BUILDING A BRIDGE TO THE PAST: ARCHAEOMETRY AT THE IPEN REACTOR

Neutron activation analysis has contributed to research in Peru in different scientific fields, particularly in archaeometry. In archaeometry, applications include the characterization of copper alloy artefacts from the tomb of El Señor de Sican to determine production methods, ceramics from the Wari Culture to study production, and distribution of Middle Horizon pottery in Cuzco, ceramics from Villa El Salvador to determine production groups, and obsidian source analysis.     

Late horizon silver,copper, and tin from Machu Picchu,Peru

Analyses of silver–copper alloy artifacts from Machu Picchu show silver contents ranging from 24 to 81%. The tin present, ranging up to 3%, originated with the copper, perhaps from admixture of recycled bronze. The presence of 0.4–0.9% lead in the silver-rich phase indicates use of silver prepared by cupellation. All the objects had been forged after casting, some extensively. All have surface enhancement of the silver arising from depletion of the copper-rich phase. Some of the tin found at the site contains inclusions of hardhead (FeSn₂) and of a nickel–arsenic–copper compound. Forming trials with duplicate silver–copper alloys show that intermediate anneals at temperatures between 500 and 600 °C facilitate making thin sheet artifacts. Mechanical tests show that the most commonly used alloys, containing 25–30% silver, are particularly well adapted to forging because of their uniform work hardening during plastic deformation. Annealing of the laboratory-made alloys in air followed by boiling in salty weak acid creates a silver-rich surface layer comparable to that found in the artifacts. Depletion forms a dense silver surface on the alloy containing more silver than the eutectic composition, but a porous surface layer on the 25% silver alloys.     

青海都兰吐蕃唐墓包金银饰的科学分析

青海都兰位于古丝绸之路南道上,都兰吐蕃墓葬群出土了为数不少的隋唐时期金银器及饰物,其中一件"粟特银包金神袛人物连珠牌饰银丝腰带"牌饰上的人物具有典型的粟特特征,这对于研究中西方文化交流,有着极为重要的价值。但很多包金银饰片出土时腐蚀严重需要进行保护处理和相关的科学研究。为此,通过电子扫描电镜、X-射线衍射等分析方法,对工艺类似腰带牌饰的样品进行科学分析。结果表明,样品为包金银器饰物,包金层为金银合金,而银本体腐蚀严重,腐蚀产物主要是氯化银,这与环境的高含盐量有关,分析结果可为吐蕃墓出土文物的研究和保护提供理论依据。     

The technology of early platinum plating: a gold mask of the La Tolita culture,Ecuador

A metallurgical study of platinum plating on a gold pendant of the La Tolita culture of northern Ecuador was carried out, using high‐magnification examination by scanning electron microscopy with analytical facilities. The plating layer was found to comprise a 25 µm thick foil of platinum grains sintered with a gold–silver alloy. The high silver content of this alloy suggests the deliberate selection of pale‐coloured, silver‐rich alluvial gold. The foil had been bonded on to the pre‐formed gold sheet by hammering and heating. It is postulated that a strip of gold sheet was plated by this method and that several pendants were cut from it.     

Technical Studies on the Bronze Age Metal Artefacts from the Graveyard of Deh Dumen,South‐Western Iran (Third Millennium BC)

During the excavations of the graveyard at the site of Deh Dumen in south‐western Iran, 15 graves from the Early/Middle Bronze Age were uncovered that contained a variety of metallic artefacts. This paper reports on the analysis of nine metal artefacts, including eight broken vessels and a decorative strip that covered the handle of a dagger. The ICP–MS results showed that the bodies of the vessels are made of tin bronze alloy with variable amounts of tin, while the internal piece of the base of one vessel is made from an arsenical copper alloy. Further, the metallic strip is a thin sheet manufactured with partially pure silver. Microanalytical and microstructural information yielded by SEM–EDS revealed elongated Cu–S inclusions and lead globules as various phases formed in bronze solid solution. This study presents some information about the transition from arsenical copper to bronze metallurgy in the third millennium bc in south‐western Iran.     

A late Devensian Nunatak on the Knoydart peninsula,NW Scotland: Implications for ice‐sheet reconstruction

Geomorphological mapping and analysis of soil mineralogy indicates that all summits on the Knoydart Peninsula were over‐ridden by the last ice sheet apart from Ladhar Bheinn (1020 m), where the ice attained a maximum altitude of c. 950 m. This figure is consistent with evidence from adjacent areas and suggests that the last ice sheet descended westwards across Knoydart from c. 1000 m to c. 900 at the west coast, implying that most theoretically‐based ice‐sheet models are substantially in error in this area.     

THE BLACK INLAY DECORATION ON A MYCENAEAN BRONZE DAGGER*

The black inlay decoration with superb marine, hunting and other scenes on Mycenaean bronze daggers and silver cups has often been referred to in the literature as niello—a mixture of sulphides of copper, silver or lead—despite the absence of any systematic analysis of these precious metal artefacts. This paper presents semi-quantitative surface analyses of an example of black inlay on a Mycenaean dagger, now in the Archaeological Museum at Patras in Greece. Using non-destructive X-ray fluorescence spectrometry, it has been established that, contrary to the traditionally-held view, the black inlay is a copper-gold alloy with some silver and possibly small amounts of tin.     

Association for Field Archaeology Members

Abstract

This article is dedicated to Ronald F. Tylecote

Archaeologists and historians of metallurgy have attempted to explain the gradual abandonment of arsenic bronze in favor of tin bronze in the ancient Old world by making comparisons between the mechanical properties of the two bronzes. These comparisons purport to show the superiority of copper-tin alloys over alloys of copper and arsenic, despite an absence of data on the physical properties of the copper-arsenic system. The study reported here presents the results of mechanical tests carried out on experimental samples of both types of bronze over a broad range of alloy compositions. Hardness, tensile strength, and elongation determinations were made on cold worked and hot worked (forged) material. Whereas tin bronzes can be work hardened more extensively than arsenic bronzes, the far greater ductility of arsenic bronze makes it a desirable alloy for the manufacture of thin metal sheet. The widespread use of low-arsenic copper-arsenic alloys in the Americas, especially in the Andean culture area, is attributable in part to the tradition there of sheet metal production in the elaboration of three-dimensional forms.     

FOURTH MILLENNIUM BC SILVER FROM TELL ESH-SHUNA, JORDAN: ARCHAEOMETALLURGICAL INVESTIGATION AND SOME THOUGHTS ON CERAMIC SKEUOMORPHS

Summary. Analytical and contextual details are given for a piece of silver sheet recovered by dry-sieving from a fourth millennium B.C. deposit at Tell esh-Shuna in the north Jordan Valley. Analysis proved that the fragment was composed of a silver-gold-copper alloy. The possible origin of such aurian silver artefacts is considered in the light of current geological evidence, and alternative mechanisms for their appearance reviewed, taking into consideration recent data pertaining to the use of 'non-utilitarian' metals in the southern Levant during the fifth and fourth millennia B.C. Reasons are given for believing that silver artefacts are under-represented in the archaeological record, and the imitation of silver vessels is suggested as a possible explanation for the appearance in Palestine of the distinctive Grey Burnished ceramics at the beginning of the Early Bronze Age.     

Entre destellos se desvanece una devoción: la imagen de oro de la Asunción,patrona de la catedral metropolitana de México

Abstract

The main purpose of this paper is to analyze representations of the Assumption of the Virgin, patroness of the Mexico City Metropolitan Cathedral in New Spain. In 1610, a superb golden figure of the Assunta was acquired and located in a silver tabernacle by the new main altarpiece, which was dedicated in 1673. In the eighteenth century, this altarpiece was substituted with a new one designed by Jerónimo de Balbás, where the golden statue was eventually relocated. Since the Assunta has generally been overlooked in colonial historiography, I intend to answer the following questions: What were the aesthetic and symbolic values, based upon the theological ideas at the time in the Spanish and Catholic worlds, guiding the representation of Mary in this golden image? What was its agency in relationship to materiality, form, and usage in liturgical contexts and religious festivals?     

MICROSTRUCTURAL CHARACTERIZATION OF EARLY WESTERN GREEK INCUSE COINS*

In this research, we studied the compositional, crystallographic and microstructural properties of a series of incuse silver didrachmae stemming from the Achaean colonies of Metapontum and Caulonia. In this paper, we address the following points: (i) the metal sources, (ii) the fabrication process and (iii) degradation phenomena, such as incrustation and embrittlement. In this investigation, we employed energy‐dispersive X‐ray fluorescence spectroscopy, X‐ray diffractometry, and scanning electron and optical microscopies. The patina is mainly composed of chlorargirite. The coins consist of a silver‐rich alloy containing ～ 1% of Au and Cu. Metallographic and local compositional analyses revealed a complex scenario of inclusions. In one instance, unalloyed copper grains, two‐phase copper/bismuth globuli and high‐bismuth filaments were observed. In other cases, globular Cu ₂ S (chalcocite) inclusions were noticed. The presence of SiO ₂ and iron oxide inclusions is ubiquitous in these samples. Distorted twin lines and strain lines can be detected, denoting work‐hardening of recrystallized flans. Grain polygonalization can occasionally be noticed, hinting at secondary recrystallization processes. The irregularly shaped iron oxide particles often act as crack initiation sites. Fracture facets are generally intergranular. On some areas, intergranular decohesion is also observed. Open cracks sometimes contain AgCl. The strain lines that can be noticed on the fracture surfaces indicate work‐hardening and residual microstructural deformation. Information regarding inclusions and the presence of significant amounts of gold can be tentatively used to address provenancing and fabrication issues.     

The Reappearing Masterpiece: Ranking American Artists and Art Works of the Late Twentieth Century

A survey of the illustrations in textbooks of modern art produces the startling finding that art scholars consider Robert Smithson's Spiral Jetty to be the most important individual work made by an American artist during the past 150 years. More generally, quantifying the evidence of the textbooks reveals the source of the pluralism, or stylistic incoherence, of American art since the late 1960s. A persistently high demand for artistic innovation has produced a regime in which conceptual approaches have predominated. The art world has consequently been flooded by a series of new ideas, often embodied in individual works, usually made by young artists who have failed to make more than one significant contribution in their careers. The monumental Spiral Jetty, made in 1970 by a young artist who was killed soon thereafter while in the process of making his art, brought together a remarkable number of the central themes of the advanced art of the time and has become a symbol for that art.     

The cologne map publisher Peter Overadt (fl. 1590–1652)

Abstract

Peter Overadt is one of the many lesser‐known figures of the second generation of the Cologne school of map making, which had been founded about 1570 by Frans Hogenberg. Overadt is noteworthy as the first continental publisher (aside from Jodocus I Hondius, who was at that time active in London) to have decorated printed topographical maps with marginal historical‐political images. During the first phase of his business (1592–1600), he issued eight maps, with a three‐sheet map of Germania as the pinnacle of his production. After 1600, Overadt's firm was primarily engaged in the publication of religious prints with a Catholic orientation. Topographical productions from this later period are three large town views and the re‐issue of a map of the Rhine area, printed from a re‐worked copper plate of 1594 by Theodoor de Bry.     

Average and core silver content of ancient-debased coins via neutron diffraction and specific gravity

The measurement of the fineness of debased ancient silver coins has proven to be a very difficult issue, which has been studied for a long time. In this paper, this subject is analysed, and the various consequences of the silver surface enrichment (SSE) are discussed exploiting the most recent investigations. A new model is proposed for the complex object that is an ancient-debased silver coin, based on the silver profiles measured on some sectioned specimens. The model is applied to a sample of 43 coins, mainly Roman victoriati, Cisalpine and Illyrian drachms (from late III to I century B.C.). The coins are investigated in two different ways: neutron diffraction (ND) and specific gravity (SG). The results of the two measurements are combined via the proposed model to provide a more complete numismatic information of the original fineness of the monetary alloy. As a result, a relation between SSE thickness and SG is derived, which, for these coinages, allows to estimate the original alloy silver content from a simple SG measurement; the same method can be used to study other debased coinages, provided that all the procedure (ND and SG) is applied.     

Gisèle Halimi entre plainte et plaidoyer: ‘On naît avocate,on ne le devient pas’

This intellectual portrait of defence lawyer and feminist activist Gisèle Halimi tests the hypothesis that her writings function like one long closing argument in a courtroom, where a passionate ‘I’ fights for Justice not only by making sure that the Law is upheld but, when necessary, trying to change the Law with the weapons authorised by the judicial system—narratives and stories. Each word is at the service of the overall agenda. One of the unexpected textual consequences of this ethical position is that it becomes radically impossible to separate autobiography from history, or the voice of the renowned public figure of Maître Halimi from Gisèle's ‘I’.     

臭氧浓度变化对馆藏银器文物腐蚀变色的影响

博物馆环境中的臭氧作为氧化剂,对文物起到氧化腐蚀的作用,会使馆藏银器文物腐蚀变色。本研究主要采用石英晶体微天平(QCM)反应性监测技术,监测电沉积金属银石英晶振片在不同臭氧浓度、不同相对湿度中的质量变化,从而推测银在臭氧中的腐蚀机理。研究结果表明,臭氧浓度对银的腐蚀具有较大的影响。随着臭氧浓度的升高,银表面质量不断增大,腐蚀程度加剧。银对相对湿度具有较小的敏感性,在不同的相对湿度下,银表面质量变化相差不大。据此推断银在臭氧中的腐蚀首先表现为银与臭氧分解产生的原子氧反应生成氧化银(Ag2O),随着Ag2O膜的不断变厚,氧化膜顶层生成过氧化银(AgO),AgO是由Ag2O与原子氧反应生成。     

‘Man is a sack of muck girded with silver’: Metal Decoration on Late-medieval Leather Belts and Purses from the Netherlands

Abstract

THE NATIONAL MUSEUM of Antiquities in Leiden recently acquired two collections of late medieval decorated leather (belts, purses, cases) and base-metal mounts (over 1500 individual pieces) excavated in the Netherlands. These decorative patterns, objects, shields, coin imitations and letters, mainly in sheet copper and lead-tin alloy, from the 14th–16th century ad and largely from Zeeland and Dordrecht, are meant to mirror similar mounts in gold and silver. They are the true ‘bling-bling’ of the common man, woman and pet in the later Middle Ages. This article aims to give an insight into the language of the body and changing attitudes towards luxury. The material is compared with collections of this type of finds elsewhere in the Netherlands, the UK, France and Germany, while research into the archaeological, literary and iconographical context of these decorations indicate what the material tells us about what people — quite literally — wanted to express.     

Was Lacquer the Key Ingredient for Luxurious Jinyin Pingtuo Products in the Tang Dynasty of China (AD 618–907)?

Jinyin pingtuo is one of the most sumptuous decorative methods applied on ‘lacquered' objects described in Tang dynasty literatures. Two Tang dynasty objects, a silver bowl and a bronze mirror, in the British Museum collection said to be made by this technique, were scientifically examined to confirm the application of the technique. Although the metal décors levelled with the rest of the surfaces on these objects suggested the application of the pingtuo method, lacquer, a major ingredient of this technique, was not identified by Py (HMDS)-GC–MS in any of the four samples analysed. The results question the use of lacquer in the pingtuo technique as usually described. The detection of shellac and oil in the bronze mirror aligns with other studies on similar objects, whereas proteinaceous materials as main ingredient of the decorative layers of the silver bowl, appear less usual. Further comparative study by scientific analysis of similar objects in other museum collections or from excavations is required to help better understand the use of lacquer in ancient China.     

成都市博物院几件院藏青铜兵器的分析研究

为了解巴蜀青铜兵器的制作技术及表面斑纹形成机理,采用金相显微镜分析,扫描电镜及能谱仪对成都市博物院的几件带斑纹的馆藏青铜兵器进行了分析。结果表明,两件截面样品均为青铜铸造组织,锡含量平均为11％。三件器物表面斑纹层均含锡和铜并具有一定抗氧化作用。斑纹工艺可分为二类：剑周99-1极可能为直接铸出凸凹不平的剑体,在凸起部位涂高锡合金膏剂,加热处理后得到。另一类可能先直接铸出金属基体,在欲成斑处涂抹合金膏剂或纯锡,加热处理打磨得到。分析结果可为深入研究巴蜀青铜兵器提供参考。     

THE DISCOVERY OF ANOMALOUSLY HIGH SILVER ABUNDANCES IN POTTERY FROM EARLY ROMAN EXCAVATION CONTEXTS IN JERUSALEM*

This is the first study on the differential distribution and concentrations of silver in ceramics recovered from archaeological excavations. The chemical compositions of 1174 pottery vessels from 38 Roman‐period sites in Israel have been determined. Unusually high and variable abundances of silver were discovered in pottery samples of all vessel types and chemical compositions from four distinct archaeological contexts dating to late first century bce to 70 ce Jerusalem. The large majority of the Jerusalem vessels could be distinguished by their silver abundances from all analysed pottery pieces recovered at rural sites outside Jerusalem, even when the pottery types and chemical compositions, except for silver, of pottery found within and outside Jerusalem were indistinguishable. The evidence is suggestive of a human origin for the high and variable silver abundances, and dispersion of the silver by aqueous transport. The differential silver concentrations found in excavated pottery from Jerusalem and other urban and rural sites suggest that attention to the distribution of silver in pottery from excavated contexts may be helpful for evaluating the nature and function of archaeological remains and patterns of urban contamination.