The archaeology and paleoenvironment of an Upper Pleistocene hyena den: An integrated approach

Data of high resolution for reconstructions of archaeological site formation processes can be obtained only by the use of precise excavation methods and comprehensive recovery techniques using fine-mesh water screening, followed by meticulous sorting and quantitative studies of all the small organic components from the screens. These methods are generally used at human occupation sites, but are not often employed at paleontological or mixed human-carnivore sites. At the site of Bois Roche, an Upper Pleistocene hyena den, we have used these meticulous recovery techniques in combination with absolute dating, geoarchaeological observations, taphonomic analyses, studies of microvertebrates and pollen analysis. Correlation of the site environmental data from pollen and microvertebrate assemblages with the vegetation record of a deep-sea core taken in the Bay of Biscay have allowed us to constrain the ages provided by ESR dating of bovid teeth and to reconstruct the physical environment of the site with a degree of confidence rarely achieved by the use of fossil remains from archaeological sites alone.     

DATING OF THE HOMINID (HOMO NEANDERTHALENSIS) REMAINS ACCUMULATION FROM EL SIDRÓN CAVE (PILOÑA,ASTURIAS, NORTH SPAIN): AN EXAMPLE OF A MULTI‐METHODOLOGICAL APPROACH TO THE DATING OF UPPER PLEISTOCENE SITES

The age of Neanderthal remains and associated sediments from El Sidrón cave has been obtained through different dating methods (¹⁴CAMS, U/TH, OSL, ESR and AAR) and samples (charcoal debris, bone, tooth dentine, stalagmitic flowstone, carbonate‐rich sediments, sedimentary quartz grains, tooth enamel and land snail shells). Detrital Th contamination rendered Th/U dating analyses of flowstone unreliable. Recent ¹⁴C contamination produced spurious age‐values from charcoal samples as well as from inadequately pretreated tooth samples. Most consistent ¹⁴C dates are grouped into two series: one between 35 and 40 ka and the other between 48 and 49 ka. Most ESR and AAR samples yielded concordant ages, ranging between 39 and 45 ka; OSL dating results permitted adequate bracketing of the sedimentary layer that contained the human remains. Our results emphasize the value of multi‐dating approaches for the establishment of reliable chronologies of human remains.     

Relative and absolute dating of the human skull and skeleton from Galley Hill,Kent

Over a period of some 100 years it has gradually been accepted that the human skeletal remains found in the late nineteenth century in ancient gravels at Galley Hill, Kent are not those of early man, but are of much more recent date. This conclusion was finally verified by means of relative (N, F) and absolute (¹⁴C) dating. Here we present the results of further analysis of the remains from Galley Hill for their uranium content by a method having general application to the relative dating of fossil human and other mammalian bone.     

The ESR geochronology and geology of the open‐air Palaeolithic deposits in Bollschweil,Germany*

This paper presents ESR (electron spin resonance) ages of rhinoceros and equine tooth enamel from the open‐air Palaeolithic site of Bollschweil on the western edge of the Black Forest near Freiburg, Germany. Bollschweil is one of very few archaeological sites in southern Germany to yield Lower or Middle Palaeolithic faunal and lithic materials from a buried, open‐air context. The geological context of the archaeological remains indicates that the loessic sediments have been reworked. Excavation at this site yielded a cold‐period fauna characterized by bones of mammoth, horse, large bovids and wooly rhinoceros. In the absence of any clear chronostratigraphic marker horizons, the age of the finds could not be determined without the use of a chronometric dating method. Lithic artefacts from the site, including a handaxe and a side scraper, suggest either a Middle Pleistocene or early Late Pleistocene age. The ESR dating results indicate that the deposit enclosing the archaeological finds should be assigned to oxygen isotope stage (OIS) 6, although there exists some possibility that some teeth were deposited later, in OIS 5.     

ESR response in tooth enamel to high-resolution CT scanning

High-resolution CT scanning of teeth with a resolution on the 20 to 30 μm scale introduces doses in the range of 250 to 420 Gy in the tooth enamel. If the induced doses cannot be precisely estimated, subsequent ESR dating analysis becomes impossible. Considering the increased availability of portable, high-resolution CT scanners, curators of valuable human dental fossils have to make an informed decision whether they want to preclude ESR analysis, one of the few dating methods that can be applied to older fossils.     

ELECTRON SPIN RESONANCE ANALYSIS OF MARINE GASTROPODS FROM COASTAL ARCHAEOLOGICAL SITES IN SOUTHERN AFRICA

Shell samples of the marine gastropod Turbo sarmaticus have been examined to assess their potential for electron spin resonance (ESR) dating. The shells were found to be composed of aragonite. ESR analysis shows the presence of three radiation sensitive peaks. Equivalent dose (ED) values for two of the peaks have been determined for thirteen samples. When the two sets of ED values are plotted against each other, four distinct clusters are found that appear to represent four different age groups. The apparent age groups determined here are consistent with the stratigraphic record of the sites.     

Comparison of three K-feldspar luminescence dating methods for Holocene samples

The luminescence dating of the K-feldspar fraction is an alternative way for samples that cannot yield reasonable equivalent dose (D_e) from quartz fraction with very weak luminescence signal. For testing the reliability of the infrared stimulated luminescence (IRSL) dating of K-feldspar, luminescence dating was applied to quartz and K-feldspar fractions respectively for several Holocene samples in this study. K-feldspar apparent ages using routine single aliquot regenerative-dose (SAR) protocol, K-feldspar ages using g value correction method and ages from isochron dating method were compared with quartz ages. It is found that the g value correction method cannot give reliable ages due to the large errors induced during measurements. The isochron dating method is effective to the sample with problematically external dose rate. However, isochron dating may introduce a relatively greater error during grain sizes — D_e curve fitting, therefore this method could obtain low-resolution ages for Holocene samples. Even K-feldspar apparent age from routine SAR protocol is relatively younger by about 10% than the quartz age, it still could establish reasonable chronological framework for Holocene samples.     

ESR dating of the Donggutuo Palaeolithic site in the Nihewan Basin, northern China

The fluvio-lacustrine sequences in the Nihewan Basin, northern China, provide important terrestrial archives about Palaeolithic settlements and, therefore, about early human occupation in high northern latitude in East Asia. Here we present detailed ESR dating of the Donggutuo Palaeolithic site, located in this basin. Four levels A, B, C and E of the Donggutuo archaeological layer yield ESR ages ranging from 1060±129 ka to 1171±132 ka with a mean of 1119±132 ka. The ages are consistent with the paleomagnetic data, which show that the Donggutuo Palaeolithic site lies just below the onset of the Jaramillo normal subchron (0.99–1.07 Ma). Furthermore, our results indicate that the reliable ESR dating range of bleached quartz using Ti-Li centre can be effectively extended to 1100 ka and the Ti-Li centre was zeroed before the last deposition, which requires improvement of the understanding of the bleaching mechanism conditions.     

ESR dose response of Al center measured in quartz samples from the Yellow River (China): Implications for the dating of Upper Pleistocene sediment

The ESR dating method requires to describe the evolution of the ESR signal intensities vs. increasing gamma doses, then to extrapolate the equivalent dose of radiation received by the sample since its deposition using mathematical fitting. The function classically used to describe the growth curves of ESR aluminium signal in quartz was recently discussed and challenged for Lower Pleistocene sediments. In the present work, some alluvial sediments sampled in Upper Pleistocene fluvial terraces of the Yellow River system (China) permit us to test the application of another extrapolation function (linear + exponential) recently proposed for Lower Pleistocene sediments. The equivalent doses obtained here for the recent deposits of the Yellow River system and the corresponding ages are promising and indicate the potential of ESR to date quartz deposits from Upper Pleistocene times.     

Implications of age variation and sexual dimorphism in modern equids for Middle Pleistocene equid taxonomy

Interspecific variation in the equid lineage is limited when compared with other large mammal lineages, while a considerable amount of intraspecific ecomorphological variation occurs. This has led to considerable debate regarding the taxonomic status of palaeontological and archaeological equid remains. The possible confounding impact of sex and age variation on analyses of archaeological equid remains has so far remained untested. This could be especially problematic when it is unknown whether an assemblage contains more than one equid species, breed or hybrid. Here, sex and age variation in modern equid species is examined and compared to variation in Pleistocene equid assemblages from northwest Europe. Sex variation in the longbones of modern equid species was found to be lower than variation over time. Similarly, age variation in dental elements of the same species is predominantly lower than diachronic variation, although caution needs to be taken when an archaeological assemblages consists mostly of elements at a similar wear stage. To assess whether late Middle Pleistocene caballoid horse fossils should be assigned to multiple species or be considered to form a monospecific group, the coefficients of variation for measurements on fossil horse remains were compared with those for modern equid specimens. Results indicate that the fossil assemblages are similarly variable to samples of modern material. Taken as a whole, the late Middle Pleistocene caballoid horse lineage is equally variable to an assemblage of modern ponies of a variety of different breeds. This implies that the variation observed between samples dating from different parts of the Middle Pleistocene can be characterised as intraspecific variation within a single species reflecting ecomorphological adaptations to the changeable Pleistocene climate. Copyright © 2010 John Wiley & Sons, Ltd.     

Aspects of Infrared Radioluminescence dosimetry in K-feldspar

Infrared radioluminescence (IRRL) of K-feldspar, detected at peak wavelength of 865 nm, is emerging as a potential geochronometric tool. The present study explores and attempts to optimize the IRRL dating protocols and proposes a revised protocol for estimation of palaeodose. UV light (395 nm; 700 mW/cm2) bleach of 800 s was optimum to remove the trapped charges responsible for IRRL and, reduced the interference of radio-phosphorescence due to prior irradiations. Validation of the proposed protocol was carried out by dose recovery tests on mineral and sediment K-feldspar samples of different provenances. An overestimation in dose recovery was observed and was attributed to difference in sensitivity of natural IRRL and regenerated IRRL. The sensitivity changes were significant and systematic and were documented by repeating bleach-IRRL cycles. Corrections for sensitivity changes between natural and regenerated IRRL, gave reliable results and, have now been included in the proposed dating protocol.     

Optically stimulated luminescence (OSL) dating investigations of rock and underlying soil from three case studies

Three rock samples and associated underlying surface (floor) soils of geoarchaeological significance from Greece, Sweden and a modern surface stone-sample from a Danish site were investigated using OSL dating. Thin slice, sub-samples, from drilled core surfaces were prepared. A single-aliquot regenerative-dose (SAR) protocol was used on whole rock slices to estimate the laboratory equivalent dose. Laboratory tests showed that the SAR protocol successfully corrected for sensitivity changes and that a known laboratory dose could be measured accurately.     

COMPOSITIONAL INHOMOGENEITY OF SEDIMENTS AND ITS POTENTIAL EFFECTS ON DOSE RATE ESTIMATION FOR ELECTRON SPIN RESONANCE DATING OF TOOTH ENAMEL

We present results of particle size and radioactivity analyses of sediment samples collected from five sites with different burial environments. The uranium, thorium and potassium concentrations in the five sample sets are shown to vary with particle size. The potential effects of the observed size-dependent variations on electron spin resonance (ESR) dating of tooth enamel are assessed using two hypothetical models. Our results show that any bias to relatively fine fractions could result in a significant overestimation of the total environmental dose rate, leading to an underestimation of the calculated ESR age.     

New datings of Amudian layers at Qesem Cave (Israel): results of TL applied to burnt flints and ESR/U-series to teeth

Because only a few radiometric data are actually available, the chronology of the Amudian – a blade-dominated industry of the Acheulo-Yabrudian Cultural Complex (AYCC) of the late Lower Paleolithic in the Levant – is still not well constrained. Qesem Cave offers the opportunity to enhance our knowledge of the chronological position of this industry which is unique to the Levant. The Qesem Amudian bearing layers yielded also human remains showing affinities with those of modern populations recovered in the Middle Paleolithic sites of Skhul and Qafzeh. The results presented here are the first attempt to apply the TL and ESR/U-series dating methods at this site and these methods yielded results which are generally in agreement. They support a time interval of hominid-bearing occupation of the areas of the cave where Amudian lithic artifacts were recovered during MIS 8 and likely 9 for the Deep Pit Area, and during MIS 8 and possibly 7 for the Upper part of the sequence (Square K/10 and the Eastern Microfauna-Bearing Area). An older occupation of the cave is also conceivable on the base of two dating results (MIS 11).     

Review and assessment of the potential of post-IR IRSL dating methods to circumvent the problem of anomalous fading in feldspar luminescence

Quartz has been the main mineral used for optically stimulated luminescence (OSL) dating of sediments over the last decade. The quartz OSL signal, however, has been shown to saturate at relatively low doses of ～200–400 Gy, making it difficult to be used for dating beyond about 200 thou-sand years (ka), unless the environmental dose rate is low. The infrared stimulated luminescence (IRSL) from feldspars has been shown to continue to grow to higher dose levels than quartz OSL. The application of IRSL dating of feldspars, however, has long been hampered by the anomalous fading effect. Recent progress in understanding anomalous fading of the infrared stimulated luminescence (IRSL) signals in potassium-feldspar has led to the development of post-IR IRSL (pIRIR) protocols and also a multiple elevated temperature (MET) stimulation (MET-pIRIR) protocol. These procedures have raised the prospect of isolating a non-fading IRSL component for dating Quaternary deposits containing feldspars. In this study, we review the recent progress made on (1) overcoming anomalous fading of feldspar, and (2) the development of pIRIR dating techniques for feldspar. The potential and problems associated with these methods are discussed.     

The E<Subscript>1</Subscript>’ center in natural quartz: Its formation and applications to dating and provenance researches

Quartz is one of the minerals useful for electron spin resonance (ESR) dating. The E₁′ center is one of well-known paramagnetic defects in crystalline quartz. This center has a unique feature; its intensity increases on heating. An electronic process to explain this increase was found to be controlled not only by the number of oxygen vacancies, which are the precursors, but also by the number of Al hole centers, which depend on the previous radiation dose and on the Al concentration.     

Fossil fruit identification by SEM investigations, a tool for palaeoenvironmental reconstruction of Dmanisi site, Georgia

Archaeological excavations and multidisciplinary studies at the site of Dmanisi (Lesser Caucasus, Georgia) have provided an assemblage of lithic artefacts and numerous palaeontological and human remains in a volcano-sedimentary context dating to the early Lower Pleistocene. The sieving of archaeological sediments from Dmanisi also yielded mineralised botanical macro-remains that were analysed according to a particular protocol. The use of scanning electron microscopy (SEM) allowed the comparison between fossil fruit remains and modern specimens, leading to a precise identification of the earlier. Seed remains recognised by this method belonging to several taxa from the Boraginaceae family as well as to the genus Celtis L., of the Ulmaceae family. The ecological requirements of these taxa suggest the presence of xeric conditions, a result that is in accordance with data obtained by faunal and stratigraphic studies.     

A NEW THERMOLUMINESCENCE DATING TECHNIQUE FOR HEATED FLINT*

A new thermoluminescence (TL) technique for determining the age of heated flint artefacts from archaeological sites is presented. It is a variant of the SAR protocol, which is usually used for OSL dating of sediment, but it is not based on a presumed model for fitting the dose–response curve. Dose recovery tests as well as comparisons with standard protocols show the accuracy of the new technique. It is found that the sensitivity of the thermoluminescence (TL) signal of flint in the orange–red waveband does not show severe changes due to the heating process while measuring the TL. This allows the application of a short SAR procedure, which requires only two dose points. The technique does not require as much instrument time as other SAR techniques, and thus is advantageous for dating very old samples. The major advantage of this new technique is the small amount of sample material required, which allows the dating of samples that are too small for standard TL dating techniques.     

Relation between radiocarbon,archaeological dating and sediment properties on the example of colluvial deposits (NE Poland)

This study focuses on the analysis of the structural and textural features of the colluvial (deluvial) deposits in the Suwałki Lake District (NE Poland) and their absolute age. The colluvium has a thickness of up to 150 cm. The dates of the peat under colluvium or lowermost fossil humus-rich horizons point to the ages from 5405±80 BP to 480 BP. Deposition of material at the footslope is a result of a denudation triggered by human action (surface water erosion and tillage erosion) and usually corresponds with the settlement stages. The ¹⁴C dating of deposited sediment sometimes indicated to older dates of colluvium then the archaeological evidence available for examined sites. Locally, the overlying fossil humic horizon was older then the lowermost one. The textural features of the colluvial deposits such as: the content of fine fraction, weak sorting and relationship between the mean grain-size (Mz) and the sorting index (σ₁) were used to recognize sediment redeposited from the upper part of the slope. Basing on the mineral composition and electrical conductivity of fossil humus horizon it is possible to say whether the soil was degraded or aggraded. These features of the humus-rich horizons occurring between colluvial sediments can be used to explain discrepancy between the radiocarbon dating and archaeological evidence.     

Radiocarbon dating and the “old shell” problem: direct dating of artifacts and cultural chronologies in coastal and other aquatic regions

Archaeologists have long recognized the problem of the “old wood” effect in radiocarbon dating charcoal and wood samples, the age of which may be hundreds of years older than their use by humans. Such problems have resulted in significant changes in how most researchers select wood and charcoal samples for ¹⁴C dating, with many now using relatively short-lived carbonized materials for dating. Despite the significant strides made in our understanding of the potential biases of the “old wood” effect, little emphasis has been placed on the possible impacts of dating “old shell” in archaeological deposits. The use of marine shell for ¹⁴C dating is widespread in coastal areas around the world, including a growing emphasis on the dating of individual shell artifacts via Accelerator Mass Spectrometry (AMS). In dating shell artifacts, we have obtained several dates older than associated ¹⁴C dates for short-lived subsistence remains from the same deposits, including great disparities (>10,000 years) and more subtle differences (≥100 years). These discrepancies appear to be due to the use of old shells by humans to make beads and other artifacts, including shells collected from fossil deposits, older archaeological sites, and beaches. The problems caused by the use of old shells to make beads and other artifacts are surmountable through careful sample selection, analysis of multiple ¹⁴C dates on a variety of materials, and proper calibration procedures.