PETROGRAPHIC AND ISOTOPIC CHARACTERIZATION OF THE MARBLE OF THE ISLAND OF TINOS (GREECE)*

Most outcrops of good‐quality crystalline marble in Mediterranean countries were exploited in Greek and Roman times. Hence, a wide variety of marble is now found in archaeological excavations. The precise determination of the provenance of a marble object is of great archaeological importance, and is now mostly obtained by coupling the petrographic study of a thin section with the analysis of the C and O stable isotopes, or by stereomicroscopy and EPR. The existing databases are considerable but still insufficient, because our knowledge about and study of ancient Mediterranean quarries remain incomplete. The contribution of this research is to add new petrographic and isotopic data on small quarries on the Greek island of Tinos that were exploited in antiquity. This marble belongs to the same geological horizon; it is quite pure, sometimes dolomitic and characterized by a low‐T, high‐P metamorphism that produced a limited recrystallization (MGS varying from 0.64 to 2.50 mm) on marine limestone protoliths. The petrographic features are quite distinctive: the fabric is strongly lineated and often stressed; and the accessory minerals are ubiquitary quartz, ore minerals, graphite and muscovite. As far as the isotopic data are concerned, δ¹³C_PDB varies from 1.1 to 2.7, and δ¹⁸O_PDB from ?1.7 to ?11.4. Both the features and the data have been compared with those of similar marbles used in antiquity, showing that their combination mirrors the fingerprint of the Tinos marble.     

MINERO‐PETROGRAPHIC AND GEOCHEMICAL CHARACTERIZATION OF ‘GRECO SCRITTO’ MARBLE FROM CAP DE GARDE,NEAR HIPPO REGIUS (ANNABA,ALGERIA)*

This work presents the results of the first mineralogical, petrographical and geochemical characterization of the marble quarried from the Cap de Garde headland, not far from Annaba (Algeria). This site is traditionally held by archaeologists to be the main source of supply of the so‐called ‘greco scritto’ marble, which was much used by the Romans for architectural and decorative–ornamental purposes, locally from the first century bc , and in Rome and central and southern Italy from the late Flavian period until the fourth century ad . The databank relating to the quarried material, created here for the first time, is used to establish the origin of ‘greco scritto’ found in six important Roman cities of North Africa: Hippo Regius and Cuicul (Djemila), in Algeria; Volubilis, in Morocco; Cyrene, in Libya; and Carthage and Utica in Tunisia. The results of this archaeometric study support the hypothesis (already put forward by authors) that the ‘greco scritto’used in the Roman Mediterranean originated from different sites, and suggest the existence of a number of North African quarries, also in the vicinity of Annaba.     

Petrographic Characterization and Provenance Determination of the Crystalline Marbles Used in the Roman City of Banasa (Morocco): New Data on the Import of Iberian Marble in Roman North Africa

This paper reports the results of an archaeometric study of the crystalline marbles used in the Roman city of Banasa (Morocco). On‐site surveys allowed a detailed inspection of the monuments of the ancient city and sampling of the different marble lithotypes used for architectural purposes and sculptures. The inventory was completed by the study of both the grey‐and‐white streaked or spotted marble items stored in the warehouse of the archaeological site and of those currently exhibited at the National Archaeological Museum of Rabat. Provenance determination of 28 samples was carried out by means of a multi‐method approach combining mineralogical–petrographic data and C–O stable isotope analyses as the first step, and cathodoluminescence microscopy as a complementary technique to verify possible unusual alternative origins of some marbles. The analytical results obtained were compared with both the most reliable international databases and the few available studies dealing with the use of marble in other Roman towns in Morocco (e.g., Volubilis, Thamusida and Sala‐Chellah). They point to a variety of classical marble sources such as Carrara, Mount Penteli, Paros, Marmara and probably Mount Filfila (Algeria), and prove a significant import of Iberian lithotypes.     

Archaeometric analysis of the ‘greco scritto’ marble slabs from the Edificio dei Triclinii at Murecine (Pompeii,Italy)

This paper presents the results of the archaeometric analysis of the greco scritto marble slabs from the Edificio dei Triclinii, an inn or statio negotiatorum discovered at Murecine in Pompeii’s suburbs in 1999–2000. A total of 14 samples were collected and subjected to standard X-ray diffraction (XRD), optical microscopy (OM) on thin sections and stable isotope ratio analysis (SIRA) to assess the stone’s identity and provenance. The results of this study substantiate the hypothesis (already put forward and based on a macroscopic identification by Perna and Scognamiglio) that the stone originates from the Hasançavuşlar quarries near Ephesus in Asia Minor, and represent the first step towards a systematic contextual and geochemical study of Ephesian greco scritto in Roman contexts and its respective contribution to the Roman stone trade.     

White and Coloured Marbles of the Roman Town of Urbs Salvia (Urbisaglia,Macerata, Marche,Italy)

The results of an archaeometric study concerning the coloured stones and 14 white marble sculptures found in the ancient city of Urbs Salvia (Urbisaglia, Macerata) – one of the main Roman archaeological sites of the Marche region (east central Italy) – are presented here. Data show the presence of the most important decorative stones used by the Romans, originating in all of the Mediterranean provinces, from Egypt and North Africa to Asia Minor, Greece, Gallia, Iberia and Italy. Thirty‐one different coloured lithotypes have been identified, including red and green porphyries as well as marmor phrygium and numidicum, namely the four most expensive stones cited in Diocletian's edict. Crustae of marmor chium, taenarium, chalcidicum, scyreticum, lucullaeum and sagarium also feature. Another significant presence is that of coloured stones that are generally rare, even in Rome and Ostia, such as cipollino mandolato (which is very abundant at Urbs Salvia, more than anywhere outside Gallia), broccatello di Spagna, alabastro a pecorella, lapis ophytes, brecciated facies of marmor iassene and cottanello antico. Worthy of mention, too, is the abundant presence of so‐called Roman breccia from Lez (Upper Garonne valley, French Pyrenees), a stone never reported outside Gallia. The 14 marble sculptures analysed come from public and private buildings of the Roman city and are now exhibited at the Archaeological Museum of Urbisaglia. Our petrographic and isotopic analyses show that they are made of Lunense (five), Pentelic (three), Parian lychnites (three), Thasian (three) and Proconnesian (one Corinthian capital) marbles. The quality of the coloured stones identified, together with the presence of sculptures made of precious imported white marble varieties, reveals an opulent town and a local patronage wishing to decorate public buildings and rich houses with the most sought‐after marbles of Rome.     

PROVENANCE STUDY OF MARBLE ARTEFACTS FROM THE ROMAN BURIAL AREA OF FASCHENDORF (CARINTHIA,AUSTRIA)*

Numerous marble artefacts were among the extraordinary findings excavated at the Roman burial area of Faschendorf (Carinthia, Austria). The provenance of marble objects, particularly in the Roman provinces, is mostly unclear. Predominantly Mediterranean marbles have been used, but there are also some marble occurrences in the eastern Alpine regions that were exploited in those times. Besides a mineralogical–petrographic analysis, grain‐size evaluation in particular, and the determination of carbon and oxygen isotopes allow an effective characterization of the Faschendorf materials. Their provenance from the Gummern Marble complex in Carinthia is very likely.     

CARBON AND OXYGEN ISOTOPIC RATIOS: A DATA BASE FOR CLASSICAL GREEK AND ROMAN MARBLE

An isotopic data base of δ¹³C and δ¹⁸O analyses of 528 samples collected from 39 classical Greek and Roman quarries of Turkey, Greece, Italy and Tunisia has been accumulated. The discriminative possibilities of the data base vary from quarry to quarry. Most quarries have a distinctive pattern for either or both variables, but some have more than one grouping. The data also overlap for many quarries preventing a unique provenance assignment. If the alternatives are known so that the total pool of possible sources is reduced, the data base can then discriminate and assign a provenance for most classical marble artifacts.     

WHITE,VEINED MARBLE FROM ROMAN AMMAIA (PORTUGAL): PROVENANCE AND USE

A multimethod approach using petrography and strontium (Sr) isotopic analysis was applied to determine the geological source of 17 marble artefacts from the Roman town of Ammaia (Portugal). All samples are calcitic, with dolomite, quartz and muscovite as accessory minerals. The marbles are characteristically medium‐grained with a maximum grain size (MGS) between 0.98 mm and 1.82 mm, have a heteroblastic texture, and have curved to embayed calcite grain boundaries. ⁸⁷Sr/⁸⁶Sr values of marble leachates range from 0.708488 to 0.708639. Comparison with Hispanic and Mediterranean marbles suggests the Estremoz Anticline as the most likely source for the Ammaia marble, especially for architectural marble. This hypothesis is supported by the geographical proximity of the Estremoz marble district and the long and expensive overland transport required for other marbles to reach Ammaia.     

AN EPR AND ISOTOPIC STUDY OF THE MARBLES OF THE TRAJAN's ARCH AT ANCONA: AN EXAMPLE OF ALLEGED HYMETTIAN PROVENANCE*

The provenance of 20 marble samples drawn from the Trajan's arch at Ancona, which is supposed to be made of Greek, Hymettian marble, has been established on the basis of the independent use of EPR and isotopic data. The results of the two methods are in good agreement and unequivocally indicate a Proconnesian provenance. Sixteen samples are assigned to this site, whereas two are classified as untypical Proconnesian samples and the remaining two are assigned an unlikely Parian provenance. No indication exists for a possible Hymettian origin of the marbles. A multi‐method approach, which employs all of the experimental variables simultaneously, demonstrates that the 18 samples identified as Proconnesian belong to several different quarrying areas within the site. This result is taken as an indication that the Proconnesian quarries were run following a highly organized, semi‐industrial production model. The origin of the Hymettian/Proconnesian misunderstanding and the possible misclassification of other Roman monuments in Italy are briefly commented on.     

SCIENTIFIC CHARACTERIZATION OF THE POHORJE MARBLES,SLOVENIA

As a former part of the great Roman Empire, Slovenia has many archaeological sites featuring buildings and objects entirely or partly constructed from marble whose provenance is doubtful. In Slovenia, the most probable source of such marble is the Pohorje Mountains. For the purpose of supporting further provenance studies, these marbles are fully scientifically characterized. The techniques used are petrographic and geochemical analysis, stable isotope ratio analysis and EPR spectroscopy. The results show that the Pohorje marbles are highly heterogeneous in both their isotopic and geochemical parameters as well as grain sizes. The parameters of the different Pohorje marble outcrops are compared between themselves and with the parameters of known ancient quarries in the Mediterranean and Austria. The use of a multi‐technique approach with combined parameters allows the best possible discrimination.     

THE PROPERTIES AND IDENTIFICATION OF MARBLE FROM PROCONNESOS (MARMARA ISLAND,TURKEY): A NEW DATABASE INCLUDING ISOTOPIC,EPR AND PETROGRAPHIC DATA*

This paper reports an updated and enlarged archaeometric database of Proconnesos marbles with the aim of attaining more reliable inter‐ and intra‐site identification. Quarry and artefact samples (n = 397) from 23 different quarrying areas were characterized using petrographic, isotopic and EPR results. The most distinct property of Proconnesos marbles is their extremely weak EPR intensity, associated with the low concentration of Mn²⁺impurities. This feature, supported by the contribution of other important isotopic and petrographic variables, forms the basis for the correct identification of Proconnesos marbles. Within the site the distribution of properties is relatively homogeneous; only limited intra‐site discrimination is possible. All the experimental results, as well as the quarry samples are made available to other researchers willing to measure additional experimental properties, thus increasing the rate of within the site discrimination. Extensive survey has proved that, although about 10% of the samples exhibit maximum grain size below 1.0 mm, no locations exist where fine grained marbles could be intentionally quarried. The historical aspects of Proconnesos marble quarrying and usage are also discussed.     

New data of 87Sr/86Sr ratio in classical marble: an initial database for marble provenance determination

⁸⁷Sr/⁸⁶Sr ratios are presented for white marbles collected from some of the most famous classical quarry areas of the Mediterranean: Carrara, Paros, Naxos, Pentelikon, Dokimeion, Hymettus, Thasos, and Proconnesus. These ratios range from 0.7071 to 0.7092. The ranges of the different quarry areas are notably superimposed; this prevents a common adoption of this parameter in distinguishing the quarry locations for the classification of the provenance of marbles used during classical times for architectural and sculptural artefacts. However some quarry areas show peculiar distributions of their isotopic values, which could help to assign the provenance to an unknown marble artefact.Adding these new data to the scarce number of strontium isotopic compositions measured on white marbles and available in the relevant literature, permits the creation of an initial database of 11 classical quarry locations. This database confirms that the strontium isotope ratio could be used in marble provenance determination, together with petrographic and geochemical methods, as an ancillary technique.     

A Multi‐Method Database of the Black and White Marbles of Göktepe (Aphrodisias), Including Isotopic,EPR, Trace and Petrographic Data

A database of the ancient marbles of Göktepe near Aphrodisias is reported, and includes 160 white, black and bichrome samples from 13 quarries and two waste deposits. The quarries are grouped into four districts. Districts 1 and 2, to the north, produced exclusively black or dark grey marbles (nero antico). Districts 3 and 4 produced white statuary marble. Nero antico and a black and white stone were also quarried in district 4, where the black marble surfaces again. The samples were characterized using petrography, isotopic analysis, EPR spectroscopy and trace analysis. The Göktepe white exhibits an unparalleled combination of fine grain, low EPR intensity and high strontium concentration that often allows easy identification. The isotopic values are less distinctive and similar to those for Carrara. In most cases, however, they are tightly grouped and also quite indicative. The black marbles exhibit a much weaker metamorphic overprint. With respect to the white marbles, they show analytical similarities but also notable differences. Therefore, establishing their provenance can be more difficult and may require the support of petrographic analysis. The results suggest that the Göktepe marbles were among the most prized and widespread statuary marbles used in Roman times, particularly from the early second century ad onwards.     

The use of white marbles for sculpture in Roman Gortyn (Crete) as revealed by archaeometric analyses

Gortyn was an important Cretan town from the late Archaic to the Hellenistic period and then became one of the provincial capitals of the Roman Empire. It controlled the whole of Crete and Cyrenaica and was a flourishing centre of trade and agricultural products in the first centuries of our era. In more than 100 years, many portions of the Greek and Roman town were unearthed under the supervision of the Italian Archaeological School of Athens and a considerable number of stone artefacts found, many of them made of imported marble since the local variety was grey and of poor quality. Statuary and other prestigious marble sculpted artefacts found in Gortyn were sampled and subjected to archaeometric examination (by way of optical microscopy in thin section, powder X-Ray diffraction and mass spectometry for the determination of the C and O isotopic ratio) in order to identify the quarries they came from. The results obtained from the analysis of several dozen white marble objects have indicated the use of a quite wide variety of species including Parian (from Lakkoi), Pentelic, Thasian (dolomitic and calcitic) and (occasionally) Proconnesian marbles. The first three, especially Pentelic, were used for most of the statuary.     

The Asiatic marbles of the Hadrian's Villa at Tivoli

Multi-method provenance studies, including petrographic, isotopic, electron paramagnetic resonance and trace chemical analyses, have been carried out on 20 white, 9 black and 1 red artifacts purposely selected to investigate the use and distribution of sculptural marbles at the Hadrian's Villa. A large fraction of the marbles tested (21 samples, 70%) are shown to be from Asia Minor, mostly originating from the recently discovered site of Göktepe near Aphrodisias (15 or 71%). All the 9 black samples investigated and 6 out of 11 white Asiatic marbles are from Göktepe, the remaining being Docimium marble from Iscehisar (4 samples) and Aphrodisias marble from the city quarries (1 sample). The single red sculpture tested proved to be Carian red marble from the Iasos quarries, whereas non-Asiatic marbles include 3 Carrara and 6 Pentelicon samples. The selection of marbles tested is preliminary and incomplete, but, despite this, the results are noteworthy, especially since the marble of other sculptures from the Villa has already been identified as Göktepe. Together with other published results, the marble distribution at the Hadrian's Villa seems to suggest that the use of sculptural marbles in the Roman world underwent considerable changes around the turn of the 1st and the 2nd century AD. The evidence supporting this hypothesis is briefly summarized in the conclusions.     

AN UPDATED,MULTI‐METHOD DATABASE OF EPHESOS MARBLES,INCLUDING WHITE,GRECO SCRITTO AND BIGIO VARIETIES*

An updated database of Ephesos marbles including 244 samples from 16 quarrying districts is reported. The unknown Greco Scritto quarries near Hasançavuslar and the Bigio marbles from the quarries of Belevi and of Mt Panayir are also presented. The paper, however, is mostly devoted to the identification of the Ephesos white marbles, whereas the problems posed by the Bigio and Greco Scritto varieties are deferred to future work. The samples have been characterized by isotopic analysis, EPR spectroscopy and additional petrographic and optical properties. Owing to the complex geology of the region, the white marbles of Ephesos exhibit rather inhomogeneous properties and are conveniently classified into four marble groups, which can be almost completely discriminated. The problem of distinguishing the Ephesos white marbles from other similar varieties has been dealt with by statistically comparing the Ephesos samples with all the similar, medium‐grained varieties present in the marble database. Although some of the four Ephesos groups can be reliably identified, general solution of the discriminant problem is difficult. Historical archaeological information is needed to reduce the complexity of the problem by eliminating unlikely provenances. In this way relevant problems, such as the discrimination between Ephesos and Proconnesos marbles, can be solved.     

ACCESSORY MINERALS AS TRACERS IN THE PROVENANCING OF ARCHAEOLOGICAL MARBLES,USED IN COMBINATION WITH ISOTOPIC AND PETROGRAPHIC DATA*

Thirty‐eight archaeological marbles (Roman and medieval) from Modena and Reggio Emilia (northern Italy) were provenanced using the accessory minerals as tracers and the results were compared with those inferred for the same artefacts using isotope composition and MGS (maximum grain size of calcite grains). The number of inferred possible sources is generally lower when using the mineralogical method, which therefore seems to be suited to marble provenancing.     

CARBON AND OXYGEN ISOTOPE RATIOS OF MARBLES FROM SOME ANCIENT QUARRIES OF WESTERN ANATOLIA AND THEIR ARCHAEOLOGICAL SIGNIFICANCE

¹³C/¹²C and ¹⁸O/¹⁶O ratios have been measured for 42 marbles from the main quarry localities of archaeological interest of Western Anatolia (Marmara, Ephesos, Aphrodisias, Denizli and Afyon) in order to test the possibility of isotopically characterizing ancient marbles from this region. The various groups of samples are not clearly distinguishable on a δ¹³C-δ¹⁸O diagram. However, if only white or slightly coloured samples are considered, the isotopic method appears to be much more selective.     

GREEN THESSALIAN STONE: THE BYZANTINE QUARRIES AND THE USE OF A UNIQUE ARCHITECTURAL MATERIAL FROM THE LARISA AREA,GREECE. PETROGRAPHIC AND GEOCHEMICAL CHARACTERIZATION

The quarries of ‘green Thessalian stone’ provide important information about the use of materials and the application of technology in late antiquity. This stone was used for decorative purposes in Imperial Rome and especially in Byzantium. Sarcophagi, column shafts, facing slabs, tubs, ambones, iconostaseis and baptismal fonts are still found in places stretching from Syria to Britain and from Tunisia to Germany, as well as Rome, Constantinople and Thessaloniki. There are two important areas of quarrying at the Chasanbali Hill in the Larisa area of central Greece. At the southern site, quarrying operations took place mainly in late Roman times, whereas the northern quarrying zone provided mostly raw materials for making pillars and other architectural pieces during the Byzantine period. Green Thessalian stone is composed of an ophicalcite, a mosaic of green serpentinite and white marble fragments. Mineralogically, the Larisa ophicalcite consists largely of serpentine, calcite, magnetite, haematite and chromite. Chemical analyses reveal a high quantity of CaO (26.39 to 31.00 wt%), while Cr varies between 940 and 1430 ppm. C and O isotopic compositions of the marble inclusions show δ¹³C values ranging from +3.12 to +3.31 ‰ and δ¹⁸O values from ?12.98 to ?13.11 ‰.