Neutron activation analysis of fine grey pottery from Conimbriga,Santa Olaia and Tavarede,Portugal

The concentrations of two major elements and thirteen trace elements in 73 selected sherds of fine grey ware from the Iron Age and Roman period, excavated at Conimbriga, Santa Olaia and Tavarede, Portugal, were determined by instrumental neutron activation analysis. These concentrations were used to calculate distance matrices which were then subjected to cluster analysis employing SAHN and k-means methods, as well as to principal components analysis, to group the sherds according to the overall similarity of their compositional characteristics. The results showed that equivalent groupings appeared regardless of the taxonomic method used. Two major clusters were recognized corresponding to two different sites, namely Conimbriga and Santa Olaia, suggesting that the ceramics from these sites were made locally. No significant differences in compositional patterns were observed between iron age and roman sherds from Conimbriga.     

Integrated geological,petrologic and geochemical approach to establish source material and technology of Late Cypriot Bronze Age Plain White ware ceramics

Late Cypriot Bronze Age Plain White Wheelmade ware samples from several Cypriot excavation sites and the northern Canaanite coast were studied to ascertain their production centres and details of their manufacturing processes and post-depositional alteration. The investigation of the ceramics, using combined geoscientific analytical techniques (XRF, ICP-MS, XRD and EPMA) allowed four groups of pottery to be distinguished based on their common raw-material sources and/or technological analogies. Sediments that were sampled in East Cyprus (eastern Mesaoria Plain) for comparative purposes indicated that most of the investigated ceramics were produced from raw materials available around the ancient settlement of Enkomi. Appraising technological variations and discriminative raw-material characteristics, several pottery producing workshops in ancient Enkomi (Eastern Cypriot coast) have been identified that merchandised their commodities on Cyprus and, in all probability, also overseas.     

Using provenance data to assess archaeological landscapes: an example from Calabria, Italy

Ceramic provenance studies have helped archaeologists examine trade and exchange in multiple scales, the organization of production, and even vessel function. Yet, they may go even further, to provide a venue for the examination of past people’s perception of their landscape. To do so, a methodology is needed that links the choices prehistoric potters made, as reflected in their ceramics, with the choices their landscape could afford them, as reflected in the extent and distribution of local clays, and the physical, chemical and mineralogical characteristics of these clays. Using the region of Bova Marina in southwestern Calabria as a case study, we have combined a raw materials survey with field and laboratory experiments, along with chemical and mineralogical analyses of the collected sediments to understand the distribution and the physical, chemical and mineralogical variability of locally available clays and provide baseline data against which prehistoric ceramic materials from the region may be compared. We show that the local sediments can be divided into three major units, based on their macroscopic, mineralogical and chemical characteristics, that correspond well with the major geological units outcropping in the study area. While two of these units have internally consistent properties, the third is variable.     

A COMPARATIVE ELECTRON MICROPROBE STUDY OF LERNA III AND IV CERAMICS AND LOCAL CLAY-RICH SEDIMENTS*

This study uses electron microprobe analysis of ceramic artefacts and local day-rich sediments and lithics to help address questions concerning the nature of the cultural change implied by ceramics from Lerna III and IV. It redresses the previous lack of a comparative collection of clay-rich sediments that adequately represents the local variation in clay and temper for the area surrounding Lerna. The resulting comparisons indicate that although they produced stylistically different ceramics, potters from both Lenta phases acquired their clays from the local Lerna area.     

Archaeological sedimentology of overbank silt deposits on the floodplain of the Ohio river near Louisville,Kentucky

The surface of the floodplain of the Ohio River about 20km southwest of Louisville, Kentucky, is a series of linear ridges and swales that are subparallel to the channel of the river, which here is relatively straight and flows southward. Numerous prehistoric occupational sites are located on these ridges. The sediments that underlie the ridges, which were examined in four archaeological excavations as deep as 8 m, are predominantly sandy silt and silty fine to very fine sand and appear to be mainly the product of overbank deposition from suspended load. Abundant cultural material and occupational sites dating as early as 10,000 years BP are found in the sediments at depths as great as 6·5 m. The fine sediments of the floodplain are underlain by sand and gravel.The context of the cultural materials and the stratigraphy and morphology of the deposits indicate that the ridged deposits began as linear riverside sand and gravel bars. These were succeeded upward by fine-grained overbank deposits in which the ridged morphology was maintained because the overbank silt and fine sand were deposited as prograding elongate bars at high water. As the floodplain ridge built upward, the sedimentation rate decreased and the sand content of the sediments diminished, and as the river channel occasionally shifted, the ridged deposits were built in successive subparallel sequences.Two archaeological consequences are implicit in this depositional model of orderly growth of the floodplain. First, available archaeological data from floodplain segments along other parts of the river should confirm the model; and second, the model should make it possible to search the floodplains of the Ohio River for stratified sites of any desired age.     

Long-term clay raw material selection and use in the region of Classical/Hellenistic to Early Byzantine Sagalassos (SW Turkey)

A provenance study was carried out on coarse ceramics from the Classical/Hellenistic to Mid-Byzantine city of Sagalassos, SW Turkey. The ceramics were sampled from the excavations of the city, and clay raw materials were sampled throughout its ancient territory. Used techniques were optical microscopy and electron microprobe analysis on thin sections, geochemical analysis (fusion ICP/MS and mineralogical analysis (X-ray diffraction). The geochemical/mineralogical diversity in the ceramics is not as wide as for the clay raw materials. It seems that even at the restricted scale of this study, the resources were limited to the area around the ancient site. The differences between the ceramics are likely due to the use of different ophiolitic clay bodies being exploited for their production.     

Hohokam and Patayan interaction in southwestern Arizona: evidence from ceramic compositional analyses

Ceramic raw material use is one line of evidence for prehistoric territorial boundaries and social interaction. In this paper, we characterize the raw materials used by Hohokam and Patayan potters along the western Hohokam frontier, using data from oxidation analysis, laser-ablation inductively-coupled plasma spectrometry, and petrographic analysis. The sample includes 150 sherds from three sites (AZ Z:1:29[ASM], AZ Z:1:30[ASM], and BMGR-02-F-04) south of Gila Bend, Arizona. Similar Lower Gila River sediments were used for Hohokam and Patayan ceramics during the period A.D. 700–1150. Patayan potters apparently used clay sources from an area dominated by Hohokam settlements, and their ceramics were transported at least 50 km into the desert interior, perhaps representing seasonal movements between the river and the desert.     

Identifying the sources of Inka period ceramics from northern Chile: results of a neutron activation study

To examine regional patterns of ceramic production and distribution during the era of Inka domination in northern Chile, we determined the elemental compositions of 157 samples of archaeological ceramics and geological clays from the sites of Catarpe and Turi using instrumental neutron activation analysis. We identified two major and three minor composition groups in the ceramics. The major groups, High Cr and Low Cr, are linked to clays from two broad geological contexts within the region, while the minor Low Na group is made up of ceramics imported from northwestern Argentina. The distribution of the composition groups indicates that, in the Catarpe–Turi region, patterns of ceramic production differed for different vessel types: jars were made from clay and temper acquired near the sites where the jars were used, while bowls were made of material coming from more distant sources. The geographical distribution of the analyzed ceramics indicates that bowls were exchanged between Catarpe and Turi in a pattern more similar to tribute/extraction than to market exchange, with Catarpe being the dominant site. The compositional analysis also demonstrates that Inka-style ceramics were being locally produced at sites in this region during the era of Inka domination.     

Archaeometrical study of Khmer stoneware from the Angkorian period: Results from the Cerangkor Project

In the area around Angkor, Cambodia, several ceramics kilns dating from the ninth to 15th centuries ce have been discovered since 1995. The technical, typological and compositional characterization of their production has been one of the main goals of the Cerangkor Project. Samples of green‐glazed ‘Kulen‐type' stoneware and non‐glazed stoneware produced in five kiln sites in the Angkor region were analysed chemically by wavelength‐dispersive X‐ray fluorescence spectrometry (WDS‐XRF) and also petrographically. The data indicate that some workshops used similar raw materials for the same types of ceramics, suggesting the exploitation of the same geological formations in the whole region. Several references groups were established for each type of stoneware offering an important database for future provenance studies of sherds from consumption sites.     

Ceramic Production in the Kur River Basin (Fars,Iran) During the Middle to Late Second Millennium bce: A Geochemical and Technological Characterization

A total of 119 middle to late second millennium bce pottery samples from six sites in the Kur River Basin (Fars, Iran) were examined to characterize these ceramics and reconstruct their manufacturing technology and the origin of the primary materials. For this, a combined study of handheld XRF and thin‐section petrography was performed. The geochemical signatures of these ceramics were defined and interpreted in their archaeological and geological framework, resulting in the determination of different production processes and clay types used for four ceramic wares (Middle Elamite, Qaleh, Shogha and Taimuran) and the identification of possible outcrops used for Shogha–Taimuran production.     

Raw Material and Technological Changes in Ceramic Productions at Sai Island,Northern Sudan,from the Seventh to the Third Millennium BC

This study presents the results of integrated mineralogical, petrographic and chemical analyses of different ceramic assemblages and local sediments from Sai Island, northern Sudan, dating to between the seventh and the third millennium bc , and highlights a significant variability in the raw materials and technology of these productions. Although archaeometric analyses of ceramics are widely employed in many parts of the world, a lamentable scientific gap exists for African pottery, which this paper aims to bridge with new and compelling results.     

PHYSICOCHEMICAL COMPOSITIONAL ANALYSIS OF CERAMICS: A CASE STUDY IN KENTING,TAIWAN*

The composition of ceramics does not just reflect the component of some specific, unprocessed, geological, raw material source, but also certain forms of human behaviour involved in its manufacture. The purpose of this research project is to apply the acid‐extraction chemical method, complemented by a thin‐section petrographic study, to the compositional analyses of certain local ceramic collections (mainly from several sites in the southern Taiwan area). The results present the raw materials that the ceramic manufacturers of the two cultural traditions (O‐laun‐pi Phase II and Phase III–IV), which overlapped temporally, used. These materials came from the same sources, but the ceramics were manufactured in different ways. Particularly, the people of O‐laun‐pi Phase III–IV also procured certain materials from either local sources or from somewhere in eastern Taiwan to make their pots. The results also indicate that there might have been a variation in terms of their manufacture among sites of the same cultural tradition.     

CHEMICAL AND MINERALOGICAL CHARACTERIZATION OF SASANIAN AND EARLY ISLAMIC GLAZED CERAMICS FROM THE DEH LURAN PLAIN,SOUTHWESTERN IRAN*

One hundred and seventy‐five glazed ceramics from Sasanian and Early Islamic period sites located on the Deh Luran Plain in southwestern Iran were examined by instrumental neutron activation analysis for characterizing differences in ceramic pastes and by laser‐ablation inductively coupled plasma mass‐spectrometry for identifying the constituents of the ceramic glazes. The results of the analysis reveal that alkaline‐based glazed ceramics have paste compositions that are distinct from contemporary and later ceramics decorated with alkaline–low‐lead and lead‐based glazes.     

ARCHAEOLOGICAL AND CHEMICAL RESEARCH ON SEDIMENTS AND CERAMICS AT POLIDEPORTIVO (SPAIN): AN INTEGRATED APPROACH*

This paper proposes a preliminary approach to the integration of archaeological evidence and various chemical analyses (phosphorus and lipid) on sediments and ceramics. Phosphorus and organic matter analyses are, thus, used for the study of sediments, and lipid analyses for pottery from structure 19 of the Late Neolithic—Early Copper site known as ‘Polideportivo’, Martos, southern Spain. The results of both types of analysis point to a predominantly domestic function for this structure.     

Compositional Analysis of Ceramics from Goguryeo Fortified Sites in Central Korea

The aim of this paper is to investigate whether the ceramics from the Goguryeo fortified sites of the Han River region in central Korea were manufactured and consumed locally during the southern expansion of the Goguryeo State (475–551 ce ). For this research, 88 ceramic samples from seven contemporary sites in the southern territories of Goguryeo were sampled and analysed by ceramic thin‐section petrography and neutron activation analysis (NAA). In addition, to establish a possible chemical fingerprint at Hongryeonbong Fort 2, five clay specimens were also gathered and analysed from the pottery firing structure. The results of this analytical study indicate that the majority of the ceramics from the Goguryeo fortified sites of central Korea were produced and circulated within this newly acquired region. In addition, it is highly probable that Hongryeonbong Fort, which contains the remains of what may be ceramic firing architecture, is the place of production for the ceramics.     

MINERALOGICAL ANALYSIS OF SUDANESE NEOLITHIC CERAMICS

The archaeologist must often determine if ceramics having similar designs and forms but from widely separated locations were locally made or are the result of diffusion. This paper describes a methodology of technological analysis of ceramics utilised to solve such a problem. Results of a mineralogical analysis of ceramics and a discussion of the cultural implications of the results is presented. It is concluded that this methodology is an essential tool in distinguishing sites and elucidating relationships within the Sudanese Neolithic.     

Application of electron microprobe analysis to identify the origin of ancient pottery production from the Castillo de Huarmey,Peru

A vast amount of ceramics (among other grave goods) were recovered from Castillo de Huarmey, a Wari culture (650–1050 ce ) archaeological site on the north coast of Peru. In order to assess ceramic production area(s) and possible trade, political or cultural interactions with other regions, and to complement earlier petrographic analysis, electron microprobe analysis (EMPA) was conducted following a rarely used methodology in archaeology. The chemical composition of individual minerals in ceramics and sediments samples from the Huarmey Valley was obtained, focusing mainly on amphiboles, feldspars and pyroxenes. The results of the analyses clearly indicate that the majority of the ceramic analysed was made of raw material of local origin.     

Temper mixture models and assessing ceramic complexity in the emerging Tarascan state

This study presents compositional data from ceramics drawn from surface survey and controlled excavations from three prehispanic sites within the relatively small Lake Pátzcuaro Basin, representing a ceramic sequence stretching nearly 1500 years, from the Preclassic to Late Postclassic Tarascan state (ca. 50 B.C.–1525 A.D.). Using neutron activation analysis, we identify compositional groups and model the importance of volcanic materials as temper in the construction of prehispanic ceramics by matching mathematical simulations of clay–ash mixes to the compositional groups. Rather than discreet clay resources and spatially circumscribed production, we argue for a broadly dispersed and highly varied organization of pre-Tarascan and Tarascan state ceramic production in which the potters' distribution and use of specific volcanic ashy additives, not clays, structured the organization of production.     

THERMOLUMINESCENT DATING OF NEOLITHIC AND CHALCOLITHIC POTTERY FROM SITES IN CENTRAL PORTUGAL

Samples of Neolithic and Chalcolithic pottery from nine sites in the Upper Alentejo and Estremadura regions of Portugal have been dated by the thermoluminescence method (quartz inclusion technique). The project was designed to help establish an absolute chronology for the Neolithic and Chalcolithic periods in this area, and to try to elucidate the chronological relationships between settlement sites and burial sites (‘dolmens’) in the same area. Portugal was confirmed, together with Brittany, as being one of the earliest foci of megalith builders.     

The 9th century BCE destruction layer at Tell es-Safi/Gath,Israel: integrating macro- and microarchaeology

Destruction events in multi-period sites are valuable marker horizons that represent time-synchronous events across the site and sometimes between sites. Destruction layers often preserve rich finds that provide insights into site use. Here we use both macro- and microarchaeological methods to study a destruction event from the late 9th century at Tell es-Safi/Gath in Israel. A major conflagration at this specific location resulted in the consolidation of parts of the roof construction materials, thus enabling us to differentiate between roof, walls and floor materials. We could reconstruct the events which lead to the formation of an approximately 80 cm thick layer. The base of this layer that overlies the floor surface is a thin charred organic material-rich ash layer. As the clays in this layer were not altered by heat and the ceramics still have preserved residues, we conclude that the ash was produced elsewhere and was redistributed to this location. Ceramics that are associated with burnt roof sediments do not have preserved residues. We also estimate the time that each of the accumulation events might have taken, and conclude that this accumulation occurred over decades. The architecture and artifacts found within and beneath the destruction do not allow us to unequivocally identify the function of this area prior to destruction. We do however identify an unusual bin and associated stone pavement, and a corner rich in artifacts, phytoliths and charred organic material. We also show that a wall was built of fired mud bricks; a most unusual occurrence for this time period in the Levant. This study demonstrates well the usefulness of an integrated macro- and microarchaeological approach to understanding the archaeological record, as well as the benefits of using an on-site laboratory.