Studying the process of enamel powder preparation for émail champlevé by colour measurements and μ‐X‐ray mappings

Colour measurements and non‐destructive μ‐X‐ray mappings have been used for the first time in a comprehensive study of medieval émail champlevé works from different production areas in France and Germany. This approach has given a new insight into the enamel powder preparation process of the glass material used for enamelling. Colour measurements demonstrated that all production centres used glass of very similar hues, but with large differences in colour saturation. The μ‐X‐ray mapping results of blue enamels are described by a semi‐qualitative approach. Significant variations in oxide contents of lead, cobalt, manganese and antimony oxides were found. The variations suggest that more than one glass material was used to prepare the powder for enamelling. The variations in antimony and cobalt show that glass had different degrees of opacity and colour depth. The manganese and lead contents, which do not correlate with the cobalt or antimony contents, indicate that probably glass of different base compositions was used to prepare the enamel powder for one champlevé field.     

A Petrographic Study of the Anthropomorphic Stelae from the Megalithic Area of Saint‐Martin‐De‐Corléans (Aosta,Northern Italy)

The Megalithic Area of Saint‐Martin‐de‐Corléans (Aosta, northern Italy) consists of anthropomorphic stelae dated to the Copper Age and the beginning of the Early Bronze Age. They were carved in different lithologies of varying provenance according to two successive artistic styles, ‘ancient’ and ‘evolved’. A minero‐chemical and a petrographic investigation were carried out on 47 stelae and on reference samples collected from eight different outcrops, aiming to define the provenance of the stone materials. The variety of rocks used for the manufacture of the stelae reflects the geological complexity of the Aosta Valley. Most of the stelae examined were classified as foliated impure marbles, grey banded marbles (‘Bardiglio’), calcschists and metabasites belonging to the Combin Zone (Piedmont Nappe), which outcrops in close proximity to the Megalithic Area. Some stelae of the evolved group consisted of massive marbles with silicate‐bearing layers, attributed to the Sion–Courmayeur Zone. Similar stone materials were reported for the stelae of the same age found at the archaeological area of Petit Chasseur (Sion, Switzerland). This is archaeometric confirmation of the archaeological affinity between the stelae occurring at the two prehistoric sites, supporting the hypothesis of cultural exchanges over the Grand St Bernard Pass since the Early Copper Age.     

Variabilité et fréquence des cycles de gel‐dégel dans la région de Québec, 1977–2006

Freeze‐thaw cycles are most common at the beginning or near the end of the winter season. These cycles have various effects on the ecosystems of Eastern Canada, affecting both biotic and abiotic components of temperate cold environments. Using air temperature minima and maxima from four meteorological stations close to Québec City, we determined the frequency of daily freeze‐thaw cycles for the last 30 years. The results show no significant increase in the number of freeze‐thaw cycles despite a small increase in air temperature. Polynomial curves describing the relationship between mean air temperatures and the number of freeze‐thaw cycles were calculated. Based on these equations and anticipating a climate change scenario, we projected future freeze‐thaw cycles. Assuming a 5 °C increase in mean air temperatures by 2100, we estimated that the number of days with a freeze‐thaw cycle could increase by approximately 20 days per winter. The increase in the number of such cycles will be concentrated during the coldest months of the winter (January and February).     

Origin of dolomites in the Cambrian (upper 3rd‐Furongian) formation,south‐eastern Sichuan Basin,China

The origin of large‐scale ancient dolomite is one of the most hotly debated topics in sedimentology. The Loushanguan group of the upper 3rd‐Furongian Cambrian series on the south‐eastern margin of the Sichuan Basin consists of numerous dolomites, and the origins of these dolomites have never been reported previously although they are probably good hydrocarbon reservoirs. Based on a systematic analysis of petrology, fluid inclusions, carbon and oxygen isotopes, trace elements and rare earth elements (REEs), this study provides some unique insights into the origins of the dolomites. Four dolomite types have been identified in the study area: dolomicrite, fabric‐retentive oolitic dolomite, fabric‐obliterative dolomite and saddle dolomite cement. In the dolomicrite and fabric‐retentive oolitic dolomite, high Sr contents (with respect to the fabric‐obliterative dolomite) and the lack of two‐phase aqueous inclusions suggest that they formed at shallow‐to‐intermediate burial depths at low temperatures (<50–60°C). Carbon and oxygen isotopes and seawater‐like REE+Y characteristics of the dolomicrite and fabric‐retentive oolitic dolomite indicate that the dolomitizing fluids were evaporated seawater or slightly modified seawater. The obliteration of the original sedimentary fabric and relatively low δ¹⁸O and Sr values compared to the fabric‐retentive dolomite indicate that fabric‐obliterative dolomite formed at intermediate‐to‐deep burial diagenesis. The chemical composition approaches pure dolomite and the REE+Y characteristics are similar to those of the fabric‐retentive dolomite, indicating that the fabric‐obliterative dolomite was formed due to the recrystallization of the previously formed fabric‐retentive dolomite at elevated burial depths and temperatures. High fluid inclusion homogenization temperatures (115–150°C), low δ¹⁸O values, nonplanar‐a crystals and seawater‐like REE+Y characteristics suggest that saddle dolomite cement formed by reprecipitation of dolomite that related to seawater‐driven and deep burial fluid. In the study area, dolomicrite and fabric‐retentive oolitic dolomite may have been formed by penecontemporaneous or seepage‐reflux dolomitization during early‐stage diagenesis. Subsequently, during progressive burial, most of the fabric‐retentive dolomite was converted into fabric‐obliterative dolomite by recrystallization. This study confirms that fabric‐obliterative dolomite was the main dolomite type, and although deeply buried, these Cambrian dolomites most likely have preserved coeval seawater geochemical signals.     

Recent Excavation and Recording at the New Neolithic Rock Art Site of Vallée Aux Noirs,Buthiers (Seine‐et‐Marne,France)

Following the exceptional discovery of Neolithic engravings on a boulder at Vallée aux Noirs in the Fontainebleau forest, south of Paris, an excavation trench was opened in order to access the buried part of the decorated rock panel and explore the stratigraphic context of the artwork. A palaeosol was found two metres below the modern ground level, underneath multiple layers of sterile sandy soil forming a very compact sequence from which only one archaeological artefact was recovered – an Iron Age fibula (c.200–300 BC). Dating of the palaeosol was attempted through two different methods: AMS dates from charcoal suggest a significant span from the Early Bronze Age to the Iron Age, while two more consistent OSL dates point to formation of the palaeosol during the Late Neolithic (3500–3000 cal BC). The entire engraved rock surface (16 m²), including its buried part, was fully recorded. Four main semiotic groups were identified: a typical fifth‐millennium crook‐hafted axe with a ring, two boats with steering oars, and a central, very tall human figure dominating the composition from its 3.5‐metre height.