Ceramic production in ancient Nasca: provenance analysis of pottery from the Early Nasca and Tiza cultures through INAA

We report the results of an instrumental neutron activation analysis (INAA) undertaken on a regional sample of pottery from the Southern Nasca Region. The samples included specimens primarily from the Early Nasca (ca. A.D. 1–450) and Tiza (ca. A.D. 1000–1476) cultures from a total of 16 different prehispanic sites. The results of the analysis demonstrate centralized production of Early Nasca polychromes and decentralized production of pottery from the Tiza culture. The results of this analysis confirm previous conclusions about the organization of these two indigenous cultures of the south coast of Peru and support the hypothesis of an excess production of polychromes at the ceremonial center Cahuachi for Early Nasca, and multiple centers of production for the Tiza culture.     

Archaeometric characterisation of coarse and painted fine ware from <Emphasis Type="Italic">Posta Crusta</Emphasis> (Foggia,Italy): technology and provenance

Coarse and painted fine wares from the Late Antique residential complex of Posta Crusta (Lucera, Foggia, Italy) have been here investigated. The ceramic characterisation was our main concern; even so, the provenance and the production technology have been further investigated, focusing on both ceramic bodies and coatings. Optical microscopy, scanning electron microscopy and a set of bulk chemical analyses (inductively coupled plasma optical emission spectrometry, inductively coupled plasma mass spectrometry, instrumental neutron activation and X-ray fluorescence) were used for the characterisation of 44 samples. Chemical and mineralogical data here obtained were compared with results previously achieved on San Giusto local production, in order to distinguish production areas and identify possible exchanges. As for coarse wares, the characterisation of Posta Crusta pottery shed new light for the reconstruction of the production/distribution framework of this part of northern Apulia. The following trends can be identified: (1) pots from Posta Crusta and San Giusto settlement that can be referred to a single production site, likely located in the nearby territory of one of this two sites; (2) pots from San Giusto kiln exported to Posta Crusta; (3) pots of unknown origin but compatible with the northern Apulian area. Furthermore, it was possible to verify that all Posta Crusta ceramics used the alluvial deposits widely outcropping in northern Apulia as received. As for painted fine wares, Posta Crusta samples enucleated a distinct and homogenous group, including six samples from San Giusto. This result is highly encouraging as it provides the clear evidence of a production group, although it is not possible to refer it to a precise locality. The marine deposits outcropping in northern Apulia can have been surely exploited for raw materials supply. Coatings texture seems to suggest two different ways of application: immersion and painting.     

The Lead Ingots from the Wreck of the Zuiddorp (1712), Western Australia: a report on their provenance and manufacture

The Dutch United East India Company ship Zuiddorp vanished on its way to Batavia in 1712 – its last port of call was the Cape of Good Hope. After its wreck was found on the Western Australian coast, archaeological investigations resulted in the retrieval of 21 lead ingots. Recent study of this artefact assemblage, comprising both great pigs and pieces, suggests that they were of north English origin. Historical records indicate that the Dutch procured large quantities of lead from English sources and maritime trade links between English and Dutch ports were well established at the beginning of the 18th century. © 2012 The Authors     

Comparison of the Different Types of Qinghua Porcelain from Jingdezhen in the Yuan Dynasty of China (ad 1271–1368) by Micro X‐ray Fluorescence Spectroscopy (μ‐XRF) and Microscopy

The Yuan Qinghua porcelain produced in the city of Jingdezhen, in China, mainly includes the gaudy blue type, a blue–grey or grey‐coloured type and the type featuring a blue colour with a slight amount of grey. For a long time, only the gaudy blue type was focused on and discussed, while the other two types, which contain equally important information with regard to recovering the manufacturing technology of Yuan Qinghua, were always ignored by scientific researchers. In this paper, by using micro X‐ray fluorescence spectroscopy (μ‐XRF), spectrophotometry and optical microscopy, all three different types of Yuan Qinghua porcelain are analysed systemically and, based on the analyses of the body, the glaze and the blue decoration, the differences in the materials and the manufacturing technologies of the three different types are discussed. This not only provides a good basis for the reconstruction of the whole picture of the manufacturing process of Yuan Qinghua porcelains in Jingdezhen, but also contributes to database‐building for the identification of Qinghua porcelain.     

The volcanic millstones from the archaeological site of Morgantina (Sicily): provenance and evolution of the milling techniques in the Mediterranean area*

The Morgantina archaeological area, inhabited from the Early Bronze Age, had its widest expansion from the fifth to the first century bc . The volcanic millstones found at Morgantina fall into three different groups on the basis of the milling technique: (i) saddle querns (known from the Middle–Late Bronze Age and Iron Age); (ii) rectangular hopper‐rubbers (Olynthian) millstones, the invention of which dates to the fifth century bc ; and finally (iii) Morgantina‐type rotary millstones (starting to be used from the fourth to the third century bc ). In order to determine the provenance of the raw materials (lavas) used for all these millstone types, we collected 38 very small rock samples for thin‐section modal mineralogy, petrography and major trace element composition. The results have contributed to classifying different lithotypes and distinguishing between provenance from Etna and the Hyblean Mountains, the two volcanic areas respectively north‐east and south‐east of Morgantina. Saddle querns are made of tholeiitic basaltic andesites from the Hyblean Mountains and transitional basalts, mugearites and hawaiites from Etna. The variety of sources of portable saddle querns, mostly used in households, indicate that there was no general preference for specific quarrying sites. By contrast, the rectangular hopper‐rubber and the Morgantina‐type millstones, which document the period of Morgantina's greatest prosperity, are almost completely made of hawaiites from Etna. The use of a specific lithotype (i.e., Etna hawaiite) for the more efficient rectangular hopper‐rubber and rotary millstones could be linked to the fact that these mills may have been operated in business establishments. It is worth noting that the Gornalunga river was, in antiquity, a waterway joining Morgantina to the final stretch of the Simeto river and then the Ionian coast. The best candidate areas for the millstone hawaiite quarrying sites from Etna are the far south‐western sectors of the volcano, along the Simeto Valley (i.e., the ‘Piano Provenzana’ Formation) or the inner suburb of present‐day Catania (i.e., the ‘Pietracannone’ Formation). The very efficient Morgantina‐type rotary millstones spread during the reign of Hieron II of Syracuse (275–215 bc ) in eastern Sicily and met the need for grinding large quantities of cereals during a relatively peaceful time and a period of agricultural development.     

Egyptian Blue cakes from the Ayanis fortress (Eastern Anatolia,Turkey): micro-chemical and -structural investigations for the identification of manufacturing process and provenance

The microstructure and chemical composition of blue cakes, found during the archaeological excavation of the Ayanis fortress (Eastern Anatolia, Turkey), have been investigated by means of scanning electron microscopy combined with energy dispersive spectrometry (SEM–EDS), X-ray diffraction (XRD), micro-Raman (μ-Raman) and optical microscopy (OM) techniques. The analysis of the Ayanis cakes has shown the presence of Egyptian blue (i.e. CuCaOSi₄O₁₀, cuprorivaite), as the major component, intermixed with minor amount of other phases such as partially reacted quartz grains, an adherent glass phase and copper oxides. Since the finding of Egyptian Blue in Turkey has been never reported so far, great attention has been paid to its characterisation. The micro-chemical and micro-structural investigations of the Ayanis cakes have allowed a further insight into the manufacturing process and into the sources of the starting materials. The results of the characterisation have revealed some significant differences with respect to Egyptian blue cakes found in Egypt and Mesopotamia, as for instance the absence of tin excluded the use of bronze scraps or filings in their preparation differently from those produced in Egypt and Mesopotamia. Furthermore, some peculiarities of Egyptian blue found in Ayanis, as the detection of zinc in the cakes, allow to put forward the hypothesis of a local production considering that a large part of the bronze artefacts found at the Ayanis fortress is characterised by the presence of zinc as minor alloying element.     

Classification and provenance of soapstones and garnet chlorite schist artifacts from Medieval sites of Tuscany (Central Italy): insights into the Tyrrhenian and Adriatic trade

Soapstones (talc-bearing schists) and garnet chlorite schist artifacts found in Medieval archaeological sites of Tuscany (Central Italy) were classified, in order to define provenance of the different lithotypes. In Italy and throughout the Central Europe, these greenschist facies metamorphic rocks are generally known, among the archaeologists, as the pietra ollare from the Alps. The investigated Tuscan archaeological sites are between 6 and 13th century AD and were strictly linked, in that period, to the well defined network trade running along Tyrrhenian coast. Samples come from little containers used for cooking and preserving food and showing traces of lathe manufacturing at their sidewalls. According to modal mineralogy, petrographic texture, XRD, SEM-EDS and whole rock chemistry we recognised, among the 18 studied findings, three different petrographic groups of the Alpine pietra ollare. (i) Fine grained magnesite talc schists (i.e. soapstones) from outcrops of the Central Alps located in the Valchiavenna area. (ii) Garnet chlorite schists from the Valle d'Aosta region. (iii) Amphibole talc schists (i.e. soapstones) with a provenance in the Ticino area. It is worth noting that artifacts of pietra ollare lithotypes from the Western Alps (i.e. garnet chlorite schists and amphibole talc schists) were not detected in the archaeological sites of the Middle Adriatic coast of the Central Italy, belonging to the same Medieval time interval. This emphasises that the petrographic groups of pietra ollare from the Alps spread to the south of the Po Plain according to Western and Eastern trade along the Italian Peninsula, using respectively, the Tyrrhenian and the Adriatic Sea commercial routes.     

Mortars in context: An integrated study of mortars and plasters from the so-called Ginnasio in Solunto (Sicily,Italy)

This paper presents a multipronged scientific study of mortars and plasters of the so-called Ginnasio in the Hellenistic–Roman city of Solunto (Sicily, Italy). A selection of 16 well-contextualized samples was collected to represent different functions and building phases of this private house. The results show that a variety of locally available raw materials was used as aggregates and to produce binders. The diversity of raw materials’ sources and production techniques identified in this study reveals the advanced technological knowledge of the builders of Solunto, indicating a complex relationship between the settlement's cityscape and its surrounding landscape.     

Biomolecular archaeology of ancient tuberculosis: response to “Deficiencies and challenges in the study of ancient tuberculosis DNA” by Wilbur et al. (2009)

It is sixteen years since the first detection of Mycobacterium tuberculosis DNA in archaeological specimens, yet the validity of findings continues to be questioned. Rigorous scientific scrutiny and debate is valuable and has led to a coalescence of procedures and precautions amongst those actively engaged in this work. It is disappointing that these good practices are not recognised by certain scientists whose primary expertise is in the related fields of archaeology, palaeopathology, and eukaryote ancient DNA. There is a danger that by constant repetition, disputable and inadequately justified concerns will assume the status of self-perpetuating myths and misunderstandings. We discuss these issues with reference to a recent article in this journal, in which clear peer-reviewed scientific data were specifically targeted as part of a general critique of the field of the palaeomicrobiology of tuberculosis. We believe we have given sufficient evidence and cogent argument to persuade the unbiased reader that the views in the critique by Wilbur et al. are unjustified.     

Use of space in a Neolithic village in Greece (Makri): phytolith analysis and comparison of phytolith assemblages from an ethnographic setting in the same area

Phytolith analyses were conducted in a Pottery Neolithic village (Makri) of Northern Greece in order to reconstruct aspects of past human activities as a function of both space and time. The analyses of phytolith assemblages were based on a reference collection of modern plant phytoliths (Tsartsidou et al., 2007), as well as an ethnographic study in an agropastoral community (Sarakini) in the same area that showed that many phytolith assemblages are characteristic of the activities carried out in different locations within and around the village (Tsartsidou et al., 2008). The same approach was used for studying the phytolith assemblages in the Neolithic village of Makri, namely measuring phytolith concentrations, diversities of phytolith assemblages relative to control samples collected from samples outside the village and detailed analysis of various phytolith morphotypes. At Makri samples from floors and various constructions (i.e. pit, platforms) were analysed, as well as sediments from an open area inside the village. The results show that Neolithic Makri was a society with a mixed agricultural and pastoral economy. Wheat and barley were cultivated for food and fodder and free-range animals were raised in a village inhabited year round. Indoor areas were not clearly differentiated from outdoor areas inside the village. The phytolith assemblages in only one series of floors produced at a specific location over an extended period of time reflected the use of that space for cereal storage or food processing. The phytolith assemblages from all the other floors examined did not reflect the local activities, but rather the constructional materials used for producing the floors.     

The use of SEM-EDS,PIXE and EDXRF for obsidian provenance studies in the Near East: a case study from Neolithic Çatalhöyük (central Anatolia)

In this paper we evaluate the relative analytical capabilities of SEM-EDS, PIXE and EDXRF for characterizing archaeologically significant Anatolian obsidians on the basis of their elemental compositions. The study involves 54 geological samples from various sources, together with an archaeological case study involving 100 artifacts from Neolithic Çatalhöyük (central Anatolia). With each technique the artifacts formed two compositional groups that correlated with the East Göllü Da? and Nenezi Da? sources. The non-destructive capabilities of these methods are emphasized (albeit with certain analytical limitations in the case of SEM-EDS), suggesting important new techniques for Near Eastern obsidian provenance studies.     

Preliminary Characterization of Pottery by Cathodoluminescence and SEM–EDX Analyses: An Example from the Yeha Region (Ethiopia)

Yeha was a political and cultural centre of the Ethio‐Sabaean culture (D’MT) in northern Ethiopia and southern Eritrea. Part of the archaeological research deals with pottery of local, regional and imported origin. The research—investigations and examinations—tries to classify local pottery in two ways: first, by analysing the mineralogy of the temper using light microscopy and cathodoluminescence; and, second, by analysing the main element composition of the clay matrix using a scanning electron microscope with energy‐dispersive X‐ray detection (SEM–EDX). The cathodoluminescence shows that the temper material has differences in the colours of feldspars with a similar mineralogical composition. The results demonstrate that the pottery was produced by using local material that originates from various sources in the Yeha region and that the same raw materials were used in different types of pottery.     

Shell-gathering from mangroves and the seasonality of the Southeast Asian Monsoon using high-resolution stable isotopic analysis of the tropical estuarine bivalve (Geloina erosa) from the Great Cave of Niah, Sarawak: methods and reconnaissance of molluscs of early Holocene and modern times

This paper describes a reconnaissance, high-resolution, study of stable isotopes (δ¹⁸O and δ¹³C) from modern shells of the estuarine bivalve Geloina erosa, and those dated to the early Holocene that were harvested by people from mangroves near the Great Cave of Niah on the north coast of Borneo. This reconnaissance study provides high-resolution palaeoclimatic-palaeohydrological information concerning early human activity in the region and the past character of the Southeast Asian Monsoon. Laser ablation continuous flow isotope ratio mass spectrometry (LA-CF-IRMS) on modern shells of Geloina erosa revealed ‘saw-tooth’ stable isotopic profiles that bear a close resemblance to peaks and troughs of trends in recent local rainfall, including the 1998 El Niño drought, highlighting the potential of Geloina erosa for reconstructing seasonality of the Southeast Asian Palaeomonsoon. LA-CF-IRMS analysis of prehistoric shells of Geloina erosa held in the Harrisson Archives of the Sarawak Museum revealed cyclical shifts in δ¹⁸O with similar amplitudes of variation as found in modern shells of Geloina erosa. As at the present day, this probably reflects the changing seasonality of the monsoon rains with shifts to negative δ¹⁸O values during periods of high runoff. Lighter mean δ¹⁸O values of the prehistoric shells, however, may indicate a greater annual surplus of rainfall and possibly consistent with the early Holocene strengthening of the summer monsoon at that time. The similarity of the last growth increment δ¹⁸O of the prehistoric shells to their mean δ¹⁸O profile values suggests that gathering took place during times of moderate runoff.     

A study by thermal treatment and X-ray powder diffraction on burnt fragmented bones from tombs II,IV and IX belonging to the hypogeic necropolis of “Sa Figu” near Ittiri,Sassari (Sardinia,Italy)

In the course of an anthropological investigation of three tombs of the hypogeic necropolis of “Sa Figu” (near the village of Ittiri in North Sardinia, Italy), numerous burnt bone fragments were collected. In particular, from the whole necropolis we selected a tenth of long bones from tomb IV, a small fragment of femur from tomb II and four fragments belonging to tomb IX. The aim of this work is to determine a temperature range to which the bone fragments were heated, in order to assess a funerary cremation which was presumably used at that time to quickly and hygienically eliminate the flashy parts of deceased people rather than a purification rite with fires inside the sepulchres. We attempted to evaluate the range of temperature to which the bones were likely subjected, making a joint use of thermal treatment and powder X-ray diffraction investigations. From our X-ray line broadening results carried out with a modern approach (Rietveld method), it emerged that a group of five fragmented burnt bones (one specimen belonging to tomb IV, the other four from tomb IX) were subjected to a heat treatment in a temperature range from 600 and 750 °C. Conversely another group of bones (belonging to tombs II and IV) turned out to be subjected to temperatures not higher than 250 °C.