A Palaeoenvironmental Investigation of Sediments from the Prehistoric Mine of Copa Hill,Cwmystwyth, mid-Wales

This paper investigates the use of mine sediments to reconstruct the vegetational changes and atmospheric pollution history associated with prehistoric and Mediaeval metal mining in the Ystwyth valley, Dyfed, mid-Wales. Pollen, charcoal, plant macrofossils, fossil insects and chemical analyses are presented from radiocarbon-dated sediments contained within a prehistoric mine situated on the upper slope of Copa Hill, close to the village of Cwmystwyth. The results provide additional support to the hypothesis that prehistoric mining had a negligible impact on woodland and that deforestation took place after Bronze Age mining ceased. Although high concentrations of Cu, Pb and Zn were determined from sediments of prehistoric and Roman Age, the patterns bear little resemblance to off site atmospheric pollution records and to the archaeological evidence for metal mining. Interpreting geochemical data from mine contexts is problematic as numerous factors influence the distribution and concentration of metals. However, an on-site and off-site approach to investigate human-environment interactions caused by metal mining is advocated.     

Heavy Metals in Sediments of the Upper Hawkesbury‐Nepean River

There is little published information on heavy metals in surficial sediments of the upper Hawkesbury‐Nepean River in central New South Wales, Australia. In the current investigation, the fine fraction (<62.5 µm) of 90 sediment samples taken from this section of the river was analysed by flame‐Atomic Absorption Spectroscopy for nine heavy metals (Ag, Cd, Pb, Zn, Cu Co, Fe, Ni and Mn) to determine background and enrichment. Sediment in the upper Hawkesbury‐Nepean River is not heavily polluted by heavy metals. Maximum enrichment over background for Ni and Ag, Cd, Pb, Zn, Cu and Mn is 3x, 5.7x, 6x, 6.7x, 12x and 13.6x, respectively. Mean heavy metal concentrations for this, the upper section of the river, are about half the mean values for the Hawkesbury River between Windsor and Broken Bay in the lower, estuarine section of the river. The highest Cu, Pb and Zn concentrations (214, 108 and 334 mg kg^?1, respectively) occur in surficial sediments in Peachtree Creek at Penrith and the Nepean River near Jacksons Lane, Castlereagh. These metal concentrations are possibly associated with industrial activity at Penrith. Two of the six sewage treatment plants on the upper Hawkesbury‐Nepean River are associated with high metal concentrations (Cu, Zn, Fe and Mn) in sediments, that is, the West Camden and Penrith sewage treatment plants. Other possible sources of heavy metals are coal mining and washing which occurs at several places in the upper catchment. The highest Cd, Co and Fe concentrations (1.7, 27.6 mg kg^?1 and 4.81%, respectively) were found in sediments 400 m downstream of the Nepean Dam and the highest concentrations of Ni and Mn (54 and 790 mg kg^?1, respectively) were located in sediment from the Nepean River at Moresby Hill Road Bridge, near Robertson and at the Avon Dam Road Bridge. The source of these metals is unknown.     

Historical signature of Roman mining activities in the Bidasoa estuary (Basque Country,northern Spain): an integrated micropalaeontological,geochemical and archaeological approach

This work presents an integrated micropalaeontological (foraminiferal content), geochemical (Pb, Zn, Cu, Ni, Cr, and Al, Pb isotope ratios, radiocarbon dating) and archaeological approach to the environmental impact caused by Roman mining in the Bidasoa estuary (northern Spain). Sediments collected in the ancient Roman port of Irun represent a typical infilling sequence, reflecting a progressive isolation from the estuarine environment. They exhibit elevated contents of Pb, clearly higher than those recommended nowadays for acceptable sediment quality. Isotope composition confirms exploitation of local galenas as the main source for this metal. Results from a borehole (25 m long) reveal that Pb pollution extended also to the adjacent estuarine area. The beginning of Roman mining activities is recorded by a marked increase in Pb concentrations. However, the maximum value appears later in time (after 660 cal AD). Although this enrichment could be related to the reworking upstreams of previously polluted materials, recently obtained archaeological data suggest that episodes of historically non-documented mining activities could have taken place in the surrounding area after Roman times.     

Trace Metal Distribution Within Marine and Estuarine Sediments of Western Moreton Bay,Queensland, Australia: Relation to Land Use and Setting

This broad‐scale investigation provides an overview of trace metal concentration and distribution within sediments in the subtropical setting of Moreton Bay on the eastern Australian coast. Samples of sediment in one‐metre long PVC cores were collected from the intertidal zone of the western shoreline of the Bay and within its main estuaries. The material is typically silty sand along the Bay shoreline, becoming more clayey within the estuaries. Downcore pH is typically between 7.0 and 8.0, with layers in some cores of pH 6.0 to 7.0. Locally, pH can fall below 5.0 due to pyrite oxidation or exceed 8.0 due to the presence of shell fragments. A comparison with results of similar studies in other highly populated centres in Australia shows that overall the Moreton Bay area sediments have relatively low metal content. Typically, concentrations are two to three times higher in fine‐grained, estuarine sediments than in sandy material along the Bay shoreline. Compared with Australian and New Zealand Environment and Conservation Council Guidelines for metal concentrations in sediments, the elements most commonly elevated and warranting further assessment are Ni, Hg, Pb, Zn, and occasionally Cd, As and Cr. The highest metal concentrations are found in estuaries, close to more populated or industrialised areas, notably along the Brisbane River. Overall, the distribution of metals in unconsolidated material is controlled by (a) the heavy metal affinity for Fe‐ and Mn‐rich oxidised sediments, (b) grain size, (c) background concentrations in local rocks, and (d) conditions of weathering and deposition. For example, natural elevation of Fe occurs in marine sediments adjacent to areas of Tertiary basalts and this has produced a relative increase in a number of trace metals in those sediments. Typically, trace metals correlate well with Al, and with Fe and Mn oxyhydroxides. The results of this study show that in the western Moreton Bay region, natural controls have the major influence over metal distribution; although urban and industrial inputs exist, for much of the area they are secondary. The main sources of introduced trace metals are presumed to be light industry (such as maritime and port facilities, petroleum refineries and storage, manufacturing and chemical processes), landfills, agriculture and intensive fertilising (for example, golf courses) as well as the composite effect of urban centres. Overall, higher concentrations of metals are closely related to intense development. If specific locations are targeted for focussed sampling, elevated concentrations of metals are likely to be found locally.     

Early medieval origins of iron mining and settlement in central Sweden: multiproxy analysis of sediment and peat records from the Norberg mining district

The historical Norberg mining district in central Sweden with its shallow, easily accessible iron ores figures prominently in the earliest documents from the 14th century concerning mining or metallurgy. This 1000-km² district is considered to be one of the first areas in Sweden exploited for iron ores and, in fact, Europe’s oldest known blast furnace, Lapphyttan, is located in the Norberg district about 10 km from the mines in the village of Norberg (Norbergsby). Earlier archaeological excavations suggest the furnace was in operation as early as the 11th or 12th century (870 and 930 ¹⁴C yr BP), and a number of other sites in the district have been dated to the 13th–15th centuries. Here, we have analyzed two lake sediment records (Kalven and Noren) from the village of Norberg and a peat record from Lapphyttan. The Lapphyttan peat record was radiocarbon dated, whereas the sediment from Kalven is annually laminated, which provides a fairly precise chronology. Our pollen data indicate that land use in the area began gradually as forest grazing by at least c. AD 1050, with indications of more widespread forest disturbance and cultivation from c. 1180 at Lapphyttan and 1250 at Kalven. Based on ²⁰⁶Pb/²⁰⁷Pb isotope ratios in Kalven’s varved sediment record, there is an indication of mining or metallurgy in the area c. 960, but likely not in immediate connection to our sites. Evidence of mining and metallurgy increases gradually from c. 1180 when there is a decline in ²⁰⁶Pb/²⁰⁷Pb ratios and an increase in charcoal particles at Lapphyttan, followed by increasing inputs of lithogenic elements in Noren’s sediment record indicating soil disturbance, which we attribute to the onset of mining the iron ore bodies surrounding Noren. From AD 1295 onwards evidence of mining and metallurgy are ubiquitous, and activities accelerate especially during the late 15th century; the maximum influence of Bergslagen ore lead (i.e., the minimum in ²⁰⁶Pb/²⁰⁷Pb isotope ratios) in both Kalven and Noren occurs c. 1490–1500, when also varve properties change in Kalven and in Noren sharp increases occur in the concentrations of a range of other ore-related metals (e.g., arsenic, cadmium, copper, iron, lead, mercury and zinc). From the 15th century onwards mining and metallurgy are the dominant feature of the sediment records.     

From Scale to Practice: A New Agenda for the Study of Early Metallurgy on the Eurasian Steppe

This paper evaluates conventional scholarship surrounding early metallurgy in the Eurasian steppe zone, with a particular focus on prehistoric developments in a region including northern Kazakhstan and the Southern Ural Mountains of the Russian Federation. Traditionally, the emergence of metallurgy in this region has been viewed either as peripheral to core developments in Mesopotamia, Europe and the Near East, or as part of a much larger zone of interaction and trade in metals and metal production technologies. Such views have deflected scholarship from pursuing questions concerning metallurgical production, consumption, trade and value, and their connection to local diachronic socio-economic change. This paper examines these key issues through recent research programs in the steppe region, and in so doing offers an important comparative case study for early metallurgy. It is suggested that in order to develop a better understanding of early mining, metallurgy and socio-economic change in the central steppe region, new theoretical and methodological approaches are needed that highlight the unique characteristics of early mining communities and their relationships to micro-regional resources and concomitant local, in addition to long-distance, trade dynamics. These issues are discussed in light of current field research by the authors and their Russian colleagues on the Middle Bronze Age Sintashta development (2,100–1,700 BC) in the Southern Ural Mountains.     

Ancient copper and lead pollution records from a raised bog complex in Central Wales,UK

This paper presents records of metal deposition as preserved by a peatland which has accumulated in the lowland coastal zone at Borth, near Aberystwyth, Ceredigion, mid-Wales, U.K. The research objective was to explore the origins and history of metal mining and (or) metallurgy by reconstructing a geochemical record of copper, lead and zinc pollution for the last four millennia. Two cores were extracted from Borth Bog, one from the raised ombrotrophic part of the bog and another from a minerotrophic part of Borth Bog close to the ancient copper workings at Llancynfelin. Although peat stratigraphy and nutrient status have influenced the geochemical record, the results suggest that an early phase of copper and lead pollution occurred at Llancynfelin whilst lead enrichment occurred in the peat core taken close to the centre of Borth Bog during the Bronze Age and the Roman occupation. Therefore the origins of copper and lead mining and metallurgy possibly extend back to the Bronze Age in central Wales. No record of historical pollution exists at either site. The results of this study also provide further evidence that lead and copper are immobile in ombrotrophic peat and that pollution records can be elucidated from minerotrophic peat. Zinc, however, may have suffered from post-depositional mobility.     

Pyrite–sulfosalt reactions and semimetal fractionation in the Chinkuashih,Taiwan, copper–gold deposit: a 1 Ma paleo‐fumarole

The mineralized fracture system that underlay paleo‐fumarole field at Chinkuashih, Taiwan has been exposed by copper–gold mining to depths of about 550 m below the paleo‐surface. Its mineralogy and systematic variations in metal and semimetal (Fe, Cu, As, Sb, Bi, Hg, Cd, Sn, Zn, Pb, Se, Te, Au, Ag) concentrations provide insights into the chemical responses of a magmatic‐vapor phase as it expands through fracture arrays to the surface and discharges as fumaroles associated with more extensive solfatara. At Chinkuashih, following initial sealing of the fractures by silica‐alunite alteration, brittle failure reestablished discharge from an underlying reservoir of magmatic vapor. Crystalline pyrite was deposited first in the fractures and was succeeded and replaced by ‘enargite’ (Cu₃(As,Sb)S₄) as sulfosalt encrustations (‘sublimate’) on fracture surfaces and in extensional cracks. Subsequent recrystallization resulted in complex exsolution intergrowths with antimony fractionation to the evolving crystal–vapor interface. Heavy metal fractionation between sulfosalt and vapor enriched the vapor phase in heavy metals that subsequently precipitated as complex Bi–Hg–Sn sulfosalts in discrete areas (paleo‐fumaroles) close to the paleo‐surface in a manner analogous to modern‐day fumaroles on active volcanoes such as Vulcano, Italy. As in similar paleo‐fumaroles (e.g., El Indio, Chile and Lepanto, Philippines), the most characteristic reaction sequence is the partial replacement of the early pyrite by enargite and Fe‐tennantite. It is proposed that this reaction tracks the decrease in the pressure of the underlying magmatic‐vapor reservoir because of the sustained discharge of vapor to the surface.     

Production Networks and Consumer Choice in the Earliest Metal of Western Europe

The earliest metal objects and metal production practices appeared in Western Europe during the fourth and third millennia BC. The presence of earlier dates for copper, gold, silver, and lead, as well as arsenical copper and tin-bronze alloys in Central and Eastern Europe implies that there is no evidence for the independent invention of metallurgy in Western Europe. Instead, the acquisition of metal objects as exotica by communities appears to have led eventually to the movement of people possessing metallurgical expertise. However, the metals, production techniques and object forms used in each region reflect local standards seen in other materials. This implies a process of incorporation and innovation by the communities involved rather than a straightforward or inevitable adoption. The presence of metal may have created new networks of communication and exchange but, due to its small scale, there is no evidence for any metallurgical revolution.     

An archaeological approach to regional environmental pollution in the south-western Iberian Peninsula related to Third millennium BC mining and metallurgy

The development of the first inter-settlement hierarchical framework in the South of the Iberian Peninsula in the Third millennium BC lead to a territorial division of labour, in which intensification of mining activities caused the first significant environmental impact on local and regional scales. To evaluate this impact we have selected the prime mining district in south-western Europe, the Iberian Pyrite Belt, and a method based on the correlation of pollen, charcoal and chemical analysis. The latter analyses were carried out on marine mollusc shells from spatially and chronologically contextualised archaeological records from a sequence ranging from the Sixth to the Second millennium BC.The results reveal that the copper metallurgy which developed in the south-western Iberian Peninsula in the Third millennium BC augmented deforestation, increased the rate of erosion processes and contaminated, at a regional scale, the waters of the Gulf of Cádiz – corresponding to the mouth of the Tinto and Odiel rivers – with heavy metals.     

Results of micrometallographic analysis of metalworking tools in graves of metallurgists in Moravia/Czech Republic

The number of finds relating to metalworking, without evidence of mining and processing facilities, is very limited. In Final Eneolith graves of specialized metallurgists that have occurred, they contain a metal-founding or metalsmithing toolkit, whose origins were from eastern Europe (the Maykop, Yamnaya Culture). Such metallurgical tools may have reached central Europe as part of the so-called Yamnaya Package before the onset of the Bee Beaker Culture (BBC); and unlike the Pontic region, these two types of metallurgy separated here. There are found an accumulation of metallurgists' graves in Moravia, where the complete metalworking toolkit is deposited in a predefined place in richly furnished male graves with a distinctive funerary architecture that exhibit a clear relationship to the grave goods. EDX-analysis detected a high content of metals (Cu, Ag, Au, Au–Ag alloy) on all working surfaces of stone tools, grinders, and boar tusks used for the final treatment of their metal products. This makes us believe that the used artefacts were laid as symbolical objects in the graves of these craftsmen who perfectly knew these advanced technologies. Due to their knowledge, their social significance gradually rose and finally reached the level of social elites, who were usually buried in a spectacular manner, including the quantity of grave goods (Überausstattung) and the pars pro toto deposition in one part of the finds.     

THERMI ON LESBOS: A CASE STUDY OF CHANGING TRADE PATTERNS

Summary Provenance studies on archaeological metal objects rely on their trace element abundance pattern and lead isotopic composition. A comparison of these features in artifacts from different archaeological sites often requires a comparison of results reported by different laboratories. In this case reasonable conclusions can only be expected if it is assured that the respective laboratories produce compatible results. A comparison of some twenty copper-based artifacts from Thermi I and II shows this compatibility still to be less than perfect between Oxford and Heidelberg — Mainz. We find the lead isotopic compositions reported by the two laboratories to agree within the stated uncertainties of the abundance ratios of 0.1 percent. The same is also true, to within 50 percent or better, for the contents of As, Sb, Ag, Au and possibly Ni. Serious discrepancies exist, however, for Co, Pb and Zn that we argue to be due to analytical problems at Oxford. Discriminant analysis of the data from all metal-bearing occupational levels at Thermi reveals a remarkably good correspondence between trace element signature and occupational level which suggests that at the beginning of the third millennium BC intercourse between Lesbians and Aegean metal traders was rare. Lead isotope data show that the change in metal, at least that upon the transition from Towns I + II to Towns III–IV, was indeed due to a change in source region of the metal and not one caused by a change in technology.     

HHpXRF study of recent zinc and lead pollution on lava stepping stones from Pompeii: Tourist footfall,tyre dust and leaded petrol

A helium-enabled Niton X-ray analyser (HHpXRF) study of 296 lava stepping stones from ancient Pompeii showed that their surfaces were contaminated with superficial deposits of Zn and Pb. Recent research has shown that concentrations of these elements are highest in urban areas, where they were attributed to tyre dust and leaded petrol, respectively. The distribution of these elements on the stepping stones is represented on maps of the site. Zn pollution is most abundant in areas visited by tourists and is attributed mostly to wear from their rubber-soled footwear. Pb pollution is attributed to the movement of onsite vehicles using leaded petrol.     

Technology and crisis: The great depression of the middle ages and the technology of the renaissance (fourteenth to sixteenth centuries)

An extremely violent crisis hit Western Europe towards the end of the Middle Ages: population, prices and agricultural production declined; the stretch of cultivated land shrank when, simultaneously, wars and internal troubles shook up the new states. While the technological level remained stagnant in agriculture as well as in the textile and building industries, it progressed remarkably in other sectors, particularly those of mining and metallurgy. The interpretation of these facts is a delicate matter; however, it is possible to throw light on the lack of interest for agricultural stock, on the states’ need of metal required for both money and the ongoing wars, and finally, on the investment possibilities of the holders of new technologies.     

The potential of stable Cu isotopes for the identification of Bronze Age ore mineral sources from Cyprus and Faynan: results from Uluburun and Khirbat Hamra Ifdan

Copper isotope ratios differ between hypogene sulfidic, supergene sulfidic and oxidized ore sources. Traditional lead isotope signatures of ancient metals are specific to deposits, while Cu isotope signatures are specific to the types of ore minerals used for metal production in ancient times. Two methodological case studies are presented: First, the mining district of Faynan (Jordan) was investigated. Here, mainly oxidized copper ores occur in the deposits. The production of copper from Fayan’s ore sources is confirmed by the measurement of the Cu isotope signature of ingots from the Early Bronze Age metal workshop from Khirbat Hamra Ifdan. Based on our results illustrating differences in the Cu isotope composition between the ore mineralizations from Timna (Israel) and Faynan, it is now possible to determine these prehistoric mining districts from which copper artifacts originated by combining trace elements and Pb isotopes with Cu isotopes. The second case study presents data on Late Bronze Age copper production in Cyprus. Oxhide ingots from the shipwreck of Uluburun (Turkey) were tested for their lead isotope signatures and assigned to Cypriot deposits in the recent decades. The oxhide ingots from Uluburun show a Cu isotope signature which we also found for oxidized copper ores from Cyprus, while younger oxhide ingots as well as metallurgical slag from the Cypriot settlements Kition and Enkomi show a different signature which might be due to the use of sulfidic ore sources from a greater depth of deposits. We assert that there could be a chronological shift from oxidized to sulfidic ore sources for the copper production in Cyprus, requiring different technologies. Therefore, Cu isotopes can be used as a proxy to reconstruct mining and induced smelting activities in ancient times.     

Abstracts

ABSTRACT

The celestial universe and the mode of action of YHWH are sometimes depicted by metallurgy. This figuration is generally understood as a picturesque representation devoid of theological significance, introduced only for describing the infinite powers of the god of Israel using the extreme physical conditions characterizing metallurgy. This explanation is however contested by: (i) the many allusions to metallurgy encountered in Biblical theology, (ii) the detailed mention, in the divine context, of all the stages of metal production: mining, ore roasting, smelting, metal purification and even of furnace re-melting, (iii) the representation of the firmament and the earth as two giant pieces of metal, (iv) the vision of the holy domain of YHWH as a giant celestial furnace. These features attest the existence of a substantial metallurgical component in Biblical theology. Furthermore, the strong bias towards copper metallurgy suggests that these representations were anchored in Bronze Age metallurgical traditions. It is concluded that Israelite theology encompasses an important metallurgical component inherited from the pre-Israelite cult of YHWH.     

Iron Age tin bronze metallurgy at Marlik,Northern Iran: an analytical investigation

The archaeological excavations performed in 1961 and 1962 at the necropolis of Marlik (Gilan District, northern Iran) revealed important archaeological remains dating to Iron Age I and II periods (late second/early first millennium BCE). While the metal collection from Marlik includes various gold, silver and bronze objects and is considered one of the most significant finds of metal objects from the prehistoric Iran, the technological investigations discussed in this paper provide information on tin bronze objects only from Marlik. Both the composition and the microstructure of 25 copper alloy objects have been determined in order to achieve a better understanding of the metallurgical processes used in northern Iran from the second to the first millennium BCE. Experimental analyses were carried out using inductively coupled plasma mass spectrometry (ICP-MS), scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDS) and optical microscopy. The results demonstrated that the copper-base objects were made of the binary copper–tin alloy with variable tin contents. Other elements such as As, Ni, Pb, Zn and Sb were detected in minor/trace amounts. Variable tin content may be due to the application of an uncontrolled procedure to produce bronze alloy (e.g. co-smelting or cementation). Microscopic observations and microanalyses revealed the presence of numerous copper sulphide inclusions, lead globules and intermetallic phases scattered in the bronze solid solution. The microstructures seen in the bronze objects under study were varied and included worked/annealed or dendritic grain structures.     

Reassessment and new data on the diachronic relationship of Thassos Island with its indigenous metal resources: a review

The extraction of mineral ores and its associated metal production has been a persistent element of the economy on Thassos Island since prehistoric times. As early as the Upper Palaeolithic, around 20,000 years ago, ochre had been mined and used for painting, while early silver extraction is attested during the Final Neolithic (early fourth millennium BC). Copper production and alloying becomes an important activity in the coastal settlements of the island during the third and second millennia. The inception of iron metallurgy has been seen in association with copper smelting as confirmed by analyses on slag found in Early Iron Age upland cemeteries. With the arrival of the Greek colonists around 650 BC, intensification in silver and gold extraction became paramount for further economic expansion. This deep history in the use of Thassian metals is being reviewed based on archaeological findings and archaeometallurgical research of the last three decades, while new analytical data on Early Bronze Age copper smelting at Aghios Antonios are being presented.     

A Speleothem Record of Early British and Roman Mining at Charterhouse,Mendip, England

The laser ablation ICP–MS transect of a speleothem from GB Cave, close to Charterhouse, Mendip Hills, UK, records Pb variations over the past 5 ka. The speleothem record correlates well with the known historical record of lead mining in the district, the principal features of which include: the Roman lead mining peak; the Dark Ages cessation; gradual, episodic revival up to the late 16th century peak; the 17th century collapse and subsequent recovery; and the final short‐lived burst at the end of the 19th century. This correlation supports the assumption that the pre‐Roman lead record also derives from local mining. Thus, this record is the first example of quantifying ancient human mining activity through trace element signature of a speleothem. This record also provides the first solid evidence of significant pre‐Roman mining activity in the Charterhouse region, and the first solid dating of that activity. This pre‐Roman mining can be divided into three main peaks dated to 1800–1500 bc , 1100–800 bc and 350–0 bc .