Pliny the Elder and Sr–Nd isotopes: tracing the provenance of raw materials for Roman glass production

In Roman and Byzantine times, natron glass was traded throughout the known world in the form of chunks. Production centers of such raw glass, active from the 4th to 8th century AD, were identified in Egypt and Syro-Palestine. However, early Roman primary glass units remain unknown from excavation or scientific analysis. The ancient author Pliny described in 70 AD that besides Egyptian and Levantine resources, also raw materials from Italy and the Gallic and Spanish provinces were used in glass making. In this study, the primary provenance of 1st–3rd century AD natron vessel glass is investigated. The use of combined Sr and Nd isotopic analysis allows the distinguishing and characterizing of different sand raw materials used for primary glass production. The isotope data obtained from the glass samples are compared to the signatures of primary glass from known production centers in the eastern Mediterranean and a number of sand samples from the regions described by Pliny the Elder as possible sources of primary glass. Eastern Mediterranean primary glass has a Nile dominated Mediterranean Nd signature (higher than −6.0 ? Nd), while glass with a primary production location in the western Mediterranean or north-western Europe should have a different Nd signature (lower than −7.0 ? Nd). Most Roman glass has a homogeneous ⁸⁷Sr/⁸⁶Sr signature close to the modern sea water composition, likely caused by the (intentional) use of shell as glass raw material. In this way, strontium and neodymium isotopes now prove that Pliny's writings were correct: primary glass production was not exclusive to the Levant or Egypt in early Roman days, and factories of raw glass in the Western Roman Empire will have been at play.     

Silk Road glass in Xinjiang,China: chemical compositional analysis and interpretation using a high-resolution portable XRF spectrometer

In this paper we explore the major, minor and some trace elements of sixty-five glass beads from eighteen oasis sites both north and south of the Taklamakan Desert, the ancient centre of the Silk Routes linking East and West; the samples date from the Warring States period (475–2211 BCE) to the Tang Dynasty (618–907 CE). Using a high-resolution portable XRF spectrometer, with special attention to issues of surface weathering and sample preparation, we obtained quantitative chemical compositional data that, when combined with archaeological context and the technology of bead manufacture, provide the basis for an understanding of both changes in glass type over time, and possible source areas for the Xinjiang glasses. While glass beads at the early sites (1st c. BCE to 4th c. CE) were coming primarily from Kushan-controlled territories in northern India, Pakistan and Afghanistan, with a small contribution from central China, most of the later glass (4th–10th c. CE) is similar to that produced in the Sasanian Empire at such sites as Veh Ardashir in central Iraq. These changes most likely reflect changing cultural and economic conditions in the Silk Road towns.     

The glass beads of Kampai Island,Sumatra

Pulau Kampai is the name of a small island on the east coast of Sumatra and also the name of a village on this island. Excavations conducted at Pulau Kampai in the mid-1970s yielded glass beads likely manufactured in India. More glass beads dating from the 11th to the 14th c. AD were found during excavations undertaken more recently. Those beads were analyzed using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Results show that the vast majority of the beads were likely imported from South Asia. Trace element signatures point toward two production areas: western India for most of the beads and northeastern India for a few high copper orange and red beads. A small number of beads have a very different composition resulting from the use of soda plant ash and a low alumina silica source indicating a possible Middle-Eastern provenance. A comparison with data published elsewhere indicates a similarity with material found in Egypt, dating from the 13th to the 15th c. AD suggesting that those beads might have reached the island during the later phases of the occupation period and might have transited through Egypt. It is uncertain where those beads were manufactured within the Middle-East. A comparison is provided with the glass beads from the site of Kampung Sungai Mas (9th to the 11th c. AD) located in Malaysia, one of the only “late” sites in the area that was studied recently using LA-ICP-MS.     

Southern African glass beads: chemistry,glass sources and patterns of trade

Three-hundred-and-sixty glass beads from 19 archaeological sites in southern Africa dating between about the 8th and 16th centuries AD were analyzed using LA-ICP-MS, determining 47 chemical elements. The eight different bead series, previously defined on morphological characteristics, possess different glass chemistries. Some bead series were made from plant-ash glasses, others from soda-alumina glasses. Zhizo series beads of the late 1st millennium AD were probably made from Iranian glass. Later bead series were made of glass probably manufactured in South Asia, though there are changes through time in both South Asian glass recipes and bead morphologies.     

THE TRADING OF ANCIENT GLASS BEADS: NEW ANALYTICAL DATA FROM SOUTH ASIAN AND EAST AFRICAN SODA–ALUMINA GLASS BEADS*

The occurrence of similar glass beads at archaeological sites in Africa and Asia bears witness to the trade relationship between the two continents. This paper reports elemental analysis results from a recent in‐depth laser ablation – inductively coupled plasma – mass spectrometry (LA–ICP–MS) study of a group of archaeological glass beads with a specific alumina‐rich composition from East Africa, India and Sri Lanka. Based on the concentrations of the trace elements, two different subgroups were identified. One subgroup occurs at early periods (fourth century bce to fifth century ace ) in South India and Sri Lanka. The second subgroup appears at later dates in Africa and was identified at different Kenyan sites dated from the ninth to the 19th century ace , and at the contemporaneous site of Chaul in western India.     

Strontium isotope analysis in ancient glass from South Asia using portable laser ablation sampling

In order to carry out strontium (Sr) isotope analysis, glass artefacts from South Asia were sampled with portable laser ablation (pLA), a relatively novel sampling technique that leaves damage invisible to the naked eye. Subsequently, thermal ionization mass spectrometry (TIMS) was used to obtain Sr isotope ratios after sample dissolution and separation. In this study, the goal was twofold: to determine whether the measurements of Sr isotope ratios were impacted by using a portable laser as a sample tool; and to assess the pertinence of using Sr isotope ratios to provenance Indian glass. Despite a deterioration in the precision of the measurement of the Sr isotope ratios for artefacts sampled with pLA compared with the traditional sampling method, the Sr isotope ratios of certain Indian glass are so different that this does not affect their separation but a comparison of data sets obtained using standard methods and pLA might be challenging.     

Agricultural Origins and Frontiers in South Asia: A Working Synthesis

The accumulation of recent data from archaeobotany, archaeozoology and Neolithic excavations from across South Asia warrants a new overview of early agriculture in the subcontinent. This paper attempts a synthesis of these data while recommending further systematic work and methodological developments. The evidence for origins and dispersals of important crops and livestock from Southwest Asia into South Asia is reviewed. In addition evidence for indigenous plant and animal domestication in India is presented. Evidence for probable indigenous agricultural developments in Gujarat, the Middle Ganges, Eastern India, and Southern India are reviewed. An attempt is made to highlight regions of important frontiers of interaction between early farmers and hunter-gatherers. The current evidence suggests that the Neolithic trajectories in different parts of South Asia differ from each other. Indigenous centers of plant domestication in India also differ from the often discussed trajectory of Southwest Asia, while suggesting some similarities with agricultural origins in Africa and Eastern North America as well as secondary agricultural developments on the peripheries of Eurasia. An erratum to this article can be found at     

Investigations of Byzantine glass bracelets from Nufăru,Romania using external PIXE–PIGE methods

The chemical composition of twenty glass bracelet fragments found in Nuf?ru, a Byzantine site from 10th–13th centuries A.D., nowadays located on Romania's territory, has been determined using Particle Induced X-ray Emission (PIXE) and Particle Induced Gamma-ray Emission (PIGE) in external beam mode. Most of the Byzantine bracelet fragments were identified as “mixed natron-plant ash” soda-lime-silica glasses. The obtained chemical compositions indicated that the manufacturing of these finery items was performed using similar raw materials and techniques, in most of the cases involving colored glass recycling. PIXE–PIGE results highlighted the glass chromophores (cobalt, manganese, copper and iron ions) and provided hints about the mineral pigments used to paint the external surface of some bracelets.     

Chemical analysis of 17th century Millefiori glasses excavated in the Monastery of Sta. Clara-a-Velha,Portugal: comparison with Venetian and façon-de-Venise production

A set of ten Millefiori glass fragments dating from the 17th century, originated from archaeological excavations carried out at the Monastery of Sta. Clara-a-Velha (Coimbra, Portugal), were characterized by X-ray electron probe microanalysis (EPMA), Raman microscopy and UV–Visible absorption spectroscopy. All glasses are of soda-lime-silica type. The use of coastal plant ash is suggested by the relatively high content of MgO, K₂O and P₂O₅, as well as by the presence of chlorine. Tin oxide or calcium antimonate were the opacifiers used in the opaque glasses, cobalt in the blue glasses, copper in the turquoise glasses, iron in the yellow and greenish glasses, and iron and copper were found in the opaque red and aventurine glasses. Based on the concentrations of alumina and silica four different sources of silica were identified, allowing the classification of the glasses into the following compositional groups: low alumina (<2 wt%), which includes a sub-group of cristallo samples with SiO₂ > 70 wt%, medium alumina (2–3 wt%), high alumina (3–6 wt%) and very high alumina (>6 wt%). Comparison with genuine Venetian and façon-de-Venise compositions showed that two fragments are of Venetian production, one of Venetian or Spanish production and the remaining are of unknown provenance. In two fragments the glass of the decoration is probably Venetian or Spanish but the glass used in the body is also of unknown provenance.     

Glass Beads from 15th–17th Century CE Jar Burial Sites in Cambodia's Cardamom Mountains

A total of 74 glass beads, included as grave goods in 15th–17th century CE jar burials from Cambodia's Cardamom Mountains, were analysed using laser ablation – inductively coupled plasma – mass spectrometry (LA–ICP–MS). Several glass types were identified, including two subtypes of high‐alumina mineral soda glass, and lead–potash glass. The final glass type represents a newly discovered and previously unidentified type of high‐alumina soda glass, with high magnesia (m‐Na–Al Mg>). This study represents the first glass data from the mid‐second millennium CE from Cambodia and sheds light on the multiple long‐distance maritime exchange networks in which the upland people buried in the jars were participating.     

Raw materials for medieval to post-medieval Tuscan glassmaking: new insight from LA-ICP-MS analyses

LA-ICP-MS analyses were performed on a set of Tuscan (post) medieval archaeological glass finds dated to the 13–16th century in order to quantitatively determine the trace element contents. The results are used for defining and distinguishing several compositional groups. The trace element data are consistent with the distinctions obtained by considering the major element data determined via quantitative SEM-EDX, but allow to obtain new insights into the nature and quality of the silica sources employed and the presumed method of ash purification.     

Transitions in Islamic plant-ash glass vessels: on-site chemical analyses conducted at the Raya/al-Tur area on the Sinai Peninsula in Egypt

This study focuses on the chemical composition of Islamic plant-ash glass (dated from the 9th to 11th centuries) excavated from the Raya/al-Tur area on the South Sinai in Egypt. Plant-ash glass objects from the Raya site were classified into three compositional types based on on-site chemical analyses with a portable X-ray fluorescence spectrometer. Based on typological characteristics and chemical composition comparisons with contemporary glass objects from other Islamic sites, one hypothesis holds that plant-ash glass objects produced in the Syria–Palestine or Mesopotamian regions could have been imported to Raya during the 9th to 10th centuries. In particular, some colorless glass vessels with a high magnesium/calcium ratio were noted to exhibit post-Sassanian cut decorations. Conversely, most of the bluish-green plant-ash glass objects from the Monastery of Wadi al-Tur near the Raya site exhibited relatively high levels of aluminum, titanium, iron, and lead. These pieces were likely produced during the Fatimid period (late 10th to 12th centuries), and based on their elemental composition, possibly originated in Egypt. The present work provides a greater understanding of chronological changes in post-9th century Islamic plant-ash glasses and the development of social and commercial networks within the Middle Eastern area.     

Too little,too late: the geochemistry of a 1773 Philadelphia porcelain openwork basket

A dated (1773) openwork basket labelled “PHILADELFIA” attributed to the Bonnin and Morris factory has a lead-bearing, silicious–aluminous–calcic (S-A-C) composition that contrasts with the phosphatic (bone ash) porcelains known to have previously been made during the mid-1760s to early 1770s in what is now the United States. The basket was underfired and so contains relics of a flint (Pb) glass flux, but kiln temperatures were nonetheless sufficient for subsolidus pseudowollastonite and anorthite to have been resorbed, implying that the duration of firing (soaking) near peak kiln temperatures was insufficient to ensure thorough vitrification. During cooling, liquidus pseudowollastonite and silica polymorphs (but not anorthite) formed, showing that the melt was confined to the tridymite–pseudowollastonite cotectic above the Trd–Wol–An eutectic (1170 °C) in the SiO₂–Al₂O₃–CaO system. Rapid cooling is also indicated by quenched silica polymorphs in the relict glass particles. Although Bonnin and Morris employed some former Bow (London, c. 1743–74) workers, the S-A-C wares initially produced by this factory are compositionally distinct from the 1773 basket, which in this regard more closely resembles the body and glaze of a reputed Chelsea triangle-period (London, c. 1745–49) vessel. Regardless of how they obtained this technology, it is ironic that Bonnin and Morris chose to abandon phosphatic pastes in favour of what in Britain had become an obsolete formula.     

Glass beads and pendants from Meroitic and Nobadian Lower Nubia,Sudan: Chemical compositional analysis using laser ablation‐inductively coupled plasma‐mass spectrometry

This paper presents a detailed elemental analysis of 64 glass beads and pendants dated to the Meroitic period (first–third centuries ad ) and the Nobadian period (fourth–sixth centuries) from burial sites in the Lower Nubian Nile Valley region. Laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) was used to determine the chemical composition of the glass and to gain knowledge about its origin. Four main glass types were identified: low‐alumina soda‐lime glass, high‐alumina glass, plant‐ash soda‐lime glass, and mixed‐alkali glass. Mineral soda‐lime glass (m‐Na‐Ca) of East Mediterranean/Egyptian provenance is dominant within the low‐alumina glass group from Meroitic and Nobadian periods. Mineral soda high‐alumina glass (m‐Na‐Al) appeared in the Nobadian bead assemblages, and the m‐Na‐Al 1 subtype was produced in Sri Lanka/South India. An initial insight into the origin of the glass beads in Nubia from the first to sixth centuries is described, indicating the first evidence for the presence of Asian objects in Nubia. The data obtained for the bead trade in North‐east Africa in this study has allowed a new light to be shed on the westward flow of Asian glass during a time of intensive maritime trade contacts with the wider Indian Ocean world.     

Land use change in Northeast China in the twentieth century: a note on sources,methods and patterns

Studies of historical change in cultivated land use in Northeast China have become important in the discussion of food supply safety and the reconstruction of land use/cover changes in China. This paper subjects a number of sources relating to land use change in the three provinces of Northeast China to comparative analysis. The data examined include Russian survey data (1914), data from local and regional Chinese governments during the Republic of China (1931), data from the Japanese Society of Manchuria Railway (SMR) for 1940 and various sets of contemporary Chinese data for the second half of the 20th century. A unified method of reconstructing the data and estimating the rate of cultivated land use change in Northeast China during the 20th century is developed here. A relational model is proposed for this purpose. It establishes a general framework for relating the various sets of data generated in different time periods and indicates ways in which the data have to be calibrated to ensure their comparability. The calibration of the data involves correlation and regression analysis. The results of the comparative analysis show that the area of and rate of change in cultivated land use in Northeast China increased until the last decade of the twentieth century. Increase rates were particularly high between 1914–1931 and 1950–1960.     

The technological development of stonepaste ceramics from the Islamic Middle East

The microstructures and chemical compositions of stonepaste bodies from the Islamic Middle East, typically produced from a mixture of ten parts crushed quartz, one part crushed glass and one part white clay, are investigated using analytical scanning electron microscopy. For comparison, replicate stonepaste bodies are produced in the laboratory at firing temperatures in the range 900–1200 °C, and are similarly examined. The stonepaste bodies are divided into four primary microstructural groups that reflect the increasing reaction during firing of the glass fragments with the clay and quartz particles. The observed microstructures are then used to assess the geographical and chronological variations in the production technology of stonepaste ceramics from Egypt, Syria, Iran, Uzbekistan and Turkey, spanning the period from 11th to 17th centuries AD.     

A chronometric tool for Hawaiian archaeology: the hydration dating of Pu'u Wa'awa'a trachytic glass

The Pu'u Wa'awa'a trachytic glass deposit located on the Big Island of Hawai'i was a source of lithic tools for much of Hawaiian prehistory. Routinely encountered at habitation sites, the glass has the potential to provide absolute dates based upon the degree of surface hydration. Infrared photoacoustic spectroscopy and secondary ion mass spectrometry were used to monitor the diffusion of water in archaeological and experimental samples. Accelerated laboratory hydration experiments show that water diffusion in trachytic glass containing a structural water content of 0.16% ± 0.03% is linear with time. Application of the calibration to trachytic glass artifacts from the Kahalu'u habitation cave have produced chronometric dates in the 17th–18th centuries. These age estimates are in agreement with radiocarbon dates and artifactual data that bracket the site occupation. However, the glass dates do not correlate well with site stratigraphy and this suggests that slight sample imperfections that retain water may be one factor that results in ages that are too early for later occupation levels.     

Stable isotopes as indicators of change in the food procurement and food preference of Viking Age and Early Christian populations on Gotland (Sweden)

Archaeological samples of human and faunal remains dating from the Viking (9–11th century AD) and Early Christian (11–12th century AD) periods of Gotland, Sweden were assayed through stable carbon and nitrogen isotope analysis in order to investigate whether changes in subsistence occurred between these periods, particularly regarding the importance of seafood. The study was concerned with how the dietary regime of the Baltic trading port and farming settlement at Ridanäs, Gotland was affected by the widespread environmental and sociocultural transformations that characterized the end of the Viking Age. More generally, the research considers how changes in both food procurement and preference may account for observed differences in the dietary regimes of individuals from the Viking Age and the Early Christian period.     

A short note on banana (Musa) phytoliths in Lapita,immediately post-Lapita and modern period archaeological deposits from Vanuatu

We present results of phytolith analysis of deposits from three prehistoric settlement sites in Vanuatu: the small islands of Vao and Uripiv off the north east coast of the main island of Malekula and at Mafilau on the west coast of Epi Island. Samples from Vao Island coarsely encompass the period from Lapita times (c. 3000 BP) to the present. The data from this site suggest deforestation by people, with a decrease in palms and increase in grasses. The data from the three sites show evidence of an introduced cultigen during different prehistoric periods. Banana (Musa) phytoliths were found in one recent Vao layer (500 BP-present) and in Mafilau layers, the latter representing the immediate post-Lapita period (c. 2800–2500 BP). This phytolith type was also found at Uripiv in Lapita layers (c. 3000–2700 BP). Banana phytoliths are diagnostic so their presence in archaeological deposits in Remote Oceania, outside their natural distribution, provides secure evidence of cultivation. This demonstrates the potential of this line of evidence for identifying both the cultigens transported by early colonists and subsequent plant introductions. The data provide the first direct evidence of banana cultivation at a Lapita site in Remote Oceania and support the contention that horticulture was an integral part of the Lapita Cultural Complex.     

Assessment of the Southern Dispersal: GIS-Based Analyses of Potential Routes at Oxygen Isotopic Stage 4

This paper explores the geographic and environmental context of the Southern Dispersal Route, which has been proposed as a migratory route for Homo sapiens from East Africa to Australasia during oxygen isotope stage (OIS) 4 (71–59 kyr). A series of assumptions and constraints garnered from modern hunter-gatherer observations are used to build a model of coastal foragers, which is then integrated with high-resolution physiographic analyses to produce a potential dispersal route along the coastline of the Indian Ocean. Paleoenvironmental conditions that may have supplied critical resources or served as obstacles to human colonization are identified and discussed in regards to human subsistence, the speed of migration, and demographic expansion. These factors suggest that rapid dispersals along coastlines and river valleys would have occurred upon the initial expansion out of Africa, but slowed as populations expanded demographically into South Asia and the Sunda Shelf. This also suggests that archaeological signatures relating to the earliest modern Homo sapiens are more likely to be recovered in South Asia.