid overlaying of the bark with calcite concretions, generated by biogeochemical agents influenced by the favorable environment of the site.