The use of reflectance values for the interpretation of natural and anthropogenic charcoal assemblages

Charcoal assemblages occur in both natural and archaeological settings. Cell wall reflectance values of charcoal in polished blocks under oil provide a proxy for temperature of formation. This paper aims to (1) determine whether wildfire charcoals and anthropological charcoals from various pyrotechnical activities can be distinguished using reflectance data and (2) establish if re-charring (i.e. use of charcoal fuel) can be recognised in the archaeological record through analysis of laboratory-produced re-charred charcoals and charcoals from an experimental iron smelt and traditional bronze casting which utilised charcoal fuel. Reflectance frequency data from assemblages representing burning of charcoal, in this case of iron smelting and bronze casting, indicates temperatures from above the mean value of charcoal production (>475°C) up to the maximum temperature reached in the subsequent process (i.e. >475 to >1,100°C). In contrast, wildfire charcoals showed a range of values including material with barely measurable reflectance (minimum values from 0.06% to 0.56%Ro) to maximum reflectance values varying from 1.65%Ro (Tilford) to 3.8%Ro (Zacca). The mean wildfire reflectance indicated temperatures in the range 325–400°C, which can therefore clearly be distinguished from that of the charcoal burning processes. The laboratory-produced re-charred charcoals take on the reflectance value of the highest temperatures experienced; reflectance values were not constrained by the original temperature of formation. High temperatures are most easily achievable by the burning of charcoal fuel, and hence high reflectance charcoals are likely to represent re-charred charcoal. Therefore, this quantitative reflectance method can be used in archaeology to determine the minimum temperature of formation of charcoals in anthropological processes which involve fire, can indicate the likelihood of use of charcoal or wood as fuel and can distinguish between an assemblage of high temperature anthropogenic charcoals and charcoals formed from natural wildfire.     

Archaeological and chemical evidence for the earliest American use of raw coal as a fuel in ironmaking

The archaeological discovery of bituminous coal in the tipple area and the subsequent analyses of specimens of the iron ore, charcoal, limestone, slag, and cast iron from the Eaton (Hopewell) blast furnace built in 1802 indicate that raw coal was used in combination with charcoal as a fuel in American iron smelting at least thirty years before it was used alone. Further, its use in this combinatory manner marks the earliest as yet attested to in the New World.     

鲁山望城岗冶铁遗址出土燃料鉴定与研究

鲁山县望城岗冶铁遗址出土的12块木炭都是栎属,其中槲栎组占比较高,麻栎组次之。表明当时的人们有意选择燃烧热值高、火力强大、燃烧持久的优质栎木作为冶铁燃料。通过对木炭样品的观察,发现58%有明显的材表,木炭样品的年轮数大于或等于10轮,直径在5.2厘米或以上,认为古人对采集冶铁燃料可能有规定。     

Tom Licence,What the Victorians Threw Away. Oxford: Oxbow Books, 2015. 108 pp., 90 illus. £9.99. isbn 9781782979756

Abstract

Beehive coke ovens in Derbyshire were used to provide fuel for local blast furnaces, for the Sheffield crucible steel industry and for railway locomotive fuel. Members of the Industrial Archaeology Section of Derbyshire Archaeological Society have made a careful survey of four ranges of beehive coke ovens at Ramshaw, near Unstone, formerly the site of Ramshaw Colliery.     

Casting the Riace Bronzes: Modern Assumptions and Ancient Facts

This article argues that classical archaeologists have seriously underestimated the output of heat required to melt a large quantity of bronze and therefore have wrongly reconstructed the ancient casting process. The idea that sufficient metal for casting a bronze of monumental proportions could be heated in a crucible with a charcoal fire ventilated by bellows is not realistic. The following observations are based on solid foundry experience: Nigel Konstam, a bronze sculptor, for many years supervised the casting of monumental bronzes comparable in size to those from Riace. This article has been written by Herbert Hoffmann drawing on Konstam's notes     

Charcoal analysis of industrial fuelwood from medieval and early modern iron-working sites in Bilsdale and Rievaulx,North Yorkshire,UK: evidence for species selection and woodland management

Abstract

This paper presents the results of species diversity and dendrological analyses of archaeological charcoal excavated from medieval and early modern iron production sites in Bilsdale, and at Rievaulx in the neighbouring valley of Ryedale, North Yorkshire, UK. Standard methods of quantification are used to assess species diversity, sampling sufficiency and taxa presence. The assessment of dendrological features provides additional evidence for growth trends and cutting cycles analogous with cyclical woodland management, as well as environmental and growing conditions. Analysis of archaeological charcoal from four medieval bloomery furnace sites in Bilsdale, and from the site of the hammersmithy and blast furnace at the early modern iron works at Rievaulx, provide comparable data-sets which indicate a change in cutting practise and dominant species selection for industrial fuelwood occurred between the 12th- and mid-16th centuries AD. Results show that dominant species presence changed from an admixture of predominantly birch (Betula sp.) and hazel (Corylus avellana) sourced from small calibre branchwood and stemwood used in the medieval bloomery furnaces, to a dominant oak (Quercus sp.) presence from standard sources used at the Rievaulx iron works by the mid-16th century. Whilst it is uncertain whether this change in dominant species composition and the source of industrial fuelwood is related to changes in local availability, or the result of the technological transition to blast furnace processing which occurred at this time, estate records reveal a woodland management campaign was instigated to supply and maintain fuelwood supplies to the iron works at Rievaulx which coincides with the introduction of Tudor arboricultural legislation in the 1540s.     

The Iron and Steel Industry of the Lipetsk Industrial Node

The Lipetsk iron and steel industry, in existence since 1899, began a major expansion program in the middle 1950's, designed to make it one of the principal steel producers of the Soviet Union. The status of the expansion program as of 1969–70 is analyzed in detail, including a rundown of ore, flux and coke sources. The use of sintered ore from near-by deposits of the Kursk Magnetic Anomaly, high-temperature oxygen-enriched air blasts in the blast furnaces, large-capacity blast furnaces and steelmaking oxygen converters are expected to reduce the costs of production below existing levels in the Soviet iron and steel industry and to foster an efficient operation based on modern, automated equipment. (See also Shabad, Basic Industrial Resources of the USSR, pp. 98–101; maps, pp. 40, 96; News Notes, Soviet Geography, February 1970, p. 143; June 1972, pp. 409–410; June 1973, p. 407.)     

Identifying archaeological wood stack charcoal production sites using geophysical prospection: magnetic characteristics from a modern wood stack charcoal burn site

Charcoal making was a common process in the woodlands of Britain for many centuries. However, historic ‘wood stack’ production sites are difficult to identify. This paper tests the hypothesis that geophysical survey is an appropriate method for the discovery and identification of archaeological charcoal making sites. A traditional wood stack charcoal kiln was constructed in Low Staindale, Dalby Forest, near Pickering, North Yorkshire, to investigate the charcoaling process and the effect of low-temperature carbonisation on the magnetic properties of the soil underlying the kiln. The results from temperature monitoring (within and beneath the charcoal stack) throughout the charcoaling process, geophysical surveys across the charcoal kiln platform, and laboratory analysis of soil and ash samples, are presented. The degree to which the magnetic properties of the ground beneath the charcoal kiln had been enhanced as a consequence of this low-temperature process is discussed. Whilst some magnetic enhancement to the soil beneath the kiln platform was recorded, enhancement appears to be the result of contamination from the wood stack sealing material rather than the effect of heat transfer resulting from the charcoaling process. The results suggest that whilst historic wood stack charcoal production sites are likely to remain an enigmatic and under-reported feature in the archaeological landscape, geophysical prospection does have the potential for identification of these sites.     

A gun-casting furnace at Scarlets,Cowden, Kent

Abstract

A timber-lined casting pit was installed between 1590 and 1664 at the blast furnace at Scarlets, Cowden, Kent. The methods of construction are similar to those used at Maynards Gate and Pippingford, Sussex. The adjacent floor is a feature paralleled at Pippingford and at Rockley, Yorkshire. The furnace has been thoroughly robbed of its stone, but its position and orientation can be satisfactorily established; evidence was found for refurbishing at the end of the 17th century, yet it seems likely that abandonment came before 1717.     

The use of wood in funerary pyres: random gathering or special selection of species? Case study of three necropolises from Poland

In this study, the analysis of charcoal remains from three prehistoric necropolises is presented. This botanical material formed part of funerary pyres and thus represents purposely gathered wood used for cremation ceremonies. Therefore, its anthracological analysis may indicate a special selection of wood, which may be a source of palaeoethnographic information about past rituals. However, a question remains as to whether or not the charcoal assemblages that originated from graves may also provide some palaeoecological information. In order to test both hypotheses, analysis of three Polish necropolises dating to the Bronze and the Iron Age were performed. In all charcoal assemblages, a taxonomic diversity among charcoals was detected, which may suggest that the wood was collected based on availability. This may also be inferred after observing that the presence of the most ubiquitous and frequently found taxa may be strongly correlated with present-day vegetation growing in the vicinity of the necropolises.     

山西阳城犁镜传统生产工艺调查

介绍了阳城犁镜的源流、现状及生产工艺,并对犁镜的材质进行了分析。阳城犁镜的生产沿用木炭竖炉炼铁、铁范铸造等古代生铁冶铸技术,是一项实用的优良传统生产工艺。     

Dating Ancient Burial Mounds in Denmark – Revealing Problematic Ancient Charcoal

The National Museum of Denmark and the Department of Geography at the University of Copenhagen have collaborated on a project investigating burial mounds near early Medieval churches. The aim was to identify a possible continuity in cult sites across the shift to Christianity in the late Viking Age. Charcoal samples from 18 mounds were radiocarbon dated but the results showed they were far older than expected. Control dating undertaken on burial mounds of known age confirmed that charcoal in the mound fill can at least be up to 3000 years older than the mound itself. As charcoal can survive in the surface soil layer for millennia, in spite of ploughing, bioturbation and frost, it may also dominate the charcoal pool of the grass or heather turfs used in the mound construction. Therefore, the article concludes, charcoal cannot be used to securely date archaeological features built with turfs and it is important to be aware of the possible presence of very old charcoal when selecting material for dating archaeological features, even those which otherwise would be judged unaffected by material from earlier archaeological periods.     

A survey of the charcoal-fuelled ironworking industries of Carmarthenshire and Pembrokeshire

Abstract

A project carried out in 2001 recorded the most important surviving remains of charcoal-fuelled blast furnaces and forges in Carmarthenshire and Pembrokeshire, and reviewed the documentary evidence relating to them. The earliest sites date to the end of the 16th and the early 17th century. The furnaces at Ponthenri (Carmarthenshire) and Blackpool (Pembrokeshire) and the forges at Llandyfan (Carmarthenshire) were surveyed. One furnace site (either Ponthenri or Pontiets) may retain below-ground evidence for experiments in coke smelting by Hugh Grundy in 1620, giving it considerable national importance. These monuments are little known; attention is drawn to their steadily deteriorating condition.     

Selective woodland exploitation for charcoal production. A detailed analysis of charcoal kiln remains (ca. 1300–1900 AD) from Zoersel (northern Belgium)

A detailed study of charcoal burning activities has been made for the Zoersel forest (Northern Belgium) based on an inventory of charcoal kiln remains, the analyses of wood charcoal and other charred botanical macroremains and radiocarbon dating of 10 of these kilns. Age determination of the youngest kilns was refined by dendrochronological analysis of trees growing on top of these kiln sites. The results show that, although many kilns were found, charcoal was produced in Zoersel only at certain moments during late and post-medieval times suggesting that charcoal burning was not a part of the regular management practice of these forests. The wood used for the production of charcoal mainly consists of taxa of alluvial (alder) forests while the kilns are situated on sites that currently are rather dry, with an oak dominated vegetation. For the older kilns, this contrast could be explained by an important change in local soil conditions. The younger kilns may be related to the conversion of alder woodland to grassland in the lower parts of the domain, with the kilns being constructed in the nearby dryer woodland areas.     

Ashes to ashes, charcoal to dust: micromorphological evidence for ash-induced disintegration of charcoal in Early Neolithic (LBK) soil features in Elsloo (The Netherlands)

Charcoal and other forms of charred organic material - an important part of the archaeological record - consist of benzenoids. Such components are unstable in basic or alkaline conditions. Since ashes are alkaline, this means that archaeological charcoal may have been disintegrated and lost if they were buried together with ashes, e.g. as in fireplaces. Ash may also cause clay translocation in decalcified loess because of the disaggregating effect of K⁺ ions in the soil solutions. We investigated the interplay of these two processes, using micromorphological samples from the Early Neolithic site at the Joannes Riviusstraat in Elsloo. Evidence for charcoal disintegration was found in the form of cavities in charcoal fragments, most commonly filled in with thick reddish limpid clay coatings. The combination of cavities and clay coatings are evidence for the disintegration of charcoal under the influence of ash. Ash may also have been instrumental in preserving small bone fragments in these decalcified well-drained loess soils. The evidence of ash-induced charcoal disintegration implies that charcoal preservation in the archaeological record is dependent on (1) whether or not is was buried alongside with ashes, and (2) on various soil characteristics that determine that determine how quickly the ash-derived alkalinity and potassium ions are leached.     

X-ray microtomographic imaging of charcoal

We assess the potential of X-ray microtomography as a tool for the non-destructive, three-dimensional examination of the internal structure of charcoal. Microtomographic analysis of a series of charcoals produced by the experimental pyrolysis of pine wood at temperatures from 300 and 600 °C in nitrogen only and in nitrogen mixed with 2% oxygen indicates that, despite substantial shrinkage, observed porosity, pore size and pore connectivity are all increased by pyrolysis and also by chemical oxidation. Analysis of a number of altered and unaltered archaeological and geological charcoals has demonstrated the capacity of the technique to identify and map the distribution of authigenic mineral contamination within charcoal fragments. The results are of significance to radiocarbon dating in that they provide insights into the mechanisms by which charcoal can be contaminated by extraneous carbon in the natural environment.     

Charcoal in alluvium of mountain streams in the Bieszczady Mountains (Polish Carpathians) as a carrier of information on the local palaeoenvironment

Fragments of charcoal are present in floodplain alluvium of the San and Strwi?? rivers in the Polish part of the Bieszczady Mountains, Polish East Carpathians. They occur as single clasts or in lenses in the basal part of fine-grained alluvium, together with unburnt wood debris, or in the middle part of the vertical sequence of the floodplain alluvium. 14 samples of charcoal from the upper courses of the San (ca. 50 km) and the Strwi?? (ca. 10 km) were dated with radiocarbon. The obtained dates fall mainly in the 15^th through 19^th century interval; only one sample is markedly older (9^th–10^th century). Taxonomic composition of the charcoal source wood was also studied and compared with that of coeval forests. Correlation of the charcoal age with the history of economic development of the studied region indicates that charcoal is of anthropogenic origin: older charcoal from intense slash-and-burn deforestation, while younger charcoal was produced by local industries.     

Quantifying woodland resource usage and selection from Neolithic to post Mediaeval times in the Irish Midlands

The antiquity and context (site or feature type) are the two principal factors that act as a framework for interpreting charcoal and wood data from archaeological sites in the recreation of past woodland environments. This research addresses these parameters through the analysis of over 18,000 charcoal fragments from 57 archaeological excavations carried out along a 61?km road scheme in the midland region of Ireland. Observations on spatial vegetation dynamics and woodland resource patterns are also reported on. The data were analysed through percentage frequency and multivariate analyses. The results reveal woodland resource usage in terms of wood types selected for use as fuel or as structural wood as well as patterns of change and variability in taxonomic composition in relation to site types, feature types and time periods. Selection was found to be low in prehistoric times and in particular at burnt mound sites/fulachta fiadh but became increasingly important as time progressed. This has important implications when charcoal from archaeological settings is used in environmental reconstructions.     

Combining pollen and charcoal: evaluating Holocene vegetation composition and dynamics

Pollen analysis reveals vegetation change on a local and regional level over (ideally) continuous time spans but with complications when it comes to the reconstruction of spatially precise species occurrence and composition. Wood charcoal analysis provides site-related information on species occurrence and woodland composition, especially when sediments containing pollen are lacking, but is normally discontinuously available and has the danger of human bias due to potential selection of certain species for e.g. fire making, house construction or charcoal making. Combining the two methods – assuming that suitable palaeoarchives are neighbouring – might compensate for their disadvantages and strengthen the interpretations on vegetation composition and dynamics on a local, extra-local and regional scale. Three examples are given where pollen analysis from “classical” archives – mires and lake sediments – was carried out, and where additionally species identification of wood charcoals was done on samples extracted from close-by archives. The first example (Kugelstattmoos, Bavarian Forest, Germany) combines a Holocene pollen diagram derived from a small mire with late medieval/early modern times charcoal spectra from charcoal production sites which are situated on the margin of the mire. Results show the local occurrence of the main woodland species Fagus sylvatica and Abies alba, and raises new questions on the montane species composition of the formerly natural forests in the Bavarian Forest. The second example (Bargstedter Moor, Schleswig-Holstein, Germany) combines Holocene pollen diagrams from a peat bog with late medieval/early modern times charcoal spectra from charcoal production sites in a woodland close to the bog. It shows the role of Quercus, Fagus, Alnus and Carpinus in medieval and early modern times woodlands and its use by man. The third example (Kleiner Tornowsee, Brandenburg, Germany) combines pollen data from sediments of a small lake with charcoal data derived from Holocene colluvisols and soils. The examples show that anthracological and palynological data complement one another to create a more detailed picture of woodland history and landscape change than one method alone would provide.