Development and evaluation of geochemical methods for the sourcing of archaeological maize

Strontium (Sr)-isotope values on bone from deer mice pairs from 12 field sites in the Chaco Canyon area, New Mexico, were compared with isotope values of synthetic soil waters from the same fields. The data indicate that mice obtain Sr from near-surface sources and that soil samples collected at depths ranging from 25 to 95 cm contain Sr that is more accessible to the deep roots of maize; thus, synthetic soil solutions provide better data for the sourcing of archaeological maize. However, the Sr-isotope composition of mice may be more valuable in sourcing archaeological remains of animals such as rabbit, turkey, and deer.     

登封南洼2004～2006年二里头文化聚落发掘简报

2004年3月至2006年12月,郑州大学历史学院考古系在郑州市文物考古研究院的配合下对南洼遗址进行了全面的调查、勘探和发掘,清理了大量的二里头时期至金元时期的遗迹,其中二里头文化的遗存最为丰富,有壕沟2条、墓葬13座、灰坑700余座、水井3处、陶窑7座,出土了大量的遗物,其中有较为丰富的白陶遗存.这些对研究二里头文化的聚落形态提供了重要资料.     

IDENTIFICATION OF POST‐DEPOSITIONAL CHEMICAL ALTERATION OF CERAMICS FROM THE NORTH COAST OF PAPUA NEW GUINEA (SANDUAN PROVINCE) BY TIME‐OF‐FLIGHT–LASER ABLATION–INDUCTIVELY COUPLED PLASMA–MASS SPECTROMETRY (TOF–LA–ICP–MS)*

The measured chemical composition of archaeological ceramics can result from a variety of geological, cultural and taphonomic factors. In the present study, we evaluate the likelihood that elevated barium concentrations in ceramics from the archaeological site of Wom/Aiser, located on the northern coast of Papua New Guinea, result from post‐depositional enrichment. Using time‐of‐flight–laser ablation–inductively coupled plasma–mass spectrometry, we mapped chemical compositional profiles across cut sections of ceramic sherds from four archaeological sites, all previously chemically characterized. We identify the formation of pronounced concentration gradients in samples from Wom/Aiser relative to sherds with low barium concentrations, consistent with post‐burial uptake.     

Ethnoarchaeological analysis of Arctic fish processing: chemical characterization of soils on Nelson Island,Alaska

Activity area analysis of archaeological soils using multi-element characterizations can illuminate how subsistence operations are organized and how subsistence behavior has changed over time, and is increasingly common at archaeological sites. However, in many regions it is impossible to examine the elemental signatures in known anthropogenic soil samples in order to compare them with unknown archaeological samples. This ethnoarchaeological study examines the chemical composition of the soils at known fish processing areas in the contemporary community of Tununak on Nelson Island, western Alaska. Using a quadrupole inductively coupled plasma mass spectrometer (Q-ICP-MS), the concentrations of the following elements in the soil extract were recorded in parts per million (ppm): aluminum (Al), barium (Ba), calcium (Ca), iron (Fe), potassium (K), magnesium (Mg), manganese (Mn), sodium (Na), phosphorus (P), strontium (Sr), titanium (Ti), and zinc (Zn). Fish processing area features are elevated in various elements, including sodium, magnesium, phosphorus, potassium, and manganese, and Ba/Sr, Ba/Ca, and Sr/Ca are also useful in distinguishing between fish processing areas and offsite areas.     

Development and application of methods used to source prehistoric Southwestern maize: a review

Archaeological cobs free of mineral contaminants should be used to source the soils in which they were grown. Mineral contaminants often contain much higher concentrations of metals than vegetal materials and can alter a cob’s apparent metal and heavy-isotope content. Cleaning a cob via immersion in an acid solution for more than a few minutes will result in the incongruent and sometimes complete leaching of metals, including strontium (Sr), from the cob. When using ⁸⁷Sr/⁸⁶Sr to determine the location of potential agriculture fields, it is best to either integrate several depth-integrated soil samples or to integrate several vegetation samples from individual fields. Biologically labile Sr in semi-arid Southwestern soils largely originates from eolian source or sources and usually is not derived from underlying bedrock. Existing Sr-isotope data indicate that archaeological cobs from Aztec Ruins came from either the Mesa Verde-McElmo Dome or Totah areas, that Pueblo Bonito and Chetro Ketl cobs, from Chaco Canyon that predate A.D. 1130, probably came from the Rio Chaco corridor, and that cobs from Chaco Canyon, that postdate A.D. 1130, probably came from either the Totah or Zuni areas.     

Provenance of glass shards in archaeological lime plasters by LA-ICP-MS: implications for the ancient routes from the Gulf of Mexico to Teotihuacan in Central Mexico

We present the chemical characteristics of samples collected from the central courtyard of Teopancazco, a neighbourhood centre in Teotihuacan (Mexico), the most important classic Mesoamerican city. The rhyolitic glass shards used as aggregates have a composition comparable to the glass material sourced from the magmatic system of Altotonga (located along the route to the Gulf Coast). People travelling from the Gulf Coast may have transported the glass shards to Teotihuacan during the Xolalpan phase (350–550 AD). However, the reasons for using glass shards as a construction material remain unknown. These new data confirm the close relationship between inhabitants of Teopancazco and the Gulf Coast already revealed by previous archaeological and archaeometric studies.     

ROMAN WINDOW GLASS: A COMPARISON OF FINDINGS FROM THREE DIFFERENT ITALIAN SITES

Thirty‐three samples of window glass and five glass lumps coming from three Italian archaeological sites—the Suasa excavations (Ancona, settled from the third century bc to the fifth to sixth centuries ad ), the Roman town of Mevaniola (Forlì‐Cesena, settled from the Imperial Age up to the fourth century ad ) and Theodoric's Villa of Galeata (Forlì‐Cesena, settled from the sixth century ad onwards)—were analysed to track the changes in the chemical composition and manufacturing technology of window glass through the centuries. The aims of this study were: (1) to establish the origin of the raw materials; (2) to verify the chemical homogeneity among samples coming from different sites and/or produced using different techniques; and (3) to sort the samples into the compositional groups of ancient glass. The analysis of all the chemical variables allowed two groups to be distinguished: (a) finds from Mevaniola and Suasa; and (b) finds from Galeata. All the samples had a silica–soda–lime composition, but the analysis of minor elements—in particular, of Fe, Mn, and Ti—made it possible to split the samples into two groups, with the higher levels of these elements always found in the Galeata samples (HIMT glass). In conclusion, it can be asserted that the main differences between the samples are related to their chronology.     

Distal cryptotephra found in a Viking boathouse: the potential for tephrochronology in reconstructing the Iron Age in Norway

Distal tephra deposits from Icelandic volcanic eruptions have been found in Norway and can be used to precisely date a variety of sedimentary environments. Tephrochronology has not yet been applied to archaeological investigations in Norway because tephra are generally not found as visible layers, but are present as very low concentrations of glass shards (i.e. cryptotephra). In this study, we present results from the analysis of cryptotephras found in an Iron Age boathouse in northern Norway. The boathouse was associated with the chieftain center at Borg on Vestvågøy in the Lofoten Islands. In 2003, a trench was excavated and the stratigraphy of the boathouse was described. Radiocarbon ages from cultural deposits show that it was constructed in the Early Iron Age c. AD 540–660 and the main period of use was at the end of the Iron Age between c. AD 1030 and AD 1270. Volcanic glass shards were isolated from sediment samples collected above and below the cultural deposit representing the main period of use. Electron microprobe analysis of the glass shards showed that the lower sample resembles the AD 860 Layer B tephra and the upper sample resembles tephra erupted from the Hekla volcanic system between AD 1104 and AD 1300. These tephrochronologic dates agree with the radiocarbon-derived dates and possibly further constrain the boathouse’s main period of use to c. AD 1030–1104. Our results demonstrate the value of using tephrochronology for archaeological studies in Norway and the potential for finding cryptotephra from other large explosive volcanic eruptions during the Iron Age.     

Archaeometric study of medieval pottery excavated at Stari (Old) Ras,Serbia

A combined study of a series of polychromatic and monochromatic glazed medieval pottery shards excavated from the archaeological area of Stari (Old) Ras in southern Serbia, including petrographic and chemical analysis, powder X-ray diffraction (PXRD) and Fourier transform infrared (FTIR) spectroscopy, allowed us to clearly distinguish between two groups of ceramics. Ras pottery, made of fine-grained well-cleaned clay and characterised by a rich mineral assemblage, was produced by firing in a temperature range between 800 and 900 °C. Reljina Gradina ceramics were produced at similar temperatures from materials which, with regard to mineralogical and chemical composition, show clear similarity with local clay, suggesting that these samples are of local origin and production. This work is the first systematic archaeometric study of medieval pottery excavated on the territory of Serbia.     

The Compositional study of ceramic samples from tombs dating to the Zhou Dynasty at Xiaoshan,Zhejiang Province (China)

Xiaoshan in Zhejiang Province was an important ceramic production area in ancient China. During recent years, local archaeologists have found a number of mound tombs dating to the Zhou Dynasty and the Spring and Autumn period. Many shards of stamped stoneware and proto‐porcelain have been unearthed from these tombs. In this paper, we report how we collected ceramic shards from tombs and samples from local ancient kilns as reference materials in order to clarify their relationship. We have used the energy‐dispersive X‐ray fluorescence technique to analyse the chemical composition of the ceramic samples. The results indicate that some of the tomb artefacts may be imported from other production areas. We infer that the other tomb samples were produced at local kilns, but due to production process–related compositional differences, there are small differences in chemical composition between different categories of samples.     

The Ben Lawers Historic Landscape Project: Simultaneous Multi-element Analysis of Former Settlement and Arable Soils by X-ray Fluorescence Spectrometry

X-ray fluorescence spectrometry (XRFS) was used in the analysis of A horizon soil samples collected from a former farming settlement and its associated area of infield (i.e. arable) located in the Central Highlands of Scotland. To date, XRFS has not been extensively used in geoarchaeological research, but in our study the simultaneous multi-element capabilities of this instrumental technique allowed the total concentrations of 25 major, minor, and trace elements to be fully quantified with acceptable levels of accuracy and precision. Included within this group of chemical elements are a number (e.g. Ba, Ca, P, Pb, Sr and Zn) that have proved to be of value to archaeological interpretation in earlier investigations undertaken in Scotland. In our preliminary work documented here, significant differences were found between the A horizon soils of former settlement and infield areas for 18 chemical elements. Subjecting the XRFS data—and three other measured variables: soil organic carbon (SOC), pH and A horizon depth—to discriminant analysis indicates that soils of former settlement and arable farming can be effectively classified according to their pH, SOC content and Ca, Cu, Mg, Rb, and Zn concentrations. The inference is that areas of former infield and settlement elsewhere at this study location in the Central Highlands may be able to be identified according to their soil chemical composition and use of discriminant function, even though the surface remains of pre-eighteenth century settlement sites are not readily evident today because they were constructed of perishable materials.     

Three-dimensional (3D) visualisation: the application of terrestrial laser scanning in the investigation of historical Scottish farming townships

Recent developments in digital technologies are heralding significant changes in the way we acquire, visualise and analyse archaeological data. Terrestrial laser scanners can be used to create photo-realistic virtual copies of landscapes, and archaeological features, and offer the potential to improve our understanding of three-dimensional (3D) spatial relationships at study sites. Here we present a methodology for the integration of a high-resolution 3D site model with soil chemical data obtained from an abandoned settlement site located in the Central Highlands of Scotland. At this site, the multi-element concentration in soil, co-visualised within a topographic setting, has an important role to play in elucidating settlement layout and activity. The methods described here are also of significance in archiving sites of archaeological/historical importance where development activities and/or environmental processes may destroy remains, or where access to field sites is restricted.     

Obsidian procurement,least cost path analysis,and social interaction in the Mimbres area of southwestern New Mexico

For over 15 years chemical compositional analyses of obsidian artifacts recovered from archaeological sites in the southwestern United States have been increasingly used to address many research agendas. Despite this increasing interest in obsidian studies, few have attempted to synthesize the ever-growing amount of data generated from the numerous projects being conducted in the southwest. Here, we synthesize and present data for 923 sourced obsidian samples recovered from over 80 archaeological sites in the Mimbres area of southwestern New Mexico. We then use least cost path analysis as a means of investigating procurement patterns as well as networks of social interaction within the region.     

A PILOT STUDY IN NON-CONTACT LASER PHOTOTHERMAL ARCHAEOMETRY OF ANCIENT STATUARY PEDESTAL STONES FROM CYPRUS

Several samples of geological stones from statuary pedestals found in various archaeological sites in Cyprus have been characterized using non-contact laser infrared photothermal radiometry. Thermal diffusivities and effective optical absorption coefficients were calculated using a one-dimensional thermal-wave model. The mean values and standard deviations were tabulated and comparisons were made with lithographic and petrographic studies of the samples. Good correlations were found, thus demonstrating that laser photothermal archaeometry is a promising methodology for the accurate, potentially non-destructive and convenient characterization of the origins of ancient stones in Cyprus and other geological and archaeological sites.     

Baseline bioavailable strontium isotope values for the investigation of residential mobility and resource-acquisition strategies in prehistoric Cambodia

Strontium (Sr) isotope ratios (⁸⁷Sr/⁸⁶Sr) measured in human skeletal material can increase one's understanding of the residential behaviour and resource-acquisition strategies of past populations. The paper maps bioavailable ⁸⁷Sr/⁸⁶Sr variation in 183 plant and soil samples across Cambodia. Bioavailable ⁸⁷Sr/⁸⁶Sr, as measured in plants, differs significantly between four major geological units. The data set will support future investigations of skeletal material from Cambodian archaeological sites. Baseline ⁸⁷Sr/⁸⁶Sr data should be applied judiciously to skeletal populations, and in concert with other lines of evidence, to identify potential geographical outliers rather than to ascribe specific locations from which individuals may have moved.     

Multi-element soil prospection aiding geophysical and archaeological survey on an archaeological site in suburban Sagalassos (SW-Turkey)

In order to take full advantage of the archaeological information contained within buried archaeological sites, it is important to apply an integrative approach combining complementary prospection methods. In this study, geochemical prospection data are combined with archaeological and geophysical survey results on an unexcavated site in suburban Sagalassos (SW-Turkey), with the aim of obtaining better insights into the structural shapes and past functionalities of the area. Spatial and multivariate statistical analyses of the chemical data reveal anomalies of K, P and Zn on a location where archaeological and geophysical results suggest the presence of ceramic producing kilns. These elemental enrichments are thought to result from burning wood or dung as fuel for the detected kilns. In addition, local anomalies of Co, Cr, Fe, Mg, Mn and Ni were found to reflect the working and storage of ophiolitic clays, employed as a raw material for ceramic production. Radiocarbon dating of charcoal in a 2.5 m deep drill core in this zone provides ages between AD 120 and 350 at depths of 50 and 60 cm. Al, As, Ba, Ca, Na, Sr, Ti and Pb are considered geogenic elements in this study. The present study supports the theory that geochemical prospection holds potential as a surveying technique, as it was found that chemical data facilitate the interpretation of structures detected by geophysical and archaeological methods, thereby creating an extra dimension to the interpretation of survey data. The results further argue in favour of using strong-acid extractions and the consideration of a large suite of elements when applying chemical soil survey as an archaeological prospection technique, and highlight the importance of considering site lithology. Multivariate statistics proved to be invaluable in distinguishing anthropogenic from lithological soil patterns.     

THE DISCOVERY OF ANOMALOUSLY HIGH SILVER ABUNDANCES IN POTTERY FROM EARLY ROMAN EXCAVATION CONTEXTS IN JERUSALEM*

This is the first study on the differential distribution and concentrations of silver in ceramics recovered from archaeological excavations. The chemical compositions of 1174 pottery vessels from 38 Roman‐period sites in Israel have been determined. Unusually high and variable abundances of silver were discovered in pottery samples of all vessel types and chemical compositions from four distinct archaeological contexts dating to late first century bce to 70 ce Jerusalem. The large majority of the Jerusalem vessels could be distinguished by their silver abundances from all analysed pottery pieces recovered at rural sites outside Jerusalem, even when the pottery types and chemical compositions, except for silver, of pottery found within and outside Jerusalem were indistinguishable. The evidence is suggestive of a human origin for the high and variable silver abundances, and dispersion of the silver by aqueous transport. The differential silver concentrations found in excavated pottery from Jerusalem and other urban and rural sites suggest that attention to the distribution of silver in pottery from excavated contexts may be helpful for evaluating the nature and function of archaeological remains and patterns of urban contamination.     

Calcium–iron–phosphate features in archaeological sediments: characterization through microfocus synchrotron X-ray scattering analyses

The occurrence of amorphous calcium (Ca)–iron (Fe)–phosphate infilling features in thin-section samples from archaeological stratigraphies is increasingly being reported and used in the cultural interpretations of sites. In some contexts, these materials are the product of dissolution and recrystallization of bone material within pores of the soil or sediment matrix. This study uses transmitted microfocus X-ray scattering to characterize and measure features of known cod fish bone (Gadus morhua) materials, and compare them to archaeological samples of amorphous Ca-Fe-phosphate infilling material found in thin section from early fishing community sites. The analyses characterize the structure of these features for the first time, and allow discussion of the diagenetic processes that lead to their formation.     

The Question of "Why It Is in Henan" and the New Direction of Chinese Scientific and Technological Archaeology

The ritual institutionalization demonstrated in the bronze production at Erlitou and further developed during the Shang and Zhou periods that formed a distinctive feature of bronze civilizations. While exploring the path of the earliest state formation, we could consider why Erlitou was chosen from the unveiling of the Bronze Age in China. Much attention had been paid to archaeological, chronological, geographic, and climatic information in the existing studies, but the relationship between bronze metal resources and the formation of the Erlitou state needed more attention. Viewing the Erlitou culture as the earliest state form in China and thus exploring the path of formation of early states was a return to the original theme of archaeology.     

Chemical Composition and Manufacturing Technology of a Collection of Various Types of Islamic Glazes Excavated from Jordan

A collection of Islamic glazed pottery shards that were excavated from the archaeological site of Dohaleh/Northern Jordan were chemically analysed. The glazes belong to three different decorative styles. The chemical analysis of the glazes was carried out using energy dispersive x-ray fluorescence. The chemical analysis results enable the classification of the glazes into the three distinct compositional groups with reference to their principal modifier, these are: the alkaline glazes, the high lead glazes and the lead–alkali glazes. In some cases the body fabric was analysed by a combination of petrographic and chemical analysis techniques. The study show that inherited traditional techniques were combined with innovative Islamic techniques were used for the production of the glazes.