Composition of white paste inlay on the pottery from sites of the 10th–8th centuries bce in the northern Pontic region

For the first time, the mineralogical–geochemical compositions of the white paste inlay found on vessels from sites (10th–8th centuries bce ) in the northern Pontic region are investigated. Samples of the white paste on vessels from settlements, burials of sedentary groups and graves of early nomads were analysed by means of scanning electron microscopy with energy-dispersive X-ray spectrometry (SEM-EDX) and X-ray diffraction (XRD) methods. Between the 10th and eighth centuries bce , various innovations occurred in the working area. Iron processing technology and the manufacture of iron products also appeared. Other innovations were changes in the manufacturing technology of ceramics. A high-quality, polished/burnished surface and ornaments with white paste inlay are characteristic of this pottery. When collating white paste mixtures of different European sites, similarities in the preparation of white paste recipes for vessels from the Balkan and northern Pontic regions are evident. During the Early Iron Age, further changes in the manufacture of the white paste were discovered in the northern Pontic region, namely the application of high-temperature firing to obtain more resistant synthesized material such as calcium alumosilicates and silicates (wollastonite). The development of iron metallurgy in this period could provide a basis for the elaboration of new techniques in ceramic manufacture.     

Tableware in the Hellenistic Tradition from the City of Kampyr Tepe in Ancient Bactria (Uzbekistan)

Slipped and unslipped wares from Kampyr Tepe dated to the Hellenistic–Seleucid and Greco‐Bactrian periods stylistically resemble tableware from the Greek tradition. Since two pottery workshops have been recovered at the site, the aim is to shed light on the provenance and the production and consumption patterns of the tableware, as well as on the degree of technological influence from Hellenistic–Mediterranean traditions. The archaeometric characterization, consisting of thin‐section petrography, XRF, XRD and SEM–EDS analysis, was performed on 44 wares and three unfired locally made pondera, which were used as reference local elemental patterns. The study demonstrated the local origin of most of the wares, which were produced using a similar clay paste, following standardized techniques in modelling and firing, while surface treatments appear to be more diversified.     

ON THE INFLUENCE OF DRYING AND FIRING OF CLAY ON THE FORMATION OF TRACE ELEMENT CONCENTRATION PROFILES WITHIN POTTERY*

On experimentally fired briquettes made of five chemically and mineralogically different clays, trace element concentration profiles from the centre to the surface of the briquettes have been measured by Neutron Activation in order to examine if drying and firing of the clays lead to a mobilization and subsequent migration of single components within a sherd. Mineralogical changes during firing have been determined by X‐ray diffraction. Generally, no such migration could be found. For two clays, arsenic was lost from the briquette during firing, forming non‐constant concentration profiles. If NaCl is present in the clay paste, sodium migrates towards the surface. Additionally, in the special case in which the presence of NaCl coincides with that of calcite, the heavier alkali elements evaporate, forming significant concentration profiles within the sherd.     

Technological features of Apulian red figured pottery

Apulian red figured pottery samples, dating back to the 5th and 4th centuries BC, from the archaeological site of Monte Sannace (Gioia del Colle, Bari, Italy) have been characterized from the physical–chemical, mineralogical and morphological points of view. Scanning electron microscopy, X-ray diffraction and atomic spectroscopy investigations have been carried out on the ceramic body, red decorated area and black gloss of the fragments, with the aim of outlining the technological features and of defining the nature of coatings and decorations. All 5th century fragments show the same features: fine texture of the ceramic body, red figures saved from the ceramic paste and black gloss painted directly on the ceramic body. The statistical treatment of compositional data of ceramic bodies excludes the local production of these objects. As regards the 4th century fragments, some show similar features to the 5th century ones; however others are characterized by the coarse texture of their ceramic body and an intermediate red layer of finer clay between the black gloss and the ceramic body. The analytical results make it possible to distinguish two different production technologies of red figured Apulian vases in Monte Sannace during the 4th century BC. Certain vases were produced using the “classic” Attic technology and others with a different technique, not previously known, which involved the application of a red engobe layer on the clay paste, before the black gloss painting.     

Pottery firing temperatures: a new method for determining the firing temperature of ceramics and burnt clay

A new method for determining the maximum firing temperature of ceramics and burnt clay is presented. The technique relies on measuring the magnetic susceptibility on a step-wise re-fired sample. The validity of the method has been tested by determining firing temperatures of two sets of clay samples fired at temperatures ranging from 400 to 1000 °C. Aliquots of the same samples have been studied petrographically by optical microscopy on thin sections and analyzed by powder X-ray diffraction in order to monitor structural and mineralogical changes as a function of temperature. The method is demonstrated on samples from four geographically widely different sites and it is applied to a larger set of ceramics of Late (ca. AD 900–AD 1450) and Inca (ca. AD 1480–AD 1532) periods from the Northwestern Argentine region, dating to a limited period of time prior to the fall of the Inca Empire. The method is shown to be a powerful tool in revealing archaeological information about the change in firing technologies in the pre-Hispanic societies in the Andean area through time.     

A processual study of Inka state formation

Traditional interpretations of how the Inka empire developed emphasize the disjunctive transformation of a village-level society through the agency of a single charismatic ruler. New evidence from the Inka heartland indicates that it was in fact the formation of a centralized state in the Cusco Valley of highland Peru that enabled the rapid campaigns of Inka territorial expansion during the 15th and 16th centuries. By using archaeological data and ethnohistoric documents to develop independent lines of evidence, it is possible to describe Inka state formation processes anthropologically. Settlement and excavation data from the Vilcanota Valley provide several indicators of the development of a centralized Inka state during the Killke Period (c. A.D. 1000–1400), while multiple accounts of the Inka past describe the transformation of Inka society over a period of several generations leading up to the first campaigns of imperial conquest. Both lines of evidence are consistent with the kinds of changes described for other known cases of state formation. The formation of the Inka state and its expansion in the Cusco region created conditions in which the agency of Inka rulers could direct the expansion of a mighty empire in only a few generations of conquest.     

The Santa María pottery of El Bolsón valley (Catamarca,Argentina): Compositional characterization and implications on the elaboration processes,ca. 1000–1600 ce

The results obtained from the multi-analytic compositional characterization of ceramic pastes and paints of the Santa María style, from the El Bolsón valley (Belén Department, Catamarca Province, Argentina), are presented here. This pottery style had a wide regional distribution in Northwestern Argentina between ca. 1000 and1600 ce and is characterized by its complex iconography painted in black, cream and red. The analyses show that the containers correspond to the technical tradition of using grog temper and suggest that its manufacture involved a double firing process. This reveals a new practice for the time.     

Production technology and knowledge transfer of calcite-tempered grey ware bowls from 2nd- to 5th-century ce Noricum (Austria)

Aspects of 2nd- to 5th-century ce Roman production technology and knowledge transfer in southern Austria (known as Noricum) were examined. With no evidence for workshops identified in the study area, 44 grey ware bowls from two sites at Aguntum and Lavant were studied macroscopically, and combined with optical microscopy, X-ray powder diffraction, prompt gamma activation, neutron activation and scanning electron microscopy, in order to understand whether one (large) workshop supplied these bowls, or whether the bowls were produced by several (small) workshops nearby. Combined with information from the geological background, the results were used to tentatively indicate the production location. The results indicate that the grey ware bowls from Aguntum and Lavant were produced by local workshops nearby. The bowls were manufactured with similar clay sources, tempered with crushed calcite-marble rocks from the Tauern Window, their surface smoothed and burnished, and fired between 800 and 850°C in a reducing atmosphere of an open fire. This is taken to suggest that Roman potters, who were located at Aguntum and Lavant, shared strategies of raw materials selection, paste preparation, finishing and firing, and transferred technological knowledge through time.     

Red ochre decorations in Spanish Neolithic ceramics: a mineralogical and technological study

Some Neolithic ceramics from south-eastern Spain have red to brown external decorations called “almagras” (red ochre). The pigment layer is essentially composed of a mixture of clay and iron oxides: haematite (red) and maghemite (brown). It is suggested that maghemite was formed during the firing process of ceramic in a reducing atmosphere. Several laboratory tests have been carried out to obtain maghemite by adding charcoal or pinewood sawdust to similar ceramic pastes. In fact, maghemite was formed, even when the piece was simply covered with pinewood sawdust before firing. The diverse original red colours are due to variations in iron oxide (or calcite) content and to redox conditions in the firing procedure. Brown- coloured ceramics owe their colour to maghemite and must be considered as a “fabrication defect”, due to the position of the ceramic piece in a zone where a reducing atmosphere prevailed in the course of firing.     

The technological development of stonepaste ceramics from the Islamic Middle East

The microstructures and chemical compositions of stonepaste bodies from the Islamic Middle East, typically produced from a mixture of ten parts crushed quartz, one part crushed glass and one part white clay, are investigated using analytical scanning electron microscopy. For comparison, replicate stonepaste bodies are produced in the laboratory at firing temperatures in the range 900–1200 °C, and are similarly examined. The stonepaste bodies are divided into four primary microstructural groups that reflect the increasing reaction during firing of the glass fragments with the clay and quartz particles. The observed microstructures are then used to assess the geographical and chronological variations in the production technology of stonepaste ceramics from Egypt, Syria, Iran, Uzbekistan and Turkey, spanning the period from 11th to 17th centuries AD.     

河南安阳灵芝窑出土瓷器的分析研究

本工作利用能量色散X-射线荧光光谱、体视及岩相显微镜、高温电子膨胀仪等实验方法,对灵芝窑有代表性的黑瓷、青瓷、白瓷等作了系统的分析测试。分析结果表明,灵芝窑不同种类的瓷器,在胎釉的化学组成、显微结构、烧制温度上等方面都存在一定的差异,由此推断,不同瓷器可能采用不同的原料及其加工工艺。     

Roman pottery production in Civitas Tungrorum,central Belgium,during the first–third centuries ce

Aspects of Roman pottery production at the workshops of Kontich, Tienen, Rumst, Grobbendonk and Clavier-Vervoz in the Civitas Tungrorum of central Belgium are explored. A total of 150 wasters from five sites were studied macroscopically, as well as via a combination of thin-section petrography, geochemistry and scanning electron microscopy, in order to gain insights into ceramic technology and aspects of the organization of production. Particular emphasis was given to the individual technological sequences and shared strategies of raw material selection, paste preparation and firing employed at the five adjacent sites. The integration of petrographic and geochemical data permitted the establishment of compositional reference groups for the Roman kiln sites of Civitas Tungrorum, which can be used to track their products within the surrounding landscape.     

The red-stained flint crescent from Gesher: new insights into PPNA hafting technology

A red-stained flint crescent found in the Pre-Pottery Neolithic A (ca. 9000 BC) site of Gesher, Israel, provides us with a unique opportunity to study the hafting technology of a particular tool type in the Levant. We present here a reconstruction, based on chemical and mineralogical analyses, of the hafting technologies and materials employed in the process. Use will also be made of relevant studies of the archaeological record. Local material was used for the production of an elastic adhesive paste, mud plaster, which was then hardened to hold the crescent securely in the haft. The study contributes insight into the hafting technology that was most probably implemented in the production and maintenance of composite tools during the Early Neolithic period.     

White Encrustation Produced from Deer Antler Phosphate on Prehistoric Ceramics from Podunavlje

The composition and structure of the white pigments used in the encrustation paste on prehistoric ceramics is analysed and described. Encrustations, pigments and their use were studied chronologically, starting with their first appearance during the early Kostolac culture (3500–3000 bc , Copper Age), their very extensive use in the Vu?edol culture (3000–2500 bc , Copper Age) and their final disappearance with the Pannonian complex of Encrusted Pottery (2000–1500 bc , Bronze Age). Most of the Kostolac and Vu?edol culture material is from the Vu?edol and Vinkovci Hotel localities. The Pannonian culture material is from the Grabrovac (Ðakovo) locality. The encrustations were analysed by deep field optical microscopy, polarization microscopy, scanning electron microscopy with EDS, and XRD. Our investigation showed that from the very beginning to the end of the use of the encrustation technique in this area and by these cultures, the composition of the white paste was quite unique. The base material is produced by burning and powdering of deer antler. Crushed freshwater clam shells (Unio sp.) were a common addition to the phosphate paste.     

PAUL‐LOUIS CYFFLÉ'S (1724–1806) TERRE DE LORRAINE: A TECHNOLOGICAL STUDY

Fragments of four Terre de Lorraine biscuit figurines were subjected to porosity analysis, X‐ray fluorescence analysis, X‐ray diffraction analysis, backscattered‐electron image analysis—coupled with energy dispersive spectrometry—and electron backscatter diffraction analysis to determine the porosity, bulk, major, minor and trace element compositions, and the composition and the proportion of their constituent phases. Cyfflé's Terre de Lorraine wares embrace two distinct types of paste, a calcareous and an aluminous–siliceous one. Both are porous (9–25% water adsorption). The former consists of a mixture of different proportions of ground quartz or calcined flint, ground Pb‐bearing glass and calcium carbonate with a refractory clay. The firing temperature was between 950 and 1050°C. For the latter, Cyfflé mixed ground pure amorphous SiO₂, ground quartz or calcined flint, ground porcelain, ground Na–Ca‐glass and coarse‐grained kaolinite with a fine‐grained kaolinitic clay. The figurines were fired below 1000°C. The result was a porous, hard paste porcelain‐like material. Cyfflé's recipes for both pastes can be calculated from the chemical and the modal analyses.     

CUERDA SECA CERAMICS FROM AL‐ANDALUS,ISLAMIC SPAIN AND PORTUGAL (10TH−12TH CENTURIES AD): INVESTIGATION WITH SEM–EDX AND CATHODOLUMINESCENCE*

Since little is known about the cuerda seca technique, our aim has been to complete an initial analysis of 11th‐century cuerda seca by studying fragments from the 10th century (Pechina, Almería) and the 12th century (Mértola and Almería), so as to establish the diachronic evolution of this technique. Characteristics specific to cuerda seca ceramic glazes were investigated using scanning electron microscopy (SEM) and quantitative chemical analysis with energy‐dispersive X‐ray spectrometry (EDX). The chemical compositions of the different‐coloured glazes (green, black, yellow and white) have given us valuable indications about the evolution of the technique. The opacification mode and the firing process were also investigated. With the help of cathodoluminescence (CL) and the study of modern ‘cuerda seca’ glazed ceramics, new hypotheses regarding the number of firing stages, taking into account glaze and paste transformations and their interactions, are put forward.     

Archaeometric study of medieval pottery excavated at Stari (Old) Ras,Serbia

A combined study of a series of polychromatic and monochromatic glazed medieval pottery shards excavated from the archaeological area of Stari (Old) Ras in southern Serbia, including petrographic and chemical analysis, powder X-ray diffraction (PXRD) and Fourier transform infrared (FTIR) spectroscopy, allowed us to clearly distinguish between two groups of ceramics. Ras pottery, made of fine-grained well-cleaned clay and characterised by a rich mineral assemblage, was produced by firing in a temperature range between 800 and 900 °C. Reljina Gradina ceramics were produced at similar temperatures from materials which, with regard to mineralogical and chemical composition, show clear similarity with local clay, suggesting that these samples are of local origin and production. This work is the first systematic archaeometric study of medieval pottery excavated on the territory of Serbia.     

COOKING AND PAINTED WARE FROM SAN GIUSTO (LUCERA,FOGGIA): THE PRODUCTION CYCLE,FROM THE SUPPLY OF RAW MATERIALS TO THE COMMERCIALIZATION OF PRODUCTS*

Archaeological excavation at the San Giusto site (Lucera, Italy) has unearthed a Late Antique kiln that was most certainly dedicated to the production of cooking ware. An archaeometric study of numerous specimens of cooking and painted ware found at this site was carried out using optical microscopy, scanning electron microscopy, micro‐Raman spectroscopy, X‐ray diffraction, X‐ray fluorescence, inductively coupled plasma mass and optical emission spectrometry and instrumental neutron activation analysis. The integration of historical–archaeological data with archaeometric data has revealed that these specimens can be attributed to the San Giusto site. Furthermore, the production cycle of this ware can thus be reconstructed: from the diversified supply of raw materials (fluvial and marine sediments), to the relatively complex preparation of the paste, to firing at variable temperatures (600–750°C for cooking ware; 850–1050°C for painted ware).     

Leftovers: The presence of manufacture-derived aquatic lipids in Alaskan pottery

Lipids preserved within the walls of ancient pottery vessels are routinely analysed to reveal their original contents. The provenience of aquatic lipids in pottery is generally connected to vessel function (e.g., for cooking or storing fish, shellfish and aquatic mammals). However, ethnographic reports from early historic Alaska mention the use of aquatic oils for waterproofing low-fired pottery. Results of lipid residue studies on Alaskan pottery reflect an exclusive function of pottery to process aquatic resources. However, can one be sure these residues are the product of vessel function and not a remnant of the manufacturing process? The study presents the results of an experiment where the preservation of aquatic lipids during the firing process at different temperatures was measured. It was found that nearly all lipids were removed at firing temperatures of ≥ 400°C. Petrographic analysis of Alaskan pottery samples indicates that firing temperatures were generally > 550°C but < 800°C. The contribution of pre-firing manufacture-derived lipids to samples fired at these temperatures may be regarded as negligible. While the possible presence of aquatic lipids from post-firing surface treatments cannot be excluded, such treatments appear unnecessary for well-fired pottery.     

On the provenance and manufacture of red-slipped fine ware from ancient Cassope (NW Greece): evidence by X-ray analytical methods

Energy-dispersive X-ray fluorescence spectroscopy was used to characterize red-slipped pottery (2nd–1st century BC) from ancient Cassope, north-western Greece. The compositional data were statistically treated by principal component analysis and chemical groups were established, representing locally produced and imported items. Mineralogical investigation by X-ray diffraction indicated firing temperatures in the range from 850 to 1000 °C for most of the sherds, while one group consisted of over-fired items, possibly in excess of 1050 °C. The morphology and elemental composition of the ceramic bodies and surface slips were examined through scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy. The analyses revealed that different pottery groups exhibit surface slips of different nature, in terms of thickness, degree of vitrification and elemental composition. Overall, the diversity in technological characteristics of the examined sherds is indicative of the socio-economic conditions prevailing in Cassopaea during the late Hellenistic period.