广东博罗先秦硬陶的XRF和INAA研究

为揭示广东博罗梅花墩、银岗、横岭山三地古陶器的产源、烧造工艺、技术传播和化交流等方面情况,用波长色散X射线荧光分析(WDXRF)、仪器中子活化分析(INAA)同时测量了广东博罗梅花墩、银岗、横岭山等三地点所出38片西周至春秋、战国硬陶中Al、Ba等元素的含量。并用主成分分析分别处理了测量数据。两套数据的分析结果均表明,梅花墩、银岗和横岭山的硬陶原料互不相同,各地点硬陶可能主要是“自烧自用”。数据分析还表明在南方各省区中,广东硬陶具有Al2O3含量偏高这一明显的地区特征。     

A study of the glazing techniques and provenances of Tang sancai glazes using elemental and lead isotope analyses

This study discusses the elemental compositions and lead isotope ratios of Tang sancai glazes unearthed from the Huangpu kiln, Huangye kiln and two Tang sancai tomb sites. The various glazes feature distinct lead isotope ratios and trace element characteristics, which can be interpreted as evidence for the use of different lead ore deposits and siliceous raw materials in the glazes. This is a strong indication that lead isotopes combined with trace element analysis could be used as a viable approach for identifying the provenance of Tang sancai of unknown origin by linking them to kiln sites, This provenance technique could be significant in the interpretation of ancient ceramic trade and communication patterns. In this study, the provenance of several Tang sancai glazes of uncertain origin were determined using this method: some Tang sancai wares unearthed in Xi'an City were produced in the kiln near Luoyang City and then traded to Xi'an City, providing an idea of ancient Tang sancai ceramic trade routes.     

Development of quartz cathodoluminescence for the geological grouping of archaeological ceramics: firing effects and data analysis

Cathodoluminescence (CL) spectrometry reveals genetic crystallographic and chemical characteristics of quartz grains specific to the thermodynamic conditions in which they crystallised and their mineralisation history. These genetic characteristics have been used successfully to determine the provenance of sediments. Geological sediments are the raw material for archaeological ceramics which means quartz CL has a potential application in ceramic provenance studies, particularly for fine wares and fabrics in which quartz is the only identifiable inclusion.     

PROVENANCE DETERMINATION OF MYCENAEAN IIIC VESSELS FROM THE 1934–1939 EXCAVATIONS AT TARSUS‐GÖZLÜKULE BY NEUTRON ACTIVATION ANALYSIS

Neutron Activation Analysis (NAA) has been carried out in order to determine the provenance of a selected set of 30 sherds of Mycenaean style excavated at Tarsus‐Gözlükule. The provenance could be established or made feasible in 80% of the samples. The results confirm the current status of research, namely that in the LH IIIC phase trade patterns changed and Mycenaean wares, which used to be exported to the Near East, were now produced locally. At Tarsus, the LH IIIC imports came from Cyprus and the eastern Aegean.     

甘肃新石器时代与青铜代陶器研究的内容和科学意义

综述了现代分析测试方法和数学方法在古代陶器成分分析、年代测定、制作工艺、产地判断、形态分析方面的应用以及甘肃新石器与青铜时代陶器研究的意义。     

Sourcing temper sands in ancient ceramics with U–Pb ages of detrital zircons: a southwest Pacific test case

Through use of methodology common in sedimentary geology, we apply U–Pb ages of detrital zircons to source nonlocal temper sand in an ancient ceramic assemblage recovered from Roviana Lagoon of the New Georgia Group in the Solomon Islands. Most potsherds from the Roviana Lagoon contain local volcanic sand as temper, but a small number of sherds contain anomalous granitic temper sand that does not appear to be local. To determine the origin of the anomalous temper, ages of zircons from the anomalous Roviana sherds are compared with ages of zircons in materials from Lizard Island off the Queensland coast and in sand from Muyuw Island in the Solomon Sea where generically similar granitic sands occur. U–Pb analyses of grains from the Roviana sherds yield Middle Miocene ages, while analyses of grains from Lizard Island granitic bedrock, sand, and local potsherds yield much older Permian-Triassic ages, disproving any possibility that the Roviana sherds were derived from Lizard Island, but suggesting local production of the Lizard Island sherds. Ages of grains in a sand sample from Muyuw Island are nearly identical to the ages of grains in the Roviana sherds. All grains in the Muyuw sand are Middle Miocene in age, overlapping closely with the Roviana age population. This strong similarity in detrital zircon signals indicates that the Roviana temper was likely derived from Muyuw Island sands. Our test case for the use of U–Pb ages of detrital zircons in sourcing temper sands is of only regional significance, and not of intrinsic global interest. The methodology, however, should find wide applicability for sourcing temper sands in many parts of the world, for it provides more specific data for the origins of tempers than either petrographic or chemical analysis.     

NEUTRON ACTIVATION ANALYSIS OF ROMAN AFRICAN RED SLIP WARE KILNS

Roman African Red Slip ware (ARS) sherds from four ARS kiln sites in modern-day Tunisia (El Mahrine, El Ala, Oudna and Pheradi Maius) have been analysed using instrumental neutron activation analysis. Multivariate statistical methods (including cluster analysis and Manhattan City Block distances), with a dilution correction applied to the data, were used to interpret the concentration data. Reference groups for each of the four kiln sites were established. Both El Mahrine and Oudna were described by two dilution-related groups. These kiln groups were all shown to be compositionally distinct from each other and suitable for use in provenance studies.     

Investigating cross-Gulf trade in the Iron Age III period: chronological and compositional data on Burnished Maroon Slipped Ware (BMSW) in southeastern Arabia and Iran

Recently obtained ceramic compositional data from the late Iron Age sites of Tepe Yahya in Iran and Sharm in the United Arab Emirates is presented in this paper. Analysis of this data suggests that a distinctive ceramic, Burnished Maroon Slipped Ware (BMSW), was produced somewhere in southern Iran and exported across the Gulf to eastern Arabia. That this trade was not limited to any defined historical period, such as that represented by the Achaemenid Empire, is suggested by a series of new AMS C¹⁴ dates from Tepe Yahya. The paper concludes with speculative comments on the possible elite nature of BMSW in societies on either side of the Straits of Hormuz.     

TOWARDS A QUANTITATIVE PETROGRAPHIC DATABASE OF KHMER STONE MATERIALS—KOH KER STYLE SCULPTURE

A comprehensive quantitative petrographic database of sandstones used by the Khmers for sculptural purposes would be a helpful tool for archaeologists, museum curators and others interested in pursuing research on early stone usage, geological source and provenance. Towards that end, this paper presents quantitative petrographic analysis of stone materials used in the production of some free‐standing sculptures and architectural elements in the Koh Ker style of the 10th century from the collections of the National Museum of Cambodia and The Metropolitan Museum of Art. These materials are compared to samples from the quarry of Thmâ Anlong near the foothills of the Phnom Kulen, Sieam Reap province. Primary and secondary detrital modes and key grain‐size parameters are used to identify three sandstone types. The free‐standing sculptures are carved from feldspathic arenite and feldspato‐lithic to litho‐feldspathic arenite. Finely carved lintels are worked from a quartz arenite, which is significantly richer in quartz grains and of a finer grain size. The geological source of the two other lithotypes will have to await detailed geological survey of the Koh Ker area accompanied by petrographic study of selected samples from documented quarries. The significance and potentiality of quantitative petrographic study of Khmer stone materials are shown in supporting and integrating archaeological investigations in South‐East Asia.     

Discoveries of Neolithic prehistoric sites at Pleistocene carbonate rock shelters on the east coast of the UAE

Three newly discovered prehistoric sites on the east coast of the United Emirates (UAE) are described. All are located on surfaces of Pleistocene carbonates or rock shelters that are generally rare along the eastern coast of the Gulf of Oman. Aqqah 1 (Le Meridien al Aqqah Beach Resort), the most important and best preserved of these sites, is a partially collapsed rock shelter with an exposed section, lithic finds and marine molluscs. Deriving an exact date from the material present is difficult because of a lack of comparanda. A bifacial fletched arrowhead made of yellow jasper and the lithic debris of five different raw materials as well as an undecorated ceramic fragment might suggest a date in the Late Neolithic or Early Bronze Age. The presence of many marine bivalves and snails with operculae, which differ from recent coastal species, indicates the collection and consumption of living molluscs by the prehistoric population of Aqqah. Nearby burials may be related to the rock shelters.     

Use-wear analysis of obsidian artifacts from Later Stone Age shell midden sites on the Red Sea Coast of Eritrea,with experimental results

This paper presents results of use-wear study on lithic artifacts from two Later Stone Age sites (Gelalo and Misse) on the Red Sea Coast of Eritrea. The sites produced large quantities of lithic artifacts in association with mollusk shells and ostrich eggshell beads, but it is unclear if all the stone tools were required for bead and mollusk shell processing. The study involved recording of microfracture damage traces in order to infer the use-material and the manner in which the artifacts were used. A large percentage of the analyzed samples from Gelalo and Misse preserve wear patterns suggestive of human use. The diagnostic wear types include: (1) dense step, snap (crushing) and hinge fractures typically confined on the working edges, and (2) feather scars organized in a scalar manner visible on the ventral and dorsal surfaces of the active parts. The observed damage patterns suggest cutting and engraving medium to hard materials. The evidence is incomplete for more generalization about the specific activities carried out at the sites. A brief experimental study involving ostrich eggshell drilling, oak twig sawing and bark scraping, meat slicing, and mollusk shell sawing and drilling was carried out to aid interpretation of wear features observed on the archaeological specimens. Wear traces produced by sawing mollusk shell and oak wood showed close affinity to those observed on the archaeological specimens. The study contributes important information about early Holocene site use on the Red Sea Coast of Eritrea. The close association of used lithic artifacts, symbolic objects (beads) and broken shell remains indicates that the sites were habitation areas.     

Chemical Characterization of Micronesian Ceramics Through Instrumental Neutron Activation Analysis: A Preliminary Provenance Study

The development of exchange models from Pacific Islands' archaeological data is a major task facing Oceanic archaeologists. Chemical characterization of ceramics can assist provenance studies required for modelling past human interactions. This regional instrumental neutron activation analysis (INAA) conducted on ceramics collected from the Micronesian ceramic-producing islands of Belau, Chuuk, Guam, Kosrae, Pohnpei, and Yap allows us to form compositional groups and provenance ceramics from the coral islands of Fais, Satawal, and Ulithi. Different island contexts, which cause post-depositional chemical transformations in ceramic sherds, do not hinder the provenance assignments.     

THERMOLUMINESCENCE DATING OF BURNT FLINT AND QUARTZ: COMPARATIVE RESULTS

Thermoluminescence dates obtained from burnt flints and quartz recovered from the same sites are compared. For the Upper Perigordian level at la Vigne Brun (Loire, France), four quartz specimens and three flints yielded average ages of 27 400 ± 2300 and 26 900 ± 2200 years respectively, which are 15% greater than the radiocarbon age obtained for the same site (Evin 1982). For the neolithic site of la Vallée aux Fleurs (Loir et Cher, France), the respective averages of three flints and three ceramic sherds were 6830 ± 560 and 6570 ± 520 years.     

Bipolar Reduction and Behavioral Variability During the Mid-Late Holocene at Eagle's Nest,Mount Sinai Harbor,New York

Recent syntheses for the Long Island Sound region argue for long-term cultural continuity amongst Holocene coastal hunter-gatherers. These notions derive primarily from studies of quartz lithic assemblages, which archaeologists argue show structural stasis over time. The remaining variability is explained with a ‘distance to source' model in which near-coastal sites tend to show a lack of quartz conservation while interior sites show quartz recycling. Under this model, technological strategies traditionally associated with raw material conservation (e.g., bipolar reduction) should not occur at near-coastal sites. We test the ‘distance to source’ model by reexamining a quartz lithic assemblage from Eagle's Nest-Long Island's richest Holocene coastal hunter-gatherer site. We find conclusive evidence for bipolar reduction in the site's “block/shatter” materials. Toolmakers used bipolar reduction to conserve raw material. Toolmakers also used anvils and bipolar reduction to open quartz cobbles, to stabilize freehand cores, to efficiently access cutting edges, and possibly to create crushed coarse quartz temper for pottery production. Our results point to previously unrecognized aspects of behavioral variability in the Eagle's Nest lithic assemblage and to possible revision of the ‘distance to source’ model. Similar variability may be present at other North American sites with quartz “block/shatter” material.     

A PROVENANCE STUDY OF POTTERY FROM ARCHAEOLOGICAL SITES NEAR CANOSA,PUGLIA (ITALY)*

Studies have been carried out to assess the provenance of selected pottery excavated at archaeological sites near Canosa, Puglia (Italy). Sixty-six sherds, ranging in date from the mid-seventh century BC to the beginning of the third century BC, were analysed by atomic absorption spectroscopy and 16 elements were determined. The analysis data were subjected to multivariate classification procedures. Tests showed that the majority of the examined sherds came from ancient local kilns; a probable Ionian origin was established for some other sherds, while the rest were of unknown origin.     

The Source Provenance of Bronze Age and Roman pottery from Cyprus

Archaeological interpretations of ancient economies have been strengthened by chemical analyses of ceramics, which provide the clearest evidence for economic activity, and comprise both the objects of exchange and its means. Pottery is often manufactured from local materials, but its compositional diversity typically prevents significant patterns of resource utilization from being identified. Centrally located and positioned on traditional shipping routes, Cyprus maintained ties with and supplied a variety of distinctive ceramic products to the major commercial centres in the eastern Mediterranean throughout Antiquity. We analysed two Cypriot .ne wares and a variety of utilitarian pottery, as well as samples of extant Cypriot clays to determine source provenance. These chemical analyses provide an objective indication of the origins of ancient (Bronze Age and Roman) ceramics manufactured on Cyprus. The distribution of the probable clay sources and the links between pottery style and the material environment also afford a perspective on the spatial organization of large‐scale pottery production on the island. Compositional analysis provides the means to assemble geographies of pottery production and to unravel the interregional system of exchange that operated in Antiquity, but the ability to accomplish these tasks is predicated on systematic analyses of ceramic products and raw materials that are found far beyond the bounds of individual archaeological sites.     

Chemical characterization of some potsherd pavements from parts of Yorubaland in southwestern Nigeria

Several samples of potsherd pavement were recovered during excavation and archaeological reconnaissance of six sites, along the trade and migration route of the Yoruba of southwestern Nigeria. A significant feature of these pavements is the similarity to Ife in design which consists of a herringbone design, with a ritual pot embedded in their middle. Microscopic analysis of samples shows the presence of high proportions of non-plastic grains, mainly quartz, micas, minor plagioclases, and traces of ferruginous grains, tourmaline and amphibole, interpreted as being produced by low temperature firing. Major, trace and rare earth elements' composition of 21 samples of sherds was determined using Inductively Coupled Plasma (ICP-MS) technique. The chemistry of the potsherd samples is generally similar to regolith derived from granitic rocks, which are abundant in the area. Principal component analysis (PCA) was used to reduce the number of variables and model-based cluster analysis was used to find clusters in the PCA scores. Model-based clustering found one major cluster in the data set, which corresponds to the local weathered granitic/pegmatitic raw materials near the sites. Our work shows that the technology for the manufacture of these pavements might have originated from Ile-Ife, but the production was geologically controlled.     

LUSTRE-DECORATED CERAMICS FROM A 15TH TO 16TH CENTURY PRODUCTION IN SEVILLE*

A set of 17 fragments of ceramics have been uncovered on the occasion of excavations of a workshop in Triana near Seville. These ceramics are typical of objects that are not commonly encountered in present collections in spite of intensive production during the 15th–16th centuries. Chemical and mineralogical analyses have been performed using various techniques (X-ray fluorescence and diffraction, SEM, ion beam analyses). The majority of the ceramic sherds represent the diversity of the Seville production; three fragments recovered in the same archaeological context were not locally produced and belong to the production of eastern Spain (Valence area). The ceramic bodies of the Seville sherds are compatible with the use of clays from the Guadalquivir valley. The glaze and the lustre decoration are comparable to those produced in eastern Spain. These conclusions are based on data that represent the production of a single workshop in Seville; the scatter of the data is due to variations in the processing and/or to alterations during the five centuries of burial of the ceramic fragments.     

TIME‐OF‐FLIGHT NEUTRON DIFFRACTION CHARACTERIZATION OF CERAMIC FINDINGS FROM SOUTHERN AND WESTERN SICILY*

We present the results of a study that is part of a wider research programme regarding knowledge of the initial living phases of Sicilian agricultural and pastoral society. Three sets of ceramic samples were analysed through time‐of‐flight neutron diffraction (TOF‐ND) to derive information about the composition of the clay and the manufacturing techniques. The first two sets of sherds came from an excavation in Licata, close to Agrigento, and are composed of findings dated around the third century bc , while the third set was of samples from prehistoric sites located in the northwestern part of Sicily. Measurements were performed to obtain a quantitative identification of the mineralogical composition of the samples in a totally non‐destructive way. Hints about manufacturing techniques and firing temperatures are derived to provide information on provenance and production processes of the objects.