Energy-Dispersive X-Ray Fluorescence analysis of Haleakalā basalt adze quarry materials, Maui, Hawai‘i

One of Hawai‘i’s major prehistoric basalt adze quarries (SIHP 50-50-11-2510) is located in the summit region of Haleakalā, Maui. Situated at approximately 2750 m above sea level (9000 ft), the quarry shares a similar high-altitude setting with the Mauna Kea adze quarry on Hawai‘i Island. Adding to a growing Energy-Dispersive X-Ray Fluorescence (EDXRF) database for the Hawaiian Islands, we present the results from 255 geological and archaeological lithic samples from the Haleakalā quarry site. We also briefly discuss why this non-destructive XRF technique is particularly applicable in the Hawaiian cultural context.     

K/AR DATING AS A MEANS OF SOURCING LEVANTINE EPIPALAEOLITHIC BASALT IMPLEMENTS

Through K/Ar dating of basalt implements from two Mount Carmel late Epipalaeolithic sites and samples of locally occurring basalts, it was possible to demonstrate clearly that the prehistoric inhabitants of these sites did not utilize the locally available Upper Cretaceous (88–77 My) basalts. The dates of the basalt implements are of Tertiary-Quaternary age (3.7-<0.250 My) which suggests the exploitation of basalt exposures at least 60 km east of the sites. This is the first direct evidence for long-distance exchange/trade of an essential raw material in the Levant as early as 13000 BP.     

X-ray fluorescence analysis and intra-island exchange in the Society Island archipelago (Central Eastern Polynesia)

We apply X-ray fluorescence (XRF) geochemical analysis to a collection of 'Opunohu Valley lithic artifacts from Mo'orea island to investigate the local scale of raw material procurement, adze production, use, and exchange within the Society Island archipelago. We use these data to document the distribution of non-local versus local volcanic artifacts in 'Opunohu Valley house sites, ritual sites, and specialized sites, as a means for establishing intra-site production and consumption patterns, and access to exotic, possibly superior, stone resources, and how these two themes correlate with site function or household wealth and status. Overall, 30% of the artifacts analyzed via WDXRF derive from non-local sources, notably two other islands in the archipelago outside of the political boundaries of Moorean chiefdoms. Our case study thus provides the first direct material evidence of intra-archipelago trade and exchange in the Society Islands. Intra-archipelago trade in adzes was certainly in place by as early as A.D. 1350, if not earlier, and continued up until the time of European contact. In addition, our analyses have identified a local adze production locale in the Afareaitu district of Mo'orea island. The patterns of local versus non-local adze production and exchange strongly suggest that dual interaction spheres were involved. The correlation between adzes and adze-related debris produced from off-island sources and sites with specialized use, which were often reserved for the social, ritual, and political elites in Ma'ohi society suggests that some of the exotic adzes derived from gift exchange between Mo'orea and ruling elites in Tahiti and the Leeward Islands. These adzes from afar would have solidified socio-political and ideological alliances between elites in the Windward and Leeward sectors of the archipelago.     

ANALYSING ARCHAEOLOGICAL BASALT USING NON‐DESTRUCTIVE ENERGY‐DISPERSIVE X‐RAY FLUORESCENCE (EDXRF): EFFECTS OF POST‐DEPOSITIONAL CHEMICAL WEATHERING AND SAMPLE SIZE ON ANALYTICAL PRECISION*

Energy‐dispersive X‐ray fluorescence (EDXRF) has been commonly used to determine geological sources of volcanic glass artefacts, but its ability to discriminate between basaltic sources is less developed. We examine the precision and accuracy of non‐destructive EDXRF for basalt artefacts by analysing varying size and weathering characteristics. The experiments identified no appreciable effect in reproducibility or measured composition due to thickness (down to 1 mm) or natural weathering of pre‐contact flake scars for the 17 elements measured in this study. Samples with surface area less than 100 mm², however, show significant variability in measured composition and reproducibility.     

ARAMAIC BASALT STATUES FROM TELL HALAF,SYRIA: LOCATING THE ANCIENT QUARRIES

Tell Halaf is the locality of the ancient Aramaic city of Guzāna (c. 1000–800 bc ) in Syria. The statues of Tell Halaf were made from monolithic basalt blocks, comprising massive as well as amygdaloidal types. However, the exact location of the original quarries was as yet unknown. Reconnaissance mapping and sampling concentrated on the four basaltic centres in the vicinity of Tell Halaf, covering both south‐eastern Turkey and north‐eastern Syria. In addition, basaltic artefacts from the two archaeological sites of Tell Beydar (c. 2700–2300 bc ) and Djebelet el Beda (c. 2600–2350 bc ) were investigated. All basalt samples were analysed for their bulk rock major and trace element compositions by X‐ray fluorescence, ICP–MS analysis and the mineral chemistry of individual minerals by combined electron microprobe analysis and laser‐ablation ICP–MS. The data show that basalt works of art from all three archaeological sites were derived from the Syrian basalt plateau of Ard esh‐Sheikh, approximately 57 km south of Tell Halaf. Accordingly, this basalt quarry was actively exploited over a considerable time span of c. 1900 years. This study demonstrates that petrographic and geochemical investigations of basalt, combined with electron microprobe and laser‐ablation ICP–MS analysis of minerals, are powerful tools to discriminate between possible sources of raw materials, especially if isotopic data yield unsatisfying results.     

Craft Specialization and Adze Production on Hawai'i Island

Abstract

Archaeological models of economic organization in complex societies frequently hinge on indications of craft specialization. Interpretations of such specialization in the Hawaiian islands often involve large-scale production of basalt adzes at Mauna Kea, the largest known quarry in the Pacific region. The recent discovery of expedient non-specialized production of adzes at Pohakuloa outside the main quarry of Mauna Kea, illustrates another dimension of Hawaiian economic systems. The identification of both small-scale and large-scale adze production has important implications for archaeological studies of craft specialization. The Hawaiian example illustrates that some aspects of production, such as context scale, and intensity, may vary within a single technological tradition. This study also suggests that previous interpretations of craft production that have emphasized differences across time — or across different categories — must also address variation among individual groups of contemporary materials.     

NATUFIAN TRADE/EXCHANGE IN BASALT IMPLEMENTS: EVIDENCE FROM NORTHERN ISRAEL*

Three Natufian base camps in Israel—el-Wad, Hayonim and Eynan—have nearby basalt sources, but K/Ar ages indicate that their inhabitants obtained implements, made of Miocene-Pliocene and Quaternary basalts, further afield. The nearest locations, in which raw material sources representing the whole range of dated basalts occur within a relatively restricted area, are to be found east of the Jordan Valley, suggesting movement of the material some 100 km to el-Wad, 60 km to Hayonim and 20 km to Eynan. The exact nature of these longdistance contacts and the underlying social and economic systems and mechanisms are yet to be determined.     

Non-destructive pXRF of mafic stone tools

Archaeological use of non-destructive pXRF has been most systematically applied to the classification and provenancing of volcanic glass (obsidian) artefacts. Comparable work has yet to be developed for non-vitreous artefacts. We report results of pXRF analysis for a sample of grey to black (mafic) aboriginal hatchets from Sydney and adjacent coastal regions to the north and south. The study shows both broad and detailed classification is achievable depending on rock type and degree of elemental depletion or enrichment of the samples. PXRF analysis reveals not only distinct patterns of resource use between the three regions of this study but also enables a high degree of geographic resolution in the case of the basalt artefacts of our sample. We conclude that non-destructive pXRF is effective for reliable characterisation of non-vitreous stone artefacts that have a sufficiently complex and enriched compositional signature (i.e., unaltered basalts); with ∼50% of the basalt hatchets in our sample matched with spatially and geologically specific sources.     

REPRODUCIBILITY OF ELEMENTAL ANALYSES OF BASALTIC STONE ARTEFACTS BY QUADRUPLE ICP–MS USING DIFFERENT SAMPLE SIZES AND DIGESTION METHODS,WITH IMPLICATIONS FOR ARCHAEOLOGICAL RESEARCH

Using high‐precision inductively coupled plasma mass spectrometry (ICP–MS), we measured >40 elements in basalts sampled by diamond micro‐drills to evaluate the effectiveness of different digestion methods and the reproducibility of elemental analysis for different sample sizes from 5 mg to 100 mg. The results indicate that those elements that are most suitable for geochemical characterization, such as rare earth elements (REE), high‐field strength elements (HFSE) and certain mobile elements (Rb, Sr, Th, U), show excellent reproducibility with an average relative standard deviation (RSD) of 3% between open‐beaker and pressured ‘bomb’ digestion methods. This observation rules out the presence of refractory phases such as zircon, which can only dissolve in pressured ‘bombs’, and suggests that the results from open‐beaker digestion are reliable. The ICP–MS data for powders of different weights ranging from 10 to 100 mg collected from two fine‐grained basalt artefacts display excellent reproducibility, with a RSD of <5% for the most important elements. The reproducibility is reduced when including the 5 mg weight fraction (RSD of ～2–9%), which is still sufficient for archaeological applications. Our results demonstrate the usefulness of 10 mg samples for elemental measurement, which is valuable for geochemical characterization and sourcing of fine‐grained basalt artefacts from museum collections that require minimal destructive sampling.     

Vitrification of basalt orthostats and mud building components from Tilmen Höyük (south-eastern Turkey): an experimental and geoarchaeological approach

Finds of basalt orthostats and mud building components from the archaeological site of Tilmen Höyük (south-eastern Turkey, early 2nd Millenium BC) preserve a glassy crust formed by vitrification of the material. It is proposed that such features are related to destructive fire events, which destroyed the wooden building elements and burned natural stones. The geoarchaeological and experimental approach confirms this hypothesis. The geochemical composition of experimental melts is comparable to that of natural basalts. Spot analyses evidence the heterogeneity of the melts, especially for mudbricks and ceiling plasters. It is concluded that the investigated finds were subjected to strong burning under oxidising conditions reached during a violent fire. Temperatures similar to those derived by experimental melting (1180–1195 °C) were likely reached in the fire at Tilmen in order to produce the glass observed.     

Geochemical sourcing of rock specimens and stone artifacts from Nihoa and Necker Islands,Hawai'i

We report geochemical analysis of seven rock specimens and six stone artifacts from Nihoa and Necker Islands, Hawai'i. The analyzed rock specimens exhibit chemistry consistent with published data sets and establish a major element distinction between Nihoa and Necker. Their trace element data indicate that the analyzed rocks and artifacts are local in origin and they reliably discriminate from sources on Kaua'i. These preliminary results support Emory's thesis that early (archaic) Hawaiian colonists on Nihoa and Necker relied on their local basaltic stone to manufacture stone tools, containers, and other portable objects.     

The provenancing of ochres from the Neolithic Temple Period in Malta

Ochres have played an important role in early human societies, and recent studies have shown that these pigments are important tools in establishing trade routes between countries as particular varieties of the material were sought for use by these ancient groups. This paper explores the provenancing of the ancient ochres used during the Neolithic Temple Period on the Maltese islands. Here ICP-AES was employed to establish geochemical trends and ‘signature’ elements present in ochre that had previously been thought to have been imported from mainland Europe. When coupled with statistical tests, data was used to link the archaeological pigments to a geological source. Results revealed a strong link between the Maltese archaeological pigments and local sources, which had never been studied prior to this project. These indicated that, contrary to popular belief, the Maltese archipelago was the most likely source for Neolithic ochre.     

Networks and Neolithisation: sourcing obsidian from Körtik Tepe (SE Anatolia)

This paper details the use of obsidian sourcing to reconstruct networks of interaction (or ‘communities of practice’) amongst populations of south-eastern Anatolia and the Near East in the context of ‘Neolithisation’ during the late 11th–early 10th millennia BC. EDXRF was used to elementally characterise 120 artefacts of Epi-Palaeolithic – Pre-Pottery Neolithic A date from Körtik Tepe in south-eastern Anatolia. Four eastern Anatolian sources are represented, mainly Bingöl A/B and Nemrut Da?, plus the first evidence for the use of Mu? obsidian. When the source data is integrated with the artefacts' techno-typological attributes it is possible to locate the assemblage within an Upper Tigris tradition (with some interesting local differences), which stands in stark contrast to contemporary practices in northern Mesopotamia and the Levant. These local and regional distinctions support recent views of the Neolithic being much more heterogeneous, with a ‘mosaic’ of community-specific/local traditions of subsistence practices, raw material choices and lithic technologies during the Younger Dryas–Early Holocene.     

Obsidian provenance for prehistoric complexes in the Amur River basin (Russian Far East)

The sources of high quality volcanic glass (obsidian) for archaeological complexes in the Amur River basin of the Russian Far East have been established, based on geochemical analyses by neutron activation and X-ray fluorescence of both ‘geological’ (primary sources) and ‘archaeological’ (artifacts from the Neolithic and Early Iron Age cultural complexes) specimens. A major obsidian source identified as the Obluchie Plateau, located in the middle course of the Amur River, was found to be responsible for supplying the entire middle and lower parts of the Amur River basin during prehistory. The source has been carefully studied and sampled for the first time. Minor use of three other sources was established for the lower part of the Amur River basin. Obsidian from the Basaltic Plateau source, located in the neighboring Primorye (Maritime) Province, was found at two sites of the Initial Neolithic (dated to ca. 11,000–12,500 BP). At two other sites from the same time period, obsidian from a still unknown source called “Samarga” was established. At the Suchu Island site of the Early Neolithic (dated to ca. 7200–8600 BP), obsidian from the ‘remote’ source of Shirataki (Shirataki-A sub-source) on Hokkaido Island (Japan) was identified. The range of obsidian transport in the Amur River basin was from 50 to 750 km within the basin, and from 550 to 850 km in relation to the ‘remote’ sources at the Basaltic Plateau and Shirataki-A located outside the Amur River valley. The long-distance transport/exchange of obsidian in the Amur River basin in prehistory has now been securely established.     

Portable EDXRF analysis of a mud brick necropolis enclosure: evidence of work organization,El Hibeh,Middle Egypt

The geochemical and sedimentological compositions of mud brick from a feature called the Square Enclosure in the eastern desert necropolis of the ancient town site of El Hibeh, Egypt, were investigated along with surface sediments from the local Nile floodplain for the purpose of establishing possible sources of the mud brick. Geochemical examination was undertaken with a portable EDXRF spectrometer; a field portable sedimentological laboratory was used to collect grain size, mineralogy, and strength analysis data. Results of the analyses produced evidence of work organization relating to the construction of the Square Enclosure. This discovery is the first archaeological evidence of work organization from the mud brick of ancient Egyptian structures and provides a valuable contribution to our knowledge of ancient Egyptian work organizational practices.     

THE CHEMICAL COMPOSITION OF SOME ARCHAEOLOGICALLY SIGNIFICANT FLINT FROM DENMARK AND SWEDEN

Flint was one of the most widely employed raw materials for artefact manufacture in Denmark and Sweden during the Stone Age, and it continued to be used during subsequent periods. Prehistoric flint mining and lithic manufacturing studies in these countries have attracted considerable attention, but there have been no recent attempts to chemically characterize the geological source materials. This paper builds on a pilot study ( Hughes et al. 2010 ) and uses energy‐dispersive X‐ray fluorescence (EDXRF) analysis to determine quantitative composition estimates for nine major, minor and certain trace elements in seven archaeologically significant flint sources in Denmark and Sweden, along with new data on a number of other sources of prehistoric significance. These data provide a geochemical foundation for ongoing research devoted to determining contrasts and continuities in the time and space utilization of flint sources in Scandinavian prehistory.     

Using portable energy dispersive X-ray fluorescence (EDXRF) analysis for on-site study of ceramic sherds at El Hibeh,Egypt

As part of its geoarchaeological research program, the El Hibeh Project of the University of California, Berkeley field-tested at the site of El Hibeh, northern Middle Egypt, the utility of a portable EDXRF unit for obtaining geochemical analyses of pottery suitable for provenance and other ceramic classification studies. When the geochemical ceramic data from the field test are combined with basic petrographic analysis for the pottery sample set, compelling results are generated. In particular, a triangular scattergram using elemental iron, strontium and rubidium data, in parts per million, provides excellent temporal and spatial separation of ceramic fabrics type, origin and date. The geochemical behavior of iron, strontium and rubidium is discussed in relation to geological source materials utilized for pottery manufacture.     

Provenancing the rhyolitic and dacitic components of the Stonehenge landscape bluestone lithology: new petrographical and geochemical evidence

The source of the bluestone component found in the Stonehenge landscape has long been the subject of great interest and considerable debate. The bluestones are a mix of lithologies, the standing orthostats being predominantly dolerites, variably ‘spotted’, with only four of them being of dacitic and rhyolitic composition and the Altar Stone being sandstone. However in the 1920s the spotted dolerites were sourced to outcrops which comprise tors in the summit regions of the Mynydd Preseli in north Pembrokeshire, west Wales. There were also speculations about the possible sources of the dacitic and rhyolitic components, ideas which were elaborated on in the early 1990s when the original petrological provenancing was supplemented by whole-rock geochemical analysis. Most recently, new petrographical investigations have been combined with zircon geochemical data to determine the possible source of one type of rhyolite, the so-called ‘rhyolite with fabric’, found abundantly as débitage in the Stonehenge landscape (but not composing the four orthostats) to outcrops in the vicinity of Pont Saeson, especially a large craggy outcrop called Craig Rhos-y-felin, located in low ground to the north of the Mynydd Preseli. In order to test this provenance whole-rock geochemical analysis has been undertaken on samples of débitage from the Stonehenge landscape and from the Pont Saeson area, including Craig Rhos-y-felin. These data are then compared with other new and existing geochemical data for dacitic and rhyolitic lithologies recovered from the Stonehenge landscape, including the four orthostats, as well as geochemical data from outcrops of the same lithologies from the two main volcanic horizons exposed across north Pembrokeshire, namely the Fishguard Volcanic Group and the Sealyham Volcanic Formation, both of Ordovician age. This study concludes that previous, 20th century, attributions of provenance to a number of dacitic and rhyolitic outcrops in the north Pembrokeshire have been in error whilst the new data for the Pont Saeson rhyolite accords well with elemental contents recorded in the ‘rhyolite with fabric’ lithology from the Stonehenge landscape débitage. This study therefore endorses the proposal that the Pont Saeson area is indeed the source of the ‘rhyolite with fabric’ lithology recovered from numerous sites in the Stonehenge landscape, and is the only reliable provenance for any of the dacitic and rhyolitic bluestone material collected to date. It also serves to endorse the use of zircon chemistry as a provenancing tool in archaeopetrological investigations.     

Geochemical discrimination of basaltic sources as a tool for provenance analyses of bifacial tools in the southern Levant: first results from the Jezreel Valley,Israel

The determination of groundstone tool sources bears the potential to examine aspects like raw material selection and preference, mobility, trade and exchange patterns, control over resources and long term use of raw material sources. The discovery of the Neolithic/Chalcolithic basanite bifacial quarry of Giv'at Kipod in the Jezreel Valley, Israel, provides the opportunity of raw material centred provenance studies of bifacials in the southern Levant. The basis for reliable provenance analyses is a clear geochemical characterization of the extraction site and its discrimination from other potential sources. To achieve this, the Miocene magmatic rocks of the Jezreel Valley were sampled and analysed by XRF and La-ICP-MS. The geochemical evaluation, combined with cluster analyses, resulted in a clear discrimination of the Giv'at Kipod lava from other basaltic sources in the area. Based on the geochemical field data, a Giv'at Kipod provenance for six bifacial tools found in three archaeological sites dated to the Neolithic and the Chalcolithic periods was established. The results suggest that the quarry was in use for several millennia. This pilot study demonstrates that for provenance analyses lava outcrops in the southern Levant can be geochemically discriminated from each other on a very small spatial scale, on the basis of a detailed field sampling and the application of multivariate methods.     

Experimental determination of use wear on stone adzes from Boomplaas Cave,South Africa

To test the assumption that Later Stone Age adzes were used primarily for woodworking, replicas of adzes were made and used to chisel and to plane wood. The use wear on these replicas was then compared with that on 51 prehistoric examples from Boomplaas Cave in the southern Cape Province, South Africa. The results show that all the prehistoric adzes examined have wood polish, and that charcoaling was part of the technique of Later Stone Age woodworking at least as early as 14,200 bp.