The first direct evidence of pre-columbian sources of palygorskite for Maya Blue

Maya Blue, a nano-structured clay–organic complex of palygorskite and indigo, was used predominantly before the Spanish Conquest. It has fascinated chemists, material scientists, archaeologists and art historians for decades because it is resistant to the effect of acids, alkalis, and other reagents, and its rich color has persisted for centuries in the harsh tropical climate of southern Mesoamerica. One of its components, palygorskite, is part of modern Maya indigenous knowledge, and ethnohistoric and archaeological data suggest that its modern sources were probably utilized in Prehispanic times. Yet no direct evidence verifies that palygorskite was actually mined from these sources to make Maya Blue. Here we characterize these sources compositionally, and compare our analyses to those of Maya Blue from Chichén Itzá and Palenque. We demonstrate that the palygorskite in most of these samples came from modern mines, providing the first direct evidence for the use of these sources for making Maya Blue. These findings reveal that modern Maya indigenous knowledge about palygorskite, its mining, and its source locations, is at least seven centuries old.     

Postclassic Maya slips and paints and their relationship to socio-political groups in El Petén,Guatemala

LA-ICP-MS analysis of the chemical composition of the exterior slips and red and black pigments used for painted decoration of the three Postclassic Maya slipped ceramic wares suggests that the Itzá and Kowoj used different pigments for exterior slips and decorative motifs. Additionally, different slips and paints were used depending on vessel form and decorative program (red, black, or red-and-black painting or incising). When examined with previous ceramic paste chemical analyses, the data aid in better understanding the changing socio-political alliances and dominance relations in central Petén at the eve of Spanish contact.     

Kings and commoners at Copan: Isotopic evidence for origins and movement in the Classic Maya period

Eight human interments were excavated in the 1990s beneath the Acropolis at the Classic Maya site of Copan in Honduras, which was the capital of a Maya kingdom from ca. AD 400 to 800. These human remains come from both royal tombs and less elaborate burials dating to the early part of this period and lie deep in the accumulated architectural layers of the Acropolis. We present a brief summary of the context, contents, and external links represented by these interments. Several lines of evidence point to connections between early Copan and Teotihuacan in the Central Highlands of Mexico, and Tikal in the central Maya lowlands of the Petén in Guatemala.     

THE OCCURRENCE OF PALYGORSKITE IN THE YUCATÁN PENINSULA: ETHNO‐HISTORIC AND ARCHAEOLOGICAL CONTEXTS*

Palygorskite is a rare clay mineral used by the ancient Mayas for fabricating the Maya blue pigment and for other purposes. It seems to have been obtained from a restricted area in the Yucatán peninsula where important archaeological sites are found. Geological samples from different localities in this area show a high content in palygorskite, indicating that this clay is widespread in Yucatán. Combining structural, morphological, compositional and geochemical methods, we analysed the common characteristics of Yucatecan palygorskites, and compared them with palygorskites from other origins around the world. These results can be used for defining a fingerprint of Yucatecan palygorskite to be used in provenance studies of archaeological artefacts, in particular the Maya blue pigment.     

Metallurgical ceramics from Mayapán,Yucatán,Mexico

Recent excavations at the Postclassic (AD 1050–1440) Maya site of Mayapán, Mexico, have uncovered a variety of metal objects, metal production debris, and ceramic objects that appear to be linked to metallurgical activities at the site. Our present study investigates a corpus of small ceramic objects to determine if these objects was used in metallurgical processes such as lost-wax casting. A variety of analytical techniques was utilized, including x-ray fluorescence, electron probe, petrography, and reflected light microscopy. Metal residues were detected on the surfaces of several objects, and copper prills were identified within the ceramic fabric, suggesting that the ceramics were exposed to liquid metal during remelting and/or casting events. A comparison of the microstructures of these metallurgical ceramics to typical ceramics from Mayapán demonstrates that the fabrics are very different, and suggests that the metallurgical ceramics were specifically engineered to function in the high temperature environment required for metallurgy. The distribution of metal and metallurgical ceramics across the site of Mayapán suggests that metal production activities may have been more widely distributed and practiced than earlier thought.     

New radiometric dating of water management features at the prehistoric Purrón Dam Complex,Tehuacán Valley,Puebla, México

Recent investigations at the prehistoric Purrón Dam Complex in the Tehuacán Valley of southern Puebla, México applied radiometric dating to more securely date the complex. Ceramic-based dating in the 1960′s placed the Dam's origin to the Formative Period. While Formative Period origins are widely accepted, the chronology lacks resolution and direct dates. Samples from impounded sediments behind the dam and from prehistoric canal fill were dated through Optically Stimulated Luminescence (OSL) as well as both standard ¹⁴C and accelerated mass spectrometry (AMS) assays. These samples directly date the functioning of the water management features within the complex. The results confirm the Formative Period origins of the Purrón Dam, and offer new insights into the construction and functioning of the dam and irrigation system.     

Deciphering the inorganic chemical record of ancient human activity using ICP-MS: a reconnaissance study of late Classic soil floors at Cancuén,Guatemala

Inorganic chemical analysis of soil floors using inductively coupled plasma-mass spectrometry (ICP-MS) was undertaken to provide information on the nature and location of past human activity in the ancient Maya city of Cancuén, Guatemala. The use of ICP-MS to detect trace and ultra-trace elemental enrichment of two excavated soil floors from the late Classic period is the first study of its kind in Mesoamerican archaeology. Geochemical background of the site was established by the analysis of palaeosols and nearby undisturbed ‘off-site’ soil profiles. Robust statistical methods used in the study clearly distinguished the level of anthropogenic enrichment across the former floors. Many elements measured showed only minor departures (10–20%) from the site's background soil chemistry. The greatest levels of elemental enrichment were detected in the rare earth elements, mercury, and gold. The latter is of particular interest considering the consensus that gold was absent from the world of the Classic-period Maya. Comparisons of the spatial pattern of mercury enrichment with lithic and archaeological data show strong linkages to past industrial and ritual activities. Elevated rare earth element concentrations were recorded broadly across both soil floors and are considered to be related to concentrated human occupation in antiquity.     

Pottery politics: Late Classic Maya palace production at Motul de San José, Petén,Guatemala

Archeologists often rely heavily on stone monuments, architecture, settlement patterns, and written texts to reconstruct ancient political systems. In this paper we focus on the role of polychrome pottery as both a reflection of and critical component in the production of power relations. We present rare direct evidence of polychrome pottery production recovered from the Maya site of Motul de San José, the presumed Late Classic (ca. 600–900 AD) capital of the epigraphically-recognized Ik’ polity. Our contextual analysis of production debris and tools complement on-going polychrome vessel style and chemical analyses of Ik’ Style polychrome vessels to suggest that Motul de San José’s royal court was an important center in the manufacture of Ik’ Style polychrome pottery. These elaborate vessels indexed the political history, power, and networks of the Ik’ polity. By combining archeological, iconographic, and epigraphic data of polychrome pottery, we shed light on Motul de San José’s internal political-economic dynamics as well as its macro-political alliances and tensions with other polities.     

Tikal timbers and temples: ancient Maya agroforestry and the end of time

Tikal, a major lowland Maya civic-ceremonial center in the heart of the Petén region of Central America, relied heavily on the adjacent lowland rainforest as a resource base for fuel and construction materials. In this study, we analyzed 135 wood samples from timbers used in the construction of all six of the city's major temples as well as two major palaces to determine which tree species were being exploited and to better understand ancient Maya agroforestry practices during the Late Classic period. We found evidence for a change in preference from the large-growing, upland forest species, Manilkara zapota, to a seasonal wetland species Haematoxylon campechianum in A.D. 741 as well as a decrease in lintel beam widths over time. Though M. zapota later returned as the wood species of choice in A.D. 810, beam widths were found to be significantly smaller. These findings concur with models that hypothesize widespread deforestation during the Late Classic period and indicate a declining forest resource base by the 9th century A.D. Because of the many large timbers available for temple construction in the 8th century, some system of forest conservation is indicated for the ancient Maya prior to the Late Classic period.     

Country Roads: Travel,Visibility, and Late Classic Settlement in the Southern Maya Mountains

Mayanist archaeology has long been concerned with creating and evaluating explanatory models for the locations of ancient sites relative to one another and to the physical geography of the Maya world. This study combines epigraphic data and spatial analyses to explore motivations for settlement location and to interrogate territorial strategies in Late Classic (a.d. 600–830) kingdoms in the southern Maya Mountains, around the modern towns of Dolores and Poptún, Guatemala. Least-cost path analyses were used to model natural travel corridors and their relationship with site location was assessed. In conjunction, viewshed analyses were applied to evaluate the importance of visual connections to likely travel routes. The results are considered in the context of the socio-politics and economics of the region, and raise questions about the character of and interconnections between travel, exchange, settlement location, and mechanisms for reinforcing territorial claims in the Late Classic Southern Maya Mountains.     

CORRELATION BETWEEN SPECTRAL,SEM/EDX AND ELECTROCHEMICAL PROPERTIES OF MAYA BLUE: A CHEMOMETRIC STUDY*

Visible spectra, composition from SEM/EDX and solid‐state electrochemical data are correlated for a set of 12 Maya Blue samples from different archaeological sites of Campeche and Yucatán (Mexico). In addition to indigo and dehydroindigo, indirubin and other possibly indigo‐type compounds can be detected in Maya Blue samples. Application of hierarchical cluster analysis techniques allows similarity relationships to be established between samples from different sites, confirming prior results which suggest that the preparation of Maya Blue pigment evolved with time during the Maya culture following a ramified scheme.     

Ancient soil resources of the Usumacinta River Region,Guatemala

In this study we present the results of a combination of methods used to identify possible agricultural activity of the ancient Maya in the Usumacinta River Basin in Guatemala. These methods included stable carbon isotope analysis of bulk soil organic matter, soil profile investigations and a spatial model of gentle slopes and well-drained soils to identify favorable agricultural conditions. Stable carbon isotope analysis of bulk soil organic matter in particular offers potentially direct evidence of agricultural activity. The δ¹³C results suggest that there is a strong signature of C₄ plants, such as maize and tropical grasses, throughout the study area. Further, the current soil conditions and extent of relatively gently sloped areas are favorable to agriculture. Overall, the results are supportive of the hypothesis that the area, located between the polities of Piedras Negras and Yaxchilán, was agriculturally important to surrounding areas.     

The Maya “Protoclassic” from the Perspective of Recent Research at Nakum,Peten, Guatemala

Recently, the Maya site of Nakum has been the subject of intensive research by the Institute of Archaeology of the Jagiellonian University, Kraków, Poland. This work has significantly enriched our knowledge of the ancient Maya of northeastern Guatemala, especially during the so-called Terminal Preclassic or Protoclassic period (ca. 100 b.c.–a.d. 300), when many Maya centers suffered decline. The Protoclassic covers the transitional moment between two important periods of Maya chronology, the Preclassic and Classic, but so far, the typical ceramic components of this phase have been found in only a handful of Maya sites. Our research indicates that Nakum underwent important building programs and stable cultural growth during the discussed period. Here we discuss evidence of architectural and cultural activity at Nakum during the Terminal Preclassic within a wider geographic context. Our research highlights the role that Nakum played within Maya geopolitics in northeastern Guatemala and also contributes to the understanding of socio-cultural processes that the Maya civilization was undergoing during the as-yet poorly understood Protoclassic period.     

SYNTHESIS AND ACID RESISTANCE OF MAYA BLUE PIGMENT*

Maya blue is an organo‐clay artificial pigment composed of indigo and palygorskite. It was invented and frequently used in Mesoamerica in ancient times (eighth to 16th centuries). We analyse in this paper one of the characteristics of Maya blue that has attracted the attention of scientists since its rediscovery in 1931: its high stability against chemical aggression (acids, alkalis, solvents, etc.) and biodegradation, which has permitted the survival of many works of art for centuries in hostile environments, such as the tropical forest. We have reproduced the different methods proposed to produce a synthetic pigment with the characteristics of the ancient Maya blue. The stability of the pigments produced using either palygorskite or sepiolite has been analysed by performing acid attacks of different intensities. The results are analysed in terms of pigment decolouration and destruction of the clay lattice, revealed by X‐ray diffraction. Palygorskite pigments are much more resistant than sepiolite pigments. It is shown that indigo does not protect the clay lattice against acid aggression. We show that Maya blue is an extremely resistant pigment, but it can be destroyed using very intense acid treatment under reflux.     

Evidence for volcanic ash fall in the Maya Lowlands from a reservoir at Tikal,Guatemala

Powder X-ray diffraction and petrographic analyses of reservoir sediments from Tikal, Guatemala have identified significant quantities of decomposed volcanic ash in the form of smectite and euhedral bipyramidal quartz crystals. X-ray fluorescence trace element content analysis was used to eliminate distant Sahara-Sahel and Antilles sources. The Zr/Y and Ni/Cr ratios of reservoir sediment from Tikal are consistent with a source from Central American volcanism (e.g., Guatemalan and Salvadoran). AMS radiocarbon dating of the smectite and crystalline quartz-rich reservoir sediments show that volcanic ash fell during the Preclassic, Classic, and Postclassic Maya cultural periods. It may now be possible to develop an effective chronology of ash fall at Tikal and the greater Peten.     

Early Maya Ritual Practices and Craft Production: Late Middle Preclassic Ritual Deposits Containing Obsidian Artifacts at Ceibal,Guatemala

This article examines Preclassic Maya ritual practices and craft production by means of a study of ritual deposits containing obsidian artifacts dated mostly to the late Middle Preclassic period (700–350 b.c.) at Ceibal, Guatemala. New ritual practices developed at Ceibal during this period, possibly through political interactions and negotiation involving emerging elites and other diverse community members. Common objects in ritual deposits in the public plaza shifted from greenstone celt caches to other artifacts, including those made of obsidian. The inhabitants of Ceibal engaged in various kinds of craft production, including the manufacture of obsidian prismatic blades. They also conducted public rituals in the Central Plaza, depositing exhausted polyhedral obsidian cores and other artifacts with symbolic significance in caches and as offerings in incipient elite burials and interments of sacrificed individuals. These cores clearly demonstrate the use of a sophisticated blade technology. Like greenstone objects, exhausted polyhedral obsidian cores deposited in cruciform arrangements along the east–west axis of the central E-Group plaza were used as symbols and markers of the center and four cardinal directions within the Maya cosmos. Public rituals were important for creating collective identities and for processes of political negotiation within the community. Emerging elites likely came to play an increasingly important role in public rituals as principal performers and organizers, setting the stage for later public events centered on rulers.     

Evaluating the use of IKONOS satellite imagery in lowland Maya settlement archaeology

This article presents an extensive evaluation, in several contiguous or near-contiguous areas, of the viability of IKONOS satellite imagery in detecting sub-canopy Maya settlement in Peten, Guatemala. Initial research in and around San Bartolo, Guatemala, led to the conclusion that IKONOS imagery could be highly effective in detecting and predicting Maya settlement of the Preclassic and Classic periods, in zones of dense occupation near swampy lowlands known as bajos. The pioneering methods at San Bartolo are applied here to other regions in the Maya lowlands, but with mixed or unpromising results. Preliminary evaluation indicates that local climate, geology, hydrology, topography, pedology, and vegetation differ dramatically in these other regions, with consequences for wider application of the settlement signature discerned at San Bartolo. Possible reasons for these difficulties are offered in this paper, along with ways to strengthen the use of multispectral imagery in archaeological survey of tropical forests.     

Archaeological Heritage in Guatemala: Indigenous Perspectives on the Ruins of Iximche’

In Guatemala local perspectives on heritage often remain unheard. In this paper a case study is presented to show the complex relationship between the highland site of Iximche’ and Tecpán, an Indigenous community nearby. Although Iximche’ is of little importance to the local economy, its significance is derived from its role as a field for different kinds of social and religious interactions. Traces of a spiritual relationship to this place can be dated back to the colonial period and today Maya from all over Guatemala go there to perform ceremonies. The place has also become a focal point of identity constructions for locals, Pan Mayan activists and the nation itself. The ruins of Iximche’ play an important role in the construction of collective memory which also includes ideas coming from external players such as Christian churches, the national government, Mayan activists, and archaeologists as well.