The early roman imperial AES coinage II: Tracing the copper sources by analysis of lead and copper isotopes—copper coins of Augustus and Tiberius*

Lead and copper isotopes of Roman Imperial copper coins (denominations as and quadrans) were analysed by MC–ICP–MS. We concentrated on well‐dated coins minted at the official mint of Rome under the Emperors Augustus and Tiberius (between 16 bc and ad 37). The lead isotope results were compared with published lead isotope data of ore bodies from the Aegaean, Cyprus, Italy and Spain, in order to fingerprint the sources of Roman copper. During the Augustan period the main copper supply, as judged from the copper coins, is from Sardinia and south‐east Spain, with minor contributions from Tuscany. Except for Tuscany, this continued into the Tiberian period, when Cypriot copper also appears. Augustan quadrantes and late Tiberian asses came solely from the Rio Tinto area in south‐west Spain. Copper isotopes were applied here for the first time to systematic archaeometric studies. They are supplementary to lead isotopes and allow further grouping and classification of the copper coins.     

STUDY OF ANCIENT GREEK COPPER COINS FROM NIKOPOLIS (EPIRUS) AND THESSALONIKI (MACEDONIA)

Ancient copper coins from the Greek cities Nikopolis in Epirus and Thessaloniki in Macedonia, minted during Roman imperial times (31 BC to AD 268), were analysed non-destructively by proton induced X-ray emission, after removal of the patina. An intercompar-ison study using different analytical methods was also performed on five coins. Eleven elements were analysed quantitatively on all coins. Statistical analysis of the results was performed for their presentation in the form of dendrograms. Finally, the variations in the concentrations of some individual elements from emperor to emperor were examined.     

DISCRIMINANT ANALYSIS OF THE CHEMICAL COMPOSITIONS AND PHYSICAL MEASUREMENTS OF 245 AUGUSTAN QUADRANTES

Previously 245 Augustan quadrantes were analysed for seven elements. Physical measurements comprised the weight, maximum thickness and diameter, minimum diameter, and die orientation for each coin. Both chemical and physical data were subjected to discriminant analysis, and centroids in multi-dimensional space were obtained for each of the four groups. A tetrahedron was drawn using the four centroids; each corner was separated from the other groups by a Mahalanobis distance. We hypothesize that the most probable relative chronology comprises the smallest sum of Mahalanobis distances connecting all four points. The most probable chronology for the quadrantes is c. 8, 9, 5, and 4 B.C.     

Stable carbon and nitrogen isotope ratios of bone collagen: Variations within individuals,between sexes,and within populations raised on monotonous diets

The stable carbon and nitrogen isotope ratios of collagen of seven bones from each of three rabbits raised on a monotonous diet, and of two bones from each of eight female and seven male mink raised on another monotonous diet, were determined. The ranges of δ¹³C values and δ¹⁵N values were 0·5‰ and 0·6‰ for the rabbit bones and 1·0‰ and 1·4‰ for the mink bones. Uncertainties in the δ¹³C and δ¹⁵N values for prehistoric human diets estimated from the isotopic composition of collagen from the small numbers of bones which are typically available for analysis, and thus likely to be of the order of ±1‰.     

Evidence for the trade of Mesopotamian and Egyptian glass to Mycenaean Greece

The origins of raw glass used to fashion Mycenaean beads were explored using trace elements analyzed by laser ablation ICP-TOFMS. The use of this minimally destructive technique for the in-situ analysis of these beads was ideal given that the material is exceedingly rare and thus too sensitive to make use of traditional micro-sampling (e.g., by scalpel). A wide range of trace elements were measured to compare these Greek glasses to other Late Bronze Age glass coming from Egypt and Mesopotamia. Of the eleven beads analyzed, four blue glasses colored with cobalt and two blue/green glasses colored with copper have trace element compositions consistent with an Egyptian origin of manufacture. The other five of the glasses, all colored with copper, were found to conform to the composition of Mesopotamian glass. These data are the first to demonstrate direct and clear evidence for the trade of raw glass to the Mycenaean states.     

CHEMICAL COMPOSITIONS OF TEN SEPTIMIUS SEVERUS DENARII

X-ray fluorescence analyses of ten Septimius Severus denarii, all having the catalog number Cohen 777, and all minted in a.d. 196, show the following: (1) copper and silver concentrations in the ten coins cover a rather broad range, (2) lead and gold concentrations correlate with the silver concentrations, (3) no elements, except silver, correlate directly with the copper contents, (4) two coins have very nearly the same compositions, but this could actually be explained by chance, given the precision of the analyses and the range of compositions found for all ten denarii, (5) weights, thicknesses, and diameters of the coins varied over a relatively wide range, but densities varied only slightly. Assuming reasonably homogeneous melts of coinage alloy, X-ray fluorescence (XRF) analyses of many more Severus denarii of a.d. 196 should enable one to deduce several details of the mint operation such as (1) the number of dies in use of C. 777 coins at one time, (2) the overall batch size of coins, and (3) the number of different Severus denarii minted from the same batch of alloy. With improved precision of XRF analyses now possible, it only remains for a source of Severus denarii to be found to enable testing of this hypothesis.     

A Second Investigation into the Chemical Composition of the Roman Provincial (Procuratorial) Coinage of Judaea,AD 6–66*

An investigation of the chemical composition of the first Roman provincial coinage of Judaea, minted in ad 6–66, was conducted. A total of 103 copper‐alloy coins were analysed by ICP‐AES. It was determined that different copper alloys were used for the coinage, a leaded tin‐bronze and a pure tin‐bronze alloy. The investigation also showed that the copper alloy was made in four different formulae with regard to the alloying elements added to copper. Trace element profiles point to the existence of a shared pool of metal for Roman coins and metalwork.     

Skeletal age at death: an evaluation of the miles method of ageing

The accuracy of Miles' method of ageing individuals within a population, based upon an analysis of the rate of dental wear, was evaluated in a sample of 202 living Lengua Indians from the Chaco area of Paraguay. The preliterate and culturally isolated status of the Lengua provided a useful base for comparison with populations that are likely to be encountered by archaeologists. The independent age estimates from maxillae and mandibles of the same individuals were found to be highly correlated with each other and to the actual ages of those individuals (Spearman rank-correlation test maxillae r_s = 0·58, mandibles r_s = 0·95, medians of populations rank-sum R = 99·5 > 95). No significant differences (P > 0·05) were found between the mean ages of any of the Miles subgroups, as indicated by the t-test for paired comparisons. The present study provides evidence of the reliability of the Miles method of ageing archaeological populations on the basis of occlusal wear. These findings are evaluated in the light of the sources of error inherent in the Miles system of analysis.     

Stable isotopes and diet at Ancient Kerma,Upper Nubia (Sudan)

Carbon and nitrogen stable isotope values were measured from bone collagen extracted from archaeological Nubian human (n = 54) and faunal (n = 61) populations from the site of Kerma, Sudan. Collagen suitable for isotopic analysis was extracted from 22 faunal and 48 human samples from the Eastern cemetery site, dated to the Middle Kerma (c. 2050–1750 BC) and Classic Kerma (c. 1750–1500 BC) periods respectively. The isotopic data indicate that the human dietary regimen included a mix of C₃ and C₄ plant-derived components, with a larger C₄ component than previously reported in archaeological Egyptian Nile Valley populations. Elevated δ¹⁵N values are attributed to consumption of dietary resources from a ¹⁵N-enriched terrestrial ecosystem. The faunal isotope data also indicate the consumption of C₃ and C₄ plants. The large range of δ¹³C values measured in both the human and faunal samples supports previous work suggesting that a significant portion of the populations buried at Kerma may have originated elsewhere, further confirming the Nile Valley as a major corridor for population movement in the region.     

Partitioning of trace elements between the ores, fluxes, slags and metal during the smelting of copper

This paper gives the results of smelting seven parcels of copper ores from well-known mining areas. The behaviour of the trace elements introduced from the ore, the fuel, and the fluxes has been investigated by analysis of the main products, metallic copper and the slags. Most of the ores were capable of giving copper of relatively high purity and therefore, in order to represent conditions believed to have existed in the Early Bronze Age, two artificial ores were made up and copper high in arsenic and nickel was obtained.The results show that it is relatively easy to smelt a wide range of copper minerals to give copper of high purity apart from iron. This latter element can be removed by careful refining. The remaining elements are present at the parts/10³ level. Wood fuel is thought to contribute little to the trace element pattern. Even if it did, it would merely reinforce the elements already contributed by the ore and flux as the timber is likely to have been grown in the immediate vicinity of the ore and will probably contain the same trace elements.Useful comparison is made between the trace element pattern resulting from these smelting runs and material from archaeological sites in the vicinity of the mining areas.     

Palaeolimnological impacts of early prehistoric farming at Lough Dargan,County Sligo,Ireland

This study provides a unique method of inquiry for archaeological investigation with an aim to assess the intensity and effects of Neolithic and Bronze Age farming practices at Lough Dargan, northwest Ireland, through a multi-proxy analysis of a lake sediment core. Chironomid (non-biting midge fly) subfossils and lake sediment geochemistry (δ¹³C, δ¹⁵N and C:N ratios) were used to assess changes in limnological conditions through time. The limnological data were compared with macroscopic charcoal concentration and pollen data to examine the potential influence that early farmers had on a freshwater lake system within a prehistorically active catchment. Results from the chironomid analysis show that the first substantial period of agricultural activity in the early Neolithic (c. 3730–3190 BC) resulted in a temporary shift to more eutrophic lake conditions. There is evidence of animal husbandry with substantial levels of animal waste reaching the lake, leaving an imprint in the geochemical record of increased δ¹⁵N values and decreased δ¹³C values and C:N ratios during this time. The chironomid community reverted back to its pre-impacted state c. 3190 BC in response to a period of reduced farming (c. 3390–3000 BC) which eventually led to a distinct lull in activity, with possible cessation of farming from 3000 to 2700 BC. A return to eutrophic conditions coincided with the gradual return of agriculture, with more permanently altered lake conditions dominating from 2400 BC, even during a 250-year period of reduced human activity commencing at c. 1440 BC. Increased sedimentation rate, along with increases in δ¹³C, δ¹⁵N and C:N, the presence of chironomid taxa indicative of erosion, more eutrophic lake conditions and high concentrations of macroscopic charcoal all point to more intensive land use practices during the Bronze Age. Palaeolimnological data exhibited an immediate response to intensified farming during this time, and were especially responsive to pastoral farming due either to scale of activity or proximity to the lakeside. The success of this study demonstrates the effectiveness of palaeolimnological analysis in the investigation of prehistoric farming. This approach will help inform Neolithic and Bronze Age land-use practice and human–environment relations in the region, and highlights the potential for chironomid-based archaeological research.     

Trace element concentrations in teeth – a modern Idaho baseline with implications for archeometry,forensics, and palaeontology

Concentrations of 69 minor and trace elements were measured in situ using laser ablation inductively-coupled plasma mass spectrometry in multiple teeth of modern herbivores (Cervus elaphus, Odocoileus hemionus, Odocoileus virginianus; n = 52), omnivores (Ursus americanus; n = 56), and carnivores (Felis concolor; n = 33; Canis lupus; n = 4) from Idaho, USA. On each tooth, two to five analyses were collected on enamel, primary dentine, and secondary dentine with spot diameters of 30–100 μm. Continuous 30-μm-wide line traverses were collected across deer, elk, and wolf teeth. Results confirm trace element concentrations below 1 ppm for many elements, including Li, Be, transition metals (excepting Mn, Fe and Zn), heavy metals (excepting Hg and Pb), the rare earths, and actinides. Strontium and Ba generally biopurify with increasing trophic level, but Ba shows decreasing discrimination with tissue type in the order secondary dentine – primary dentine – enamel. Most elements show strong zoning within tissues and variable trophic level behavior, so concentrations in omnivores rarely fall between herbivores and carnivores. Trace element mass balance suggests that soil and dust, not food, commonly deliver the largest trace element load in terrestrial carnivores and omnivores, even for elements that biopurify, like Ba. Use of trace elements for inferring past diets are likely compromised by unknown rates of dust and soil ingestion rather than indicating the degree of herbivory and carnivory. The low concentrations of many elements provide multiple sensitive markers of post-burial overprinting that can be used to discriminate altered vs. original biogenic compositions. REE and actinide trends do not directly follow bedrock compositions.     

An archaeometric study of Hellenistic glass vessels: evidence for multiple sources

In the present study, 53 glass fragments from core-formed vessels and 3 glass beads are investigated using SEM/EDX, EPMA and LA-ICP-MS. All samples were excavated in the Latin settlement of Satricum in central west Italy and apart from two, were found in the so-called fourth–third c. BC Hellenistic Votive deposit, also known as Votive Deposit III, discovered in front of the sanctuary of Mater Matuta on top of the acropolis. The analytical results indicate that the glass from Satricum is a typical soda-lime-silica type with natron used as a flux. Its chemical compositions display a relatively low compositional variation. Small differences in the concentrations of major and minor oxides (SiO₂, Al₂O₃, CaO and Fe₂O₃) and in trace elements (Sr, Zr and Nd) between individual samples suggest the use of different types of raw materials, especially sand. In turn, this suggests that the glass derived from more than one glass making centre. The combined investigation of colourants (Co, Cu and Mn) reinforces and confirms the idea that glass from Satricum was made using different manufacturing traditions during the Hellenistic period.     

Bronze production in Southwestern Iberian Peninsula: the Late Bronze Age metallurgical workshop from Entre Águas 5 (Portugal)

Archaeological works at Entre Águas 5 (Portugal) uncovered a seasonal LBA settlement with significant metallurgical remains (crucibles, moulds, prills and a tuyere) related to bronze production. Radiocarbon dating ascribes an occupation period (10th–9th century BC) previous to Phoenician establishment in Southwestern Iberia. In spite of the proliferation of metal artefacts during LBA, the production of bronze alloys is still poorly understood. An integrated analytical approach (EDXRF, optical microscopy, SEM–EDS, micro-EDXRF and Vickers microhardness) was used to characterise this metallurgy. Crucibles show immature slags with copious copper nodules, displaying variable tin content (c. 0–26 wt.%), low iron amount (<0.05 wt.%) and different cooling rates. Certain evidences point to direct reduction of oxide copper ores with cassiterite. Scorched moulds with residues of copper and tin indicate local casting of artefacts. Finished artefacts also recovered at the site have an analogous composition (bronze with ∼10 wt.% Sn and low amounts of Pb, As and Fe) typical of coeval metallurgy in SW Iberia. Some artefacts reveal a relationship between typology and composition or manufacture: a higher tin content for a golden coloured ring or absence of the final hammering for a bracelet. An uncommon gilded nail (gold foil c. 140 μm thick; 11.6 wt.% Ag; ∼1 wt.% Cu) attests the existence of evolved prestige typologies. This LBA settlement discloses a domestic metallurgy whose main features are typical in Iberian Peninsula. Finally, it should be emphasized that a collection as comprehensive and representative of a single workshop has rarely been studied, enabling a deeper understanding of the various operations involving the bronze production and manufacture of artefacts.     

PRE-COLUMBIAN METALLURGY: TECHNOLOGY,MANUFACTURE, AND MICROPROBE ANALYSES OF COPPER BELLS FROM THE GREATER SOUTHWEST*

Twenty-four cast copper crotals (commonly called bells), one 'spilled bell’, one tinkler bell and a number of minerals from locations throughout the Greater Southwest were analysed for their elemental composition by a PIXE nuclear microprobe at Los Alamos National Laboratory, New Mexico, USA. Sixteen bells contained minor and trace amounts of silver, antimony, arsenic, lead, and in some cases tin, strontium, and selenium. Nine bells contained little or no detectable amounts of these elements. This suggests that several workshops throughout the Greater Southwest and Mexico might have manufactured these bells.     

Age and exploitation of obsidian from the Medicine Lake Highland,California

The relationship between major and minor elements, trace element composition, and age of obsidian sources within a volcanic field, is of considerable interest for obsidian source and artifact research in the New and Old World. The present study investigates this relationship in the Medicine Lake Highland of western North America. Geological evidence had indicated a very young age for all obsidian sources in the Highland, yet archaeological evidence suggested that obsidian was utilized for several thousand years. X-ray fluorescence analysis distinguished the latest flow (Glass Mountain) from the Cougar Butte, Grasshopper Flat, and Lost Iron Wells sources. Data obtained from two nearby archaeological sites showed that obsidian from the latter two sources was used by c. 7500 bc, while Glass Mountain material was not used (or available) until after 1360± 240 bp. These findings indicate that inferences of an extremely recent age for all obsidian sources in the volcanic field were unwarranted. Further analysis of major and minor elements indicated different hydration rates for these sources. The results argue that significant geochemical variability, as well as age differences, can exist between obsidian sources within the same volcanic field.     

Land Snails from an Ancient Shipwreck: The Need to Detect Wreck-Independent Finds in Excavation Analysis

Land snails recovered from shipwreck excavations can potentially provide information regarding human-based dispersal of the involved species and also contribute to hypotheses regarding a ship's route and geographical origins of some of its cargo. Such faunal material, however, must be subjected to critical study to ascertain whether they represent specimens originally associated with the ship itself or are simply elements introduced to the site after the ship sank. The excavation of a Late Bronze Age shipwreck at Uluburun, in southern Turkey, produced 36 land snails. Of these, 32 specimens are believed to have been on board the vessel in antiquity. Three other specimens represent an endemic Metafruticicola species, which lives exclusively in a 10 km zone in the region of Uluburun. The proximity of the species' habitat to the shipwreck site suggests that these specimens are intrusive elements. The intrusive nature of a single Zonites specimen also recovered from the excavation is amply demonstrated by a detailed comparative study of Zonites specimens collected in the same locality. The last study, which involves the analysis of spatial shell variations of populations collected from 61 separate localities (totalling 367 specimens) within a 50 km area extending from Megisti (Kastelórizo) and Kas to Finike, suggests that: (1) Zonites beydaglariensis is conspecific with Z. caricus, and (2) the shipwreck specimen not only belongs to this species, but that it originates from a population on the rocky Uluburun peninsula 0·8–1·2 km north of the shipwreck site. The specimen was probably blown into the sea by a natural phenomenon and settled on the shipwreck site.     

Proto-Cities or Non-Proto-Cities? On the Nature of Cucuteni–Trypillia Mega-Sites

The Eneolithic Cucuteni–Trypillia mega-sites were undoubtedly the largest residential agglomerates in southeastern Europe from c. 4100 to 3400 cal BC. Their sheer size and estimated population have triggered animated discussion of whether or not they should be regarded as ‘proto-cities’. Considering trajectories of change in, for instance, density of dwellings and settlement size, this paper discusses a series of issues that will help the reader decide in which category these large sites should be placed, while at the same time examining the arguments for and against Trypillia low-density settlement patterns, recently problematized by Chapman and Gaydarska (2016).     

Direct chronometry (14C AMS) of the earliest copper metallurgy in the Guadalquivir Basin (Spain) during the Third millennium BC: first regional database

The characterisation of copper metallurgy in the Third millennium BC in the Southeast of the Iberian Peninsula as a simple and technological process on a domestic scale was the central axis that sustained a belated, underdeveloped appreciation for the Prehistory of the Iberian Peninsula and Western Europe dependent on the origin of social complexities. Nevertheless, this characterisation was incomplete since it was based more on the contexts of consumption than those of production and in territories used for agricultural rather than for mining purposes. Above all, however, it was incomplete because it lacked a precise spatial and temporal framework that evaluated the variability of the behaviours it articulated.To overcome these deficiencies, we have developed a systematic programme of interdisciplinary research aimed at documenting and dating, through the use of ¹⁴C AMS, the direct contexts of copper production of eight settlements that cover the populational variability (from 300 to 0.25 ha of surface area), chronology (between c. 3000 BC and c. 2000 BC), economic (settlements dedicated to mining, agriculture, etc.) and territorial along the axis of the backbone of the most fertile soils and primary (main) supplies of copper in the Iberian Peninsula: the Guadalquivir Basin.Results consist of the first systematic database, with sixty-six precise, direct radiocarbon dating of the metallurgical production of copper during the Third millennium BC, in the Iberian Peninsula and Western Europe. At the same time, it presents a variability of contexts (e.g. household, workshop, partial-time, full-time, factory, smelting quarter, etc.), in both time and space, affording a precise evaluation of social and territorial variability of behaviours that the production of copper shows us, a new historical explanation and the link between this and the development of social complexity.