Sample preparation for accelerator-based radiocarbon dating

Although several efficient sample preparation methods have been devised for conventional radiocarbon dating, the advent of the accelerator mass spectrometer (AMS) dating technique with its much smaller sample requirement and different counting method has meant that new preparation routes have had to be developed. Techniques used for the Oxford AMS system are described in this paper.     

METHODOLOGICAL DEVELOPMENTS IN THE LUMINESCENCE DATING OF BRICK FROM ENGLISH LATE‐MEDIEVAL AND POST‐MEDIEVAL BUILDINGS*

Fired clay brick samples, obtained from a group of seven high‐status late‐medieval and post‐medieval buildings in England ranging in age from c. ad 1390 to 1740, were dated by the luminescence method using an optically stimulated luminescence (OSL) technique. The results obtained indicate that, when applied to quartz extracted from brick, the technique is capable of producing dates that are in consistently good agreement with independent dating evidence for the buildings. For six samples taken from a group of four dating ‘control’ buildings the mean difference between the central values of luminescence and assigned ages was 5 ± 10 years (SD, n = 6). The methodology used is appropriate for application to other standing buildings in other temporal and geographic regions, and may be used with confidence where conventional dating methods are less certain. The study also examines the luminescence characteristics of quartz and the characteristics of the lithogenic radionuclides in brick samples and identifies various aspects related to the assessment of experimental uncertainty in testing the reliability of the method.     

New evidence for Bronze Age agricultural settlements in the Zhunge’er (Junggar) Basin,China

Abstract

The Zhunge’er (Junggar) Basin in northern Xinjiang was a key crossroads in antiquity for the dispersal of ideas and technological innovations from the Eurasian steppe into the heartland of central China. The Bronze Age chronology of the Zhunge’er Basin is chiefly based on relative dating and little is known about subsistence strategies, although the strong tradition of nomadic and transhumant pastoralism among modern populations suggests that there may have been a high degree of mobility. The visibility of ancient cemeteries and the need to salvage graves before they are looted have resulted in a lack of focus on settlements, with a consequent assumption that in antiquity agriculture played a limited role. This assumption has been challenged by rescue excavations at the Jimusa’er (Jimsar) Luanzagangzi site, which indicate that agriculture may have been a significant component of Bronze Age subsistence strategies. Small-scale soundings at settlement sites provide well-stratified sequences of material for absolute dating which can be used to place the artifacts recovered from graves in a more secure chronological context.     

Thousand years of vegetation history revealed by pollen in a sandy soil,central Netherlands

Abstract

Within the scope of an interdisciplinary research project to determine the genesis and age of small clusters of oak trees, three soil sections in and three outside oak clusters in an ancient woodland/heath on the Veluwe, central Netherlands, were sampled for palynological analysis. The sections within the clusters show an undisturbed development from the Medieval period onwards, the sections outside the clusters are missing ca. 15 cm because of sod cutting associated with plaggen soil formation. The rate of downward movement of pollen was established, using known dates from the near surroundings.     

Thermoluminescent dating in its application to archaeology: A review

This paper sets out to describe the fundamentals of thermoluminescent (TL) dating and to explain the principles of operation of the different methods at present in use. The various complicating factors associated with TL dating are discussed, together with the measures which can be taken to recognize and as far as possible to correct them. Those materials from archaeological contexts which are suitable for dating by the TL technique are described and the criteria for the selection of suitable samples, and the methods of obtaining the desired ancilliary information relating to the environment of the site, are discussed.     

Radiocarbon dating of prehistoric hearths in alpine northern Sweden: problems and possibilities

The chronology of prehistoric Sami settlement sites has previously been established by conventional radiocarbon dating of bulk charcoal samples associated with hearths from sunken hut floors (stállo-foundations). Here we present results of a comprehensive dating exercise of stállo-foundations in the alpine area of northern Scandinavia using Accelerator Mass Spectrometry (AMS) radiocarbon dating of charcoal. Over a 3 km² study area, AMS calibrated ages of hearth charcoal from 22 stállo-foundations across 12 sites securely date these features to between cal. AD 640 and AD 1180. Only small variations in age were found between charcoal samples from different areas of a given hearth. Statistical analysis of all the charcoal AMS radiocarbon dates obtained reveals that 12 stállo-foundations across nine sites are contemporaneous and date to the Viking Period (AD 800–AD 1050). The tightly constrained AMS-based chronology of stállo-foundations contrasts with the existing chronology based on conventional radiocarbon analysis, which places these features within a significantly greater time-frame of between AD 600 and AD 1900, with most dates ranging between AD 800 and AD 1350.This discrepancy is likely to result from the necessity of collecting composite hearth charcoal particles, which may originate from different phases of occupation, in order to achieve the required final carbon content for conventional radiocarbon analysis. We argue that the new AMS-based radiocarbon chronology of stállo-foundations presented here supersedes the existing chronology based on conventional (Gas Proportional counting) radiocarbon analysis and we advocate the use of AMS radiocarbon dating in future hearth investigations.     

ONLY TIME WILL TELL: A REVIEW OF THE METHODOLOGY OF DIRECT ROCK ART DATING

Epistemology has not kept pace with the progress experienced in the direct dating of rock art. This paper reviews the experimental methods that have been developed in recent years. While many do provide important information about the possible age of rock art, it is of concern that the precipitate archaeological interpretations these data are used for are often not warranted. Some are attributable to not understanding the severe qualifications that apply to most dating results, others perhaps to over-enthusiasm on the part of some researchers. The introduction of archaeological dynamics into direct dating of rock art threatens the reliability of this young methodology. Some of the pitfalls are considered in this paper, and a general rationale for the direct dating of rock art is developed.     

Taming the control of chronology in ancient agricultural structures in the Calchaqui Valley,Argentina. Non-traditional data sets

The absolute chronology of the agricultural soil from organic matter has always been difficult to measure due to several reasons. In our work on the Prehispanic agriculture in the Calchaqui Valley – Argentina, however, an absolute chronology is necessary to distinguish the Inca prevalence of the previous agricultural structure. Instead of looking for a new dating methodology, we have used the 14C method trying to eliminate the error sources typical of soils. Thus, we have dated new types of agricultural structures, with the assumption that they would have worked as archaeological “seals”. In the present paper we show that the dating of the beginning of the use of the Prehispanic agricultural systems has been successful.     

INFRARED STIMULATED LUMINESCENCE DATING OF ARCHAEOSEDIMENTS

In this study the feasibility of infrared stimulated luminescence (IRSL) for dating loessic colluvial sediments, deposited as a result of human activity, is investigated. It is demonstrated that the ‘IRSL-clock’is reset after a few minutes of daylight exposure even under foggy weather conditions. Samples of independently known age were taken at the Neolithic Bruchsal Aue site in south-west Germany. Different laboratory procedures are tried and a method is suggested (narrow wave-length band in the blue, preheat at 220° C for 5 min) to overcome age underestimates. This laboratory technique yielded archaeologically reasonable ages for colluvial sediments and hollow fillings. The IRSL-ages demonstrate that the deposition of the colluvia is related to soil erosion triggered by human activities, such as wood clearing and agriculture. The successful dating of archaeosediments has a great potential for applications in environmental archaeology as well as in geomorphology and in particular for the reconstruction of man-landscape interactions in central Europe.     

Meta-analysis of dendrochronological dating of mass movements

Absolute dating of mass movements is crucial for disentangling possible release factors and determining the frequency of events. Here, we present an overview of a recent approach to dendrochronological dating of rockfalls, flows, landslides and avalanches. The results, based on 69 casestudies, show that methodological approaches to sampling and material processing differ considerably for different types of mass movements. Landslides are usually detected through abrupt growth changes and changes in stem eccentricity, whereas high-energy events as avalanches and flows are mostly identified by the formation of traumatic resin ducts, reaction wood, growth injuries and eccentricity changes. Cross-dating of dead wood is applicable as well. The dating of most mass movements except landslides is common, even with sub-annual resolution. In comparison to other methods of absolute dating, the main benefit of dendrochronology still lies in the high temporal resolution of the results. If living material is accessible, on-going research progress makes absolute dating of most mass-wasting events possible with sub-annual precision.     

Iron Age Diet at Sisak,Croatia: Archaeobotanical Evidence of Foxtail Millet (Setaria Italica [L.] P. Beauv.)

Recent excavations at Sisak, Croatia, unearthed an Early Iron Age pot filled with archaeobotanical remains within the floor of a structure dating to between the sixth and fourth centuries BC. Burnt in situ the archaeobotanical remains provide unique evidence for diet and agriculture in a region where archaeobotanical evidence is rare. The preliminary results from this analysis are outlined here, with a focus on the discovery of foxtail millet (Setaria italica [L.] P. Beauv.) and its contribution to the diet of the Early Iron Age population at Sisak.     

Dendrochronological dating of wooden artifacts by measuring the tree rings using magnifying glass and photography-assisted method: an example of a Dutch panel painting

Dendrochronology, an analysis of tree rings, is a commonly used method for dating wooden structures in archaeological remains and historical objects. Fascinating subjects of examination are the historical oil paintings on oak panels. Here, we applied a tree ring analysis on three boards of a Dutch painting from the Sinebrychoff Art Museum (Helsinki). Tree rings were measured using the conventional lens-assisted method, in addition to the photography-based approach, where the widths of the rings were determined from digital enlargements of the photos. These two methods produced comparable tree ring series. The lens- and photography-based records of the measured panel exhibited higher agreement with each other than the conventional, lens-based, record against the different master chronologies. Dendrochronological cross-dating against the master chronology showed that the rings of the panel represent the period ad 1413–1620. Cross-dating was attained by comparing the tree ring series of the panel painting with the previously published chronologies obtained from timber transported from the historical ports of the Eastern Baltic Sea to Western Europe. Photography appears as a promising method to be used for dendrochronological investigations of archaeological and historical objects, alongside the conventional methods. We note that the importance of using photographs of tree ring cross sections was highlighted already in the 1930s. In the digital era, the photographic approach shows obvious benefits for archival purposes and remeasuring the rings, with additional future prospects of image processing and analyses.     

14C测定判别武王克商年代范围始末

武王克商年代是我国古代编年中的一个关键点,近年来^14C测定技术有了重要发展,我国^14C测年界在此基础上探讨了^14C方法应用于商周历史纪年的希望。1996年夏商周断代工程正式立项,利用^14C测定判别武王克商年代范围的任务得以实施。1998年初两个常规^14C实验室以3‰测定精度,前后开始对陕西丰镐遗址出土样品^14C测定,并于1998年10月6－7日先后公布了^14C数据,提出武王克商代范围应判别在公元前1050－1020年间。1998年下半年AMS室开始测定。三室测定数据对比结果基本相合,利用殷墟,琉璃河等遗址出土的样品系列作^14C测定得出的结果,与上述年代范围一致。1998年11月30日公布了天计算结果,与测定结果不谋而合,经多方面反复验证,历时近二年,都无法动摇已有的判别结果,具有较高的可信度。     

Middle Anglo-Saxon Downham Road,Ely: extending the West Fen Road site

ABSTRACT

The large Middle Anglo-Saxon site at West Fen Road, Ely, represents one of the most extensively investigated English archaeological sites of the long eighth century. Recent investigations have significantly expanded its known extent, providing important insights into the origins, development and the nature of the site and modifying previous interpretations. The evidence demonstrates the existence of three separate extensive areas of ditched enclosures used primarily for stock management dating to c. 720/50–825/50, although craft activities and occupation also took place. These enclosures were connected by a network of routeways and droveways and have extensive open areas between them, linked to arable agriculture. The scale of activity and evidence for grid planning indicate that this agriculture landscape was controlled by the contemporary monastic community at Ely.     

Joined-Up Archaeology at Old Scatness,Shetland: Thin Section Analysis of the Site and Hinterland

Abstract

Excavations on the multi-period settlement at Old Scatness, Shetland have uncovered a number of Iron Age structures with compacted, floor-like layers. Thin section analysis was undertaken in order to investigate and compare the characteristics of these layers. The investigation also draws on earlier analyses of the Iron Age agricultural soil around the settlement and the midden deposits that accumulated within the settlement, to create a 'joined-up' analysis which considers the way material from the settlement was used and then recycled as fertiliser for the fields. Peat was collected from the nearby uplands and was used for fuel and possibly also for flooring. It is suggested that organic-rich floors from the structures were periodically removed and the material was spread onto the fields as fertilisers. More organic-rich material may have been used selectively for fertiliser, while the less organic peat ash was allowed to accumulate in middens. Several of the structures may have functioned as byres, which suggests a prehistoric plaggen system.     

The archaeology of radiocarbon accelerator dating

Accelerator mass spectrometry (AMS) allows radiocarbon dating to be carried out by direct counting of¹⁴C atoms, rather than the conventional counting of radioactive disintegrations. The result is that samples up to 1000 times smaller can be handled. The approach was tested in principle by 1977 and for archaeological operation by 1983. More than 2000 samples per year are now being dated worldwide. The machines can now operate to about ± 80 years or better. Dates older than 40,000 years have not yet been achieved, but the ability to use small samples has already had considerable impact on dating the period 10,000–30,000 years ago. Bone is an ideal material for the new technique, since amino acids can normally be isolated and purified from gram-size samples. Studies of the origins of domestication are aided by the dating of individual grains and seeds. Because small samples can be mobile in the soil, careful sample selection strategies and procedures are required. The full impact of the technique can be assessed only through the rapid and comprehensive publication of archaeological results.     

Recent carbon isotope research and its implications for African archaeology

A number of new developments in the carbon isotope field are reviewed, some of these having immediate and others potential application to African archaeology. Mass spectrometric analysis of¹³C/¹²C ratios in human and animal bone collagen makes it possible to reconstruct prehistoric foodwebs and to draw conclusions about dietary adaptations. Alternatively, where dietary behaviour is known, analysis of the bone of certain animal species allows for reconstruction of past environments. Ratio mass spectrometers are widely available in research institutions, and provided that the proper techniques for sample preparation are followed, this method of analysis should be of immediate use to most Africanists. It is already making an impact on African archaeology. The development of accelerator-based or high energy mass spectrometry (HEMS) radiocarbon dating provides the potential for extending the method back to 100,000 years, particularly in the case of bone samples. Practical applications, however, are still a few years off. In the immediate future HEMS dating is likely to be applied to small samples of ages less than 50,000 years. In competition with HEMS is the use of mini-counters for conventional radiocarbon dating of small samples. This procedure is available in a few laboratories with more under development. Dating of small samples has potential applications in many areas, specifically in the direct age measurement of critical specimens as opposed to the dating of associated materials.     

Thermoluminescence dates for the Middle Palaeolithic site of Chez-Pinaud Jonzac (France)

Thermoluminescence dating of heated flint artefacts from the Middle Palaeolithic sequence of Chez-Pinaud Jonzac (France) places an assemblage of Quina type Mousterian into MIS 4, while the overlying assemblage of Denticulate Mousterian which is followed by two layers with Mousterian of Acheulean Tradition are all assigned to MIS 3. TL dating is used to verify the mixed nature of deposits from which diagnostic Middle as well as Upper Palaeolithic tools were recovered. The TL ages are significantly different for samples from this layer and broadly agree with the archaeological attributions. While the study is generally limited by the low number of heated samples available, a correlation with a generalized chronostratigraphic sequence is possible by including proxy data from the faunal remains associated with the lithic assemblages in question. The Quina Mousterian in southwestern France, therefore, can be placed by chronometric dating methods in MIS 4 to MIS 3.     

Frequency of fast geomorphological processes in high-gradient streams: case study from the Moravskoslezské Beskydy Mts (Czech Republic) using dendrogeomorphic methods

High-gradient streams are localities with the most dynamic activity of geomorphological processes in medium-high mountains. This study of the frequency of floods and debris flows in a selected high-gradient stream in the Moravskoslezské Beskydy Mts was based on a dendrogeomorphic approach. It makes use of the most accurate methods applied in the dating of historic geomorphological processes. Individual events were reconstructed on the basis of the dating of various growth disturbances displayed in 99 samples taken from 56 predominantly broad-leaved trees.     

Expanding the utility of Uranium-series dating of speleothems for archaeological and palaeontological applications

Uranium-series (U-series) dating of speleothems is frequently used for palaeoclimate studies but its archaeological and palaeontological applications are limited to stratigraphically significant speleothem formations, such as flowstones, to provide maximum and minimum temporal points. This study targeted soda straw stalactites for U-series dating. In contrast to other speleothem formations, soda straw stalactites are fragile, have typically short life spans (usually only years but rarely up to a few hundred years) and are frequently incorporated into cave deposits. Results of thermal ionisation mass spectrometry (TIMS) U-series dating of soda straw stalactites from palaeontological excavations at Blanche Cave, South Australia, show that small, dense, clean straws tend to yield ages closest to the time of stratigraphic deposition. A correlation between soda straw U-series ages and radiocarbon ages of charcoal from the site is shown. Multiple soda straw age determinations for a single stratigraphic unit are required in order to verify age concordance. In conjunction with other dating methods, U-series dating of soda straw stalactites may help to significantly constrain the age of stratigraphic units and associated archaeological and palaeontological deposits in order to provide more robust chronologies. Here we advocate the collection of soda straw stalactites at future excavations of limestone cave sites.