Ceramic production in ancient Nasca: provenance analysis of pottery from the Early Nasca and Tiza cultures through INAA

We report the results of an instrumental neutron activation analysis (INAA) undertaken on a regional sample of pottery from the Southern Nasca Region. The samples included specimens primarily from the Early Nasca (ca. A.D. 1–450) and Tiza (ca. A.D. 1000–1476) cultures from a total of 16 different prehispanic sites. The results of the analysis demonstrate centralized production of Early Nasca polychromes and decentralized production of pottery from the Tiza culture. The results of this analysis confirm previous conclusions about the organization of these two indigenous cultures of the south coast of Peru and support the hypothesis of an excess production of polychromes at the ceremonial center Cahuachi for Early Nasca, and multiple centers of production for the Tiza culture.     

浅析贵州民间砂器工艺特点与重要历史价值

贵州砂器工艺是一项非常有特色的民间传统工艺,它所蕴含的古代文化信息十分丰富。通过对贵州民间砂器制作工艺中成型技术、烧制与鼓风方式等与新石器时代制陶工艺的比较,可看出其基本原理及一些重要工序或器械都直接继承了新石器时代的制陶工艺,或者在原始工艺基础上进行了改进。其中包括一些发明创造体现了山区劳动人民的聪明智慧,反映了人类在生存斗争中的创造能力。贵州砂器工艺的历史价值不可低估,值得保护和研究。     

The forest or the trees? Behavioral and methodological considerations for geochemical characterization of heavily-tempered ceramic pastes using NAA and LA-ICP-MS

In this paper, the utility of LA-ICP-MS for instrumentally separating clay and temper within pottery samples is examined through a well-known case study that has been previously characterized through NAA and petrography. Coarse Orange pottery is composed of kaolinitic clays heavily tempered within volcanic ash from the basalt-rich Tuxtla Mountains of southern Veracruz, Mexico. We attempt to address the following topics with analyses on this pottery: 1) can LA-ICP-MS replicate the same groups previously identified by NAA and petrography; 2) can instrumental isolation of the clay fraction within the pottery replicate known patterns in raw clay source geochemistry in the Tuxtla Mountains; 3) can data for both the clay and volcanic ash fractions of each pottery sherd be combined to simulate the bulk INAA data? The results demonstrate that the clay fraction of the pottery sherds can be isolated. Furthermore, the LA-ICP-MS data for the clay fractions display nearly identical chemistry to available NAA data for raw clay samples collected from geological contexts in the region. Instrumentally isolating the clay fraction in this case eliminates the homogenizing effects of adding a common temper and increases the chemical separation among groups making it easier to identify clay procurement strategies for each specimen. However, focusing only on the clay fraction ignores significant tempering variation. Attempts to simulate the bulk NAA by combining LA-ICP-MS data for clays and temper was reasonably successful in reestablishing the tempering variation lost by exclusive focus on clays, but such an approach could not replace the more precise data generated from NAA and petrography.     

Ceramic production,consumption and exchange in the Banda area,Ghana: Insights from compositional analyses

Ceramic production, exchange and consumption in the Banda area, west central Ghana has been affected by historical developments ranging from recent competition with alternative vessels (made of metal and plastic) to political economic upheavals that altered community relationships within and outside the region. In this study, we explore spatial and temporal patterning in pottery production, exchange and consumption using a combination of analytical techniques. Instrumental neutron activation analysis (INAA) of a large sample (491 specimens) of archaeological and ethnographic pottery, clay and temper samples from sites across the Banda area has led to the identification of seven compositional groups whose differential distribution implies shifts in resource selection through the last thousand years. Laser ablation-ICP-MS analysis was used to explore the effects of distinctive tempering agents (crushed slag) on the bulk chemical signature of a subset of Banda ceramics, while petrographic analysis provides insight into the preparation of ceramic fabrics. We integrate insights from these diverse physical studies to investigate the dynamics of pottery production, exchange and consumption over the course of the last millennium in the Banda area and explore potential linkages with broader political economic transformations.     

The mineralogy and petrography of Low Lands Ware 1 (Roman lower Rhine–Meuse–Scheldt basin; the Netherlands,Belgium, Germany)

Over the last 80 years Belgian, Dutch and German archaeologists working in the lower Rhine–Meuse–Scheldt basin have encountered a Roman pottery group that occurs in large quantities at most Roman sites in the region. Several researchers have separately tried to define this pottery, resulting in different names. Petrographic and geochemical analyses of 100 samples have now shown that the production of this ware predominantly made use of one source of raw material, divisible into three sub-groups on the basis of technological choices. The probable source lies in the early-Pleistocene Tegelen-formation, a clay rich in muscovite mica and garnet, which outcrops in the tertiary Scheldt escarpment (Nl) and the campine microcuesta (B). On the basis of geographical characteristics, Roman finds and the presence of a large Medieval pottery industry, production in the Bergen-op-Zoom area is suggested. In view of these new findings the name ‘Low Lands Ware 1’ is introduced to refer to this pottery group.     

Pottery production and distribution in prehistoric Bronze Age Cyprus. An application of pXRF analysis

Portable X-ray Fluorescence (pXRF) analysis of over 400 samples of Early and Middle Bronze Age Cypriot pottery from four widely separated sites identifies both local and non-local products at each. A series of analyses of sub-sets of the data highlights differences in the clays used at each site and for some distinctive types and wares. When assessed in the context of general typological, technological and stylistic factors these variations provide the basis for considering patterns of local production and inter-regional relationships across the island. Although the great majority of pots were locally made, particular wares and shapes were brought in from elsewhere. For some sites finer, more highly decorated vessels are mostly imports, but at others both simpler and more complex vessels were made of the same local clays. While small juglets or flasks may have been containers for transporting small quantities of rare substances, larger vessels are likely to have held less precious material. Open vessels, especially small bowls – some of which are plain, utilitarian items – represent another aspect of social behaviour and inter-regional relationships.     

陶器形态与折衷陶器研究

陶器形态指陶器各组成部分造型及其组合方式。通过陶器形态研究归纳陶器的时代风格,并为辨识兼有两个考古学文化要素的折衷陶器提供依据,在此基础上,运用动作习惯和文化习惯概念探讨折衷陶器的形成和文化属性,为研究考古学文化之间文化交流提供依据。本文以中日学者的研究成果为基础,探讨研究陶器形态的基本方法。     

双墩遗址黑陶渗炭工艺初探

双墩遗址是淮河流域新石器时代中期的一个重要遗址。该遗址出土了相当数量的黑陶,黑陶的制作工艺有多种,为探明双墩遗址黑陶的制作工艺,采用了XRD、喇曼光谱、重烧试验、显微、岩相、SEM和EDS探针等技术,对双墩遗址出土黑陶和局部发黑陶器进行了综合的测试分析。结果指出,陶器整个表层的黑色物质是炭黑。碳元素沿剖面的分布为:内外表层高而中间低,而内外表层0.6mm范围内炭含量的分布不甚均匀,存在明显的高低起伏,表明双墩遗址主要采用渗炭工艺制作黑陶。     

Differentiation of ceramic chemical element composition and vessel morphology at a pottery production center in Roman Galilee

Cooking pots and bowls from two production locations ca. 200 m from each other at the rural settlement of Kefar Hananya in Roman Galilee were compared employing chemical element composition and vessel-shape analyses. Splits of each pulverized sample, all of which were taken from ceramic wasters, were analyzed by both instrumental neutron activation and high-precision X-ray fluorescence analyses, and computerized vessel-shape analysis was employed for morphological analysis of the same vessel forms from each location. Several statistical techniques (bivariate plots, principal component analysis, cluster analysis and discriminant analysis) were used for analyzing the resultant data. It was found that both the cooking pots and bowls made at each location could be distinguished by employing either chemical composition or morphological analysis. The implications of this work, with regard to investigating both production and consumption sites, and for pottery provenance studies, are discussed. The findings suggest that these analytical techniques can be useful as an aid for chronological differentiations of archaeological pottery.     

Computerized morphological classification of ceramics

A novel morphological analysis of ceramic assemblages is presented using objective, automatic and computerized method for clustering and classification. The analysis is based on the entire shape of the potsherds, as expressed by three mathematical representations of their profiles. The similarity between profiles is mathematically defined in terms of the above mentioned representations. Cluster Analysis and Discriminant Analysis are used to reveal a hierarchical classification of pottery assemblages. The method is illustrated here by a detailed analysis of an assemblage which was classified previously by a pottery expert. A quantitative comparison of the two typologies reveals the power and archaeological sense of the new method.     

An Optimized Approach for Protein Residue Extraction and Identification from Ceramics After Cooking

Extraction of protein residues from archaeological matrices, such as pottery clay, lithics, and grinding stones, has proven to be methodologically challenging. Protein residue analysis is fraught with technical challenges in analytical chemistry. In cooking pottery, protein residues are thought to bind to clay surfaces in vessel walls through a variety of primarily non-covalent interactions. Removal of protein residues requires the disruption of these interactions, and a diverse set of tools has been proposed and applied. Here, we test extraction procedures through varying combinations of physical parameters and solvents to derive an optimal approach yielding efficiencies of recovery from experimental pottery above 60%. The utility of our extraction approach was further validated through liquid chromatography?Cmass spectrometry analysis of experimental residues. We have identified several hurdles to developing a successful study of protein residues from pottery, each of which is surmountable with additional method development in the realm of archaeological chemistry.     

古代陶器的研究视野——有关中国考古学方法的几点思考

本文以史前陶器为例,拓展了陶器研究中的新视野：指出陶器并非只是生活用品或文化序列的标志物,它与自然环境、经济方式、社会组织、意识形态等方面均有着密切的关系。而要真正全面了解陶器所潜藏的各种古代文化信息,就必须首先寻找获取信息的新途径。就史前陶器而言,传统的地层学、类型学方法已不能满足考古学发展的新要求,而自然科学技术、考古统计学、民族考古学、实验考古学则是有效地获得材料的主要途径。从某种意义上说,考古方法体系的陈旧比考古理论的滞后更加不利于中国考古学的健康发展。     

On pottery change and northern Iroquoian origins: An assessment from the Finger Lakes region of central New York

Pots as tools is a concept that has been widely accepted and developed since Braun’s classic 1983 publication. However, in northeastern North America archaeologists continue to use pottery primarily as an aid to culture history and research problems based thereon. In central New York State it has been postulated that a change in pottery forming technique heralds the onset of Iroquoian pottery traditions at around AD 1000. Empirical data on pottery forming and two other pottery traits do not support this postulation. Rather the trends in these traits are consistent with social learning theory and changes in mobility and population aggregation. Following Engelbrecht (1999, 2003) we suggest that a more fruitful approach to understanding the evolution of northern Iroquoian groups is to be found in ethnogenesis theory as described by Moore (1994, 2001).     

荥阳官庄遗址制陶作坊出土陶泥陶坯的科学分析

河南省荥阳官庄遗址发现了用于制陶的粘土原料以及未烧制的陶坯,这为研究西周中期以后中原制陶技术提供了不可多得的研究资料。为此,本研究利用能量色散X射线荧光光谱仪、X射线衍射分析仪分析了部分原料和陶坯,并使用马弗炉对其中的陶泥进行了烧制实验。结果发现,官庄遗址的制陶原料含铁量较高,烧制过程中析出磁铁矿等铁类矿物,且烧成陶色偏深;此外,制陶原料和同期陶片之间物相的趋同性和化学成分的聚类性,显示陶器本地生产的特性。研究结果为研究西周晚期至春秋早期时期制陶技术提供了基础材料。     

Characterization of Iron age pottery from eastern Turkey by laser- induced breakdown spectroscopy (LIBS)

Selected pottery sherds coming from the Ayanis, Dilkaya and Karagündüz excavations in eastern Turkey and dated from the Early to Middle Iron Age were examined as regards their composition by using laser-induced breakdown spectroscopy (LIBS). The objective of the study was first to investigate the potential of the LIBS technique in the compositional analysis of pottery and further to explore correlations in spectral data, by using chemometrics methods that would possibly enable discrimination among different sherds. This work is part of a broader study aiming to examine clay variability both before and during the Urartian State period and to explore possible relationships and differences among pottery objects from fortresses and settlements or settlements and cemeteries on the basis of the clay composition of sherds. Preliminary results demonstrate that by using the LIBS technique it is possible to analyse pottery sherds in qualitative and semi-quantitative ways, providing information on the clay and slip composition. Furthermore, encouraging results have been obtained by carrying out principal component analysis (PCA) on the LIBS spectra, which suggest that in certain cases, it is possible to directly correlate spectral information with the origin of pottery sherds.     

Using hearths for temper: petrographic analysis of Middle Woodland charcoal-tempered pottery in Northeast Florida

Charcoal-tempered pottery is uncommon in North America, but was produced with notable frequency in Northeast Florida from ca. AD 300–600. Thirty-six thin sections of pottery were analyzed by petrographic analysis and compared to 10 clay samples in order to characterize the paste of charcoal-tempered wares in terms of charcoal and mineralogical composition and abundance, assess the number of clay sources used to make the pottery, identify the species of wood represented in charcoal inclusions, and infer techniques of ceramic production. This analysis identified four temper categories, three texture groups, and three distinct clay resources used to make charcoal-tempered pottery, all of which were likely local to Northeast Florida. Identified wood taxa include pine (Pinus sp.), cedar (cf. Juniperus sp.), cypress (cf. Taxodium sp.), and sassafras (Sassafras albidum), with pine suspected to be the most common. These genera of charred wood, which exhibit minimal shrinkage in the samples, along with the prevalence of bone and grog inclusions, indicate that hearth contents were processed as temper, sometimes in combination with quartz sand. Potential reasons for the use of hearth contents as temper are considered.     

Non-destructive fabric analysis of prehistoric pottery using high-resolution X-ray microtomography: a pilot study on the late Mesolithic to Neolithic site Hamburg-Boberg

The characterisation of prehistoric pottery fragments presents a quite complex task. In provenance studies, petrographic and chemical analyses of the ceramic materials are employed to investigate potential production areas in respect to the geolocial background. Moreover, also the production technology of the firing process, as well as the forming techniques used by the prehistoric potters are of great interest. Their investigation is most often accompanied by a destructive preparation of the samples. In this paper, we want to present high-resolution X-ray microtomography (μ-CT), a non-destructive and non-invasive method, as a supplementary research tool in the study of prehistoric pottery.     

Technological Choices in Hand‐Made Indigenous Pottery from Western Mallorca (Balearic Islands,Spain) (C.1200–75 bc): An Archaeometric Approach

This paper addresses the technological choices observed in Mallorca (Spain) for the production of hand‐made pottery during the Late Bronze and Iron Age. We have conducted a diachronic analysis of the ceramic assemblages recovered from two archaeological sites placed in the same territory by means of X‐ray fluorescence and optical microscopy by thin‐section analysis. The archaeometric characterization of the hand‐made vessels allows us to establish several compositional groups related to the use of different raw materials and certain paste recipes associated with the archaeological sites and periods considered. Thus, this study evidences different productive strategies in each site and across time in the same geographical area.     

Identification of Pottery‐Forming Techniques using Quantitative Analysis of the Orientation of Inclusions and Voids in Thin Sections

The relationship between forming techniques and orientation of the components of ceramic materials in the context of pottery technology has long been recognized and used for identification of the techniques employed to create archaeological ceramics. The alignment of inclusions is usually characterized by qualitative categories or ordinal scales. This paper evaluates the potential of quantitative orientation analysis for identification of pottery‐forming techniques. A collection of experimental pottery formed using five forming techniques and combined techniques was analysed. The forming techniques were characterized by the intervals of the mean direction and the circular standard deviations of the orientation of the major axes of the ellipses equivalent to the objects representing random sections of inclusions and voids. The most informative criteria for the identification of pottery techniques are the circular standard deviation of the inclusion/void orientations in the core area of the vessel wall in a perpendicular thin section and the mean direction in a tangential section.     

CHALLENGES IN THE ANALYSIS OF HETEROGENEOUS POTTERY BY LA–ICP–MS: A COMPARISON WITH INAA*

Tempers added to pottery have the potential to obscure geographical variation in the chemistry of exploited clay resources when analysed using bulk methods. A pilot study was conducted to assess the possibility of using LA–ICP–MS to analyse clay matrix in pottery with extremely subtle partitions between INAA chemical groups. LA–ICP–MS was used to analyse the clay matrix of 32 pottery samples from seven Middle and Late Woodland period (c. ad 200–800) sites in north‐east Florida and results were compared to data from INAA of the same samples. The results reveal many of the challenges in analysing highly heterogeneous materials with LA–ICP–MS. However, the study also generated data that are potentially useful in the determination of pottery provenance. In some respects, LA–ICP–MS of clay matrix replicated the chemical variation recorded by INAA, and in other respects the results are divergent. The similarities and differences between these results are explained by specific differences between the methods and the materials analysed (matrix versus bulk analysis). Suggestions for improving the method are discussed.