Response of cathodoluminescence of alkali feldspar to He+ ion implantation and electron irradiation

Cathodoluminescence (CL) of minerals such as quartz and zircon has been extensively studied to be used as an indicator for geodosimetry and geochronometry. There are, however, very few investigations on CL of other rock-forming minerals such as feldspars, regardless of their great scientific interest. This study has sought to clarify the effect of He+ ion implantation and electron irradiation on luminescent emissions by acquiring CL spectra from various types of feldspars including anorthoclase, amazonite and adularia. CL intensities of UV and blue emissions, assigned to Pb²⁺ and Ti⁴⁺ impurity centers respectively, decrease with an increase in radiation dose of He⁺ ion implantation and electron irradiation time. This may be due to decrease in the luminescence efficiencies by a change of the activation energy or a conversion of the emission center to a non-luminescent center due to an alteration of the energy state. Also, CL spectroscopy of the alkali feldspar revealed an in-crease in the blue and yellow emission intensity assigned to Al-O^?-Al/Ti defect and radiation-induced defect centers with the radiation dose and the electron irradiation time. Taken together these results indicate that CL signal should be used for estimation of the α and β radiation doses from natural radionuclides that alkali feldspars have experienced.     

Observation and analysis of NI 520.0 nm auroral emissions

The results from the analysis of simultaneous auroral ground-based optical measurements of the N(²D) 520.0 nm, N₂⁺ 1NG 470.9 nm, O(³P) 844.6 nm and the O(¹D) 630.0 nm emission intensities are presented. The data were obtained during auroral observations at Gillam (56.35°N, 265.32°E) over an observation period of about 8 hours, from UT 2:33 hrs to UT 10:06 hrs, on 20 March 1985. The soft electron flux measurements on board the DMSP satellite for the time of the experiment have also been considered in the analysis. The N(²D) density and the N(²D) 520.0 nm integral emission rate I(520.0) were calculated employing a one- and two-dimensional time-dependent ion-chemistry model and the model predictions have been compared with the experimental I(520.0) nm emission rates. It was found that the model predictions of the NI I(520.0) nm intensity based on the electron energy fluxes inferred from the experimental I(844.6)/I(427.8) emission rate ratios are smaller in magnitude than the experimental values by a factor of 5–8 after allowing for horizontal transport of [N(²D)] by neutral winds. Assuming soft electron precipitation, suggested by the OI I(630.0) nm emission measurements and the DMSP satellite electron flux data, provided good agreement between the model and experimental results. Based on the results obtained it was concluded that horizontal transport played a minor role and that the observed N(²D) I(520.0) nm emissions were mostly produced by precipitating soft electron fluxes with energies below about 100 eV.     

THE SPATIOTEMPORAL EVOLUTION OF U.S. CARBON DIOXIDE EMISSIONS: STYLIZED FACTS AND IMPLICATIONS FOR CLIMATE POLICY

We characterize the evolution of U.S. carbon dioxide (CO₂) emissions using an index number decomposition technique which partitions the 1963–2008 growth of states’ energy‐related CO₂ into changes in five driving factors: the emission intensity of energy use, the energy intensity of economic activity, the composition of states’ output, per capita income and population. Compositional change and declining energy intensity attenuate emissions growth, but their impacts are offset by increasing population and income. Despite absolute interstate divergence in both emissions and their precursors, states’ emission‐ and energy intensities—and ultimately, CO₂—appear to be stochastically converging. We assess the implications of these trends using a novel vector autoregression (VAR) emission forecasting technique based on our index numbers. The resulting emission projections are comparable to, but generally exceed, those forecast by the 2010 EIA Annual Energy Outlook.     

SCIENTIFIC ANALYSIS OF SEVENTH‐CENTURY GLASS FRAGMENTS FROM THE CRYPTA BALBI IN ROME*

Inductively coupled plasma emission spectroscopy, reflectance spectroscopy and X‐ray diffraction were used to study seventh‐century AD glass fragments from the Crypta Balbi in Rome. All the samples were found to be silica‐soda‐lime glasses. Iron determines the colour of blue‐green, green and yellow‐green transparent glasses; chemical composition suggests deliberate addition of iron and/or manganese in about half the samples. Copper was found as the main colourant in red, pale blue and blue‐green opaque fragments; elemental copper acts as an opacifier in red glass, and calcium antimonate in white, pale blue and blue‐green glasses. Detection of antimony in transparent fragments suggests recycling of opaque mosaic tesserae.     

VELOX: a new VLF/ELF receiver in Antarctica for the Global Geospace Science mission

VELOX (VLF/ELF Logger Experiment), a new facility for systematically studying the characteristics of magnetospherically generated ELF/VLF radio noise received at a high-latitude ground station (Halley, Antarctica, 76°S, 26°W, L = 4.3), measures continuously at 1 s resolution the absolute power (peak, mean, and minimum), arrival azimuth, and polarisation ellipticity in 8 logarithmically spaced frequency bands ranging from 500 Hz to 9.3 kHz. All filtering etc. is done in real time using Digital Signal Processing (DSP) techniques. Key parameters (1 kHz and 3 kHz power channels only, at 1-minute intervals) for each day are extracted and regularly transferred to the Global Geospace Study Central Data Handling Facility. Data from the first year of operation (1992) show that, whilst the upper channels (6 kHz and 9.3 kHz) are dominated by thunderstorm (spheric) noise, which is strongest at night and repeatable from day to day, magnetospheric chorus and hiss emissions are more important in the 1–4 kHz range of high attenuation in the Earth-ionosphere waveguide. They are highly variable in intensity from below system noise level (15–20 dB above the reference level 10⁻³³ T² Hz⁻¹) up to a maximum of 60–70 dB. Three classes of event are usually observed during specific local time sectors: substorm-related chorus events in the midnight-dawn sector, dawn chorus, and hiss-like events in the afternoon; all may occasionally be completely absent on quiet days. The substorm chorus events are shorter (typically 10–20 minutes) and more narrow-band than dawn chorus. Both upper and lower cut-off frequencies rise rapidly (∼ 100 Hz/min), consistent with the energy dispersion of resonant electrons as they drift eastward from injection near midnight, and with the inward drift, driven by substorm-enhanced electric fields, of whistler ducts which support propagation to the ground. Afternoon emission events are often punctuated by sudden deep fading, to noise level within 1–2 minutes, usually followed by complete recovery after a few minutes. All frequencies in the emission band are affected simultaneously. The explanation for this effect is unknown, though it could be a cut-off of propagation through the ionosphere to the ground by irregularities or gradients tilting the wave-normals out of the transmission cone. A similar system to VELOX will be deployed on a network of Automatic Geophysical Observatories extending to higher latitudes, south of Halley.     

旅游业碳排放强度分布及其驱动因子的时空异质研究——基于30个省(市、区)2005-2014年的面板数据分析

本文利用交通运输业、邮电业、商业、餐饮业、住宿业以及社会服务业这6个行业面板数据,在揭示2005年至2014年30个省(市、区)旅游业碳排放总量与强度的时空动态变化关系时,借助LMDI法分解出影响我国旅游业碳排放增加量的关键因素。研究结果表明:①旅游业碳排放总量在时间上呈逐年上升趋势,且中、西部地区增长速度要显著高于东部地区;②旅游业碳排放强度在时间上呈逐年递减趋势,且中、西部地区下降速度要显著低于东部地区;③影响我国旅游业碳排放增加量的关键因素取决于经济产出因子(TEO)、接待人次因子(TP)、行业结构因子(TIS)、能源效率因子(TEE)、能源结构因子(TES)5个方面,前两者为增量因子,后三者为减量因子。     

Optical observations of gravity waves in the auroral zone

Night-time observations of O(¹D) λ630 nm and O(¹S) λ558 nm thermospheric emissions were made at Mawson, Antarctica (67.6°S, 62.9°E) from 1982 to 1989, using a three-field photometer. Crossspectral analysis of the data was used to extract frequencies and horizontal trace velocities of periodic structures. Structures in the λ630 nm emission were characteristic of large-scale waves, and those in the λ558 nm emission were characteristic of medium-scale waves. The results showed distinct polarisation of the propagation azimuths; waves in the λ630 nm emission propagated approximately northwestward throughout the 8 yr period, whilst propagation azimuths of waves in the λ558 nm emission appeared to be solar-cycle-dependent. It is suggested that waves observed in the λ630 nm emission were of predominantly auroral electrojet origin, whilst those observed in the λ558 nm emission were of both auroral and tropospheric origin.     

Carbon offsetting and renewable energy development

New carbon crediting and offsetting mechanisms are being developed under the Paris Agreement. Polluters can meet their emission reduction targets by acquiring and retiring carbon offset credits. Globally, most of these credits come from renewable energy sources. However, their additionality is increasingly questionable. Global renewable electricity capacity continues to grow. Greenhouse gas emissions from coal-fired power generation are starting to fall, as governments and organisations pledge to curtail emissions, more capital is mobilised for energy transition, and renewable energy technologies become commercially competitive. The opportunity to earn carbon offset credits is becoming less indispensable to renewable energy development. Aggregate emissions could rise above the baseline level when polluters increase their emission budgets by using carbon credits generated from a renewable energy installation that is part of the baseline scenario. To safeguard environmental integrity, the conditions for including renewable energy in carbon crediting and offsetting schemes should be reconsidered.     

THE COLOURED TESSERAE DECORATING THE VAULTS OF THE FARAGOLA BALNEUM (ASCOLI SATRIANO,FOGGIA, SOUTHERN ITALY)

Twenty‐six tesserae (red, orange, yellow, light amber, green, blue and white) from the balneum of the villa at Faragola (Ascoli Satriano, Foggia) have been examined by colorimetry, ICP–MS, ICP–OES and SEM–EDS. Different types of calcareous sands have been used as the source of silica (network former), also providing the stabilizing agent. A natron‐type soda source served as the network modifier; however, the use of a sodium‐rich plant ash and the recycling process have been hypothesized for the production of two tesserae (FT 1 red and FT 3 orange). The colouring and opacifying agents were Cu oxide (cuprite, orange), metallic copper (red), Pb antimonates (yellow), Ca antimonates (white), a mixture of copper (Cu²⁺) and Pb antimonates (green), a mixture of cobalt (Co²⁺) or copper (Cu²⁺) and Ca antimonates (blue). The light amber tesserae should owe their colour to iron (Fe³⁺) alone or associated with sulphide (S^2?) and Ca antimonates. It is likely that the Faragola tesserae were locally produced in a secondary glass workshop.     

Multi-Isotope Investigations for Scientific Characterisation and Provenance Implication of Banded Travertines from Tripolis Antique City (Denizli–Turkey)

The coloured stones used in buildings and monuments were an indicator of power and wealth during the ancient times. In this study, Tripolis city samples have been compared with Tripolis quarry samples in order to recognise the provenance of the banded travertine blocks in the ancient city. The banded travertine samples have similar mineral compositions and mainly consist of calcite with minor amounts of dolomite, aragonite, clay and iron oxide minerals. These results are also supported by CRS studies. Calcite is in the form of needle-shaped crystals ranging between 0.163–1.418?mm (in city) and 0.303–1.270?mm (in quarry). Tripolis banded travertine samples show the similar compositional spread in terms of major oxide, trace elements. δ¹³C_V-PDB values of banded travertines range from 1.93 to 5.25‰ (in city) and 2.99 to 3.99‰ (in quarry), δ¹⁸O_V-PDB values change between (?16.93)–(?10.08) ‰ and (?15.93)–(?13.01)‰, respectively. The U–Th radiometric ages are determined between ～267 and 9?ka in Tripolis city samples and ～350 and 2?ka in Tripolis quarry samples. The minero-petrographic, geochemical, C–O and U–Th isotope results fairly matched with each other. It seems highly probable that the banded travertines in Tripolis city were extracted from the Tripolis quarry, which is located at the northeast of the antique city with a distance of 3?km.     

京津冀地区旅游业的碳排放测算与比较研究

本文借鉴"旅游消费剥离系数"概念构建了京津冀地区旅游业碳排放量的计算方法,并对京津冀三省份的旅游碳排放指标进行了比较分析。研究表明:2010-2012年京津冀地区的旅游碳排放总量持续攀升,从591.018万吨增加到696.3万吨,而旅游者的人均碳排放总量持续递减;2010-2012年北京市旅游业碳排放总量均排名首位,河北省始终最低,但是增长势头迅猛;从人均总量对比情况看,2010-2012年河北旅游业碳排放人均总量在京津冀中最低,同时,北京人均总量却是最高的,2010-2012年京津冀地区中只有北京的人均总量逐年下降,天津旅游业碳排放量人均总量呈现倒U型变化特征,而河北呈现持续上升特征。未来京津冀地区需要从节能减排行动纲要制定、企业节能技术创新等方面推进旅游节能减排工作。     

The Effect of NAFTA on Energy and Environmental Efficiency in Mexico

Prior to Mexico's entry to the North American Free Trade Agreement (NAFTA), predictions of the consequent impact on the environment in that country ranged from the dire to very optimistic. This article investigates NAFTA's outcomes in terms of energy use and the emission of atmospheric pollutants. Specifically, has entry into NAFTA led to a convergence or divergence in indicators of emissions, environmental efficiency, and emissions‐specific technology in Mexico, the United States, and Canada? A battery of tests is applied to these indicators for energy use and carbon, sulfur, and NOx emissions in the three countries. The results show that the extreme predictions of the outcomes of NAFTA have not materialized. Rather, trends that were already present before the introduction of NAFTA continue and, in some cases, improve post‐NAFTA, but not yet in a dramatic way. There is strong evidence of convergence across the three countries toward a lower intensity of energy use and emissions per unit of GDP. Although intensity is rising initially for some variables in Mexico, it eventually begins to fall post‐NAFTA. Per capita emissions of sulfur and NOx also show convergence, but this is not the case for energy and carbon, and the latter variables also drift moderately upwards. The state of technology in energy efficiency and sulfur abatement is improving in all countries, although there is little, if any, sign of convergence and NAFTA has no effect on the rate of technology diffusion. However, total energy use and carbon emissions increase both pre‐ and post‐NAFTA and total NOx emissions increase in Mexico. Only total sulfur emissions are stable and falling in all three NAFTA partners.     

Atomic oxygen concentrations from rocket airglow observations in the equatorial region

A rocket payload designed to measure mesospheric sodium, hydroxyl and oxygen nightglow emissions, in addition to electron density and temperature, was launched from the Alcantara Launch Center (2°S, 44°W), Brazil, at 23:52 LST on 31 May 1992. The height profiles of the atomic oxygen OI557.7 nm and molecular oxygen Atmospheric (0-0) band emissions showed maxima at 100±3 km and 98±3 km, respectively. The emission data are used to calculate the atomic oxygen concentration profiles. The results show the validity for the equatorial region of the empirical parameters proposed by McDade et al. (1986).     

SYNTHESIS AND ACID RESISTANCE OF MAYA BLUE PIGMENT*

Maya blue is an organo‐clay artificial pigment composed of indigo and palygorskite. It was invented and frequently used in Mesoamerica in ancient times (eighth to 16th centuries). We analyse in this paper one of the characteristics of Maya blue that has attracted the attention of scientists since its rediscovery in 1931: its high stability against chemical aggression (acids, alkalis, solvents, etc.) and biodegradation, which has permitted the survival of many works of art for centuries in hostile environments, such as the tropical forest. We have reproduced the different methods proposed to produce a synthetic pigment with the characteristics of the ancient Maya blue. The stability of the pigments produced using either palygorskite or sepiolite has been analysed by performing acid attacks of different intensities. The results are analysed in terms of pigment decolouration and destruction of the clay lattice, revealed by X‐ray diffraction. Palygorskite pigments are much more resistant than sepiolite pigments. It is shown that indigo does not protect the clay lattice against acid aggression. We show that Maya blue is an extremely resistant pigment, but it can be destroyed using very intense acid treatment under reflux.     

Chemical composition and colouring agents of Roman mosaic and millefiori glass, studied by electron microprobe analysis and Raman microspectroscopy

About 100 fragments of Roman mosaic and millefiori glass were stylistically attributed to a Hellenistic type, a Ptolemaic and Romano-Egyptian period type and an early imperial period type. Twelve representative fragments were studied by electron microprobe analysis and Raman microspectroscopy. Eleven of them display a Na-pronounced recipe with low K, Mg and P contents, typical for the Roman period. Minor differences in composition are unsystematic, not reflecting the stylistic classification. Ionic colouring agents are Mn³⁺ for violet, Cu²⁺ for light blue, Co²⁺ for deep blue and Fe³⁺ for brown translucent colours. Calcium antimonates, lead antimonate and cuprite are the colourants responsible for white, yellow and red colours, respectively, and additionally serve as opacifiers. Mixing of ionic colouring agents and opacifying colourants led to a more differentiated palette of colours. Pb was used as yellow colouring agent, as a flux material and as a stabiliser for the colourant crystals. The remaining fragment consisting of a K-pronounced but still Na-bearing glass matrix was most likely produced during the Middle Ages or later.     

A SCIENTIFIC INVESTIGATION ON THE PROVENANCE AND TECHNOLOGY OF A BLACK‐FIGURE AMPHORA ATTRIBUTED TO THE PRIAM GROUP*

The restoration of a Greek black‐figure amphora provided an opportunity to study the provenance and production technology of the vase. The composition of the ceramic body, determined by inductively coupled plasma optical emission spectroscopy (ICP–OES), matches that of Attic products. Investigation by X‐ray diffraction and reflectance spectroscopy suggests a maximum firing temperature around 900°C and a body re‐oxidation temperature around 800°C, respectively. The morphology and composition of black, red and dark red surface areas were studied by scanning electron microscopy and X‐ray energy‐dispersive analysis; the black areas show the features of a typical well‐vitrified black gloss, while the red areas were most probably obtained by simple burnishing of the body; the dark red additions, on the other hand, are the likely result of a partial re‐oxidation of a clay–ochre mixture.     

Non-destructive in situ analysis of polychromy on ancient Cypriot sculptures

The study focuses on the characterization of polychromy on limestone sculptures from Cyprus, attributed to the Cypro-Archaic—end of the Hellenistic periods. Polychromy components were identified by integrating digital microscopy, imaging under ultraviolet (UV) light, visible-induced luminescence (VIL), X-ray fluorescence spectroscopy (XRF) and fibre optics reflectance spectroscopy (FORS). Data acquisition was performed directly in exhibition rooms at the Cyprus Museum (Nicosia) and the Paphos District Archaeological Museum (Paphos). Among the identified materials, there are iron-containing (red, yellow, green) and copper-containing (green and blue) pigments. The precision of pigment identification by non-destructive techniques is discussed, and specific pigment names are proposed: red iron oxide, yellow iron oxide-hydroxide, green earth and Egyptian blue. Interesting results were obtained by VIL, which allowed identifying traces of Egyptian blue otherwise undetectable with the naked eye. Complementary, this study discusses advantages and problems of combined and separate use of portable XRF and FORS, raising the question of their complementarity and interchangeability for the purposes of pigment identification.     

甘肃省天水伏羲庙壁画颜料显微分析

为了解甘肃省天水伏羲庙壁画的制作工艺和颜料成分,采用偏光显微镜、显微拉曼光谱和扫描电子显微镜-能潜分析对6个样品进行了分析。结果表明,所使用的颜料为矿物质颜料,多为绿,白、红、蓝色等。其绿色颜料为人造碱式氯化铜,白色颜料碳酸钙,红色为朱砂和铅丹,蓝色颜料为青金石。